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    Method for separating single-wall carbon nanotubes and compositions thereof
    3.
    发明授权
    Method for separating single-wall carbon nanotubes and compositions thereof 失效
    分离单壁碳纳米管的方法及其组合物

    公开(公告)号：US07074310B2

    公开(公告)日：2006-07-11

    申请号：US10379273

    申请日：2003-03-04

    申请人： Richard E. Smalley ,  Robert H. Hauge ,  W. Carter Kittrell ,  Ramesh Sivarajan ,  Michael S. Strano ,  Sergei M. Bachilo ,  R. Bruce Weisman

    发明人： Richard E. Smalley ,  Robert H. Hauge ,  W. Carter Kittrell ,  Ramesh Sivarajan ,  Michael S. Strano ,  Sergei M. Bachilo ,  R. Bruce Weisman

    IPC分类号： G01N27/447 ,  B03C5/00 ,  B01D15/08

    CPC分类号： G01N21/6428 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/172 ,  C01B2202/02 ,  C01B2202/22 ,  G01N21/6489 ,  G01N21/65 ,  G01N33/574 ,  G01N33/588 ,  G01N2021/6417 ,  G01N2021/7786

    摘要： The invention relates to a process for sorting and separating a mixture of (n, m) type single-wall carbon nanotubes according to (n, m) type. A mixture of (n, m) type single-wall carbon nanotubes is suspended such that the single-wall carbon nanotubes are individually dispersed. The nanotube suspension can be done in a surfactant-water solution and the surfactant surrounding the nanotubes keeps the nanotube isolated and from aggregating with other nanotubes. The nanotube suspension is acidified to protonate a fraction of the nanotubes. An electric field is applied and the protonated nanotubes migrate in the electric fields at different rates dependent on their (n, m) type. Fractions of nanotubes are collected at different fractionation times. The process of protonation, applying an electric field, and fractionation is repeated at increasingly higher pH to separated the (n, m) nanotube mixture into individual (n, m) nanotube fractions. The separation enables new electronic devices requiring selected (n, m) nanotube types.

    摘要翻译： 本发明涉及一种根据（n，m）型分选（n，m）型单壁碳纳米管的混合物的方法。 （n，m）型单壁碳纳米管的混合物被悬浮，使得单壁碳纳米管分散分散。 纳米管悬浮液可以在表面活性剂 - 水溶液中进行，并且包围纳米管的表面活性剂保持纳米管分离并与其他纳米管聚集。 将纳米管悬浮液酸化以质子化纳米管的一部分。 施加电场，并且质子化的纳米管在电场中以取决于它们的（n，m）类型的不同速率迁移。 在不同的分馏时间收集纳米管的级分。 在越来越高的pH下重复质子化，施加电场和分级的过程，以将（n，m）纳米管混合物分离成单个（n，m）纳米管部分。 该分离使需要所选（n，m）纳米管类型的新电子器件成为可能。

    Entangled single-wall carbon nanotube solid material and methods for making same
    5.
    发明授权
    Entangled single-wall carbon nanotube solid material and methods for making same 失效
    缠结单壁碳纳米管固体材料及其制备方法

    公开(公告)号：US06899945B2

    公开(公告)日：2005-05-31

    申请号：US10391988

    申请日：2003-03-19

    申请人： Richard E. Smalley ,  Ramesh Sivarajan

    发明人： Richard E. Smalley ,  Ramesh Sivarajan

    IPC分类号： D01F9/127 ,  B32B3/20

    CPC分类号： B82Y30/00 ,  D01F9/127 ,  Y10S977/75 ,  Y10T428/249975 ,  Y10T428/249977 ,  Y10T428/24998 ,  Y10T428/24999 ,  Y10T428/249991

    摘要： Buckyrock is a three-dimensional, solid block material comprising an entangled network of single-wall carbon nanotubes (SWNT), wherein the block comprises greater than 75 wt % SWNT. SWNT buckyrock is mechanically strong, tough and impact resistant. The single-wall carbon nanotubes in buckyrock form are present in a random network of individual single-wall carbon nanotubes, SWNT “ropes” and combinations thereof. The random network of the SWNT or SWNT ropes can be held in place by non-covalent “cross-links” between the nanotubes at nanotube contact points. In one embodiment, SWNT buckyrock is made by forming a SWNT-water slurry, slowly removing water from the slurry which results in a SWNT-water paste, and allowing the paste to dry very slowly, such that the SWNT network of the SWNT-water paste is preserved during solvent evaporation. Buckyrock can be used in applications, such as ballistic protection systems, involving light-weight material with mechanical strength, toughness and impact resistance.

    摘要翻译： Buckyrock是包含单壁碳纳米管（SWNT）的缠结网络的三维固体块材料，其中该块包含大于75wt％的SWNT。 SWNT buckyrock机械坚固，坚固耐冲击。 单斜壁碳纳米管的单壁碳纳米管存在于单个单壁碳纳米管，SWNT“绳索”及其组合的随机网络中。 SWNT或SWNT绳索的随机网络可以通过在纳米管接触点处的纳米管之间的非共价“交联”保持在适当位置。 在一个实施方案中，通过形成SWNT-水浆料，缓慢地从浆料中除去水，从而产生SWNT-水糊剂，并使糊料非常缓慢地干燥，从而使SWNT-水的SWNT网络 溶剂蒸发时保留糊状物。 Buckyrock可用于应用，如防弹系统，涉及具有机械强度，韧性和抗冲击性的轻质材料。

    Solvent-based and water-based carbon nanotube inks with removable additives
    6.
    发明授权
    Solvent-based and water-based carbon nanotube inks with removable additives 有权
    具有可除去添加剂的溶剂型和水性碳纳米管油墨

    公开(公告)号：US09296912B2

    公开(公告)日：2016-03-29

    申请号：US12855640

    申请日：2010-08-12

    申请人： Ramesh Sivarajan ,  Henning Richter ,  Viktor Vejins

    发明人： Ramesh Sivarajan ,  Henning Richter ,  Viktor Vejins

    IPC分类号： H01B1/04 ,  C01B31/02 ,  C09D11/52 ,  C09D11/03

    CPC分类号： C09D11/52 ,  C09D11/03

    摘要： In accordance with some embodiments, compositions and methods for forming solvent-based and water-based carbon nanotubes inks with removable additives are provided. In some embodiments, the ink composition comprises one or more carbon nanotubes, a solvent, and a removable additive, which may function as a stabilizing agent, a viscosity adjustment agent, or any suitable combination thereof. The removable additive may be removed from articles derived from the ink composition by means of thermal annealing.

    摘要翻译： 根据一些实施方案，提供了用于形成具有可除去添加剂的溶剂基和水基碳纳米管油墨的组合物和方法。 在一些实施方案中，油墨组合物包含一种或多种碳纳米管，溶剂和可除去的添加剂，其可用作稳定剂，粘度调节剂或其任何合适的组合。 可以通过热退火将可除去的添加剂从衍生自油墨组合物的制品中除去。

    SOLVENT-BASED AND WATER-BASED CARBON NANOTUBE INKS WITH REMOVABLE ADDITIVES
    7.
    发明申请
    SOLVENT-BASED AND WATER-BASED CARBON NANOTUBE INKS WITH REMOVABLE ADDITIVES 有权
    基于溶剂和水的碳纳米管与可除去的添加剂

    公开(公告)号：US20110048277A1

    公开(公告)日：2011-03-03

    申请号：US12855640

    申请日：2010-08-12

    申请人： Ramesh Sivarajan ,  Henning Richter ,  Viktor Vejins

    发明人： Ramesh Sivarajan ,  Henning Richter ,  Viktor Vejins

    IPC分类号： C09D11/00 ,  B82Y99/00

    CPC分类号： C09D11/52 ,  C09D11/03

    摘要： In accordance with some embodiments, compositions and methods for forming solvent-based and water-based carbon nanotubes inks with removable additives are provided. In some embodiments, the ink composition comprises one or more carbon nanotubes, a solvent, and a removable additive, which may function as a stabilizing agent, a viscosity adjustment agent, or any suitable combination thereof. The removable additive may be removed from articles derived from the ink composition by means of thermal annealing.

    摘要翻译： 根据一些实施方案，提供了用于形成具有可除去添加剂的溶剂基和水基碳纳米管油墨的组合物和方法。 在一些实施方案中，油墨组合物包含一种或多种碳纳米管，溶剂和可除去的添加剂，其可用作稳定剂，粘度调节剂或其任何合适的组合。 可以通过热退火将可除去的添加剂从衍生自油墨组合物的制品中除去。

    Memory elements and cross point switches and arrays of same using nonvolatile nanotube blocks
    8.
    发明授权
    Memory elements and cross point switches and arrays of same using nonvolatile nanotube blocks 有权
    存储元件和交叉点开关以及使用非易失性纳米管块的阵列

    公开(公告)号：US07835170B2

    公开(公告)日：2010-11-16

    申请号：US11835613

    申请日：2007-08-08

    申请人： Claude L. Bertin ,  X. M. Henry Huang ,  Thomas Rueckes ,  Ramesh Sivarajan

    发明人： Claude L. Bertin ,  X. M. Henry Huang ,  Thomas Rueckes ,  Ramesh Sivarajan

    IPC分类号： G11C11/00

    CPC分类号： G11C5/063 ,  B82Y10/00 ,  G11C13/0002 ,  G11C13/0021 ,  G11C13/025 ,  G11C17/16 ,  G11C17/165 ,  G11C2213/19 ,  G11C2213/77 ,  G11C2213/79 ,  H01L27/10 ,  H01L27/105 ,  H01L27/1052 ,  H01L27/112 ,  H01L29/0665 ,  H01L29/0669 ,  H01L29/0673 ,  H01L51/0048 ,  H01L51/0591 ,  Y10S977/943

    摘要： Under one aspect, a covered nanotube switch includes: (a) a nanotube element including an unaligned plurality of nanotubes, the nanotube element having a top surface, a bottom surface, and side surfaces; (b) first and second terminals in contact with the nanotube element, wherein the first terminal is disposed on and substantially covers the entire top surface of the nanotube element, and wherein the second terminal contacts at least a portion of the bottom surface of the nanotube element; and (c) control circuitry capable of applying electrical stimulus to the first and second terminals. The nanotube element can switch between a plurality of electronic states in response to a corresponding plurality of electrical stimuli applied by the control circuitry to the first and second terminals. For each different electronic state, the nanotube element provides an electrical pathway of different resistance between the first and second terminals.

    摘要翻译： 在一个方面，覆盖的纳米管开关包括：（a）包括不对齐的多个纳米管的纳米管元件，所述纳米管元件具有顶表面，底表面和侧表面; （b）与纳米管元件接触的第一和第二端子，其中第一端子设置在并基本上覆盖纳米管元件的整个顶表面，并且其中第二端子接触纳米管的底表面的至少一部分 元件; 和（c）能够向第一和第二端子施加电刺激的控制电路。 纳米管元件可以响应于由控制电路施加到第一和第二端子的对应的多个电刺激而在多个电子状态之间切换。 对于每个不同的电子状态，纳米管元件提供在第一和第二端子之间具有不同电阻的电路径。

    Applicator liquid for use in electronic manufacturing processes
    9.
    发明授权
    Applicator liquid for use in electronic manufacturing processes 有权
    用于电子制造工艺的涂布器液体

    公开(公告)号：US07504051B2

    公开(公告)日：2009-03-17

    申请号：US10860432

    申请日：2004-06-03

    申请人： Rahul Sen ,  Ramesh Sivarajan ,  Thomas Rueckes ,  Brent M. Segal

    发明人： Rahul Sen ,  Ramesh Sivarajan ,  Thomas Rueckes ,  Brent M. Segal

    IPC分类号： C01B31/02 ,  D01F9/12 ,  H01L29/08

    CPC分类号： B82Y10/00 ,  H01C17/0652 ,  H01L51/0003 ,  H01L51/0025 ,  H01L51/0048 ,  Y10S977/742 ,  Y10S977/743 ,  Y10S977/753 ,  Y10T428/29 ,  Y10T428/2982 ,  Y10T428/30

    摘要： Certain spin-coatable liquids and application techniques are described, which can be used to form nanotube films or fabrics of controlled properties. A spin-coatable liquid containing nanotubes for use in an electronics fabrication process includes a solvent containing a plurality of nanotubes. The nanotubes are at a concentration of greater than 1 mg/L. The nanotubes are pretreated to reduce the level of metallic and particulate impurities to a preselected level, and the preselected metal and particulate impurities levels are selected to be compatible with an electronics manufacturing process. The solvent also is selected for compatibility with an electronics manufacturing process.

    摘要翻译： 描述了一些可旋涂的液体和应用技术，其可以用于形成纳米管膜或受控特性的织物。 包含用于电子制造工艺的纳米管的可旋涂的液体包括含有多个纳米管的溶剂。 纳米管的浓度大于1mg / L。 预处理纳米管以将金属和颗粒杂质的水平降低到预选的水平，并且预选的金属和微粒杂质水平被选择为与电子制造工艺兼容。 溶剂也被选择用于与电子制造工艺的兼容性。