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    Nickel supported on titanium stabilized promoted calcium aluminate carrier
    6.
    发明授权
    Nickel supported on titanium stabilized promoted calcium aluminate carrier 有权
    镍负载钛稳定的促进铝酸钙载体

    公开(公告)号：US07378369B2

    公开(公告)日：2008-05-27

    申请号：US10806259

    申请日：2004-03-22

    申请人： Shizhong Zhao ,  Yeping Cai ,  Jurgen Ladebeck

    发明人： Shizhong Zhao ,  Yeping Cai ,  Jurgen Ladebeck

    IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00

    CPC分类号： B01J23/78 ,  B01J21/04 ,  B01J21/063 ,  B01J23/005 ,  B01J23/8946 ,  B01J35/0053 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/0207 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1094 ,  C01B2203/127 ,  Y02P20/52

    摘要： A calcium-promoted alumina supported nickel reforming catalyst stabilized with titanium is disclosed. The catalyst is particularly useful for reforming reaction in feed streams containing significant quantities of CO and CO2, low quantities of steam (the feed stream having a H2O/CH4 of less than 0.8 and a CO2/CH4 of greater than 0.5) and relatively high quantities of sulfur compounds (up to about 20 ppm). The catalyst comprises from about 25 wt % to about 98 wt % alumina as a support, from about 2 wt % to about 40 wt % nickel oxide, which is promoted with from about 0.5 wt % to about 35 wt % calcium oxide, and which is stabilized with from about 0.01 wt % to about 20 wt % titanium, wherein the calcium oxide is combined with the alumina to form calcium aluminate. The catalyst can be used in reforming reactions to produce syngas and has advantages in producing low hydrogen to carbon monoxide ratio syngas for applications such as iron ore reduction.

    摘要翻译： 公开了一种用钛稳定的钙促进氧化铝负载镍重整催化剂。 该催化剂特别适用于在含有大量CO和CO 2的少量蒸汽（含有H 2 O / CH 3）的进料流中的重整反应中， SUB> 4 小于0.8且CO 2/2 / CH 4大于0.5）和相对较高量的硫化合物（高达约20ppm ）。 催化剂包含约25重量％至约98重量％的作为载体的氧化铝，约2重量％至约40重量％的氧化镍，其以约0.5重量％至约35重量％的氧化钙促进，其中 用约0.01重量％至约20重量％的钛稳定，其中氧化钙与氧化铝组合以形成铝酸钙。 催化剂可用于重整反应以产生合成气，并且具有生产低氢至一氧化碳比的合成气的优点，用于诸如铁矿石还原的应用。

    Promoted calcium-aluminate supported catalysts for synthesis gas generation
    8.
    发明申请
    Promoted calcium-aluminate supported catalysts for synthesis gas generation 有权
    促进铝酸钙负载催化剂合成气生成

    公开(公告)号：US20060009352A1

    公开(公告)日：2006-01-12

    申请号：US10888645

    申请日：2004-07-09

    申请人： Shizhong Zhao ,  Yeping Cai ,  X.D. Hu ,  Jurgen Ladebeck ,  Jon Wagner

    发明人： Shizhong Zhao ,  Yeping Cai ,  X.D. Hu ,  Jurgen Ladebeck ,  Jon Wagner

    IPC分类号： B01J23/10

    CPC分类号： B01J23/63 ,  B01J21/063 ,  B01J21/066 ,  B01J23/02 ,  B01J23/10 ,  B01J23/58 ,  B01J23/6484 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8474 ,  B01J35/0053 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/10 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1094 ,  Y02P20/52

    摘要： A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.

    摘要翻译： 公开了一种促进的钙 - 氧化铝载体重整催化剂，其特别可用于重整反应，其中低H 2 / CO比合成气如小于2.3直接产生。 催化剂包含约25重量％至约98重量％的氧化铝，约0.5重量％至约35重量％的氧化钙，约0.01重量％至约35重量％的助催化剂和约0.05重量％至约 30重量％的活性金属。 助催化剂选自钛，锆，钇，铌，镧系元素，例如但不限于镧，铈，镨，钕，ium，钐，铕，钆，镱和组合 其中。 活性金属选自镍，钴，铑，钌，钯，铂，铱及其组合作为活性金属，其中氧化钙与氧化铝组合以形成富铝的铝酸钙。

    Process for production of a water gas shift catalyst
    9.
    发明授权
    Process for production of a water gas shift catalyst 有权
    生产水煤气变换催化剂的方法

    公开(公告)号：US07064097B1

    公开(公告)日：2006-06-20

    申请号：US10669977

    申请日：2003-09-24

    申请人： Yeping Cai ,  Sally L. Davies ,  Jon P. Wagner

    发明人： Yeping Cai ,  Sally L. Davies ,  Jon P. Wagner

    IPC分类号： B01J23/70 ,  B01J23/72

    CPC分类号： C01B3/16 ,  B01J23/007 ,  B01J23/80 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/03 ,  C01B2203/0283 ,  C01B2203/1041 ,  C01B2203/1076 ,  C01B2203/1094 ,  Y02P20/52

    摘要： A process for the preparation of water gas shift catalyst is described. The process includes mixing a copper salt and a zinc salt with an aluminum component in a solution, precipitating a precipitate from the solution, drying an forming the precipitate into the water gas shift catalyst. In an alternate process the aluminum component is prepared separately from the solution of the copper salt and the zinc salt prior to the mixing of the components. After the components are mixed a precipitate is precipitated from the solution, the precipitate is dried and formed into the catalyst.

    摘要翻译： 描述了一种制备水煤气变换催化剂的方法。 该方法包括将铜盐和锌盐与溶液中的铝组分混合，从溶液中沉淀出沉淀物，将沉淀物干燥形成水煤气变换催化剂。 在替代方法中，在组分混合之前，将铝组分与铜盐和锌盐的溶液分开制备。 在组分混合后，从溶液中沉淀出沉淀物，将沉淀物干燥并形成催化剂。