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公开(公告)号：US20110137098A1
公开(公告)日：2011-06-09
申请号：US12961308
申请日：2010-12-06
申请人： STEFFEN TSCHIRSCHWITZ , Stephan Deuerlein , Jochen Bürkle , Markus Schmitt , Steffen Oehlenschläger , Kathrin Wissel-Stoll , Veronika Wloka
发明人： STEFFEN TSCHIRSCHWITZ , Stephan Deuerlein , Jochen Bürkle , Markus Schmitt , Steffen Oehlenschläger , Kathrin Wissel-Stoll , Veronika Wloka
IPC分类号： C07C5/29
CPC分类号： C07C5/2789 , C07C5/29 , C07C2527/126 , C07C13/18
摘要： A process for isomerizing a saturated hydrocarbon, by performing the isomerization in the presence of a superacidic ionic liquid comprising an organic cation and an inorganic anion, where the anion is a superacidic aluminum trichloride-Lewis base adduct, and of an olefin.
摘要翻译： 通过在包含有机阳离子和无机阴离子的超酸离子液体存在下进行异构化的方法使饱和烃异构化，其中阴离子是超酸性三氯化铝 - 路易斯碱加合物和烯烃。
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公开(公告)号：US20110137097A1
公开(公告)日：2011-06-09
申请号：US12961281
申请日：2010-12-06
申请人： STEFFEN TSCHIRSCHWITZ , Stephan Deuerlein , Jochen Bürkle , Markus Schmitt , Michael Schreiber , Steffen Oehlenschläger
发明人： STEFFEN TSCHIRSCHWITZ , Stephan Deuerlein , Jochen Bürkle , Markus Schmitt , Michael Schreiber , Steffen Oehlenschläger
IPC分类号： C07C5/29
CPC分类号： C07C5/29 , C07C2523/72 , C07C2527/126 , C07C2531/02 , C07C13/18
摘要： A process for isomerizing a saturated, branched and cyclic hydrocarbon, in which a tertiary carbon atom of the hydrocarbon is converted to a secondary carbon atom in the course of isomerization, by performing the isomerization in the presence of a superacidic ionic liquid comprising an organic cation and an inorganic anion, where the anion is a superacidic aluminum trichloride-Lewis base adduct, and of a copper(II) compound.
摘要翻译： 一种使异构化过程中烃的叔碳原子转化为仲碳原子的饱和，支链和环状烃的异构化方法，该方法是在含有有机阳离子的超酸离子液体存在下进行异构化 和无机阴离子，其中阴离子是超酸性三氯化铝 - 路易斯碱加合物和铜（II）化合物。
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公开(公告)号：US08410327B2
公开(公告)日：2013-04-02
申请号：US12961281
申请日：2010-12-06
申请人： Steffen Tschirschwitz , Stephan Deuerlein , Jochen Bürkle , Markus Schmitt , Michael Schreiber , Steffen Oehlenschläger
发明人： Steffen Tschirschwitz , Stephan Deuerlein , Jochen Bürkle , Markus Schmitt , Michael Schreiber , Steffen Oehlenschläger
IPC分类号： C07C2/42
CPC分类号： C07C5/29 , C07C2523/72 , C07C2527/126 , C07C2531/02 , C07C13/18
摘要： A process for isomerizing a saturated, branched and cyclic hydrocarbon, in which a tertiary carbon atom of the hydrocarbon is converted to a secondary carbon atom in the course of isomerization, by performing the isomerization in the presence of a superacidic ionic liquid comprising an organic cation and an inorganic anion, where the anion is a superacidic aluminum trichloride-Lewis base adduct, and of a copper(II) compound.
摘要翻译： 一种使异构化过程中烃的叔碳原子转化为仲碳原子的饱和，支链和环状烃的异构化方法，该方法是在含有有机阳离子的超酸离子液体存在下进行异构化 和无机阴离子，其中阴离子是超酸性三氯化铝 - 路易斯碱加合物和铜（II）化合物。
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公开(公告)号：US09376457B2
公开(公告)日：2016-06-28
申请号：US13225046
申请日：2011-09-02
申请人： Stephan Deuerlein , Imme Domke , Alexej Michailovski , Reinhold Rieger , Piyada Charoensirisomboon , Christian Eichholz , Robert Bayer
发明人： Stephan Deuerlein , Imme Domke , Alexej Michailovski , Reinhold Rieger , Piyada Charoensirisomboon , Christian Eichholz , Robert Bayer
CPC分类号： C07F7/1804 , C07B2200/11 , H01F1/0054
摘要： The present invention relates to a stable mixture comprising surface-modified particles which are obtained by reacting metal oxide or semimetal oxide particles with at least one compound selected from among silicon-comprising compounds bearing one, two or three alkoxy radicals and at least one solvent, at least one surface-active substance or a mixture thereof, the use of these particles in systems in which they are brought into contact with at least one solvent, where the mass ratio of solvent to modified particle is greater than 500, and also the use of these particles in agglomeration-deagglomeration cycles.
摘要翻译： 本发明涉及包含表面改性颗粒的稳定混合物，其通过使金属氧化物或半金属氧化物颗粒与至少一种选自含有一个，两个或三个烷氧基的含硅化合物和至少一种溶剂的化合物反应而获得， 至少一种表面活性物质或其混合物，在与溶剂与改性颗粒的质量比大于500的至少一种溶剂接触的体系中使用这些颗粒，以及使用 的这些颗粒在聚集 - 解聚周期中。
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公开(公告)号：US08993819B2
公开(公告)日：2015-03-31
申请号：US13545446
申请日：2012-07-10
CPC分类号： C07C6/04 , C07C2531/22 , C07C2601/18 , Y02P20/127 , C07C13/24
摘要： The present invention provides a process for preparing cycloheptene and derivatives thereof by ring-closing metathesis of unsymmetric 1,8-dienes whose C—C double bond at the 8 position is nonterminal. Cycloheptene and the cycloheptanone, cycloheptylamine, cycloheptanecarbaldehyde, cycloheptanecarboxylic acid and cycloheptanecarbonyl chloride conversion products thereof, and the derivatives thereof, are important synthesis units for active ingredient compounds. The ring-closing metathesis is preferably performed as a reactive distillation. The unsymmetric 1,8-dienes for the ring-closing metathesis can be obtained by catalytic decarbonylation or oxidative decarboxylation from the corresponding unsaturated carboxylic acids or carboxylic acid derivatives.
摘要翻译： 本发明提供了一种通过非对称1,8-二烯的闭环复分解来制备环庚烯及其衍生物的方法，其中8位的C-C双键是非末端的。 环庚烯和环庚酮，环庚胺，环庚烷甲醛，环庚烷羧酸和环庚烷碳酰氯的转化产物及其衍生物是活性成分化合物的重要合成单元。 闭环复分解优选作为反应蒸馏进行。 用于闭环复分解的不对称1,8-二烯可以通过相应的不饱和羧酸或羧酸衍生物的催化脱羰或氧化脱羧获得。
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公开(公告)号：US08933262B2
公开(公告)日：2015-01-13
申请号：US13479961
申请日：2012-05-24
申请人： Eckhard Stroefer , Otto Machhammer , Stefan Bitterlich , Roman Prochazka , Mario Emmeluth , Julia Leschinski , Emmanouil Pantouflas , Dirk Klingler , Stephan Deuerlein , Stephan Schunk , Jochem Henkelmann , Dieter Stützer
发明人： Eckhard Stroefer , Otto Machhammer , Stefan Bitterlich , Roman Prochazka , Mario Emmeluth , Julia Leschinski , Emmanouil Pantouflas , Dirk Klingler , Stephan Deuerlein , Stephan Schunk , Jochem Henkelmann , Dieter Stützer
IPC分类号： C07C263/00 , C07C263/10
CPC分类号： C07C263/10 , C07C265/14
摘要： The present invention relates to a process for preparing polyisocyanates from natural raw material sources, in which a composition comprising low molecular weight aromatics which comprise at least one hydroxy group or at least one alkoxy group per molecule (oxyaromatics) is produced from a biomass material, these oxyaromatics are converted into the corresponding aromatic amines and, optionally after condensation with formaldehyde, reacted further with phosgene to give compounds comprising isocyanate groups.
摘要翻译： 本发明涉及一种由天然原料来制备多异氰酸酯的方法，其中包括每分子含有至少一个羟基或至少一个烷氧基的含低分子量芳族化合物的组合物（氧化芳族化合物）由生物质材料制备， 这些氧化芳烃转化为相应的芳族胺，并且任选地在与甲醛缩合后，与光气进一步反应，得到包含异氰酸酯基团的化合物。
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公开(公告)号：US08568677B2
公开(公告)日：2013-10-29
申请号：US13271550
申请日：2011-10-12
CPC分类号： B01D53/8628 , B01D53/9413 , B01D2251/202 , B01D2251/204 , B01D2251/206 , B01D2251/208 , B01D2251/506 , B01D2255/207 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/50 , B01D2257/402 , B01D2257/404 , B01D2258/0283 , C07C51/42 , Y02C20/10 , Y02P20/153 , Y02P20/328 , Y02P20/51 , C07C55/14
摘要： The present invention relates to the use of a zeolite catalyst comprising at least one transition metal and in addition sulfur and/or phosphorus atoms for reducing the content of nitrogen oxides in a gas, and also to a process for reducing the content of nitrogen oxides in a gas by bringing this gas into contact with such a zeolite catalyst.
摘要翻译： 本发明涉及包含至少一种过渡金属和另外的硫和/或磷原子的沸石催化剂用于降低气体中氮氧化物含量的用途，还涉及一种降低氮氧化物含量的方法 通过使这种气体与这种沸石催化剂接触而产生气体。
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公开(公告)号：US20120087851A1
公开(公告)日：2012-04-12
申请号：US13271550
申请日：2011-10-12
IPC分类号： B01D53/56
CPC分类号： B01D53/8628 , B01D53/9413 , B01D2251/202 , B01D2251/204 , B01D2251/206 , B01D2251/208 , B01D2251/506 , B01D2255/207 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/50 , B01D2257/402 , B01D2257/404 , B01D2258/0283 , C07C51/42 , Y02C20/10 , Y02P20/153 , Y02P20/328 , Y02P20/51 , C07C55/14
摘要： The present invention relates to the use of a zeolite catalyst comprising at least one transition metal and in addition sulfur and/or phosphorus atoms for reducing the content of nitrogen oxides in a gas, and also to a process for reducing the content of nitrogen oxides in a gas by bringing this gas into contact with such a zeolite catalyst.
摘要翻译： 本发明涉及包含至少一种过渡金属和另外的硫和/或磷原子的沸石催化剂用于降低气体中氮氧化物含量的用途，还涉及一种降低氮氧化物含量的方法 通过使这种气体与这种沸石催化剂接触而产生气体。
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公开(公告)号：US09024050B2
公开(公告)日：2015-05-05
申请号：US13434176
申请日：2012-03-29
申请人： Stephan Deuerlein , Imme Domke , Alexej Michailovski , Reinhold Rieger , Piyada Charoensirisomboon , David F. Blackwood , Christian Eichholz , Robert Bayer , Dennis Loesch , Igor Shishkov
发明人： Stephan Deuerlein , Imme Domke , Alexej Michailovski , Reinhold Rieger , Piyada Charoensirisomboon , David F. Blackwood , Christian Eichholz , Robert Bayer , Dennis Loesch , Igor Shishkov
CPC分类号： C07F7/0836 , H01F1/0054
摘要： The present invention relates to a stable mixture comprising surface-modified particles which are obtained by reacting metal oxide or semimetal oxide particles with at least one compound selected from among silicon-comprising compounds bearing at least one metaloxy radical and optionally further alkoxy and/or hydroxy radical(s) and at least one solvent, at least one surface-active substance or a mixture thereof, a process for producing the mixture, the use of these particles in systems in which they are brought into contact with at least one solvent, where the mass ratio of solvent to modified particle is greater than 500, and also the use of these particles in agglomeration-deagglomeration cycles.
摘要翻译： 本发明涉及包含表面改性颗粒的稳定混合物，其通过使金属氧化物或半金属氧化物颗粒与至少一种选自含有至少一个金属氧基的含硅化合物和任选的其它烷氧基和/或羟基的化合物反应而获得 自由基和至少一种溶剂，至少一种表面活性物质或其混合物，制备该混合物的方法，在与至少一种溶剂接触的体系中使用这些颗粒，其中 溶剂与改性颗粒的质量比大于500，并且还使用这些颗粒在聚集 - 解聚缩循环中。
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公开(公告)号：US20130018205A1
公开(公告)日：2013-01-17
申请号：US13545446
申请日：2012-07-10
IPC分类号： C07C4/10 , C07C209/22 , C07C1/22 , C07C51/235 , C07C51/60 , C07C45/34 , C07C51/00
CPC分类号： C07C6/04 , C07C2531/22 , C07C2601/18 , Y02P20/127 , C07C13/24
摘要： The present invention provides a process for preparing cycloheptene and derivatives thereof by ring-closing metathesis of unsymmetric 1,8-dienes whose C—C double bond at the 8 position is nonterminal. Cycloheptene and the cycloheptanone, cycloheptylamine, cycloheptanecarbaldehyde, cycloheptanecarboxylic acid and cycloheptanecarbonyl chloride conversion products thereof, and the derivatives thereof, are important synthesis units for active ingredient compounds. The ring-closing metathesis is preferably performed as a reactive distillation. The unsymmetric 1,8-dienes for the ring-closing metathesis can be obtained by catalytic decarbonylation or oxidative decarboxylation from the corresponding unsaturated carboxylic acids or carboxylic acid derivatives.
摘要翻译： 本发明提供了一种通过非对称1,8-二烯的闭环复分解来制备环庚烯及其衍生物的方法，其中8位的C-C双键是非末端的。 环庚烯和环庚酮，环庚胺，环庚烷甲醛，环庚烷羧酸和环庚烷碳酰氯的转化产物及其衍生物是活性成分化合物的重要合成单元。 闭环复分解优选作为反应蒸馏进行。 用于闭环复分解的不对称1,8-二烯可以通过相应的不饱和羧酸或羧酸衍生物的催化脱羰或氧化脱羧获得。
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