摘要:
A stable suspension for the production of a temperature-regulating, polymer-containing material or fabric, comprises a solvent and a plurality of microcapsules containing at least one phase-change material. The microcapsules are incorporated in the polymer-containing material, and the stable suspension is characterized in that the solvent is capable of dissolving a fabric-forming component selected from the group consisting of at least one of the polymer and precursors thereof and the suspension is stable for at least about 20 hours. A method for manufacturing a suspension comprising a solvent and a plurality of microcapsules containing at least one phase-change material comprises providing microcapsules containing a phase-change material, providing a solvent capable of dissolving a fabric-forming component selected from the group consisting of at least one of the polymer and precursors thereof, and mixing the solvent and the microcapsules to form the suspension.
摘要:
A material for energy management and peak energy reduction in a building structure, comprises an insulative base material, a first phase change material, and a functional polymeric phase change material that dynamically absorbs and releases heat to adjust heat transfer. The functional polymeric phase change material has at least one phase change temperature in the range between −10° C. and 100° C. and a phase change enthalpy of at least 5 Joules per gram, the functional polymeric phase change material including a plurality of polymer chains that include a backbone chain and a plurality of side chains, wherein a first portion of the plurality of polymer chains are crosslinked to each other, wherein a second portion of the plurality of polymer chains are crosslinked with the first phase change material and a third portion of the plurality of side chains are mechanically entangled with the inorganic insulative base material.
摘要:
An article comprises a substrate and a functional polymeric phase change material bound to the substrate. In some aspects the functional polymeric phase change material is chemically bound to the substrate and can be accomplished by at least one of covalent bonding or electrovalent bonding. The functional polymeric phase change material can comprise a reactive function selected from the group consisting of an acid anhydride group, an alkenyl group, an alkynyl group, an alkyl group, an aldehyde group, an amide group, an amino group and their salts, a N-substituted amino group, an aziridine, an aryl group, a carbonyl group, a carboxy group and their salts, an epoxy group, an ester group, an ether group, a glycidyl group, a halo group, a hydride group, a hydroxy group, an isocyanate group, a thiol group, a disulfide group, a silyl or silane group, an urea group, and an urethane group, and wherein the substrate comprises at least one of cellulose, wool, fur, leather, polyester and nylon. Methods of producing the articles are also disclosed.
摘要:
A material for energy management and peak energy reduction in a building structure, comprises an insulative base material, a first phase change material, and a functional polymeric phase change material that dynamically absorbs and releases heat to adjust heat transfer. The functional polymeric phase change material has at least one phase change temperature in the range between −10° C. and 100° C. and a phase change enthalpy of at least 5 Joules per gram, the functional polymeric phase change material including a plurality of polymer chains that include a backbone chain and a plurality of side chains, wherein a first portion of the plurality of polymer chains are crosslinked to each other, wherein a second portion of the plurality of polymer chains are crosslinked with the first phase change material and a third portion of the plurality of side chains are mechanically entangled with the inorganic insulative base material.
摘要:
An article comprises a substrate, a first functional polymeric phase change material, and a plurality of containment structures that contain the first functional polymeric phase change material. The article may further comprise a second phase change material chemically bound to at least one of the plurality of containment structures or the substrate. In certain embodiments, the article further comprises a second phase change material and a binder that contains at least one of the first polymeric phase change material and the second phase change material. The containment structure may be a microcapsule or a particulate confinement material.
摘要:
A composition comprising a functional polymeric phase change material, the functional polymeric phase change material carrying at least one reactive function, wherein the reactive function is capable of forming at least a first covalent bond. In certain embodiments, the reactive function is capable of forming at least a first covalent bond with a second material. In other embodiments, the functional polymeric phase change material comprises at least one crystallizable section and may also comprise a backbone chain and a plurality of side chains, wherein the plurality of side chains form the crystallizable section.
摘要:
In accordance with one aspect, a thermally regulating construction material comprises a base material and a polymeric phase change material bound to the base material, wherein the base material provides reversible temperature regulation properties to the building construction material. In accordance with another aspect, an insulation material for use in building construction comprises a base material and a polymeric phase change material bound to the base material, wherein the base material provides reversible temperature regulation properties to the insulation material. The base material may be selected from the group consisting of foam insulation, loose fill insulation, and batted insulation.
摘要:
An article having reversible thermal regulation properties comprises a substrate and a functional polymeric phase change material having a heat carrying capacity. The article is further characterized by a chemical function having moisture adsorbing properties that increase the heat carrying capacity.
摘要:
An article comprises a substrate, a first functional polymeric phase change material, and a plurality of containment structures that contain the first functional polymeric phase change material. The article may further comprise a second phase change material chemically bound to at least one of the plurality of containment structures or the substrate. In certain embodiments, the article further comprises a second phase change material and a binder that contains at least one of the first polymeric phase change material and the second phase change material. The containment structure may b a microcapsule or a particulate confinement material.
摘要:
An article comprises a substrate and a functional polymeric phase change material bound to the substrate. In some aspects the functional polymeric phase change material is chemically bound to the substrate and can be accomplished by at least one of covalent bonding or electrovalent bonding. The functional polymeric phase change material can comprise a reactive function selected from the group consisting of an acid anhydride group, an alkenyl group, an alkynyl group, an alkyl group, an aldehyde group, an amide group, an amino group and their salts, a N-substituted amino group, an aziridine, an aryl group, a carbonyl group, a carboxy group and their salts, an epoxy group, an ester group, an ether group, a glycidyl group, a halo group, a hydride group, a hydroxy group, an isocyanate group, a thiol group, a disulfide group, a silyl or silane group, an urea group, and an urethane group, and wherein the substrate comprises at least one of cellulose, wool, fur, leather, polyester and nylon. Methods of producing the articles are also disclosed.