摘要:
A method of improving the adhesion of primers and adhesives to the surface of a polymeric material is provided. In this method, the adhesion is improved by modifying the polymeric material with a filler. Preferably, the filler comprises hollow microspheres or nanoparticles. Silica is a preferred filler.
摘要:
Polymer compositions having thermoplastic and elastomeric features are provided. These polymer compositions, which are also characterized by superior compatibility with water-based and solvent-based adhesives, comprise at least one thermoplastic elastomer and at least one maleated ethylene copolymer. The compositions of the invention are useful in articles of manufacture that require flexibility and are fabricated with adhesives, including sporting goods, and particularly athletic shoes.
摘要:
Disclosed laminates particularly useful as safety glazings comprising a polymeric interlayer sheet, wherein the polymeric interlayer sheet comprises a blend composition of an ethylene copolymer A and an ethylene copolymer B, which has a melt flow rate of less than 100g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg, and wherein the ethylene copolymer A comprises copolymerized units of ethylene and about 3 to about 20 wt % of an ester or anhydride of a C4-C8 unsaturated acid having two carboxylic acid groups and the ethylene copolymer B comprises copolymerized units of ethylene and about 6 to about 40 wt % of a polar monomer selected from the group consisting of vinyl acetate, alkyl(meth)acrylates, and mixtures thereof.
摘要:
A hot melt adhesive composition comprising: (a) a functional copolymer obtained from copolymerization of ethylene and a comonomer selected from maleic anhydride, citraconic anhydride, itaconic anhydride, tetrahydrophthalic anhydride, maleic acid, citraconic acid, itaconic acid, fumaric acid, tetrahydrophthalic acid, the corresponding salts, monoesters and diesters of these acids, and mixtures of any of these, wherein the functional copolymer is present in an amount from about 5 to about 95 weight % of the combined total amount of (a) and (b); and (b) at least one ethylene copolymer obtained from copolymerization of ethylene with a polar monomer wherein said polar comonomer is present in the copolymer in an amount of from 8 to 40 weight %, wherein said ethylene copolymer is selected from the group consisting of ethylene/vinyl acetate copolymers, ethylene/alkyl (meth)acrylate copolymers and ethylene/alkyl (meth)acrylate/carbon monoxide terpolymers, in an amount from about 5 to about 95 weight % of the combined total amount of (a) and (b); wherein the composition has a melt index of 100 grams/10 minutes or higher. Articles comprising and process using the hot melt adhesive are also disclosed.
摘要:
This invention relates to crosslinked polymer foam compositions of an ethylene vinyl acetate copolymer, an ethylene/acrylic acid copolymer or ionomer, and a crosslinking agent. Such compositions exhibit enhanced melt strength, as well as lower density and compression set. They are especially useful as midsoles or insoles for footwear.
摘要:
A blend of 5 to 95 percent of an ethylene vinyl alcohol copolymer and 95 to 5 percent of an amorphous polyamide having fewer than about 0.100 equivalents of carboxyl end groups per kilogram of polyamide exhibits improved oxidative and thermal stability. The blend is useful for preparing films and multiple layered structures including thermoformed structures and oriented shrink films.
摘要:
Blends of a major portion of ethylene vinyl alcohol copolymer (EVOH) and a minor portion of an amorphous polyamide and preferably also a semicrystalline nylon are disclosed. These blends may be formed into films or multilayer structures, which can be thermoformed into containers or other articles. The presence of the minor portion of amorphous polyamide permits thermoforming of the EVOH at lower temperatures without the formation of defects.
摘要:
A composition that can be used as foam composition is disclosed, which comprises or is produced from an ethylene acrylate dipolymer, an acid copolymer, and optionally a soft ethylene polymer. The ethylene acrylate dipolymer comprises repeat units derived from ethylene and at least one alkylacrylate. The acid copolymer comprises repeat units derived from ethylene and acrylic acid, methacrylic acid, or combinations thereof. The soft ethylene polymer comprises ethylene and an α-olefin, vinyl acetate, or combinations thereof.
摘要:
Disclosed in a composition comprising at least one ionomer (A) and at least one blend comprising at least one polyamide and at least one ionomer (B) wherein the polyamide is an aliphatic polyamide and the ionomer (B) is a copolymer of ethylene, an α, β-unsaturated C3-C8 carboxylic acid, at least one ethylenically unsaturated dicarboxylic acid or derivative thereof, and optionally an alkyl (meth)acrylate.
摘要:
Disclosed is a composition comprising polyamide comprising nylon-6 and optionally nylon-6,66, nylon-66, nylon-610, nylon-612, nylon-11, nylon-12 and an ionomer comprising an ethylene carboxylic acid copolymer, wherein 30 to 90% of the total carboxylic acid functionalities are neutralized to salts with a mixture of zinc cations and cations of a second metal selected from Group 1 of the Periodic Table of the Elements wherein the salts comprise from 20 to 90% equivalents of zinc. Articles prepared from the composition have improved salt stress crack resistance when exposed to zinc chloride solutions.