公开(公告)号：US06288290B1

公开(公告)日：2001-09-11

申请号：US09420860

申请日：1999-10-19

申请人： Seiichi Teshima ,  Masayoshi Konishi ,  Kozo Tajiri ,  Yoshinobu Asako ,  Sadao Miki

发明人： Seiichi Teshima ,  Masayoshi Konishi ,  Kozo Tajiri ,  Yoshinobu Asako ,  Sadao Miki

IPC分类号： C07C1908

CPC分类号： C07C47/55 ,  C07B39/00 ,  C07C17/14 ,  C07C17/18 ,  C07C22/08 ,  C07C25/22 ,  C07C45/41 ,  C07C45/63 ,  C07C22/04 ,  C07C47/546

摘要： This invention relates to a method for the production of an aromatic compound (II) having a (CH2)nCX2Br group (wherein X represents a fluorine or chlorine atom and the X's may be same or different, and n is an integer in the range of 0 to 4) by the reaction of photo-bromination of an aromatic compound (I) having a (CH2)nCX2H group (wherein X and n are as defined above) with a brominating agent, wherein the photo-bromination reaction is carried out while removing hydrogen bromide generated in the reaction system and/or in an atmosphere of a low oxygen content, and a halogen-containing naphthalene compound represented by the following formula (1): wherein Y represents —CF2H, —CF2Br, or —CHO group, Z1 and Z2 independently represent a halogen atom, and p and q independently are an integer in the range of 0 to 3.

摘要翻译： 本发明涉及一种具有（CH2）nCX2Br基团的芳族化合物（II）的制备方法（其中X表示氟或氯原子，X可以相同或不同，n是在 通过使具有（CH 2）n C X 2 H基团（其中X和n如上定义的）的芳族化合物（I）与溴化剂进行光溴化反应，其中光溴化反应进行同时 除去在反应体系中和/或低氧气氛中产生的溴化氢和由下式（1）表示的含卤素的萘化合物：其中Y表示-CF 2 H，-CF 2 Br或-CHO基， Z 1和Z 2独立地表示卤原子，p和q独立地为0〜3的整数。

公开(公告)号：US06433231B1

公开(公告)日：2002-08-13

申请号：US09886805

申请日：2001-06-21

申请人： Seiichi Teshima ,  Masayoshi Konishi ,  Kozo Tajiri ,  Yoshinobu Asako ,  Sadao Miki

发明人： Seiichi Teshima ,  Masayoshi Konishi ,  Kozo Tajiri ,  Yoshinobu Asako ,  Sadao Miki

IPC分类号： C07C4700

摘要： A method for producing inexpensively in a high yield a halogen-containing aromatic compound, particularly a halogen-containing aromatic compound incorporating therein a bromodifluoroalkyl group, and a halogen-containing naphthalene compound useful as a raw material for a resin excelling in heat resistance, chemical resistance and water repellency, and having a low dielectric constant and a low refractivity are provided. This invention relates to a method for the production of an aromatic compound (II) having a (CH2)nCX2Br group (wherein X represents a fluorine or chlorine atom and the X's may be same or different, and n is an integer in the range of 0 to 4) by the reaction of photo-bromination of an aromatic compound (I) having a (CH2)nCX2H group (wherein X and n are as defined above) with a brominating agent, wherein the photo-bromination reaction is carried out while removing hydrogen bromide generated in the reaction system and/or in an atmosphere of a low oxygen content, and a halogen-containing naphthalene compound represented by the following formula (1): wherein Y represents —CF2H, —CF2Br, or —CHO group, Z1 and Z2 independently represent a halogen atom, and p and q independently are an integer in the range of 0 to 3.

公开(公告)号：US20090010603A1

公开(公告)日：2009-01-08

申请号：US11664818

申请日：2005-10-07

申请人： Takuo Sugioka ,  Yasunori Tsujino ,  Kozo Tajiri ,  Yoshinobu Asako

发明人： Takuo Sugioka ,  Yasunori Tsujino ,  Kozo Tajiri ,  Yoshinobu Asako

IPC分类号： G02B6/00 ,  C08K3/00 ,  G02B6/02

CPC分类号： C08K3/22 ,  G02B6/30 ,  G02B2006/1215

摘要： To provide to a resin composition for an optical packaging material having a coefficient of thermal expansion approximately same as that of quartz and Pyrex (registered trade name) and capable of providing an optical packaging material exhibiting excellent flame retardancy and an optical packaging component, and an optical module and its production method. A molded body, an optical packaging component and an optical module having a low coefficient of thermal expansion and excellent flame retardancy can be obtained using a resin composition for an optical packaging material comprising a resin and inorganic fine particles which are made of a hydrolyzed condensate compound of an alkoxide compound and/or a carboxylic acid salt compound and have an average radius of gyration of 50 nm or smaller.

摘要翻译： 为了提供具有与石英和Pyrex（注册商标）大致相同的热膨胀系数的光学包装材料用树脂组合物，能够提供具有优异的阻燃性的光学包装材料和光学包装成分， 光模块及其制作方法。 使用包含树脂的光学包装材料用树脂组合物和由水解缩合物化合物制成的无机细颗粒，可以获得具有低热膨胀系数和阻燃性优异的成型体，光学包装部件和光学组件 的醇盐化合物和/或羧酸盐化合物，其平均回转半径为50nm以下。

公开(公告)号：US07364771B2

公开(公告)日：2008-04-29

申请号：US10795122

申请日：2004-03-05

申请人： Kozo Tajiri ,  Shinichi Goto ,  Yoshinobu Asako ,  Kumiko Kawada

发明人： Kozo Tajiri ,  Shinichi Goto ,  Yoshinobu Asako ,  Kumiko Kawada

IPC分类号： B05D3/12

CPC分类号： C08J5/18 ,  B05D1/005 ,  C08G73/1039 ,  C08J2379/08 ,  H05K1/0346

摘要： A method for producing a fluorine-containing polyimide film excelling in heat resistance, resistance to chemicals, water repellency, dielectric properties, electrical properties, and optical properties and a spin coater suitable for the method are to be provided. A method for the production of a fluorine-containing polyimide film which comprises forming a coating film of a fluorine-containing polyimide precursor in an atmosphere having a relative humidity thereof adjusted to a level of not more than 50 RH % and then subjecting the fluorine-containing polyimide precursor to heat treatment thereby forming a fluorine-containing polyimide film is provided. By adjusting the relative humidity in accordance with this method, the fluorine-containing polyimide precursor can be prevented from being decomposed by the absorption of moisture and consequently prevent effectively the fluorine-containing polyimide film from forming piriform spots and scratches. Further, by forming the coating film while keeping the coating film sprayed with a gas particularly during the course of spin coating thereby giving rise to a layer of air flow on the coating film, misty substances of the coating solution generated within the spin coater can be prevented from adhering again to the coating film and consequently ensure the production of a coating film of uniform quality. This formation of the layer of air flow can be facilitated by providing the spin coater with a lid and furnishing the lid with a gas feed port.

摘要翻译： 本发明提供一种耐热性，耐化学品性，防水性，介电性，电性能，光学性能优异的含氟聚酰亚胺膜的制造方法和适用于该方法的旋涂机。 一种含氟聚酰亚胺薄膜的制造方法，其特征在于，在相对湿度为50％RH以下的气氛中，形成含氟聚酰亚胺前体的涂膜， 提供含有聚酰亚胺前体的热处理，从而形成含氟聚酰亚胺膜。 通过根据该方法调整相对湿度，可以防止含氟聚酰亚胺前体因吸湿而分解，从而有效地防止含氟聚酰亚胺膜形成梨状斑点和划痕。 此外，通过形成涂膜，同时特别是在旋涂过程中特别是喷涂气体的涂膜，从而在涂膜上产生空气流，在旋涂机中产生的涂布溶液中的雾状物质可以是 防止再次粘附到涂膜上，从而确保制造质量均匀的涂膜。 通过为旋转涂布机提供盖子并为盖子提供气体供给口，可以方便地形成气流层。

公开(公告)号：US20100284664A1

公开(公告)日：2010-11-11

申请号：US11886073

申请日：2006-03-10

申请人： Go Masuda ,  Kozo Tajiri ,  Tomomi Makino ,  Yoko Matsui

发明人： Go Masuda ,  Kozo Tajiri ,  Tomomi Makino ,  Yoko Matsui

IPC分类号： G02B6/00 ,  C08G69/08

CPC分类号： C08G73/1039

摘要： The invention aims to provide a method by which a solution of polyimide can be easily obtained. Further, the invention aims to provide a fluorinated polyimide solution by which fluorinated polyimide excellent especially as an optical material and an electronic functional material can easily be produced. The production method of the soluble polyimide solution according to invention is characterized by mixing a mixture containing a polyamide acid, a cyclodehydration reagent, and a solvent by a rotation-revolution mixing method. Further, the fluorinated polyimide solution of the invention is a solution of polyimide defined by the following formula (II): wherein, X and Y independently represent divalent organic groups; Z represents chlorine atom, bromine atom, or iodine atom; p represents an integer of 1 to 3; q represents an integer of 0 to 2; and p+q=3.

摘要翻译： 本发明的目的在于提供一种容易得到聚酰亚胺溶液的方法。 此外，本发明的目的在于提供一种氟化聚酰亚胺溶液，通过该氟化聚酰亚胺溶液，可以容易地制造出特别优选作为光学材料和电子功能材料的氟化聚酰亚胺。 根据本发明的可溶性聚酰亚胺溶液的制备方法的特征在于通过旋转 - 旋转混合法混合含有聚酰胺酸，环化脱水剂和溶剂的混合物。 此外，本发明的氟化聚酰亚胺溶液是由下式（II）定义的聚酰亚胺溶液：其中，X和Y独立地表示二价有机基团; Z表示氯原子，溴原子或碘原子; p表示1〜3的整数， q表示0〜2的整数， 和p + q = 3。

公开(公告)号：US06569908B2

公开(公告)日：2003-05-27

申请号：US09764910

申请日：2001-01-16

申请人： Tetsuro Noguchi ,  Kozo Tajiri

发明人： Tetsuro Noguchi ,  Kozo Tajiri

IPC分类号： B01F312

CPC分类号： C01B33/1465

摘要： The present invention also provides a process for producing a colloidal dispersion of silica particle agglomerates having a specific surface area, as determined by nitrogen adsorption method, of 100 m2/g to 400 m2/g, an average secondary particle diameter of 20 nm to 300 nm and a pore volume of 0.5 ml/g to 2.0 ml/g, which comprises using a colloidal dispersion of silica particle agglomerates having a specific surface area, as determined by nitrogen adsorption method, of 300 m2/g to 1,000 m2/g and a pore volume of 0.4 ml/g to 2.0 ml/g as a seed dispersion, adding a feed solution comprising at least one of an aqueous active silicic acid solution and alkoxysilanes to the seed dispersion in small portions in the presence of an alkali to grow silica particle agglomerates.

摘要翻译： 本发明还提供了通过氮吸附法测定的比表面积为100m 2 / g〜400m 2 / g，平均二次粒径为20nm〜300μm的二氧化硅粒子聚集体的胶体分散体的制造方法 nm，孔体积为0.5ml / g至2.0ml / g，其包括使用通过氮吸附法测定的具有比表面积的二氧化硅颗粒附聚物的胶态分散体为300m 2 / g至1,000m 2 / g，以及 将孔体积为0.4ml / g至2.0ml / g作为种子分散体，在碱存在下，将少量含有活性硅酸水溶液和烷氧基硅烷中的至少一种的进料溶液加入到种子分散体中以生长 二氧化硅颗粒附聚物。

公开(公告)号：US08218923B2

公开(公告)日：2012-07-10

申请号：US12476462

申请日：2009-06-02

申请人： Takami Ushiwata ,  Koki Hirano ,  Kozo Tajiri ,  Tomomi Makino

发明人： Takami Ushiwata ,  Koki Hirano ,  Kozo Tajiri ,  Tomomi Makino

IPC分类号： G02B6/30 ,  G02B6/12

CPC分类号： B29D11/00673 ,  G02B6/1221 ,  G02B6/13 ,  G02B6/138 ,  G02B6/423

摘要： An optical waveguide substrate with an optical fiber fixation groove, including an optical waveguide which contains a lower cladding layer on a base substrate, wherein the lower cladding layer has an optical fiber fixation groove and a core groove, and a weir is provided between the optical fiber fixation groove and the core groove. The optical waveguide substrate with an optical fiber fixation groove is produced by forming a lower cladding layer on a base substrate using a male stamp produced from a female stamp and then successively forming a core layer and an upper cladding layer thereon.

摘要翻译： 一种具有光纤固定槽的光波导基板，包括在基底基板上包含下包层的光波导，其中下包层具有光纤固定槽和芯槽，并且在光学器件之间设置有堰 纤维固定槽和芯槽。 具有光纤固定槽的光波导基板通过使用由阴印制成的公印模在基底基板上形成下包层，然后在其上依次形成芯层和上包层来制造。

公开(公告)号：US20120101213A1

公开(公告)日：2012-04-26

申请号：US13379840

申请日：2010-06-28

申请人： Kozo Tajiri ,  Go Masuda ,  Tomomi Makino ,  Atsushi Okada

发明人： Kozo Tajiri ,  Go Masuda ,  Tomomi Makino ,  Atsushi Okada

IPC分类号： C08G73/10 ,  C08K3/04 ,  C08L79/08

CPC分类号： G03G15/0233 ,  C08G73/1039 ,  C08G73/1046 ,  C08G73/1064 ,  C08L79/08 ,  C08L2203/20 ,  G03G5/0571 ,  G03G5/14765 ,  G03G15/0818 ,  G03G15/1685 ,  G03G15/2057 ,  G03G15/751

摘要： Provided are a polyimide which is inexpensive, has various excellent material properties including strength, heat resistance, low moisture absorption, mold releasability (detachability), dielectric properties, electrical properties, and optical properties, and can exhibit a high level of water repellency, and a polyamic acid composition useful as a raw material therefor. Also provided are the polyimide which can give a polyimide composition that, besides having such excellent material properties, is capable of having a controlled surface resistivity, and a polyamic acid composition useful as a raw material therefor. The polyimide is a highly water-repellent polyimide for copier members which is obtained using one or more acid dianhydrides and one or more diamine compounds, and is characterized in that at least one of the acid dianhydrides and the diamine compounds is a compound having an ether bond and/or a thioether bond in the molecule and that the total number of ether bonds and thioether bonds in the repeating unit constituting the polyimide and derived from the acid dianhydrides and the diamine compounds is 2 or larger.

摘要翻译： 提供廉价的聚酰亚胺，具有强度，耐热性，低吸湿性，脱模性（剥离性），介电特性，电性能和光学性能等各种优异的材料性能，并且可以表现出高水平的拒水性， 可用作原料的聚酰胺酸组合物。 还可以提供聚酰亚胺，其可以得到除了具有这样优异的材料性能之外还能够具有受控表面电阻率的聚酰亚胺组合物和可用作原料的聚酰胺酸组合物。 聚酰亚胺是使用一种或多种酸二酐和一种或多种二胺化合物获得的复印机构件的高度疏水性聚酰亚胺，其特征在于，酸酐和二胺化合物中的至少一种是具有醚 键和/或硫醚键，并且构成聚酰亚胺并衍生自酸性二酸酐和二胺化合物的重复单元中的醚键和硫醚键的总数为2以上。

公开(公告)号：US06146712A

公开(公告)日：2000-11-14

申请号：US199781

申请日：1998-11-25

申请人： Masayo Maeda ,  Kozo Tajiri

发明人： Masayo Maeda ,  Kozo Tajiri

IPC分类号： B41M5/00 ,  B41M5/50 ,  B41M5/52 ,  B05D3/06

CPC分类号： B41M5/52 ,  B41M5/508 ,  B41M5/5209 ,  B41M5/5236 ,  B41M5/5245 ,  B41M5/5254

摘要： The present invention provides an ink-jet recording sheet which is excellent in water resistance, capable of providing excellent ink-drying property and image quality, substantially free from blurring, and suitable for use as OHP sheets of which a high transparency is necessitated. The present process for producing an ink-jet recording sheet comprises applying to a base sheet, an aqueous solution of a water-soluble resin having no radically polymerizable double bond in the molecule and selected from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide, polyacryloyl morpholine, water-soluble polyvinyl acetal, poly-N-vinyl acetamide, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, gelatin, casein and derivatives of them, irradiating the resultant coating layer with electron beam before the coating layer is dried, to form a hydrogel, and drying the hydrogel. In the present invention, the water-soluble resin is usable in combination with a polyalkylene oxide compatible with the water-soluble resin.

摘要翻译： 本发明提供一种喷墨记录纸，其耐水性优异，能够提供优异的油墨干燥性和图像质量，基本上没有模糊，并且适用于需要高透明度的OHP片材。 本发明的喷墨记录纸的制造方法包括向基片施加在分子中不具有自由基聚合性双键的水溶性树脂的水溶液，选自聚乙烯醇，聚乙烯吡咯烷酮，聚丙烯酰胺 ，聚丙烯酰吗啉，水溶性聚乙烯醇缩醛，聚-N-乙烯基乙酰胺，羟乙基纤维素，羟丙基纤维素，甲基纤维素，羟丙基甲基纤维素，羟乙基甲基纤维素，明胶，酪蛋白及其衍生物， 在涂层干燥之前，形成水凝胶，并干燥水凝胶。 在本发明中，水溶性树脂可与与水溶性树脂相容的聚环氧烷结合使用。

公开(公告)号：US08155493B2

公开(公告)日：2012-04-10

申请号：US12430302

申请日：2009-04-27

申请人： Takami Ushiwata ,  Koki Hirano ,  Kozo Tajiri ,  Tomomi Makino

发明人： Takami Ushiwata ,  Koki Hirano ,  Kozo Tajiri ,  Tomomi Makino

IPC分类号： G02B6/10 ,  B32B38/00 ,  B05D5/12

CPC分类号： G02B6/10 ,  G02B6/02033 ,  G02B6/138 ,  H04M1/0274 ,  Y10T156/1052

摘要： The invention provides a flexible optical waveguide in which an optical waveguide film is directly formed on a substrate without using an adhesive and which is excellent in flexibility of the optical waveguide film, including the substrate, and excellent in adhesiveness between the substrate and the optical waveguide film, as well as a process for producing the flexible optical waveguide in a simple and easy manner. The flexible optical waveguide includes a lower cladding layer, a core layer, and an upper cladding layer successively formed on a substrate and a surface of the substrate, on which surface the lower cladding layer is to be formed, has an arithmetic average roughness (Ra) of 0.03 μm or higher. The flexible optical waveguide can be produced by subjecting a surface of the substrate, on which surface the lower cladding layer is to be formed, to physical treatment with a whetstone or chemical treatment with a corona discharge and then successively forming the lower cladding layer, the core layer, and the upper cladding layer on the surface of the substrate.

摘要翻译： 本发明提供了一种挠性光波导，其中在不使用粘合剂的情况下将光波导膜直接形成在基板上，并且包括基板的光波导膜的柔性优异，并且基板和光波导之间的粘合性优异 薄膜，以及以简单和容易的方式制造柔性光波导的工艺。 柔性光波导包括下基层，芯层和上包覆层，其依次形成在基板上和基板的要在其上形成下包层的表面的表面上，具有算术平均粗糙度（Ra ）为0.03μm以上。 柔性光波导可以通过对其上形成有下表面层的基板的表面进行物理处理，用电石粉进行化学处理，然后依次形成下包层， 芯层和衬底表面上的上覆层。