Selective xylenes isomerization and ethylbenzene conversion
    1.
    发明授权
    Selective xylenes isomerization and ethylbenzene conversion 失效
    选择性二甲苯异构化和乙苯转化

    公开(公告)号:US06355853B1

    公开(公告)日:2002-03-12

    申请号:US09511936

    申请日:2000-02-24

    IPC分类号: C07C527

    摘要: This invention is drawn to a process for isomerizing a non-equilibrium mixture of xylenes and ethylbenzene using a catalyst comprising a zeolite, a platinum-group metal and a silica binder, resulting in a greater yield of para-xylene at favorable conditions compared to processes of the known art.

    摘要翻译: 本发明涉及使用包含沸石,铂族金属和二氧化硅粘合剂的催化剂使二甲苯和乙苯的非平衡混合物异构化的方法,在有利条件下与步骤相比,产生更高的对二甲苯收率 的已知艺术。

    Solid acid catalyst
    3.
    发明授权
    Solid acid catalyst 有权
    固体酸催化剂

    公开(公告)号:US08314045B1

    公开(公告)日:2012-11-20

    申请号:US12913618

    申请日:2010-10-27

    摘要: A porous solid acid catalyst having high concentration of acidic sites and a large surface area includes a porous silica support and a sulfonated carbon layer disposed within the pores of the silica support. The catalyst, in certain embodiments, has a concentration of —SO3H groups of at least about 0.5 mmol/g and a predominant pore size of at least about 300 Å. The catalyst is used to catalyze a variety of acid-catalyzed reactions, including but not limited to alkylation, acylation, etherification, olefin hydration and alcohol dehydration, dimerization of olefin and bicyclic compounds, esterification and transesterification. For example, the catalyst can be used to catalyze esterification of free fatty acids (FFAs) and, in certain embodiments, to catalyze transesterification of triglycerides in fats and oils. The catalyst is prepared by impregnating a silica support with a phenol-containing material, processing the material to form a polymer, carbonizing the polymer to form a carbon layer within the silica support, and sulfonating the resulting carbon layer to form sulfonated carbon.

    摘要翻译: 具有高浓度酸性位点和大表面积的多孔固体酸催化剂包括多孔二氧化硅载体和设置在二氧化硅载体的孔内的磺化碳层。 在某些实施方案中,催化剂具有至少约0.5mmol / g的-SO 3 H基团浓度和至少约300A的主要孔径。 催化剂用于催化各种酸催化反应,包括但不限于烷基化,酰化,醚化,烯烃水合和醇脱水,烯烃和双环化合物的二聚,酯化和酯交换。 例如,催化剂可用于催化游离脂肪酸(FFA)的酯化,并且在某些实施方案中催化甘油三酯在脂肪和油中的酯交换。 催化剂是通过用含苯酚的材料浸渍二氧化硅载体,加工该材料以形成聚合物,碳化聚合物以在二氧化硅载体内形成碳层并磺化所得的碳层以形成磺化碳来制备的。

    Apparatus for dispensing particulate material
    6.
    发明授权
    Apparatus for dispensing particulate material 失效
    用于分配颗粒材料的装置

    公开(公告)号:US5950694A

    公开(公告)日:1999-09-14

    申请号:US34688

    申请日:1998-03-04

    摘要: A dispensing apparatus for particulate matter which distributes the particulate matter, at substantially the same rate, uniformly across a given area of a vessel and comprises a particle container having an opening at one end for receiving particulate material into an upwardly directed end and an outlet end at an opposite end for flowing particulate material. A rotor having multiple elongated, hollow arms, an opening at one end for receiving particulate material from the particle container, the multiple arms each having at least one aperture located in a lower portion thereof for discharging particulate material, wherein the rotor is rotatably positioned below and adjacent to the outlet end of the particle container to permit the flow of particulate material from the particle container to the rotor. A baffle plate having multiple elongated leaves, rotatably positioned around a vertical central axis of the rotor and having dimensions capable of reducing the flow of particulate material from the rotor apertures is located in close proximity to each of the apertures of the rotor. A fastening member is provided on the rotor for releasably fastening the baffle plate to the rotor. A rotating member is also provided for rotating the rotor in communication with the particle container in order to evenly distribute particulate matter on a bed below.

    摘要翻译: 一种用于颗粒物质的分配装置,其以基本相同的速率均匀地分布在容器的给定区域上,并且包括在一端具有开口的颗粒容器,用于将颗粒材料接收到向上指向的端部和出口端 在另一端用于流动颗粒材料。 具有多个细长的空心臂的转子,一端的开口用于从颗粒容器接收颗粒材料,多个臂各自具有位于其下部的至少一个孔,用于排出颗粒材料,其中转子可旋转地定位在下方 并且与颗粒容器的出口端相邻,以允许颗粒材料从颗粒容器流到转子。 具有多个细长叶片的挡板,其可旋转地定位在转子的垂直中心轴线周围并且具有能够减小颗粒材料从转子孔的流动的尺寸位于转子的每个孔附近。 在转子上设有紧固件,用于将挡板可释放地固定到转子上。 还提供旋转构件,用于使转子与颗粒容器连通,以将颗粒物质均匀地分布在下面的床上。