公开(公告)号：US5032611A

公开(公告)日：1991-07-16

申请号：US320599

申请日：1989-03-08

申请人： Ryusuke Taguchi ,  Hideo Sugawara ,  Yukio Miyazaki ,  Taku Mizuno ,  Masahide Nomura ,  Machiko Sugiyama ,  Hideo Saito ,  Goro Yabuta ,  Akiya Furuichi ,  Yasuhiko Hamazaki ,  Katsuhiro Nakamura

发明人： Ryusuke Taguchi ,  Hideo Sugawara ,  Yukio Miyazaki ,  Taku Mizuno ,  Masahide Nomura ,  Machiko Sugiyama ,  Hideo Saito ,  Goro Yabuta ,  Akiya Furuichi ,  Yasuhiko Hamazaki ,  Katsuhiro Nakamura

IPC分类号： C12P1/06 ,  A01N43/08 ,  A01N63/02 ,  C07D307/58 ,  C07D307/68 ,  C07G99/00 ,  C12P17/04 ,  C12R1/01

CPC分类号： A01N43/08 ,  C07D307/58 ,  Y10S435/911

摘要： Disclosed in the present invention are: a substance F-0368 or salts thereof having the following structural formula ##STR1## a method for production of the substance F-0368 or salts thereof, wherein an F-0368-substance-producing-microorganism belonging to a genus Kitasatosporia is cultured, and the substance F-0368 is isolated and collected from the cultured substance; a method for production of the substance F-0368 or salts thereof, wherein 3-methyl-4-lower alkoxy carbonyl-2(5H)-furanone represented by the following general formula is subjected to hydrolytic reaction ##STR2## (where: R represents a straight or branched lower alkyl group having 1 to 6 carbon atoms); a composition which consists essentially of the substance F-0368 or salt thereof, a diluent permissible in the agricultural chemicals, and a carrier or an excipient; a preventive agent for plant diseases such as rice blast disease and bacterial leaf blight disease, which consists essentially of an effective amount of the substance F-0368 or salts thereof as the active component, a diluent permissible in the agricultural chemicals, and a carrier or an excipient; a method for preventing plant diseases, wherein plants are treated with the preventive agent; a disinfectant for agricultural use to prevent plant disease such as rice blast disease and bacterial leaf blight disease, which consists essentially of an effective amount of the substance F-0368 or salts thereof, as the active component, a diluent permissible in the agricultural chemicals, and a carrier or an excipient; materials for agricultural use containing therein the substance F-0368 or salts thereof; a method for growing plants, wherein the plants are cultivated by use of the agricultural materials; and an F-0368-substance-producing microorganism (Kitasatosporia sp. F-0368; FERM BP-2259).

摘要翻译： 在本发明中公开的是具有以下结构式的物质F-0368或其盐：其中产生F-0368物质的微生物属于F-0368或其盐， 培养北海孢属，从培养物中分离收集F-0368物质; 制备物质F-0368或其盐的方法，其中由以下通式表示的3-甲基-4-低级烷氧基羰基-2（5H） - 呋喃酮进行水解反应（其中：R表示 具有1至6个碳原子的直链或支链低级烷基）; 基本上由物质F-0368或其盐组成的组合物，农药中允许的稀释剂，以及载体或赋形剂; 用于植物疾病如稻瘟病和细菌性叶枯病的预防剂，其基本上由有效量的F-0368物质或其盐作为活性成分，农药中允许的稀释剂和载体或 赋形剂 预防植物病害的方法，其中用预防剂处理植物; 用于农业用途的消毒剂，以防止植物病害如稻瘟病和细菌性叶枯病，其主要由有效量的作为活性成分的有效量的物质F-0368或其盐，农药中允许的稀释剂， 和载体或赋形剂; 含有物质F-0368或其盐的农业用材料; 一种用于种植植物的方法，其中通过使用农业材料培育植物; 和产生F-0368的微生物（Kitasatosporia sp.F-0368; FERM BP-2259）。

公开(公告)号：US5102794A

公开(公告)日：1992-04-07

申请号：US640867

申请日：1991-01-14

申请人： Ryusuke Taguchi ,  Hideo Sugawara ,  Yukio Miyazaki ,  Taku Mizuno ,  Masahide Nomura ,  Machiko Sugiyama ,  Hideo Saito ,  Goro Yabuta ,  Akiya Furuichi ,  Yasuhiko Hamazaki ,  Katsuhiro Nakamura

发明人： Ryusuke Taguchi ,  Hideo Sugawara ,  Yukio Miyazaki ,  Taku Mizuno ,  Masahide Nomura ,  Machiko Sugiyama ,  Hideo Saito ,  Goro Yabuta ,  Akiya Furuichi ,  Yasuhiko Hamazaki ,  Katsuhiro Nakamura

IPC分类号： C12P1/06 ,  A01N43/08 ,  A01N63/02 ,  C07D307/58 ,  C07D307/68 ,  C07G99/00 ,  C12P17/04 ,  C12R1/01

CPC分类号： A01N43/08 ,  C07D307/58 ,  Y10S435/911

摘要： Substance F-0368 of the formula: ##STR1## or salts thereof is prepared by culturing Kitasatosporia sp. F-0368 in a culture medium thereby producing substance F-0368, and then isolating and collecting substance F-0368 from the culture medium.

公开(公告)号：US4904470A

公开(公告)日：1990-02-27

申请号：US21125

申请日：1987-03-03

申请人： Hideo Sugawara ,  Tomonori Takashina ,  Nobuko Takahashi ,  Machiko Sugiyama ,  Akio Seino ,  Yukio Miyazaki

发明人： Hideo Sugawara ,  Tomonori Takashina ,  Nobuko Takahashi ,  Machiko Sugiyama ,  Akio Seino ,  Yukio Miyazaki

IPC分类号： C07G11/00 ,  A23K1/17 ,  A23K1/18 ,  A61K35/66 ,  A61K35/74 ,  A61P31/04 ,  C12P1/06 ,  C12R1/465

CPC分类号： C12P1/06 ,  A23K20/195 ,  A23K50/30

摘要： An antibiotic F-0769 having the following properties:(1) Outer appearance: White or light yellow powder,(2) Melting point: 245.degree.-250.degree. C.,(3) Specific rotation: [.alpha.].sub.D.sup.25 =-37.5.degree. (c=1, methanol),(4) Solubility in solvents: Soluble in methanol, ethanol, acetone, chloroform, ethyl acetate and benzene; and insoluble in water and hexane,(5) Elementary analysis (found %): C:57.53, H:7.36, O:21.17, N:12.97,(6) Ultraviolet absorption spectrum (as measured in methanol: As shown in FIG. 1, .lambda.max(E.sub.1 cm.sup.1%)=213 nm (466), 286 nm (200)(7) Infrared absorption spectrum (as measured by KBr method): As shown in FIG. 2,(8) Nuclear magnetic resonance spectra (as measured in heavy chloroform): .sup.1 H-NMR spectrum is as shown in FIG. 3, and .sup.13 C-NMR spectrum is as shown in FIG. 4,(9) Distinction among basicity, acidity and neutrality: Neutral substance,(10) Amino acid analysis: As a result of the hydrolysis with 6N hydrochloric acid at 110.degree. C. for 18 hours, amino acids i.e. threonine, valine and leucine were detected,(11) Color reactions: Positive in the iodine reaction and in the potassium permanganate reaction; and negative in the ninhydrin reaction and in the ferric chloride reaction,(12) Thin layer chromatography (by means of silica gel, Art, 5715, manufactured by Merck Co.):______________________________________ Solvent system Rf value ______________________________________ Ethyl acetate 0.16 Ethyl acetate-methanol (5:1) 0.33 Chloroform-methanol (10:1) 0.68 Ethyl acetate-acetone (1:1) 0.31 Acetone-benzene (5:1) 0.40 ______________________________________ (13) Molecular weight (as measured by Rast method): About 745

摘要翻译： 具有以下性质的抗生素F-0769：（1）外观：白色或浅黄色粉末，（2）熔点：245〜-250℃，（3）比旋光度：αD25= -37.5° （c = 1，甲醇），（4）溶剂中的溶解度：溶于甲醇，乙醇，丙酮，氯仿，乙酸乙酯和苯; 并且不溶于水和己烷，（5）元素分析（发现％）：C：57.53，H：7.36，O：21.17，N：12.97，（6）紫外吸收光谱（在甲醇中测定： 1，λmax（E1cm1％）= 213nm（466），286nm（200）（7）红外吸收光谱（通过KBr法测定）：如图2所示，（8）核磁共振谱 如在重氯仿中测得）：1 H-NMR光谱如图3所示，13C-NMR谱如图4所示，（9）碱度，酸度和中性之间的区别：中性物质，（10）氨基 酸分析：由于6N盐酸在110℃水解18小时，检测出氨基酸，即苏氨酸，缬氨酸和亮氨酸，（11）色素反应：碘反应和高锰酸钾反应中呈阳性 ;在茚三酮反应和氯化铁反应中为负，（12）薄层色谱法（通过硅胶，Art，5715，由Merck Co.制造）： - 溶剂sy 茎Rf值乙酸乙酯0.16-乙酸乙酯 - 甲醇（5:1）0.33-氯仿 - 甲醇（10:1）0.68乙酸乙酯 - 丙酮（1:1）0.31-乙酮 - 苯（5:1）0.40- （13）分子量（用Rast法测定）：约745

公开(公告)号：US4328211A

公开(公告)日：1982-05-04

申请号：US231359

申请日：1981-02-04

申请人： Hideo Sugawara ,  Yukio Miyazaki ,  Akio Seino

发明人： Hideo Sugawara ,  Yukio Miyazaki ,  Akio Seino

IPC分类号： C07K14/195 ,  A61K35/74 ,  A61P31/04 ,  C07G11/00 ,  C07K14/005 ,  C07K14/41 ,  C12P1/06 ,  C12P21/00 ,  C12R1/03 ,  C12R1/465 ,  A61K35/00

CPC分类号： C12R1/03 ,  C12P1/06

摘要： Antibiotic Actinomadura-L-31 A has the characteristics as the hydrochloride salt:appearance: white or pale yellow powdermelting point: non-clear melting pointspecific rotation: [.alpha.].sub.D.sup.25 -34.degree. (C: 0.5, pH: 7.5 water)elementary analysis: (found) C: 51.71%; H: 6.23%; O: 21.03%; N: 13.94%; S: 5.82%; Cl: 1.17%constitutive aminoacids: aspartic acid; glutamic acid; glycin; valine; phenylalanine; histidine; leucine; tryptophanultraviolet absorption spectrum: FIG. 1, maximum absorption:280 nm: E.sub.1 cm.sup.1% =45.2290 nm: shoulder E.sub.1 cm.sup.1% =38infrared spectrum: FIG. 2, absorption (cm.sup.-1) 3350, 3050, 2950, 1660, 1530, 1430, 1395, 1340, 1255, 1235, 1100, 745, 700Antibiotic Actinomadura-L-31 B has the characteristics as the hydrochloride salt:appearance: white to pale yellow powdermelting point: non-clear melting pointspecific rotation: [.alpha.].sub.D.sup.25 -26.degree. (C: 0.5; pH: 7.5 water)elementary analysis: (found) C: 51.10%; H: 6.34%; O: 20.75% N: 14.81%; S: 5.91%; Cl: 1.08%constitutive aminoacids: aspartic acid; threonine; glutamic acid; proline; glycin; valine; phenylalanine; tryptophanultraviolet absorption spectrum: FIG. 3, maximum absorption:280 nm: E.sub.1 cm.sup.1% =44.8290 nm: shoulder E.sub.1 cm.sup.1% =37.3infrared spectrum: FIG. 4, absorption (cm.sup.-1) 3350, 3050, 2950, 1660, 1520, 1440, 1390, 1340, 1260, 1230, 1100, 745, 700.

摘要翻译： 抗生素Actinomadura-L-31A具有盐酸盐的特点：外观：白色或浅黄色粉末熔点：非澄清熔点比旋光度：αD25-34℃（C:0.5，pH7.5水） 元素分析：（发现）C：51.71％; H：6.23％; O：21.03％; N：13.94％; S：5.82％; Cl：1.17％组成型氨基酸：天冬氨酸; 谷氨酸; 甘氨酸 缬氨酸 苯丙氨酸 组氨酸 亮氨酸 色氨酸紫外吸收光谱： 1，最大吸收：280nm：E1cm1％= 45.2 290nm：肩部E1cm1％= 38红外光谱： 2，吸光度（cm-1）3350,3050,2950,1660,1530,1430,1395,1340,1255,1235,1100,745,700抗生素放线索-L-31B具有盐酸盐的特征：外观： 白色至浅黄色粉末熔点：非澄清熔点比旋光度：αD25 -26℃（C:0.5; pH7.5水）元素分析:(发现值）C：51.10％; H：6.34％; O：20.75％N：14.81％; S：5.91％; Cl：1.08％组成型氨基酸：天冬氨酸; 苏氨酸 谷氨酸; 脯氨酸 甘氨酸 缬氨酸 苯丙氨酸 色氨酸紫外吸收光谱： 3，最大吸收：280nm：E1cm1％= 44.8 290nm：肩部E1cm1％= 37.3红外光谱： 4，吸收（cm-1）3350,3050,2950,1660,1520,1440,1390,1340,1260,1230,1100,745,700。

公开(公告)号：US09910545B2

公开(公告)日：2018-03-06

申请号：US12503395

申请日：2009-07-15

申请人： Kazuhiro Nakajima ,  Tomotake Nashiki ,  Hideo Sugawara

发明人： Kazuhiro Nakajima ,  Tomotake Nashiki ,  Hideo Sugawara

IPC分类号： G06F3/044 ,  G02B5/22 ,  B32B3/00

CPC分类号： G06F3/044

摘要： The transparent conductive film of the present invention is a transparent conductive film, comprising: a transparent film substrate; a patterned transparent conductive layer formed on one side of the transparent film substrate; and a colored layer provided on at least one of an opposite side of the transparent conductive layer from the transparent film substrate and an opposite side of the transparent film substrate from the transparent conductive layer, wherein the colored layer has an average absorptance of from 35% to 90% for light in the wavelength range of from 380 nm to 780 nm.

公开(公告)号：US09523147B2

公开(公告)日：2016-12-20

申请号：US13458640

申请日：2012-04-27

申请人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

发明人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

IPC分类号： C23C14/56 ,  C23C14/08 ,  C23C14/14 ,  C23C14/34 ,  H01L21/67

CPC分类号： C23C14/562 ,  C23C14/086 ,  C23C14/14 ,  C23C14/34 ,  C23C14/568 ,  H01L21/67132 ,  H01L21/67173 ,  Y10T428/31678

摘要： A method of continuously subjecting an elongated substrate to vacuum film formation is disclosed. The method comprises the steps of: feeding a first substrate from a first roll chamber in a first direction from the first roll chamber toward a second roll chamber; degassing the first substrate; forming a film of a second material on the first substrate, in a second film formation chamber; and rolling up the first substrate in the second roll chamber, thereby producing the first substrate, and comprises similar steps to produce a second substrate. In advance of producing the first substrate with the second material film, the first cathode electrode of the first film formation chamber is removed from the first film formation chamber, and, in advance of producing the second substrate with the first material film, the second cathode electrode of the second film formation chamber is removed from the second film formation chamber.

摘要翻译： 公开了一种连续使细长衬底经受真空成膜的方法。 该方法包括以下步骤：将来自第一辊室的第一衬底沿第一方向从第一辊室向第二辊室供给; 对第一衬底进行脱气; 在第二成膜室中在第一基板上形成第二材料的膜; 并卷起第二辊室中的第一基板，从而制造第一基板，并且包括类似的步骤以产生第二基板。 在利用第二材料膜制造第一基板之前，第一成膜室的第一阴极电极从第一成膜室除去，并且在用第一材料膜制造第二基板之前，第二阴极 从第二成膜室除去第二成膜室的电极。

公开(公告)号：US09513747B2

公开(公告)日：2016-12-06

申请号：US13271625

申请日：2011-10-12

申请人： Kazuhiro Nakajima ,  Tomotake Nashiki ,  Hideo Sugawara

发明人： Kazuhiro Nakajima ,  Tomotake Nashiki ,  Hideo Sugawara

IPC分类号： B32B3/10 ,  B32B3/14 ,  B32B7/02 ,  G06F3/044 ,  G06F3/045

CPC分类号： G06F3/044 ,  G06F3/045 ,  G06F2203/04103 ,  Y10T428/24802 ,  Y10T428/24868 ,  Y10T428/2495

摘要： The present invention provides a transparent conductive film in which the difference in visibility between the pattern portion and the pattern opening portion is kept small even when a transparent conductive layer is patterned. The transparent conductive film has a first dielectric layer, a second dielectric layer, and a transparent conductive layer in this order on a transparent film substrate, a thickness d21 of the first dielectric layer is larger than a thickness d22 of the second dielectric layer, the thickness d21 of the first dielectric layer is 8 to 40 nm and the thickness d22 of the second dielectric layer is 5 to 25 nm, and a difference between the thickness d21 of the first dielectric layer and the thickness d22 of the second dielectric layer, d21-d22, is 3 to 30 nm.

摘要翻译： 本发明提供了一种透明导电膜，其中即使在透明导电层被图案化时，图案部分和图案开口部分之间的可见性差也保持较小。 透明导电膜在透明膜基板上依次具有第一电介质层，第二电介质层和透明导电层，第一电介质层的厚度d21大于第二电介质层的厚度d22， 第一电介质层的厚度d21为8〜40nm，第二电介质层的厚度d22为5〜25nm，第一电介质层的厚度d21与第二电介质层的厚度d22之差d21 -d22，为3〜30nm。

公开(公告)号：US09297066B2

公开(公告)日：2016-03-29

申请号：US13559041

申请日：2012-07-26

申请人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

发明人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

IPC分类号： C23C14/56 ,  C23C14/02

CPC分类号： C23C16/44 ,  C23C14/021 ,  C23C14/562 ,  C23C16/06 ,  C23C16/56 ,  Y10T428/31678

摘要： The film formation method comprises the steps of: unrolling and feeding an elongated substrate wound in a roll form from a first roll chamber in a direction from the first roll chamber toward a second roll chamber, using a first surface as a surface for film formation; degassing the fed substrate; forming a first material film on the first surface of the degassed substrate in a first film formation chamber; forming a second material film on the first material film in a second film formation chamber; taking up the substrate in a roll form in the second roll chamber, the substrate having the material films formed thereon; unrolling and feeding the taken up substrate from the first roll chamber in the direction, using a second surface opposite the first surface of the substrate as a surface for film formation; and repeating all the above treatments.

摘要翻译： 成膜方法包括以下步骤：使用第一表面作为成膜表面，从第一辊室向第一辊室向第二辊室展开卷绕并卷绕成辊状的细长基材; 对进料基材进行脱气; 在第一成膜室中在脱气基板的第一表面上形成第一材料膜; 在第二成膜室中在第一材料膜上形成第二材料膜; 在第二辊室中以辊状卷取基板，其中形成有材料膜的基板; 使用与基板的第一表面相对的第二表面作为成膜的表面，使卷取的基板从第一辊室沿着该方向展开和进给; 并重复所有上述处理。

公开(公告)号：US09249503B2

公开(公告)日：2016-02-02

申请号：US13559094

申请日：2012-07-26

申请人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

发明人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

IPC分类号： C23C14/56

CPC分类号： C23C14/562 ,  Y10T428/31678

摘要： The film formation method comprises the steps of: unrolling and feeding an elongated substrate wound in a roll form from a first roll chamber in a first direction from the first roll chamber toward a second roll chamber, using a first surface as a surface for film formation; degassing the substrate fed in the first direction; forming a second material film on the first surface of the substrate in a second film formation chamber; taking up the substrate in a roll form in the second roll chamber, the substrate having the second material film formed thereon; unrolling and feeding the substrate from the second roll chamber in a second direction from the second roll chamber toward the first roll chamber; forming a first material film on the second material film in a first film formation chamber; taking up the substrate in a roll form in the first roll chamber.

摘要翻译： 成膜方法包括以下步骤：使用第一表面作为成膜表面，从第一辊室向第二辊室，以第一方向从第一辊室开始卷绕并卷绕成卷状的细长衬底 ; 对沿第一方向进给的基板进行脱气; 在第二成膜室中在所述基板的第一表面上形成第二材料膜; 在第二辊室中以辊状卷取基板，其上形成有第二材料膜的基板; 从第二辊室朝向第一辊室从第二辊室向第二方向展开和供给衬底; 在第一成膜室中在第二材料膜上形成第一材料膜; 在第一辊室中以辊状卷取基材。

公开(公告)号：US09243320B2

公开(公告)日：2016-01-26

申请号：US13559155

申请日：2012-07-26

申请人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

发明人： Tomotake Nashiki ,  Yoshimasa Sakata ,  Hideo Sugawara ,  Kenkichi Yagura ,  Akira Hamada ,  Yoshihisa Ito ,  Kuniaki Ishibashi

IPC分类号： C23C14/56

CPC分类号： C23C14/562 ,  Y10T428/31678

摘要： The film formation method comprises the steps of: unrolling and feeding an elongated substrate wound in a roll form from a first roll chamber in a first direction from the first roll chamber toward a second roll chamber; degassing the fed substrate; forming a first material film on a first surface in a first film formation chamber; guiding the substrate having the first material film formed thereon to a second film formation chamber in a second direction from the second roll chamber toward the first roll chamber; forming, in the second film formation chamber, a second material film on a second surface opposite the first surface of the substrate when it is being guided in the second direction; taking up, in a third roll chamber provided between the first roll chamber and the second roll chamber, the substrate in a roll state.

摘要翻译： 成膜方法包括以下步骤：从第一方向从第一辊室向第二辊室展开卷绕并卷绕成卷状的细长基材从第一辊室; 对进料基材进行脱气; 在第一成膜室中的第一表面上形成第一材料膜; 将其上形成有第一材料膜的基板从第二辊室朝向第一辊室沿第二方向引导到第二成膜室; 在所述第二成膜室中，当在所述第二方向上被引导时，在与所述基板的所述第一表面相对的第二表面上形成第二材料膜; 在设置在第一辊室和第二辊室之间的第三辊室中卷绕处于辊状态的基板。