摘要:
A polyether copolymer comprising the repeating units represented by the following general formula (I) ##STR1## and the repeating units represented by the following formula (II) ##STR2## the molar ratio of (I)/{(I)+(II)} being from 0.1 to 0.8 and the polyether copolymer having a melt viscosity of at least 500 poise as measured at 400.degree. C. is produced by allowing a dihalogenobenzonitrile, 1,4-bis(4'-halobenzoyl)benzene, and 4,4'-biphenol to react with each other in an aprotic polar solvent in the presence of an alkali metal compound. The polyether copolymer exhibits excellent heat-resistance, solvent resistance, and mechanical strength, and is suitable as a material for resin compositions, heat-resistant laminates, fiber, and film.
摘要:
A polyetheric copolymer, a polyetheric block copolymer, and compositions of these copolymers containing:a benzonitrile recurring unit as represented by the following general formula (I): ##STR1## and a benzophenone recurring unit as represented by the following general formula (II): ##STR2## which copolymer has a molar ratio of the recurring unit (I) to a sum of the recurring units (I) and (II), i.e., (I)/[(I)+(II)], in the range from 0.15:1 to 0.40:1, as well as a melt viscosity (zero shear viscosity) at 400.degree. C. in the range from 500 to 100,000 poise.The polyetheric copolymer is crystalline and is a macromolecular compound having excellent heat resistance and mechanical strength.Disclosed herein are methods for the preparation of the polyetheric copolymer, the polyetheric block copolymer and the compositions containing the same.The polyetheric copolymers, the polyetheric block copolymers and their compositions are useful in various fields.
摘要:
New and useful aromatic polyethers, which are high in glass transition temperatures, possess excellent mechanical properties, thermal resistance, solvent resistance, and generate fluorescence, are described. Also described are fluorescent resin compositions containing the aromatic polyethers. Processes for preparing the aromatic polyethers and the fluorescent resin compositions are also described.
摘要:
New and useful aromatic polyethers, which are high in glass transition temperatures, possess excellent mechanical properties, thermal resistance, solvent resistance, and generate fluorescence, are described. Also described are fluorescent resin compositions containing the aromatic polyethers. Processes for preparing the aromatic polyethers and the fluorescent resin compositions are also described.
摘要:
Disclosed is a syndiotactic, polystyrenic resin composition comprising (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight, and optionally (C) from 0.5 to 10.0 parts by weight, relative to 100 parts by weight of the component (a) of (A), of a polyphenylene ether (having an intrinsic viscosity in chloroform at 25° C. of 0.4 dl/g or higher) and/or (D) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of a styrene-olefin copolymer having a styrene content of from 5 to 35% by weight and/or (E) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of at least one selected from paraffinic oils, paraffinic waxes, mineral oils and siloxanic oils. The composition may optionally contain (F), from 0.5 to 350 parts by weight, relative to 100 parts by weight of the resin components, of an inorganic filler and (G) from 0.1 to 10 parts by weight, relative to the same, of a polymer which is miscible with or has an affinity for the component (a) of (A) and which has a polar group. The composition can be formed into articles having good heat resistance, a high modulus of elasticity and good toughness. In addition, the articles are advantageous in that their surface layers are hardly peeled.
摘要:
Disclosed is a syndiotactic, polystyrenic resin composition comprising (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a block or graft styrene-olefin copolymer having a styrene content of from 40 to 85% by weight; the composition can be formed into articles having good heat resistance, a high modulus of elasticity and good toughness. In addition, the articles are advantageous in that their surface layers are hardly peeled.
摘要:
Disclosed is a syndiotactic, polystyrenic resin composition comprising (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight, (E) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of at least one selected from paraffinic oils, paraffinic waxes, mineral oils and siloxanic oils. The composition can be formed into articles having good heat resistance, a high modulus of elasticity and good toughness. In addition, the articles are advantageous in that their surface layers are hardly peeled.
摘要:
A battery jar material for sealed secondary batteries comprising a resin composition which comprises 50 to 98% by weight of (A) a styrenic polymer having a syndiotactic configuration, 2 to 50% by weight of (B) at least one polymer selected from the group consisting of polyolefins and styrenic elastomers, and 0 to 10% by weight of (C) a polyphenylene ether, or a resin composition which comprises 100 parts by weight of a resin component having the same composition as the above resin composition, 1 to 350 parts by weight of (D) an inorganic filler, and 0 to 5 parts by weight of (E) a polyphenylene ether modified with a polar group; and a battery jar for sealed secondary batteries made of this material. A battery jar material and a battery jar for sealed secondary batteries which show excellent heat resistance, resistance to electrolytes, resistance to oil and grease, electric insulation, mechanical strengths, and moldability and enable decrease in thickness are provided.
摘要:
Disclosed is a syndiotactic, polystyrenic resin composition comprising (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a block or graft styrene-olefin copolymer having a styrene content of from 40 to 85% by "weight, and (C) from 0.5 to 10.0 parts, relative to 100 parts by weight of component (a) of (A), of a polyphenylene ether. The ". composition can be formed into articles having good heat resistance, a high modulus of elasticity and good toughness. In addition, the articles are advantageous in that their surface layers are hardly peeled.