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公开(公告)号：US4839027A
公开(公告)日：1989-06-13
申请号：US273708
申请日：1988-11-16
IPC分类号： B01J29/14 , B01J29/44 , B01J29/74 , C10G35/085 , C10G35/095
CPC分类号： C10G35/095 , B01J29/068 , B01J29/146 , B01J29/44 , B01J2229/26 , B01J2229/42 , B01J29/67 , B01J29/7415 , B01J29/7423 , B01J29/7484
摘要： Catalytic reformng of a naphtha feed to provide high octane aromatic components employs a low acidity refractory oxide-bound intermediate and/or large pore zeolite prepared with at least an extrusion-facilitating amount of low acidity refractory oxide in colloidal form and containing at least one metal species selected from the platinum group metals.
摘要翻译： 用于提供高辛烷值芳族组分的石脑油进料的催化改造采用低酸度难熔氧化物结合的中间体和/或大孔沸石，其至少具有促进胶体形式的低酸耐火氧化物的挤出促进量，并含有至少一种金属 物种选自铂族金属。
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2.发明授权
公开(公告)号：US4888105A
公开(公告)日：1989-12-19
申请号：US156067
申请日：1988-02-16
IPC分类号： B01J29/64 , C07C5/41 , C10G35/095
CPC分类号： C10G35/095 , B01J29/64 , C07C5/417 , B01J2229/26 , B01J2229/42
摘要： The dehydrocyclization of a feed containing one or more acyclic hydrocarbons capable of undergoing ring closure to provide aromatic hydrocarbons is accomplished by contacting the feed under dehydrocyclization conditions with a zeolite L dehydrocyclization catalyst which is substantially free of zeolite T and which contains at least one Group VIII metal component, thereby converting at least a portion of the acyclic hydrocarbon content of the feed to aromatic compound(s). Use of the foregoing zeolite L dehydrocyclization catalyst has been found to result in less non-selective hydrocracking of naphtha range materials to gaseous hydrocarbons and greater conversion of low octane paraffins to high octane aromatics than that achieved with a zeolite L synthesized by a prior procedure which results in the co-production of zeolite T contaminant.
摘要翻译： 含有一个或多个能够进行闭环以提供芳族烃的无环烃的进料的脱氢环化通过使脱氢环化条件下的进料与基本上不含沸石T的沸石L脱氢环化催化剂接触并且其含有至少一个第VIII族 金属组分，从而将进料的至少一部分无环烃含量转化为芳族化合物。 已经发现使用上述沸石L脱氢环化催化剂导致石脑油范围材料对气态烃的非选择性加氢裂化较少，并且与通过先前方法合成的沸石L所达到的相比，低辛烷值链烷烃的转化率高于高辛烷值。 导致沸石T污染物的共同生产。
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3.发明授权Process for dispersing or redispersing a Group VIII noble metal species on a porous inorganic support 失效将VIII族贵金属物质分散或再分散在多孔无机载体上的方法
公开(公告)号：US4952543A
公开(公告)日：1990-08-28
申请号：US282363
申请日：1988-12-09
摘要： A process for dispersing or dispersing relatively large crystallites of an agglomerated Group VIII noble metal species present on a porous inorganic support is disclosed. The process includes contacting the agglomerated noble metal species, e.g., palladium or platinum, present on the support, e.g., alumina, silica or a zeolite such as ZSM-5 from which at least a major portion of any extraneous matter such as coke or other residue has previously been removed, with nitric oxide (NO) alone or in admixture with a source of halogen such as Cl.sub.2 and thereafter removing sorbed nitrogen oxide(s) and halogen, if present. The thus treated metal-loaded catalyst demonstrates substantially increased benzene hydrogenation activity (BHA) compared to the same catalyst prior to treatment indicating significant dispersion/redispersion of the metal crystallites as smaller crystallites.
摘要翻译： 公开了一种用于分散或分散存在于多孔无机载体上的聚集的第VIII族贵金属物质的较大微晶的方法。 该方法包括使存在于载体上的附聚的贵金属物质例如钯或铂接触，例如氧化铝，二氧化硅或诸如ZSM-5的沸石，其中至少大部分任何外来物质如焦炭或其它物质 先前已经除去了一氧化氮（NO）或与卤素源如Cl 2混合，然后除去吸附的氮氧化物和卤素（如果存在）。 如此处理的金属负载的催化剂在处理之前与相同的催化剂相比显示出显着增加的苯加氢活性（BHA），表明作为较小晶粒的金属微晶的显着分散/再分散。
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4.发明授权
公开(公告)号：US4600700A
公开(公告)日：1986-07-15
申请号：US687410
申请日：1984-12-28
申请人： William D. McHale
发明人： William D. McHale
摘要： A process is described for regenerating a coke-deactivated platinum-containing zeolite catalyst material, which includes oxidizing the deactivated catalyst material in the presence of water under conditions which do not cause significant agglomeration of the platinum on the catalyst.
摘要翻译： 描述了一种用于再生焦炭失活的含铂沸石催化剂材料的方法，其包括在不引起铂在催化剂上的显着附聚的条件下在水存在下氧化失活的催化剂材料。
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公开(公告)号：US4303782A
公开(公告)日：1981-12-01
申请号：US113900
申请日：1980-01-21
CPC分类号： C08G65/20 , C08G65/06 , C08G65/2657
摘要： A method of polymerizing cyclic ethers especially tetrahydrofuran to form high molecular weight polymers using a zeolitic polymerization catalyst.
摘要翻译： 使用沸石聚合催化剂聚合环醚，特别是四氢呋喃以形成高分子量聚合物的方法。
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公开(公告)号：US4261810A
公开(公告)日：1981-04-14
申请号：US130802
申请日：1980-03-17
IPC分类号： C10G35/22
CPC分类号： C10G35/22 , Y10S585/906 , Y10S585/951
摘要： Process for reforming a hydrocarbon charge under reforming conditions in a reforming zone containing a sulfur-sensitive metal containing reforming catalyst wherein over-cracking of the charge stock and excessive temperature rise in the reforming zone is suppressed by pre-conditioning the catalyst, prior to contact with the charge, with a reformate of specified octane number and aromatics content.
摘要翻译： 在包含含硫敏感金属的重整催化剂的重整区中，在重整条件下重整烃装料的方法，其中通过在接触之前预处理催化剂来抑制电荷原料的过度裂化和重整区的过度温度升高 负责重组指定的辛烷值和芳烃含量。
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公开(公告)号：US4493764A
公开(公告)日：1985-01-15
申请号：US618791
申请日：1984-06-08
IPC分类号： B01J23/656 , C10G35/09 , C10G35/06
CPC分类号： C10G35/09 , B01J23/6565
摘要： There is provided, in accordance with the present invention, a catalyst composition made up of a mixture of two components, one component comprising a minor proportion of platinum and rhenium on a support and the second component comprising a minor proportion of iridium and rhenium on a separate support. A process for reforming a charge stock, such as naphtha, utilizing such catalyst is also provided.
摘要翻译： 根据本发明，提供了由两种组分的混合物组成的催化剂组合物，一种在载体上包含少量铂和铼的组分，第二组分包含少量的铱和铼 单独支持。 还提供了利用这种催化剂重整电荷原料如石脑油的方法。
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公开(公告)号：US4575416A
公开(公告)日：1986-03-11
申请号：US631681
申请日：1984-07-16
IPC分类号： B01J29/00 , B01J29/08 , B01J29/40 , B01J29/50 , B01J29/60 , B01J29/65 , B01J29/80 , C10G45/64 , C10G73/02
CPC分类号： B01J29/80 , C10G45/64 , B01J29/084 , B01J29/40
摘要： A catalytic dewaxing process is improved by the use of a mixed zeolite catalyst which combines the following components: a first zeolitic catalyst having a Constraint Index not less than 1, a second, different, catalytic component of specified characteristics, and a hydrogenation component. This process for preparing the catalyst is also disclosed. Examples of specific combinations of dewaxing catalysts include ZSM-5 and Dealuminized Y, ZSM-5 and ZSM-12, and ZSM-5 and TEA Mordenite.
摘要翻译： 通过使用组合以下组分的混合沸石催化剂来改进催化脱蜡方法：具有不小于1的约束指数的第一沸石催化剂，特定特征的第二种不同的催化组分和氢化组分。 还公开了该制备催化剂的方法。 脱蜡催化剂的具体组合的实例包括ZSM-5和脱铝Y，ZSM-5和ZSM-12，以及ZSM-5和TEA丝光沸石。
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公开(公告)号：US4477590A
公开(公告)日：1984-10-16
申请号：US525778
申请日：1983-08-24
CPC分类号： B01J23/6565 , C10G35/09
摘要： There is provided, in accordance with the present invention, a catalyst composition made up of a mixture of two components, one component comprising a minor proportion of platinum and rhenium on a support and the second component comprising a minor proportion of iridium and rhenium on a separate support. A process for reforming a charge stock, such as naphtha, utilizing such catalyst is also provided.
摘要翻译： 根据本发明，提供了由两种组分的混合物组成的催化剂组合物，一种在载体上包含少量铂和铼的组分，第二组分包含少量的铱和铼 单独支持。 还提供了利用这种催化剂重整电荷原料如石脑油的方法。
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公开(公告)号：US4359400A
公开(公告)日：1982-11-16
申请号：US228855
申请日：1981-01-27
摘要： Supported multi-metallic platinum-containing hydrocarbon conversion catalysts which are at least partially deactivated due to the deposition of carbonaceous residues thereon during contact with hydrocarbons are regenerated by (1) contacting the catalyst with oxygen to burn at least a portion of the carbonaceous residues from the catalyst, (2) contacting the carbonaceous residue depleted catalyst with hydrogen at an elevated temperature to convert a substantial portion of the non-platinum component present in the catalyst to its metallic form, (3) contacting the reduced catalyst with dry hydrogen chloride in the absence of oxygen, (4) treatment of the hydrogen chloride treated catalyst with chlorine, and (5) reduction of the chlorine treated catalyst with a reducing agent, such as hydrogen.
摘要翻译： 由于在与烃接触期间由于其上的碳质残渣沉积而至少部分失活的支持的多金属含铂烃转化催化剂通过（1）使催化剂与氧接触以将至少一部分碳质残渣从 催化剂，（2）在高温下将含碳残余物贫化催化剂与氢气接触以将存在于催化剂中的大部分非铂组分转化为其金属形式，（3）使还原的催化剂与干氯化氢接触 无氧，（4）用氯处理氯化氢处理的催化剂，和（5）用还原剂如氢气还原氯处理的催化剂。
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