Poly(ester-carbonate)s, articles formed therefrom, and methods of manufacture

    公开(公告)号:US10899877B2

    公开(公告)日:2021-01-26

    申请号:US16095755

    申请日:2017-04-28

    Abstract: A poly(carbonate-ester) copolymer including carbonate units of the formula (I); and ester units of the formula (II) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; and R1 and J are each independently a bisphenol A divalent group, or a phthalimidine divalent group or a third divalent group of the formula (III), (IV), (V), (VI) or (VII) wherein Xa is a C6-12 polycyclic aryl, C3-18 mono- or polycycloalkylene, C3-18 mono- or polycycloalkylidene, -(Q1)x-G-(Q2)y- group wherein Q1 and Q2 are each independently a C1-3 alkylene, G is a C3-10 cycloalkylene, x is 0 or 1, and y is 1, provided that the at least one bisphenol A divalent group, at least one phthalimidine divalent group, and at least one third divalent group are present in the poly(carbonate-ester) copolymer.

    Poly(ester-carbonate) copolymers, articles formed therefrom, and methods of manufacture

    公开(公告)号:US10370487B2

    公开(公告)日:2019-08-06

    申请号:US16096502

    申请日:2017-04-28

    Abstract: A poly(ester-carbonate) copolymer comprises carbonate units of the formula (I); and ester units of the formula (II) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; and R1 and J are each independently (a) a bisphenol A divalent group and (b) a C16 or higher divalent group (b), wherein the C16 or higher divalent group is present in an amount of 40 to 50 mol %; the ester units are present in an amount of 40 to 60 mol %; the poly(ester-carbonate) copolymer has a weight average molecular weight of 18,000 to 24,000 Daltons; and a sample of the composition has a glass transition temperature of 210° C. to 235° C. as determined by differential scanning calorimetry (DSC) as per ASTM D3418 with a 20° C./min heating rate; and a melt viscosity of less than 1050 Pa-s at 644 sec-1 and 350° C., determined according to ISO 11443.

    Laser weldable compositions, articles formed therefrom, and methods of manufacture

    公开(公告)号:US10456987B2

    公开(公告)日:2019-10-29

    申请号:US16096010

    申请日:2017-04-28

    Abstract: A laser weldable composition comprising a polyester component, 5 to 50 weight percent of a filler; and 10 to 30 wt. % of a poly(ester-carbonate) copolymer comprising carbonate units and ester units of the formula (I) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; R1 and J are each independently (a) a bisphenol A divalent group, and (b) a C16 or higher divalent group (b1), (b2), or (b1) and (b2), wherein (b1) is a phthalimidine divalent group, and (b2) is a third divalent group, wherein the C16 or higher divalent group (b1), (b2) or a combination of (b1) and (b2) is present in an amount of 40 mol % to 50 mol % based on the total moles of the bisphenol A divalent groups and the C16 or higher divalent group; and the composition, when molded into an article having a 2.0 mm thickness, provides a near infrared transmission at 960 nanometers of greater than 50% and a thermal resistance according to HDT 1.8 MPa flat (ISO 75/Af) is greater than 160° C.

    Compatibilized compositions, articles formed therefrom, and methods of manufacture

    公开(公告)号:US10767045B2

    公开(公告)日:2020-09-08

    申请号:US16095153

    申请日:2017-04-28

    Abstract: A melt-blend composition is formed from, based on the total weight of the melt-blend composition, 0 to 5 wt. % of an additive; and 95 to 100 wt. % of a polymer composition, wherein the polymer composition comprises, based on the total weight of the polymer composition, 5 to 95 wt. % of a first copolycarbonate consisting of bisphenol A carbonate units and first additional carbonate units of the formula (II), (II), (III), (IV) or (V); 95 to 5 wt. % of a second copolycarbonate consisting of bisphenol A carbonate units and second additional carbonate units (phthalimidine carbonate units); and 0.001 to 0.1 wt. % of a transesterification catalyst, wherein the melt-blended composition has a haze of less than 15% and a transmission greater than 75%, each measured using the color space CIE1931 (Illuminant C and a 2° observer) at a 3.2 mm thickness.

    Thermoplastic composition and laser-welded article

    公开(公告)号:US10370533B2

    公开(公告)日:2019-08-06

    申请号:US15307945

    申请日:2015-05-19

    Inventor: Tony Farrell

    Abstract: A composition includes specific amounts of an amorphous polycarbonate, a partially crystalline polyester, and an ultraviolet absorbing agent comprising a hydroxyaryl group and a hydrogen-bond accepting group. The ultraviolet absorbing agent has a lambda-max less than 400 nanometers. The composition excludes white pigments, and colorants having a lambda-max of 400 to 700 nanometers. The composition is useful for forming a near infrared laser-transmissive part in a laser welded article that further includes a near infrared laser-absorbing part.

Patent Agency Ranking