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    Highly filled, pasty, composition containing silicoorganic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings
    2.
    发明授权
    Highly filled, pasty, composition containing silicoorganic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings 失效
    含有硅胶有机纳米混合和/或微混合胶囊的高填充，糊状组合物，用于耐刮擦和/或耐磨涂层

    公开(公告)号：US06830816B2

    公开(公告)日：2004-12-14

    申请号：US10112042

    申请日：2002-04-01

    申请人： Reiner Mehnert ,  Hans-Juergen Glaesel ,  Helmut Langguth ,  Jaroslaw Monkiewicz ,  Roland Edelmann ,  Bjoern Borup

    发明人： Reiner Mehnert ,  Hans-Juergen Glaesel ,  Helmut Langguth ,  Jaroslaw Monkiewicz ,  Roland Edelmann ,  Bjoern Borup

    IPC分类号： C08K320

    CPC分类号： C09C1/3081 ,  C01P2004/88 ,  C08K9/06 ,  C09C3/12 ,  Y10T428/2995 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31935

    摘要： The present invention relates to a composition containing silico-organic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings, wherein the silico-organic nanohybrid and/or microhybrid system includes one or more small metal oxide cores A and a substantially complete, silico-organic shell B, and the composition can be obtained by a reaction performed in situ, in a synthetic resin or in a synthetic-resin precursor compound, between metal oxide particles (KA-O) and at least one organofunctional silicon compound which contains an organofunctional group and at least one hydrolyzable group or at least one hydroxy group. The present invention also relates to the use of such compositions as the base for lacquers for producing a scratch-resistant and abrasion-resistant coating on a substrate as well as articles provided with corresponding scratch-resistant as well as abrasion-resistant coatings.

    摘要翻译： 本发明涉及包含用于耐刮擦和/或耐磨涂层的硅 - 有机纳米混合和/或微混合胶囊的组合物，其中硅 - 有机纳米混合和/或微混合系统包括一个或多个小金属氧化物核心A和 基本上完全的硅 - 有机壳B，并且组合物可以通过在合成树脂或合成树脂前体化合物中原位进行的金属氧化物颗粒（KA-O）与至少一种有机官能团 含有有机官能团和至少一个可水解基团或至少一个羟基的硅化合物。 本发明还涉及这样的组合物作为基底用于在基材上生产耐刮擦和耐磨涂层以及具有相应的耐刮擦和耐磨涂层的制品的用途。

    Composition for producing a barrier layer for gases
    3.
    发明申请
    Composition for producing a barrier layer for gases 审中-公开
    用于制备气体阻挡层的组合物

    公开(公告)号：US20070099004A1

    公开(公告)日：2007-05-03

    申请号：US10576467

    申请日：2004-10-13

    申请人： Roland Edelmann ,  Jaroslaw Monkiewicz ,  Bjorn Borup ,  Reiner Mehnert ,  Christian Elsner ,  Hubert Culik ,  Christian Breitwieser

    发明人： Roland Edelmann ,  Jaroslaw Monkiewicz ,  Bjorn Borup ,  Reiner Mehnert ,  Christian Elsner ,  Hubert Culik ,  Christian Breitwieser

    IPC分类号： B32B27/00 ,  C08G77/04 ,  C08L83/04

    CPC分类号： C09D183/04 ,  C08G77/22 ,  C08G77/26 ,  C08G77/50 ,  C08K5/053 ,  C09D4/00 ,  Y10T428/31663 ,  C08G77/00

    摘要： Organosilane-based composition for producing a barrier layer for gases, comprising (i) at least one organoalkoxysilane whose organofunctionality displays at least one unsaturated hydrocarbon group, (ii) at least one aminoalkylalkoxysilane, (iii) at least one polyol, (iv) optionally, another alkoxysilane or alkoxysiloxane, and (v) optionally, at least one nano- or microscale semimetal oxide or metal oxide, semimetal oxide hydroxide or metal oxide hydroxide, or sernimetal hydroxide or metal hydroxide, and/or (vi) at least one cocondensate composed of the components (i), (ii), (iii), and, optionally, (iv), and also, optionally, (v), and/or (vii) reaction products produced under hydrolysis conditions from the components (i), (ii), (iii), and, optionally, (iv), and also, optionally, (v) (viii) and organic solvent, with the proviso that there is a molar ratio (i):(ii):(iii) where (i)=1 and (ii)=from 0.5 to 1.5, and (iii)=from 0.3 to 1.1. The invention also relates to a process for producing, and the use of, the composition, and to packaging materials produced using the composition.

    摘要翻译： 包含（i）至少一种有机烷氧基硅烷，其有机官能团显示至少一个不饱和烃基，（ii）至少一个氨基烷基烷氧基硅烷，（iii）至少一种多元醇，（iv）任选地 ，（v）任选的至少一种纳米或微米级半金属氧化物或金属氧化物，半金属氧化物氢氧化物或金属氧化物氢氧化物或氢氧化金属或金属氢氧化物，和/或（vi）至少一种缩聚物 由组分（i），（ii），（iii），和任选地（ⅳ），以及（ⅴ），（ⅴ），（Ⅴ）和/ ），（ⅱ），（ⅲ）和（ⅳ），（ⅳ），以及任选的（ⅴ）（Ⅷ）和有机溶剂，条件是摩尔比（ⅰ） （iii）其中（i）= 1和（ii）= 0.5至1.5，（iii）= 0.3至1.1。 本发明还涉及一种用于生产和使用组合物以及使用该组合物生产的包装材料的方法。

    Polymerizable organosilicon nanocapsules
    4.
    发明授权
    Polymerizable organosilicon nanocapsules 失效
    可聚合的有机硅纳米胶囊

    公开(公告)号：US08043701B2

    公开(公告)日：2011-10-25

    申请号：US11258025

    申请日：2005-10-26

    申请人： Roland Edelmann ,  Jaroslaw Monkiewicz

    发明人： Roland Edelmann ,  Jaroslaw Monkiewicz

    IPC分类号： B32B5/00 ,  B01J13/02

    CPC分类号： C08K9/06 ,  B01J13/02 ,  B82Y30/00 ,  C01P2004/64 ,  C01P2006/12 ,  C09C1/00 ,  C09C1/3081 ,  C09C1/3684 ,  C09C1/407 ,  C09C3/12 ,  Y10T428/2984

    摘要： The present invention provides a polymerizable organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle comprising at least one oxide or mixed oxide, KA-O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R  (Ia) wherein R is a vinyl or allyl group; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA-O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA-O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attached thereto.

    摘要翻译： 本发明提供了一种可聚合的有机硅纳米胶囊，其包括：纳米级芯A，其包括：至少一种包含至少一种氧化物或混合氧化物的颗粒，KA-O，其至少一种金属或半金属选自包括主要 元素周期表第2至6组，周期表第1至8族，镧系元素及其混合物; 和有机硅壳B，其包括：至少一种具有式（Ia）的有机硅化合物：（Si'O-）xSi-R（Ia）其中R是乙烯基或烯丙基; 其中x是0至20的数; 其中Si的剩余游离价各自独立地为（KA-O） - ， - SiO-或-Z; 其中Si'的剩余游离价各自独立地为（KA-O） - ， - SiO-，-R或-Z; 其中Z各自独立地为羟基或烷氧基; 并且其中壳体B中的每个Si和Si'具有不超过一个连接到其上的R基团。

    Aminopropyl-functional siloxane oligomers
    5.
    发明授权
    Aminopropyl-functional siloxane oligomers 有权
    氨基丙基官能的硅氧烷低聚物

    公开(公告)号：US06395858B1

    公开(公告)日：2002-05-28

    申请号：US09427479

    申请日：1999-10-27

    申请人： Helmut Mack ,  Dieter Barfurth ,  Roland Edelmann ,  Albert-Johannes Frings ,  Michael Horn ,  Peter Jenkner ,  Ralf Laven ,  Jaroslaw Monkiewicz ,  Burkhard Standke

    发明人： Helmut Mack ,  Dieter Barfurth ,  Roland Edelmann ,  Albert-Johannes Frings ,  Michael Horn ,  Peter Jenkner ,  Ralf Laven ,  Jaroslaw Monkiewicz ,  Burkhard Standke

    IPC分类号： C08G7726

    CPC分类号： C08G77/045 ,  C07F7/21 ,  C08G77/26

    摘要： The present invention relates to mixtures of catenate and cyclic siloxane oligomers of the formulae I and II where the substituents R consist of (i) aminopropyl-functional groups of the formula —(CH2)3—NH2 or —(CH2)3—NHR′ or —(CH2)3—NH(CH2)2—NH2 or —(CH2)3—NH(CH2)2—NH(CH2)2—NH2,in which R′ is a linear, branched or cyclic alkyl group of 1 to 18 carbon atoms or an aryl group of 6 to 12 carbon atoms, and (ii) methoxy, ethoxy, 2-methoxyethoxy and/or propoxy groups, and (iii) if desired, alkyl, alkenyl, isoalkyl or cycloalkyl groups of 1 to 18 carbon atoms and/or aryl groups of 6 to 12 carbon atoms, and where not more than one aminopropyl-functional group is attached to one silicon atom and the degree of oligomerization of compounds of the formula I is within the range 2

    摘要翻译： 本发明涉及式I和II的链状酯和环状硅氧烷低聚物的混合物，其中取代基R由（i）式 - （CH 2）3 -NH 2或 - （CH 2）3 -NHR'的氨基丙基官能团或 - （CH 2）3 -NH（CH 2）2 -NH 2或 - （CH 2）3 -NH（CH 2）2 -NH（CH 2）2 -NH 2，其中R'是直链，支链或环状烷基， 18个碳原子或6至12个碳原子的芳基，和（ii）甲氧基，乙氧基，2-甲氧基乙氧基和/或丙氧基，和（iii）如果需要，可以是1-18的烷基，烯基，异烷基或环烷基 6〜12个碳原子的碳原子和/或芳基，并且其中不超过一个氨基丙基官能团连接到一个硅原子上，并且式I化合物的低聚度在2 = 0.5的商。 本发明还涉及制备所述混合物及其应用的特殊方法。

    Polymerizable organosilicon nanocapsules
    9.
    发明申请
    Polymerizable organosilicon nanocapsules 失效
    可聚合的有机硅纳米胶囊

    公开(公告)号：US20060063002A1

    公开(公告)日：2006-03-23

    申请号：US11258025

    申请日：2005-10-26

    申请人： Roland Edelmann ,  Jaroslaw Monkiewicz

    发明人： Roland Edelmann ,  Jaroslaw Monkiewicz

    IPC分类号： B32B9/02

    CPC分类号： C08K9/06 ,  B01J13/02 ,  B82Y30/00 ,  C01P2004/64 ,  C01P2006/12 ,  C09C1/00 ,  C09C1/3081 ,  C09C1/3684 ,  C09C1/407 ,  C09C3/12 ,  Y10T428/2984

    摘要： The present invention provides a polymerizable organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle comprising at least one oxide or mixed oxide, KA-O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R   (Ia) wherein R is a vinyl or allyl group; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA-O)—, SiO— or -Z; wherein remaining free valences of Si′ are each independently (KA-O)—, SiO—, -R, or -Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attatched thereto.

    摘要翻译： 本发明提供了一种可聚合的有机硅纳米胶囊，其包括：纳米级芯A，其包括：至少一种包含至少一种氧化物或混合氧化物的颗粒，KA-O，其至少一种金属或半金属选自包括主要 元素周期表第2至6组，周期表第1至8族，镧系元素及其混合物; 和有机硅壳B，其包括：至少一种具有式（I）的有机硅化合物

    Surface coating composition comprising silicon compounds
    10.
    发明授权
    Surface coating composition comprising silicon compounds 失效
    包含硅化合物的表面涂料组合物

    公开(公告)号：US06695904B2

    公开(公告)日：2004-02-24

    申请号：US10227295

    申请日：2002-08-26

    申请人： Rosemarie Burger ,  Jaroslaw Monkiewicz ,  Roland Edelmann ,  Bjoern Borup

    发明人： Rosemarie Burger ,  Jaroslaw Monkiewicz ,  Roland Edelmann ,  Bjoern Borup

    IPC分类号： C09D18306

    CPC分类号： C09D183/04 ,  C08G77/06 ,  C08K3/36 ,  C23C2222/20

    摘要： A composition which retains a flash point of more than 21° C. even on storage and is obtainable by mixing and reacting (i) from 50 to 70% by weight of at least one alkyltrialkoxysilane, (ii) from 10 to 25% by weight of at least one alkoxysiloxane and/or at least one tetraalkoxysilane, (iii) from 15 to 25% by weight of at least one aqueous silica sol, (iv) from 0.1 to 5% by weight of at least one acid, and (v) from 0.1 to 60% by weight of at least one alcohol and/or glycol, the sum of the above components being not more than 100% by weight, by introducing components (i) and (ii) and also, if desired, a fraction of component (v) as an initial charge, adding component (iii), adjusting the mixture to a temperature in the range from −5 to 10° C., and subsequently adding component (iv), then allowing the mixture to continue reacting, thereafter distilling off hydrolysis alcohol under reduced pressure, and replacing it by adding component (v); which composition is useful for producing a coating on surfaces and also as a base material for paints; a process for preparing such a composition; and coatings and articles obtainable by applying such a composition.

    摘要翻译： 即使在储存时也保持闪点超过21℃的组合物，并且可通过混合并使（i）50至70重量％的至少一种烷基三烷氧基硅烷，（ii）10至25重量％ 的至少一种烷氧基硅氧烷和/或至少一种四烷氧基硅烷，（iii）15至25重量％的至少一种水性二氧化硅溶胶，（iv）0.1至5重量％的至少一种酸，和（v ）0.1至60重量％的至少一种醇和/或二醇，上述组分的总和不超过100重量％，通过引入组分（i）和（ii），并且如果需要，可以使用 将组分（v）的馏分作为初始电荷，加入组分（iii），将混合物调节至-5至10℃的温度，随后加入组分（iv），然后使混合物继续反应 然后在减压下蒸馏除去水解醇，并通过加入组分（v）代替; 该组合物可用于在表面上生产涂层以及用作涂料的基材; 制备这种组合物的方法; 以及通过应用这种组合物可获得的涂层和制品。