公开(公告)号：US06437090B1

公开(公告)日：2002-08-20

申请号：US09334915

申请日：1999-06-17

申请人： Shinji Murai ,  Shuji Hayase ,  Shinetsu Fujieda ,  Rumiko Hayase ,  Yasuyuki Hotta

发明人： Shinji Murai ,  Shuji Hayase ,  Shinetsu Fujieda ,  Rumiko Hayase ,  Yasuyuki Hotta

IPC分类号： C08G5968

CPC分类号： C08G59/18 ,  C08G59/68

摘要： A curing catalyst comprising at least one of a cationic curing catalyst component and an organo-metallic compound component. At least one of these components is capable of reversibly repeating the dissolution and precipitation through heating and cooling. The cationic curing catalyst component includes in its molecule at least one substituted or unsubstituted hydrocarbon group having 10 or more carbon atoms, or at least one cyclic organic structure having a substituted or unsubstituted hydrocarbon group having 10 or more carbon atoms.

摘要翻译： 包含阳离子固化催化剂组分和有机金属化合物组分中的至少一种的固化催化剂。 这些组分中的至少一种能够通过加热和冷却可逆地重复溶解和沉淀。 阳离子固化催化剂组分在其分子中包含至少一个具有10个或更多个碳原子的取代或未取代的烃基，或至少一个具有取代或未取代的具有10个或更多个碳原子的烃基的环状有机结构。

公开(公告)号：US07126054B2

公开(公告)日：2006-10-24

申请号：US10180018

申请日：2002-06-27

申请人： Shinji Murai ,  Hiroyasu Sumino ,  Satoshi Mikoshiba ,  Shuji Hayase

发明人： Shinji Murai ,  Hiroyasu Sumino ,  Satoshi Mikoshiba ,  Shuji Hayase

IPC分类号： H01L31/04

CPC分类号： H01G9/2031 ,  H01G9/2009 ,  Y02E10/542

摘要： Disclosed is a dye-sensitized solar cell comprising a gel electrolyte that contains a gelling agent and an electrolyte, wherein the gelling agent contains at least one kind of a polymer selected from the group consisting of a first polymer in which polysulfonic acid is crosslinked by a metal ion having a valency of not less than two, a second polymer in which polycarboxylic acid is crosslinked by a metal ion having a valency of not less than two, a third polymer in which a quaternary ammonium salt of polysulfonic acid is crosslinked by a metal ion having a valency of not less than two and a fourth polymer in which a quaternary ammonium salt of polycarboxylic acid is crosslinked by a metal ion having a valency of not less than two.

摘要翻译： 公开了一种染料敏化太阳能电池，其包含凝胶电解质，其含有胶凝剂和电解质，其中，所述胶凝剂含有选自第一聚合物中的至少一种的聚合物，其中聚磺酸通过 化合价不低于2的金属离子，多元羧酸通过不少于2价的金属离子交联的第二聚合物，其中多磺酸的季铵盐通过金属交联的第三种聚合物 具有不小于2的化合价的离子和其中多元羧酸的季铵盐通过不少于2的化合价的金属离子交联的第四聚合物。

公开(公告)号：US5773192A

公开(公告)日：1998-06-30

申请号：US794587

申请日：1997-02-03

申请人： Shinji Murai ,  Yoshihiko Nakano ,  Ken Uchida ,  Shuji Hayase

发明人： Shinji Murai ,  Yoshihiko Nakano ,  Ken Uchida ,  Shuji Hayase

IPC分类号： B41M5/36 ,  C07F7/08 ,  C08F4/00 ,  C08G77/48 ,  C08G77/60 ,  C08L83/02 ,  C08L83/16 ,  G03F7/004 ,  G03F7/027 ,  G03F7/029 ,  G03F7/075 ,  G03F7/023 ,  G08G77/00

CPC分类号： G03F7/027 ,  B41M5/368 ,  C07F7/0821 ,  C08G77/60 ,  G03F7/0045 ,  G03F7/029 ,  G03F7/075 ,  G03F7/0757

摘要： Disclosed are an organic silicon compound having a repeating unit represented by general formula (I) shown below, a resist, a thermal polymerization composition and a photopolymerization composition containing the organic silicon compound, ##STR1## wherein R.sup.1 is a t-butyl group or a pyranyl group, R.sup.2 is an hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 1 to 24 carbon atoms, or a substituted or unsubstituted aralkyl having 7 to 24 carbon atoms, R.sup.3 is a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 24 carbon atoms or an alkoxyl group, and k represents an integer from 0 to 4.

摘要翻译： 公开了具有下述通式（I）表示的重复单元的有机硅化合物，抗蚀剂，热聚合组合物和含有有机硅化合物的光聚合组合物，其中，R 2表示氢原子，取代基 或未取代的碳原子数1〜24的烷基，取代或未取代的碳原子数为1〜24的芳基或取代或未取代的碳原子数为7〜24的芳烷基，R3为取代或未取代的碳原子数为1〜24的烷基 取代或未取代的碳原子数为6〜24的芳基，取代或未取代的碳原子数为7〜24的芳烷基或烷氧基，k表示0〜4的整数。

公开(公告)号：US5362559A

公开(公告)日：1994-11-08

申请号：US89634

申请日：1993-07-12

申请人： Shuji Hayase ,  Yoshihiko Nakano ,  Yukihiro Mikogami ,  Akira Yoshizumi ,  Shinji Murai ,  Rikako Kani

发明人： Shuji Hayase ,  Yoshihiko Nakano ,  Yukihiro Mikogami ,  Akira Yoshizumi ,  Shinji Murai ,  Rikako Kani

IPC分类号： B05D1/20 ,  C09D183/16 ,  B32B5/00

CPC分类号： B82Y30/00 ,  B05D1/202 ,  B82Y40/00 ,  C09D183/16 ,  Y10T428/261

摘要： Disclosed are a polysilane monomolecular film and a polysilane built-up film formed by building up a plurality of said monomolecular films, said monomolecular film consisting of a polysilane having a repeating unit represented by general formula (1) given below: ##STR1## where, R.sup.1 represents a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms or a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, R.sup.2 represents a divalent hydrocarbon group having 1 to 4 carbon atoms which can be substituted, and X represents hydroxyl group, amino group, carboxyl group, or a hydrophilic group having at least one selected from the group consisting of hydroxyl group, amino group, carboxyl group, amide linkage, ester linkage, carbamate linkage and carbonate linkage. The polysilane monomolecular film and built-up film can be formed on a substrate by an LB technique. In the films, the molecules of the polysilane having the repeating unit (1), that is, the Si-Si backbones are oriented in a fixed direction.

摘要翻译： 公开了一种聚硅烷单分子膜和聚硅烷叠层膜，其通过构建多个所述单分子膜而形成，所述单分子膜由具有由以下给出的通式（1）表示的重复单元的聚硅烷组成：＆lt; IMAGE＆gt;（1 ）其中，R1表示取代或未取代的碳原子数1〜24的烷基或碳原子数6〜24的取代或未取代的芳基，R2表示可被取代的碳原子数1〜4的二价烃基，X 表示羟基，氨基，羧基或具有选自羟基，氨基，羧基，酰胺键，酯键，氨基甲酸酯键和碳酸酯键中的至少一种的亲水基团。 可以通过LB技术在基板上形成聚硅烷单分子膜和积层膜。 在膜中，具有重复单元（1）的聚硅烷的分子，即Si-Si主链在固定方向上取向。

公开(公告)号：US20070137702A1

公开(公告)日：2007-06-21

申请号：US11671227

申请日：2007-02-05

申请人： Shinji Murai ,  Satoshi Mikoshiba ,  Hiroyasu Sumino ,  Shuji Hayase

发明人： Shinji Murai ,  Satoshi Mikoshiba ,  Hiroyasu Sumino ,  Shuji Hayase

IPC分类号： H01L31/00

CPC分类号： H01G9/2009 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521

摘要： The present invention provides a dye sensitized solar cell comprising an n-type semiconductor electrode containing a dye, an opposed electrode, and a gel electrolyte arranged between the n-type semiconductor and the opposed electrode and containing a gelling agent and an electrolyte that contains iodine, wherein the gelling agent contains a compound including an N-containing group and at least one atomic group selected from a group consisting of a sulfonic group and a carboxylic group.

摘要翻译： 本发明提供了一种染料敏化太阳能电池，其包含n型半导体电极，其含有染料，相对电极和布置在n型半导体和相对电极之间的凝胶电解质，并含有胶凝剂和含有碘的电解质 其中，所述胶凝剂含有包含含氮基团和至少一个选自磺酸基和羧基的原子团的化合物。

公开(公告)号：US07196264B2

公开(公告)日：2007-03-27

申请号：US10326131

申请日：2002-12-23

申请人： Shinji Murai ,  Satoshi Mikoshiba ,  Hiroyasu Sumino ,  Shuji Hayase

发明人： Shinji Murai ,  Satoshi Mikoshiba ,  Hiroyasu Sumino ,  Shuji Hayase

IPC分类号： H01L31/00

CPC分类号： H01G9/2009 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521

摘要： The present invention provides a dye sensitized solar cell comprising an n-type semiconductor electrode containing a dye, an opposed electrode, and a gel electrolyte arranged between the n-type semiconductor and the opposed electrode and containing a gelling agent and an electrolyte that contains iodine, wherein the gelling agent contains a compound including an N-containing group and at least one atomic group selected from a group consisting of a sulfonic group and a carboxylic group.

摘要翻译： 本发明提供了一种染料敏化太阳能电池，其包含n型半导体电极，其含有染料，相对电极和布置在n型半导体和相对电极之间的凝胶电解质，并含有胶凝剂和含有碘的电解质 其中，所述胶凝剂含有包含含氮基团和至少一个选自磺酸基和羧基的原子团的化合物。

公开(公告)号：US07812252B2

公开(公告)日：2010-10-12

申请号：US11671227

申请日：2007-02-05

申请人： Shinji Murai ,  Satoshi Mikoshiba ,  Hiroyasu Sumino ,  Shuji Hayase

发明人： Shinji Murai ,  Satoshi Mikoshiba ,  Hiroyasu Sumino ,  Shuji Hayase

IPC分类号： H01L31/00

CPC分类号： H01G9/2009 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521

摘要： The present invention provides a dye sensitized solar cell comprising an n-type semiconductor electrode containing a dye, an opposed electrode, and a gel electrolyte arranged between the n-type semiconductor and the opposed electrode and containing a gelling agent and an electrolyte that contains iodine, wherein the gelling agent contains a compound including an N-containing group and at least one atomic group selected from a group consisting of a sulfonic group and a carboxylic group.

摘要翻译： 本发明提供了一种染料敏化太阳能电池，其包含n型半导体电极，其含有染料，相对电极和布置在n型半导体和相对电极之间的凝胶电解质，并含有胶凝剂和含有碘的电解质 其中，所述胶凝剂含有包含含氮基团和至少一个选自磺酸基和羧基的原子团的化合物。

公开(公告)号：US5969059A

公开(公告)日：1999-10-19

申请号：US41794

申请日：1998-03-13

申请人： Shinji Murai ,  Shuji Hayase

发明人： Shinji Murai ,  Shuji Hayase

IPC分类号： C08K5/04 ,  C08F283/00 ,  C08G59/40 ,  C08G59/42 ,  C08G59/68 ,  C08J5/24 ,  C08K5/14 ,  C08K5/1515 ,  C08K5/5419 ,  C08L63/00

CPC分类号： C08F283/00 ,  C08G59/42

摘要： An impregnation resin composition comprising an alicyclic epoxy compound, an acid anhydride, an aluminum compound having an organic group, and butylglycidyl ether, wherein the alicyclic epoxy compound contains not more than 30 ppm in concentration of Na ion component.

摘要翻译： 包含脂环族环氧化合物，酸酐，具有有机基团的铝化合物和丁基缩水甘油醚的浸渍树脂组合物，其中脂环族环氧化合物含有不超过30ppm的Na离子组分浓度。

公开(公告)号：US5624788A

公开(公告)日：1997-04-29

申请号：US490614

申请日：1995-06-15

申请人： Shinji Murai ,  Yoshihiko Nakano ,  Ken Uchida ,  Shuji Hayase

发明人： Shinji Murai ,  Yoshihiko Nakano ,  Ken Uchida ,  Shuji Hayase

IPC分类号： B41M5/36 ,  C07F7/08 ,  C08F4/00 ,  C08G77/48 ,  C08G77/60 ,  C08L83/02 ,  C08L83/16 ,  G03F7/004 ,  G03F7/027 ,  G03F7/029 ,  G03F7/075 ,  G03F7/023 ,  G08G77/00

CPC分类号： G03F7/027 ,  B41M5/368 ,  C07F7/0821 ,  C08G77/60 ,  G03F7/0045 ,  G03F7/029 ,  G03F7/075 ,  G03F7/0757

摘要： Disclosed are an organic silicon compound having a repeating unit represented by general formula (I) shown below, a resist, a thermal polymerization composition and a photopolymerization composition containing the organic silicon compound, ##STR1## wherein R.sup.1 is a t-butyl group or a tetrahydropyranyl group, R.sup.2 is an hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 1 to 24 carbon atoms, or a substituted or unsubstituted aralkyl having 7 to 24 carbon atoms, R.sup.3 is a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 24 carbon atoms or an alkoxyl group, and k represents an integer from 0 to 4.

摘要翻译： 公开了具有下述通式（I）表示的重复单元的有机硅化合物，抗蚀剂，热聚合组合物和含有有机硅化合物的光聚合组合物，R 2是氢原子， 取代或未取代的碳原子数为1〜24的烷基，取代或未取代的碳原子数为1〜24的芳基或取代或未取代的碳原子数为7〜24的芳烷基，R3为取代或未取代的烷基， 碳原子，取代或未取代的碳原子数为6〜24的芳基，取代或未取代的碳原子数为7〜24的芳烷基或烷氧基，k表示0〜4的整数。

公开(公告)号：US6025117A

公开(公告)日：2000-02-15

申请号：US986517

申请日：1997-12-08

申请人： Yoshihiko Nakano ,  Rikako Kani ,  Shuji Hayase ,  Yasuhiko Sato ,  Seiro Miyoshi ,  Toru Ushirogouchi ,  Sawako Yoshikawa ,  Hideto Matsuyama ,  Yasunobu Onishi ,  Masaki Narita ,  Toshiro Hiraoka

发明人： Yoshihiko Nakano ,  Rikako Kani ,  Shuji Hayase ,  Yasuhiko Sato ,  Seiro Miyoshi ,  Toru Ushirogouchi ,  Sawako Yoshikawa ,  Hideto Matsuyama ,  Yasunobu Onishi ,  Masaki Narita ,  Toshiro Hiraoka

IPC分类号： C08G77/60 ,  C08G83/00 ,  G03F7/075 ,  G03F7/09 ,  G03F7/00

CPC分类号： C08G83/003 ,  C08G77/60 ,  G03F7/0754 ,  G03F7/091

摘要： A polysilane having a repeating unit represented by the following general formula (LPS-I), ##STR1## wherein A is a bivalent organic group, R.sup.1 substituents may be the same or different and are selected from hydrogen atom and substituted or unsubstituted hydrocarbon group and silyl group. The polysilane is excellent in solublity in an organic solvent so that it can be formed into a film by way of a coating method, which is excellent in mechanical strength and heat resistance. The polysilane can be employed as an etching mask to be disposed under a resist in a manufacturing method of a semiconductor device. The polysilane exhibits anti-reflective effect during exposure, a large etch rate ratio in relative to a resist, and excellent dry etching resistance.

摘要翻译： 具有由以下通式表示的重复单元的聚硅烷（LPS-I），其中A是二价有机基团，R 1取代基可以相同或不同，并且选自氢原子和取代或未取代的烃基和甲硅烷基。 聚硅烷在有机溶剂中的共溶剂性优异，可以通过涂布法形成膜，机械强度和耐热性优异。 在半导体器件的制造方法中，可以将聚硅烷用作蚀刻掩模以设置在抗蚀剂下。 聚硅烷在曝光期间表现出抗反射效果，相对于抗蚀剂具有大的蚀刻速率比和优异的耐干蚀刻性。