-
公开(公告)号：US4655879A
公开(公告)日：1987-04-07
申请号：US664902
申请日：1984-10-26
申请人： Rolf Brockmann , Lutz Jeromin , Wilhelm Johannisbauer , Helmut Meyer , Otto Michel , Juergen Plachenka
发明人： Rolf Brockmann , Lutz Jeromin , Wilhelm Johannisbauer , Helmut Meyer , Otto Michel , Juergen Plachenka
IPC分类号： B01D3/14 , B01D3/32 , C07C27/00 , C07C29/80 , C07C29/88 , C07C31/22 , C07C67/00 , B01D3/34 , B01D1/22
CPC分类号： B01D3/322 , B01D3/148 , C07C29/80 , Y10S203/20
摘要： An improved process for purification of glycerol obtained from natural sources comprising alkalizing a glycerol-containing crude mixture in the presence of air for oxidation, evaporating the mixture in a thin-layer evaporator with redistillation of the residue, rectification and reevaporation in a packed column characterized by low-pressure-loss plates with a falling-film evaporator designed for internal and external partial condensation and to separate off unwanted constituents of the mixture, bleaching the product with activated carbon and separating the bleach in known manner.
摘要翻译： 从天然来源纯化甘油的改进方法，包括在空气存在下使含甘油的粗混合物碱化以进行氧化，在薄层蒸发器中蒸发混合物，重新蒸馏残余物，在填充塔中进行精馏和再蒸发 通过设计用于内部和外部部分冷凝的降膜蒸发器的低压损耗板和分离混合物的不需要的成分，用活性炭漂白产物并以已知的方式分离漂白剂。
-
公开(公告)号：US5527974A
公开(公告)日：1996-06-18
申请号：US284531
申请日：1994-09-29
申请人： Lutz Jeromin , Wilhelm Johannisbauer , Stefan Blum , Reinhold Sedelies , Heinrich Moormann , Bernd Holfoth , Juergen Plachenka
发明人： Lutz Jeromin , Wilhelm Johannisbauer , Stefan Blum , Reinhold Sedelies , Heinrich Moormann , Bernd Holfoth , Juergen Plachenka
CPC分类号： B01D17/0211 , B01D17/02 , B01D61/147 , B01D61/16 , C02F1/444 , C07C29/76 , C07C31/225 , C12C11/02 , B01D2311/04
摘要： The glycerol water (sweet water) accumulating in the high-pressure hydrolysis of natural fats and oils with steam into fatty acid and glycerol is continuously purified. Fats larger than 100 .mu.m in diameter are separated from the aqueous phase in a plate-type phase separator and are returned to the high-pressure hydrolysis process. The aqueous phase thus prepurified is passed through a cross-flow filtration membrane, more particularly a microfiltration membrane, and the concentrate is returned to the entrance of the plate-phase separator. Large product streams of glycerol water can be purified continuously, effectively and particularly economically despite frequent changes of provenance.
摘要翻译： 将天然脂肪和油中蒸汽高压水解的甘油水（甜水）持续纯化。 在板式相分离器中将直径大于100μm的脂肪与水相分离，并返回到高压水解过程。 将如此预纯化的水相通过交叉流过滤膜，更特别是微滤膜，并将浓缩物返回到板相分离器的入口。 甘油水的大量产物流可以连续，有效和特别经济地纯化，尽管原产地频繁变化。
-
公开(公告)号：US4595461A
公开(公告)日：1986-06-17
申请号：US599089
申请日：1984-04-11
申请人： Lutz Jeromin , Wilhelm Johannisbauer , Klaus Thorausch , Franjo Skrapac , Helmut Hartmann , Karl Hentschel , Otto Michel
发明人： Lutz Jeromin , Wilhelm Johannisbauer , Klaus Thorausch , Franjo Skrapac , Helmut Hartmann , Karl Hentschel , Otto Michel
CPC分类号： C07C51/445 , C07C51/44 , Y10S203/16 , Y10S203/20 , Y10S203/90
摘要： A process for the nondegenerative distillation of C.sub.6 -C.sub.24 -fatty acids, of the type obtained by splitting natural fats and oils or by synthetic processes, such as for example the oxidation of paraffins, the crude product is thermally dried under reduced pressure, the dried and heated crude product is subjected to fractional evaporation in falling-film evaporators, optionally in the presence of superheated steam, and the various vapor fractions are deposited in condensers. The thermal drying process is conducted at a temperature of 60.degree.-80.degree. C. and a pressure of 90-100 mbars. The de-watered crude product is fractionated in a film-forming evaporator and, after distillation, passes to a rectification column which condenses the low boiling constituents as the main runnings.
摘要翻译： 通过分离天然脂肪和油或通过合成方法（例如石蜡氧化）得到的类型的C 6 -C 24脂肪酸的非退化蒸馏方法，粗产物在减压下热干燥，干燥 并且加热的粗产物在降膜蒸发器中任选地在过热蒸汽的存在下进行分级蒸发，并且各种蒸气馏分沉积在冷凝器中。 热干燥过程在60-80℃的温度和90-100mbar的压力下进行。 脱水的粗产物在成膜蒸发器中分馏，并在蒸馏之后进入精馏塔，其将低沸点组分作为主要流路冷凝。
-
公开(公告)号：US5710261A
公开(公告)日：1998-01-20
申请号：US594506
申请日：1996-01-31
IPC分类号： C07H15/04
CPC分类号： C07H15/04 , Y10S159/10 , Y10S159/16
摘要： Aliphatic alcohols with up to 30 and especially with 6 to 18 carbon atoms are separated from a mixture of alkyl glycosides and alcohols which are unreacted during the production of these glycosides, by single or multi-stage distillation. The alcohols are distilled off by a drop film evaporator to impoverish the reaction mixture to residual alcohol contents of 5 wt % and under. The strip load of the drop film evaporator is set to at least 1.0 m.sup.3 /h m, especially at least 1.8 m.sup.3 /h m and preferably at least 3.0 m.sup.3 /h m. It is possible to reduce the alcohol content of the product to any value between 0.1 and 5 wt % at acceptable overall cost.
摘要翻译： 通过单阶段或多阶段蒸馏，在生产这些糖苷期间将具有多达30个，特别是6至18个碳原子的脂族醇从烷基糖苷和醇的混合物中分离出来，所述烷基糖苷和醇是未反应的。 通过滴膜蒸发器蒸馏掉醇，将反应混合物贫化至5重量％以下的残留醇含量。 降膜蒸发器的带材负载设定为至少1.0m 3 / h m，特别是至少1.8m 3 / h m，优选至少3.0m 3 / h m。 可以以可接受的总成本将产品的醇含量降低至0.1至5重量％之间的任何值。
-
公开(公告)号：US5646311A
公开(公告)日：1997-07-08
申请号：US654483
申请日：1996-05-28
申请人： Tracy K. Hunt , Lutz Jeromin , Wilhelm Johannisbauer , Bernhard Gutsche , Volkmar Jordon , Herbert Wogatzki
发明人： Tracy K. Hunt , Lutz Jeromin , Wilhelm Johannisbauer , Bernhard Gutsche , Volkmar Jordon , Herbert Wogatzki
CPC分类号： C07D311/72 , C07C67/03 , C07C67/54
摘要： Starting from a mixture containing tocopherol, fats and/or fat derivatives, more particularly fatty acids, and optionally sterol and/or sterol derivatives, the free fatty acids present in the mixture are esterified with an alcohol. The mixture is then transesterified with an alcohol in the presence of a basic catalyst. After the transesterification, the excess lower alcohol is distilled off from the reaction mixture. The transesterification catalyst and the glycerol present, if any, are removed and the fatty acid alkyl ester is distilled off from the mixture. Distillation of fatty acid alkyl esters can be accomplished with a packed column in sequence with a wiped film evaporator. The simultaneous recovery of tocopherol and sterol is possible. Tocopherols and sterols can be separated by the crystallization of sterols from a blend of organic solvents.
摘要翻译： 从含有生育酚，脂肪和/或脂肪衍生物，更特别是脂肪酸和任选的固醇和/或固醇衍生物的混合物开始，混合物中存在的游离脂肪酸被醇酯化。 然后将混合物在碱性催化剂存在下用醇酯交换。 酯交换后，从反应混合物中蒸馏出多余的低级醇。 酯交换催化剂和存在的甘油（如果有的话）被除去，并从混合物中蒸出脂肪酸烷基酯。 脂肪酸烷基酯的蒸馏可以用填充柱依次用擦膜蒸发器完成。 生育酚和甾醇的同时回收是可能的。 生育酚和甾醇可以通过固醇与有机溶剂的混合物的结晶分离。
-
公开(公告)号：US5076896A
公开(公告)日：1991-12-31
申请号：US365577
申请日：1989-06-13
申请人： Franz-Josef Carduck , Lutz Jeromin , Gerd Geobel , Wilhelm Johannisbauer , Georg Fieg , Theo Fleckenstein
发明人： Franz-Josef Carduck , Lutz Jeromin , Gerd Geobel , Wilhelm Johannisbauer , Georg Fieg , Theo Fleckenstein
IPC分类号： C07C29/86
CPC分类号： C07C29/86 , Y10S203/20
摘要： A process for the separation of propylene glycol from a mixture of low-boiling fatty alcohols and propylene glycol which comprises extracting the mixture with water to produce a water-propylene glycol mixture and fractionating the water-propylene glycol mixture to produce propylene glycol that is substantially anhydrous and an apparatus for carrying out the process.
摘要翻译： 一种用于从低沸点脂肪醇和丙二醇的混合物中分离丙二醇的方法，其包括用水萃取混合物以产生水 - 丙二醇混合物并将水 - 丙二醇混合物分馏以产生基本上为 无水和用于进行该过程的装置。
-
7.发明授权Recovery of tocopherol and sterol from tocopherol and sterol containing mixtures of fats and fat derivatives 失效从生育酚和含有脂肪和脂肪衍生物混合物的固醇中回收生育酚和固醇
公开(公告)号：US5627289A
公开(公告)日：1997-05-06
申请号：US387933
申请日：1995-02-27
IPC分类号： A23L3/3544 , C07D311/72 , C07J9/00 , C07J75/00 , C11B3/02 , C11B7/00 , C11C3/10
CPC分类号： A23L3/3544 , C07D311/72
摘要： A process is provided for simultaneously recovering tocopherol and sterol from a mixture containing tocopherol, fats and/or fat derivatives, more particularly fatty acids, and sterol and/or sterol derivatives, more particularly from a steamer distillate of natural oils and fats. The steps of said process comprise:free fatty acids present in the mixture are esterified with a lower alcohol, preferably methanol, 0.4 to 1.6 and more particularly 1 to 1.5 parts by volume of mixture being esterified with 1 part by volume of the lower alcohol,the mixture is subsequently transesterified with the lower alcohol in the presence of a basic catalyst,the excess lower alcohol is distilled off from the reaction mixture after the transesterification,the transesterification catalyst and the glycerol optionally present are removed, more particularly by washing,the fatty acid alkyl ester is distilled off from the mixture, more particularly after removal of the transesterification catalyst, andif desired, tocopherol and sterol are separated by methods known per se. After the transesterification reaction, the alkali catalyst is preferably neutralized with an inorganic acid and the mixture is then washed with water.
摘要翻译： PCT No.PCT / EP93 / 02207 Sec。 371日期：1995年2月27日 102（e）1995年2月27日PCT PCT 1993年8月18日PCT公布。 公开号WO94 / 00650 PCT 日期1994年5月17日提供了一种从含有生育酚，脂肪和/或脂肪衍生物，特别是脂肪酸和甾醇和/或固醇衍生物的混合物中同时回收生育酚和固醇的方法，更特别是来自天然油的蒸馏馏分和 脂肪 所述方法的步骤包括：混合物中存在的游离脂肪酸用低级醇优选甲醇酯化，优选甲醇为0.4至1.6，更特别为1至1.5体积份的混合物与1体积份低级醇酯化， 该混合物随后在碱性催化剂的存在下与低级醇进行酯交换，在酯交换反应后，从反应混合物中蒸出过量的低级醇，任选存在的酯交换催化剂和甘油被去除，更特别是通过洗涤除去脂肪 从混合物中蒸馏掉酸性烷基酯，更特别是在除去酯交换催化剂后，如果需要，通过本身已知的方法分离生育酚和固醇。 酯交换反应后，碱催化剂优选用无机酸中和，然后将混合物用水洗涤。
-
8.发明授权Process for the acid-catalyzed cleavage of fatty acid glycerides and apparatus therefor 失效脂肪酸甘油酸的酸性催化清除方法及其设备
公开(公告)号：US5128070A
公开(公告)日：1992-07-07
申请号：US388206
申请日：1989-08-01
申请人： Reinhold Sedelies , Wilhelm Johannisbauer , Guenter Wozny , Lutz Jeromin , Gerhard Dieckelm , Manfred Lindemann , Gerd Matrong
发明人： Reinhold Sedelies , Wilhelm Johannisbauer , Guenter Wozny , Lutz Jeromin , Gerhard Dieckelm , Manfred Lindemann , Gerd Matrong
CPC分类号： C11C1/04
摘要： Process for the acid-catalyzed hydrolysis of fatty acid glycerides, wherein the process is carried out continuously with the glyceride and the water being moved countercurrent to each other, and apparatus therefor.
摘要翻译： 脂肪酸甘油酯的酸催化水解的方法，其中该方法与甘油酯和水相互逆流地连续进行，以及其装置。
-
9.发明授权公开(公告)号：US08404468B2
公开(公告)日：2013-03-26
申请号：US12601471
申请日：2008-05-14
申请人： Martin Lucia , Irina Obraztsova , Baldomero F. Cordero , Angeles M. Vargas , Albrecht Weiss , Bernhard Gutsche , Wilhelm Johannisbauer , Herminia Rodriguez
发明人： Martin Lucia , Irina Obraztsova , Baldomero F. Cordero , Angeles M. Vargas , Albrecht Weiss , Bernhard Gutsche , Wilhelm Johannisbauer , Herminia Rodriguez
摘要： The present invention pertains to a method for the efficient production of carotenoids. In particular, the present invention is directed to a method for producing carotenoid and carotenoid-containing cells, especially astaxanthin and astaxanthin-containing cells, by generating mutant microorganisms belonging to the photoautotrophic algae of the Class Chlorophyceae and culturing same. The present invention further relates to methods of generating microorganisms producing high yields of carotenoids, in particular astaxanthin, products containing said microorganisms or said carotenoids, and the use of said carotenoids produced by the microorganisms according to the present invention and deposited mutant strains generated from said microorganisms.
摘要翻译： 本发明涉及一种有效生产类胡萝卜素的方法。 特别地，本发明涉及通过产生属于类绿藻的光自养藻类的突变微生物并进行培养的方法来生产含有类胡萝卜素和类胡萝卜素的细胞，特别是虾青素和含虾青素的细胞。 本发明还涉及产生高产量的类胡萝卜素，特别是虾青素，含有所述微生物或所述类胡萝卜素的产品的微生物的生产方法，以及由本发明的微生物产生的所述类胡萝卜素的用途以及由所述微生物产生的沉积的突变菌株 微生物。
-
公开(公告)号：US5973173A
公开(公告)日：1999-10-26
申请号：US844804
申请日：1997-04-22
IPC分类号： C07C51/083 , C07C51/44 , C11B3/00 , C11B3/12
CPC分类号： C07C51/083 , C07C51/44
摘要： Pure azelaic acid is obtained by working up a reaction mixture containing C.sub.1-18 monocarboxylic acids, mainly pelargonic acid, and C.sub.4-16 dicarboxylic acids, mainly azelaic acid, obtained from the ozonolysis of oleic acid or a starting mixture containing oleic acid. All but C.sub.9 are separated off to obtain a prepurified product containing more than 75% by weight of oleic acid and the prepurified product is concentrated to more than 90% by weight of oleic acid in several process steps. In a first process step (1), the dicarboxylic acids with chain lengths of
摘要翻译： 通过处理由油酸的臭氧分解或含有油酸的起始混合物得到的含有C1-18单羧酸（主要是壬酸）和C4-16二羧酸（主要是壬二酸）的反应混合物，得到纯壬二酸。 分离除了<2重量％的一元羧酸和一部分链长
C9的二羧酸以获得含有超过75重量％油酸的预纯化产物，并且预纯化产物是 在几个工艺步骤中浓缩至大于90重量％的油酸。 在第一方法步骤（1）中，通过分馏作为第一次运行除去在预纯化产物中存在链长
-
-
-
-
-
-
-
-
-
搜索结果
24 条记录 (耗时 0.029 秒)
