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1.发明授权Self-assembling antireflective coating comprising surface modified high refractive index nanoparticles 有权包含表面改性的高折射率纳米颗粒的自组装抗反射涂层公开(公告)号：US08202573B2
公开(公告)日：2012-06-19
申请号：US12670124
申请日：2008-09-02
申请人： Richard J. Pokorny , Thomas P. Klun , Marc D. Radcliffe , Robert F. Kamrath , Christopher B. Walker, Jr.
发明人： Richard J. Pokorny , Thomas P. Klun , Marc D. Radcliffe , Robert F. Kamrath , Christopher B. Walker, Jr.
IPC分类号： C09D163/00 , C09D171/00 , C09D201/00 , B05D7/00 , B05D5/06
CPC分类号： G02B1/11 , B82Y20/00 , C08K3/22 , C08K9/06 , C09D5/006 , C09D7/62 , G02B2207/101 , Y10T428/24942
摘要： Presently described are self-assembling antireflective (“AR”) coating compositions comprising high refractive index surface modified nanoparticles. Also described are various articles such as protective films, optical displays, and windows, comprising such (e.g. dried and cured) AR coating.
摘要翻译： 目前描述的是包含高折射率表面改性纳米颗粒的自组装抗反射（“AR”）涂层组合物。 还描述了包括这种（例如干燥和固化的）AR涂层的各种制品，例如保护膜，光学显示器和窗户。
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公开(公告)号：US08343622B2
公开(公告)日：2013-01-01
申请号：US12165765
申请日：2008-07-01
申请人： Lan H. Liu , Robert F. Kamrath , Encai Hao , Taun L. McKenzie , Marc D. Radcliffe , Richard J. Pokorny , Christopher B. Walker, Jr. , Anthony M. Renstrom
发明人： Lan H. Liu , Robert F. Kamrath , Encai Hao , Taun L. McKenzie , Marc D. Radcliffe , Richard J. Pokorny , Christopher B. Walker, Jr. , Anthony M. Renstrom
CPC分类号： G02B1/111 , B82Y20/00 , B82Y30/00 , G02F1/133502 , Y10T428/25 , Y10T428/254 , Y10T428/26 , Y10T428/265 , Y10T428/2995 , Y10T428/31855
摘要： Antireflective films comprising a flexible high refractive index layer that comprises at least 60 wt-% of inorganic nanoparticles, the nanoparticles having a refractive index of at least 1.60, dispersed in a crosslinked organic material. Also described are surface treated nanoparticles.
摘要翻译： 包含柔性高折射率层的抗反射膜，其包含分散在交联的有机材料中的至少60重量％的无机纳米颗粒，纳米颗粒具有至少1.60的折射率。 还描述了表面处理的纳米颗粒。
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公开(公告)号：US08137801B2
公开(公告)日：2012-03-20
申请号：US12304505
申请日：2007-06-06
申请人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/265 , Y10T428/269 , Y10T428/3154 , Y10T428/31935
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有表面层的抗反射膜，该表面层包含包含至少一种氟化可自由基聚合材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US08343624B2
公开(公告)日：2013-01-01
申请号：US13365313
申请日：2012-02-03
申请人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one free-radically polymerizable fluoropolymer and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有包含包含至少一种可自由基聚合的含氟聚合物和表面改性的无机纳米颗粒的可聚合低折射率组合物的反应产物的表面层的抗反射膜。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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5.发明授权Perfluoropolyether urethane additives having (meth)acryl groups and hard coats 有权具有（甲基）丙烯酸基团和硬涂层的全氟聚醚氨基甲酸酯添加剂公开(公告)号：US08147966B2
公开(公告)日：2012-04-03
申请号：US12718481
申请日：2010-03-05
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
IPC分类号： B32B27/40
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
摘要翻译： 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。
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6.发明授权Perfluoropolyether urethane additives having (meth)acryl groups and hard coats 有权具有（甲基）丙烯酸基团和硬涂层的全氟聚醚氨基甲酸酯添加剂公开(公告)号：US07718264B2
公开(公告)日：2010-05-18
申请号：US11277162
申请日：2006-03-22
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
IPC分类号： B32B17/40
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
摘要翻译： 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。
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7.发明授权Coating compositions comprising non-ionic surfactant exhibiting reduced fingerprint visibility 有权包含非离子表面活性剂的涂料组合物表现出降低的指纹可视性公开(公告)号：US09296904B2
公开(公告)日：2016-03-29
申请号：US13526800
申请日：2012-06-19
申请人： Richard J. Pokorny , Thomas P. Klun , Christopher B. Walker, Jr. , David B. Olson , Joan M. Noyola , Michelle L. Toy , Evan L. Schwartz
发明人： Richard J. Pokorny , Thomas P. Klun , Christopher B. Walker, Jr. , David B. Olson , Joan M. Noyola , Michelle L. Toy , Evan L. Schwartz
IPC分类号： C08F220/24 , C09D5/16 , C09D7/12 , C08F220/34 , C09D4/06 , C08G18/50 , C08G18/81 , C08G18/28 , C08F222/10
CPC分类号： C09D5/1618 , C08F220/34 , C08F2222/1026 , C08G18/283 , C08G18/5015 , C08G18/8116 , C09D4/06 , C09D7/63 , C08F2220/346 , C08F220/24 , C08F220/40 , C08F220/20
摘要： Presently described are coating compositions comprising a polymerizable resin composition and a non-ionic unpolymerizable surfactant. In some embodiments, the coating comprises greater than 10 wt-% of non-ionic unpolymerizable surfactant. In other embodiments, the coating composition comprises an an additive comprising a silicone group or a fluorinated group and a hydrophobic group. Also described are articles comprising the cured coating compositions. In one embodiment, an article is described comprising a cured coating wherein the cured coating exhibits a property of an initially visible simulated fingerprint reducing in visibility in 1-20 minutes. Also described is a method of determining the fingerprint visibility of a coating composition and a polyacylate composition useful as an additive. In another embodiment a coated surface is described comprising a polymeric organic material comprising a plurality of pores wherein a portion of the pores are interconnected and comprise a lipophilic liquid.
摘要翻译： 目前描述的是包含可聚合树脂组合物和非离子不可聚合表面活性剂的涂料组合物。 在一些实施方案中，涂层包含大于10重量％的非离子不可聚合表面活性剂。 在其它实施方案中，涂料组合物包含包含硅氧烷基团或氟化基团和疏水基团的添加剂。 还描述了包含固化的涂料组合物的制品。 在一个实施方案中，描述了包含固化涂层的制品，其中固化的涂层表现出在1-20分钟内可见度的最初可见的模拟指纹的性质降低。 还描述了确定涂料组合物和可用作添加剂的聚丙烯酸酯组合物的指纹可见性的方法。 在另一个实施方案中，描述了涂覆的表面，其包括包含多个孔的聚合有机材料，其中一部分孔相互连接并且包含亲油性液体。
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8.发明授权Coating compositions comprising non-ionic surfactant exhibiting reduced fingerprint visibility 有权包含非离子表面活性剂的涂料组合物表现出降低的指纹可视性公开(公告)号：US08742022B2
公开(公告)日：2014-06-03
申请号：US13307137
申请日：2011-11-30
申请人： Richard J. Pokorny , Thomas P. Klun , Christopher B. Walker, Jr. , David B. Olson , Joan M. Noyola , Michelle L. Toy , Evan L. Schwartz
发明人： Richard J. Pokorny , Thomas P. Klun , Christopher B. Walker, Jr. , David B. Olson , Joan M. Noyola , Michelle L. Toy , Evan L. Schwartz
IPC分类号： C08F220/24 , C08F18/20 , C08K5/5419 , C09D5/16 , C08F220/28 , C08J7/04 , C09D7/12
CPC分类号： C09D7/125 , C08F220/24 , C08F2220/285 , C08J7/047 , C09D5/1618 , C09D7/1233 , C09D7/63 , C09D7/65 , Y10S525/92 , Y10T428/249953 , Y10T428/31544 , Y10T428/31663
摘要： Presently described are coating compositions comprising a polymerizable resin composition and a non-ionic unpolymerizable surfactant. In some embodiments, the coating comprises greater than 10 wt-% of non-ionic unpolymerizable surfactant. In other embodiments, the coating composition comprises an an additive comprising a silicone group or a fluorinated group and a hydrophobic group. Also described are articles comprising the cured coating compositions. In one embodiment, an article is described comprising a cured coating wherein the cured coating exhibits a property of an initially visible simulated fingerprint reducing in visibility in 1-20 minutes. Also described is a method of determining the fingerprint visibility of a coating composition and a polyacylate composition useful as an additive. In another embodiment a coated surface is described comprising a polymeric organic material comprising a plurality of pores wherein a portion of the pores are interconnected and comprise a lipophilic liquid.
摘要翻译： 目前描述的是包含可聚合树脂组合物和非离子不可聚合表面活性剂的涂料组合物。 在一些实施方案中，涂层包含大于10重量％的非离子不可聚合表面活性剂。 在其它实施方案中，涂料组合物包含包含硅氧烷基团或氟化基团和疏水基团的添加剂。 还描述了包含固化的涂料组合物的制品。 在一个实施方案中，描述了包含固化涂层的制品，其中固化的涂层表现出在1-20分钟内可见度的最初可见的模拟指纹的性质降低。 还描述了确定涂料组合物和可用作添加剂的聚丙烯酸酯组合物的指纹可见性的方法。 在另一个实施方案中，描述了涂覆的表面，其包括包含多个孔的聚合有机材料，其中一部分孔相互连接并且包含亲油性液体。
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公开(公告)号：US08476398B2
公开(公告)日：2013-07-02
申请号：US13396669
申请日：2012-02-15
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
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10.发明授权Substrate comprising unmatched refractive index primer at optically significant thickness 有权基材包含光学显着厚度的无与伦比的折射率底漆公开(公告)号：US08611010B2
公开(公告)日：2013-12-17
申请号：US12241310
申请日：2008-09-30
IPC分类号： G02B1/10
CPC分类号： G02B1/111
摘要： A method of reducing optical fringing of a coated substrate is described. The method comprises providing a (e.g. light transmissive) substrate; providing a primer having an unmatched refractive index, and applying the primer to the substrate forming a primer layer having an optically significant thickness. The primer layer in combination with the substrate has a percent reflectance at a maximum at a wavelength of interest. Also described are articles comprising a substrate, a primer having an unmatched refractive index, a high refractive index layer, and optional low refractive index layer such as an antireflective film article.
摘要翻译： 描述了减少涂覆的基底的光学边缘的方法。 该方法包括提供（例如透光）基板; 提供具有无与伦比的折射率的底漆，并将底漆施加到形成具有光学显着厚度的底漆层的基材上。 与基底组合的底漆层在感兴趣的波长处具有最大值的百分比反射率。 还描述了包括基材，具有无与伦比的折射率的底漆，高折射率层和任选的低折射率层如抗反射膜制品的制品。
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