摘要:
To mitigate bubble blockage in water passageways (78, 85), in or near reactant gas flow field plates (74, 81) of fuel cells (38), passageways are configured with (a) intersecting polygons, obtuse angles including triangles, trapezoids, or (b) hydrophobic surfaces (111), or (c) differing adjacent channels (127, 128), or (d) water permeable layers (93, 115, 116, 119) adjacent to water channels or hydrophobic/hydrophilic layers (114, 120).
摘要:
To mitigate bubble blockage in water passageways (78, 85), in or near reactant gas flow field plates (74, 81) of fuel cells (38), passageways are configured with (a) cross sections having intersecting polygons or other shapes, obtuse angles including triangles and trapezoids, or (b) hydrophobic surfaces (111), or (c) differing adjacent channels (127, 128), or (d) water permeable layers (93, 115, 116, 119) adjacent to water channels or hydrophobic/hydrophilic layers (114, 120), or (e) diverging channels (152).
摘要:
To mitigate bubble blockage in water passageways (78, 85), in or near reactant gas flow field plates (74, 81) of fuel cells (38), passageways are configured with (a) intersecting polygons, obtuse angles including triangles, trapezoids, or (b) hydrophobic surfaces (111), or (c) differing adjacent channels (127, 128), or (d) water permeable layers (93, 115, 116, 119) adjacent to water channels or hydrophobic/hydrophilic layers (114, 120).
摘要:
Fuel cells (38) have water passageways (67; 78, 85; 78a, 85a) that provide water through reactant gas flow field plates (74, 81) to cool the fuel cell. The water passageways may be vented to atmosphere (99), by a porous plug (69), or pumped (89, 146) with or without removing any water from the passageways. A condenser (59, 124) receives reactant air exhaust, may have a contiguous reservoir (64, 128), may be vertical, (a vehicle radiator, FIG. 2), may be horizontal, contiguous with the top of the fuel cell stack (37, FIG. 5), or below (124) the fuel cell stack (120). The passageways may be grooves (76, 77; 83, 84) or may comprise a plane of porous hydrophilic material (78a, 85a) contiguous with substantially the entire surface of one or both of the reactant gas flow field plates. Air flow in the condenser may be controlled by shutters (155). The condenser may be a heat exchanger (59a) having freeze-proof liquid flowing through a coil (161) thereof, the amount being controlled by a valve (166). A deionizer (175) may be used.
摘要:
A fuel cell stack (31) includes a plurality of fuel cells (9) each having an electrolyte such as a PEM (10), anode and cathode catalyst layers (13, 14), anode and cathode gas diffusion layers (16, 17), and water transport plates (21, 28) adjacent the gas diffusion layers. The cathode diffusion layer of cells near the cathode end (36) of the stack have a high water permeability, such as greater than 3×10−4 g/(Pa s m) at about 80° C. and about 1 atmosphere, whereas the cathode gas diffusion layer in cells near the anode end (35) have water vapor permeance greater than 3×10−4 g/(Pa s m) at about 80° C. and about 1 atmosphere. In one embodiment, the anode gas diffusion layer of cells near the anode end (35) of the stack have a higher liquid water permeability than the anode gas diffusion layer in cells near the cathode end; a second embodiment reverses that relationship.
摘要:
Fuel cells (38) have minute water passageways (67) that provide water through one or both reactant gas flow field plates (74, 82) of each fuel cell, whereby the fuel cell is cooled evaporatively. The water passageways (67; 78, 85; 78a, 85a) may be vented by a porous plug (69), or by a microvacuum pump (89) that does not pump any water from the passageways, or simply vented (99) to atmosphere. A condenser (59) may have a contiguous reservoir (64); the condenser (59) may be vertical, such as a vehicle radiator (FIG. 1), or may be horizontal, contiguous with the top of the fuel cell stack (37, FIG. 5). The passageways may be grooves (76, 77; 83, 84) in the reactant gas flow plates (75, 81) or the passageways may comprise a plane of porous hydrophilic material (78a, 85a) contiguous with substantially the entire surface of one or both of the reactant gas flow field plates.
摘要:
A fuel cell power plant (19) has a stack of fuel cells (20) cooled by a mixture of water with a non-volatile, miscible fluid that sufficiently depresses the freezing point, such as polyethylene glycol (PEG). The water and fluid are mixed in a reservoir (21), a small pump (22, 60) flows the mixture through coolant channels (28) in or adjacent water transport plates (29); heat of the catalytic reaction warms the water transport plates causing water to evaporate therefrom thereby cooling the stack. The PEG is non-volatile at stack operating temperature and does not evaporate; concentrated PEG is returned (33) to the reservoir (21). Water in the process air flow channels (41), including evaporated process water, is recovered in a condensation-rate-controlled (53, 54)) condenser (46) in communication (48) with the reservoir (21) for remixture with the concentrated PEG solution. Hydrophobic gas diffusion layers (72) shield the proton exchange membrane (70) from the PEG.
摘要:
A PEM fuel cell power plant includes fuel cells, each of which has a cathode reactant flow field plate which is substantially impermeable to fluids, a water coolant source, and a fluid permeable anode reactant flow field plate adjacent to said water coolant source. The anode reactant flow field plates pass water from the coolant sources into the cells where the water is evaporated to cool the cells. The cathode flow field plates prevent reactant crossover between adjacent cells. By providing a single water permeable plate for each cell in the power plant the amount of water present in the power plant at shut down is limited to a degree which does not require adjunct water purging components to remove water from the plates when the power plant is shut down during freezing ambient conditions. Thus the amount of residual ice in the power plant that forms in the plates during shut down in such freezing conditions will be limited. The power plant can thus be restarted and brought up to full operating power levels quickly due to the reduced amount of ice that must be melted during startup. The power plant is thus well suited for use in powering vehicles.
摘要:
A fuel cell includes an electrode assembly having an electrolyte between a cathode catalyst and an anode catalyst, and a flow field plate having a channel for delivering a reactant gas to the electrode assembly. The flow field plate includes a channel having a channel inlet. A porous diffusion layer is located between the electrode assembly and the flow field plate. The porous diffusion layer includes a first region near the channel inlet and a second region downstream from the first region relative to the channel inlet. The first region includes a filler material that partially blocks pores of the first region such that the first region has a first porosity and the second region has a second porosity that is greater than the first porosity.
摘要:
A fuel cell is provided that includes a water transport plate separating an air flow field and a water flow field. The driving force for moving water across the water transport plate into the water flow field is produced by a differential pressure across a restriction. The restriction is arranged between an air outlet of the cathode water transport plate and a head of a reservoir that is in fluid communication with the water flow field.