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公开(公告)号：US06224748B1
公开(公告)日：2001-05-01
申请号：US08169107
申请日：1993-12-20
IPC分类号： C10G4702
CPC分类号： C07C5/2724 , B01J21/06 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C01P2002/54 , C07C5/2791 , C10G2400/10 , C07C9/00 , C07C9/16
摘要： A process for hydrocracking heavy, high aromatic content feeds, such as cycle oil, using a catalyst composition containing a hydrogenation/dehydrogenation component, such as a noble metal, and an acidic solid component including a Group IVB metal oxide modified with an oxyanion of a Group VIB metal.
摘要翻译： 使用包含氢化/脱氢组分如贵金属的催化剂组合物和包含用氧阴离子改性的IVB族金属氧化物的酸性固体组分加氢裂化重质，高芳族化合物进料如循环油的方法， VIB族金属。
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公开(公告)号：US6162757A
公开(公告)日：2000-12-19
申请号：US357546
申请日：1999-07-20
CPC分类号： B01J37/03 , B01J21/066 , B01J23/10 , C07C5/2705 , C07C2521/06 , C07C9/00
摘要： A novel synthesis composition of a solid acid containing zirconium, in addition to a rare earth element, such as cerium, has the potential for catalytic conversions of hydrocarbons, especially for isomerization of paraffins, ring opening of cyclics, hydrocracking, alkylation, hydrogenation of polynuclear aromatics, selective catalytic reduction of nitrogen oxides, and oligomerization of light olefins.
摘要翻译： 含有锆的固体酸的新型合成组合物除了稀土元素如铈之外，具有烃的催化转化的潜力，特别是对于链烷烃的异构化，环化开环，加氢裂化，烷基化，多核氢化 芳族化合物，氮氧化物的选择性催化还原和轻质烯烃的低聚。
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公开(公告)号：US5543036A
公开(公告)日：1996-08-06
申请号：US167108
申请日：1993-12-16
IPC分类号： B01J21/06 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , C01G25/02 , C07C5/27 , C10G67/04 , C10G17/00 , C10G17/095 , C10G45/04
CPC分类号： B01J21/06 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C07C5/2724 , C07C5/2791 , C01P2002/54 , C10G2400/10
摘要： A process for hydrotreating a hydrocarbon feedstock, such as light cycle oil, using a catalyst composition containing a hydrogenation/dehydrogenation component and an acidic solid component including a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. The hydrotreating process removes contaminants, such as sulfur and/or nitrogen, from the feedstock.
摘要翻译： 使用包含氢化/脱氢组分的催化剂组合物和包含用VIB族金属的氧阴离子改性的IVB族金属氧化物的酸性固体组分对烃原料如轻质循环油进行加氢处理的方法。 加氢处理工艺从原料中除去污染物，如硫和/或氮。
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公开(公告)号：US5126296A
公开(公告)日：1992-06-30
申请号：US614345
申请日：1990-11-16
申请人： Scott Han , Clarence D. Chang
发明人： Scott Han , Clarence D. Chang
CPC分类号： B01J37/26 , B01J29/405 , B01J2229/183
摘要： A method for enhancing the activity of a porous crystalline zeolite having a framework silica-to-alumina mole ratio of 25 or more which comprises contacting the zeolite with a solution comprising a hydrate of trivalent metal fluoride in aqueous media under conditions sufficient to cause incorporation of said metal in the framework of said zeolite.
摘要翻译： 一种增强框架二氧化硅 - 氧化铝摩尔比为25或更高的多孔结晶沸石的活性的方法，其包括使沸石与包含三价金属氟化物的水合物的溶液在水性介质中接触，所述条件足以引起 所述金属在所述沸石的骨架中。
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公开(公告)号：US5453556A
公开(公告)日：1995-09-26
申请号：US264089
申请日：1994-06-22
CPC分类号： C10G50/02 , C07C2/10 , C07C2521/06 , C07C2523/30
摘要： There is provided an oligomerization process. The process involves the use of a catalyst comprising an acidic solid. The acidic solid may comprise a Group IVB metal oxide, such as zirconia, modified with an oxyanion of a Group VIB metal, such as tungsten. The oligomers produced by this process may be hydrogenated to produce thermally stable lubricants and lubricant additives.
摘要翻译： 提供了低聚方法。 该方法包括使用包含酸性固体的催化剂。 酸性固体可以包含用VIB族金属如钨的氧阴离子改性的IVB族金属氧化物，例如氧化锆。 通过该方法制备的低聚物可以被氢化以产生热稳定的润滑剂和润滑剂添加剂。
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6.发明授权Process for reducing the durene content of effluent resulting from the catalytic conversion of C.sub.1 -C.sub.4 oxygenates to gasoline 失效降低由C1-C4含氧化合物催化转化成汽油所产生的流出物的杜烯含量的方法
公开(公告)号：US4973784A
公开(公告)日：1990-11-27
申请号：US449169
申请日：1989-12-13
申请人： Scott Han , Clarence D. Chang
发明人： Scott Han , Clarence D. Chang
CPC分类号： B01J29/04 , C07C2/12 , C07C2529/70
摘要： A reduction in the durene content of an effluent resulting from the zeolite-catalyzed conversion of a C.sub.1 -C.sub.4 oxygenate such as methanol to gasoline is disclosed wherein either the total effluent from said conversion or a bottoms fraction thereof containing durene is contacted with a particular zeolite catalyst to convert said durene to other products.
摘要翻译： 公开了由C1-C4含氧化合物如甲醇沸石催化转化为汽油的流出物的杜烯含量的降低，其中来自所述转化的总流出物或其含有杜烯的塔底馏分与特定的沸石接触 将所述杜烯转化成其它产物的催化剂。
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公开(公告)号：US4943545A
公开(公告)日：1990-07-24
申请号：US258090
申请日：1988-10-14
申请人： Clarence D. Chang , Scott Han , Bruce P. Pelrine
发明人： Clarence D. Chang , Scott Han , Bruce P. Pelrine
CPC分类号： B01J29/40 , B01J29/084 , B01J29/90 , B01J2229/42 , Y10S423/22 , Y10S423/23 , Y10S423/27 , Y10S423/29 , Y10S423/33 , Y10S423/36
摘要： Zeolitic catalysts containing framework displaced aluminum, e.g., steamed or spent catalysts, are activated by contact with aqueous fluoride solution under mild conditions. The treatment can enhance catalytic activity, ion-exchange capacity and crystallinity by replacing aluminum in the zeolitic framework.
摘要翻译： 含有骨架置换铝的沸石催化剂，例如蒸汽或废催化剂，通过在温和条件下与氟化钠水溶液接触来活化。 该处理可以通过在沸石框架中代替铝来提高催化活性，离子交换容量和结晶度。
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8.发明授权Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index 失效改性结晶硅铝酸盐沸石催化剂及其在生产高黏度指数的润滑剂中的应用
公开(公告)号：US4876411A
公开(公告)日：1989-10-24
申请号：US27034
申请日：1987-03-19
申请人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
发明人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
IPC分类号： C10G50/02
CPC分类号： C10G50/02
摘要： The present invention provides a process for modifying a crystalline aluminosilicate zeolite having a Constraint Index of from about to about 12 which comprises:(a) steaming the as synthesized crytalline aluminosilicate zeolite containing organic template material to decompose at least a portion of said template material and to extract zeolitic aluminum; and,(b) contacting the zeolite resulting from step (a) in the ammonium, alkali metal or hydrogen form with a dealuminizing agent which forms a water-soluble complex with aluminum to remove a further quantity of zeolitic aluminum therefrom wherein said treated catalyst is employed in the making of lube oil from olefins.
摘要翻译： 本发明提供了一种修饰约约至约12的约束指数的结晶硅铝酸盐沸石的方法，该方法包括：（a）蒸煮含有有机模板材料的合成的胆固醇铝硅酸盐沸石，以分解所述模板材料的至少一部分，以及 提取沸石铝; 和（b）将由步骤（a）得到的沸石以铵，碱金属或氢的形式与脱铝剂接触，脱铝剂与铝形成水溶性络合物，以从中除去另外量的沸石铝，其中所述处理过的催化剂为 用于从烯烃制备润滑油。
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公开(公告)号：US5449847A
公开(公告)日：1995-09-12
申请号：US228772
申请日：1994-04-18
CPC分类号： C07C2/74 , C07C2101/14 , C07C2521/06 , C07C2523/30 , C07C2523/42
摘要： There is provided a process for preparing tercyclohexane by reacting benzene with hydrogen. The process involves the use of a catalyst comprising an acidic solid and a hydrogenation component. The acidic solid may comprise a Group IVB metal oxide, such as zirconia, modified with an oxyanion of a Group VIB metal, such as tungsten. The hydrogenation component may comprise platinum.
摘要翻译： 提供了一种通过使苯与氢反应制备三环己烷的方法。 该方法包括使用包含酸性固体和氢化组分的催化剂。 酸性固体可以包含用VIB族金属如钨的氧阴离子改性的IVB族金属氧化物，例如氧化锆。 氢化组分可以包含铂。
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公开(公告)号：US5173461A
公开(公告)日：1992-12-22
申请号：US497046
申请日：1990-03-21
申请人： Robert P. Absil , Scott Han , David S. Shihabi , David O. Marler , Clarence D. Chang , Donna M. Mitko
发明人： Robert P. Absil , Scott Han , David S. Shihabi , David O. Marler , Clarence D. Chang , Donna M. Mitko
CPC分类号： B01J29/40 , C07C6/126 , B01J2229/12 , B01J2229/26 , B01J2229/32 , B01J2229/42 , C07C2529/40
摘要： A catalyst comprising a molecular sieve having a lattice aluminum content in which the silica/alumina framework mole ratio is less than 55, and having a diffusion rate constant of less than about 150 sec.sup.-1 .times.10.sup.-6 is particularly useful for vapor-phase disproportionation of toluene.
摘要翻译： 包含具有格子铝含量的分子筛的催化剂，其二氧化硅/氧化铝骨架摩尔比小于55，并且具有小于约150秒-1×10 -6的扩散速率常数特别适用于气相歧化 甲苯。
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