公开(公告)号：US5599424A

公开(公告)日：1997-02-04

申请号：US571732

申请日：1995-12-13

申请人： Shoji Matsumoto ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Yasufumi Izutsu

发明人： Shoji Matsumoto ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Yasufumi Izutsu

IPC分类号： H01L21/302 ,  H01L21/02 ,  H01L21/3065 ,  H01L21/822 ,  H01L21/8242 ,  H01L21/8246 ,  H01L27/04 ,  H01L27/10 ,  H01L27/105 ,  H01L27/108 ,  H01L21/00

CPC分类号： H01L28/40

摘要： On a silicon substrate, a silicon oxide layer, a first platinum layer, a dielectric film and a second platinum layer are formed, and then the second platinum layer and the dielectric film are dry etched, via a resist layer, in a 1-5 Pa low pressure region with a mixed gas of HBr and 0.sub.2 as the etching gas. As soon as the first platinum layer is exposed, the unetched portion of dielectric film is etched off in a 5-50 Pa high pressure region, and then the first platinum layer is dry etched again in the low pressure region to form a capacitor consisting of a top electrode, a capacitance insulation layer and a bottom electrode in a semiconductor integrated circuit chip. Using this manufacturing method prevents the deterioration in definition caused by the use of a thick resist and the operation failure of circuit elements such as transistors due to over etching on the insulation layer.

摘要翻译： 在硅衬底上形成氧化硅层，第一铂层，电介质膜和第二铂层，然后通过抗蚀剂层在1-5中干法蚀刻第二铂层和电介质膜 Pa低压区域，混合气体为HBr和O2作为蚀刻气体。 一旦露出第一铂层，在5-50Pa高压区域中蚀刻介电膜的未蚀刻部分，然后在低压区域再次干法蚀刻第一铂层，形成由 半导体集成电路芯片中的顶部电极，电容绝缘层和底部电极。 使用该制造方法可以防止由于在绝缘层上的过度蚀刻而使用厚的抗蚀剂引起的定义的劣化以及诸如晶体管的电路元件的操作故障。

公开(公告)号：US5527729A

公开(公告)日：1996-06-18

申请号：US412563

申请日：1995-03-29

申请人： Shoji Matsumoto ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Yasufumi Izutsu

发明人： Shoji Matsumoto ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Yasufumi Izutsu

IPC分类号： H01L21/302 ,  H01L21/02 ,  H01L21/3065 ,  H01L21/822 ,  H01L21/8242 ,  H01L21/8246 ,  H01L27/04 ,  H01L27/10 ,  H01L27/105 ,  H01L27/108 ,  H01L21/70 ,  H01L27/00

CPC分类号： H01L28/40

摘要： On a silicon substrate, a silicon oxide layer, a first platinum layer, a dielectric film and a second platinum layer are formed, and then the second platinum layer and the dielectric film are dry etched, via a resist layer, in a 1-5 Pa low pressure region with a mixed gas of HBr and O.sub.2 as the etching gas. As soon as the first platinum layer is exposed, the unetched portion of dielectric film is etched off in a 5-50 Pa high pressure region, and then the first platinum layer is dry etched again in the low pressure region to form a capacitor consisting of a top electrode, a capacitance insulation layer and a bottom electrode in a semiconductor integrated circuit chip. Using this manufacturing method prevents the deterioration in definition caused by the use of a thick resist and the operation failure of circuit elements such as transistors due to over etching on the insulation layer.

摘要翻译： 在硅衬底上形成氧化硅层，第一铂层，电介质膜和第二铂层，然后通过抗蚀剂层在1-5中干法蚀刻第二铂层和电介质膜 Pa低压区域，混合气体为HBr和O2作为蚀刻气体。 一旦露出第一铂层，在5-50Pa高压区域中蚀刻介电膜的未蚀刻部分，然后在低压区域再次干法蚀刻第一铂层，形成由 半导体集成电路芯片中的顶部电极，电容绝缘层和底部电极。 使用该制造方法可以防止由于在绝缘层上的过度蚀刻而使用厚的抗蚀剂引起的定义的劣化以及诸如晶体管的电路元件的操作故障。

公开(公告)号：US06468875B2

公开(公告)日：2002-10-22

申请号：US09768170

申请日：2001-01-24

申请人： Yasuhiro Uemoto ,  Eiji Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

发明人： Yasuhiro Uemoto ,  Eiji Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

IPC分类号： H01L2120

CPC分类号： H01L27/11502 ,  H01L28/40 ,  H01L28/56

摘要： A method for fabricating a capacitor for an integrated circuit, comprising the steps of forming a titanium film for an adhesion layer over a substrate, forming a titanium dioxide film for a diffusion barrier layer by annealing the titanium film after ion-implantation of oxygen ion into a surface region of the titanium film so as to change titanium in the surface region to titanium dioxide, and forming a high dielectric constant capacitor on the titanium dioxide film.

摘要翻译： 一种用于制造用于集成电路的电容器的方法，包括以下步骤：在衬底上形成用于粘附层的钛膜，通过在离子注入氧离子之后将钛膜退火形成用于扩散阻挡层的二氧化钛膜 钛膜的表面区域，以将表面区域中的钛变为二氧化钛，并在二氧化钛膜上形成高介电常数电容器。

公开(公告)号：US5929475A

公开(公告)日：1999-07-27

申请号：US573134

申请日：1995-12-15

申请人： Yasuhiro Uemoto ,  Eigi Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

发明人： Yasuhiro Uemoto ,  Eigi Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

IPC分类号： H01L21/02 ,  H01L21/314 ,  H01L27/115 ,  H01L29/76 ,  H01L27/108 ,  H01L31/062

CPC分类号： H01L27/11502 ,  H01L28/40 ,  H01L28/56

摘要： A method for fabricating a capacitor for an integrated circuit, comprising the steps of forming a titanium film for an adhesion layer over a substrate, forming a titanium dioxide film for a diffusion barrier layer by annealing the titanium film after ion-implantation of oxygen ion into a surface region of the titanium film so as to change titanium in the surface region to titanium dioxide, and forming a high dielectric constant capacitor on the titanium dioxide film.

摘要翻译： 一种用于制造用于集成电路的电容器的方法，包括以下步骤：在衬底上形成用于粘附层的钛膜，通过在离子注入氧离子之后将钛膜退火形成用于扩散阻挡层的二氧化钛膜 钛膜的表面区域，以将表面区域中的钛变为二氧化钛，并在二氧化钛膜上形成高介电常数电容器。

公开(公告)号：US06204111B1

公开(公告)日：2001-03-20

申请号：US09238157

申请日：1999-01-28

申请人： Yasuhiro Uemoto ,  Eiji Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

发明人： Yasuhiro Uemoto ,  Eiji Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

IPC分类号： H01L218242

CPC分类号： H01L27/11502 ,  H01L28/40 ,  H01L28/56

摘要： A method for fabricating a capacitor for an integrated circuit, comprising the steps of forming a titanium film for an adhesion layer over a substrate, forming a titanium dioxide film for a diffusion barrier layer by annealing the titanium film after ion-implantation of oxygen ion into a surface region of the titanium film so as to change titanium in the surface region to titanium dioxide, and forming a high dielectric constant capacitor on the titanium dioxide film.

摘要翻译： 一种用于制造用于集成电路的电容器的方法，包括以下步骤：在衬底上形成用于粘附层的钛膜，通过在离子注入氧离子之后将钛膜退火形成用于扩散阻挡层的二氧化钛膜 钛膜的表面区域，以将表面区域中的钛变为二氧化钛，并在二氧化钛膜上形成高介电常数电容器。

公开(公告)号：US06214660B1

公开(公告)日：2001-04-10

申请号：US09177620

申请日：1998-10-23

申请人： Yasuhiro Uemoto ,  Eigi Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

发明人： Yasuhiro Uemoto ,  Eigi Fujii ,  Koji Arita ,  Yoshihisa Nagano ,  Yasuhiro Shimada ,  Masamichi Azuma ,  Atsuo Inoue ,  Yasufumi Izutsu

IPC分类号： H01L213205

CPC分类号： H01L27/11502 ,  H01L28/40 ,  H01L28/56

摘要： A method for fabricating a capacitor for an integrated circuit, comprising the steps of forming a titanium film for an adhesion layer over a substrate, forming a titanium dioxide film for a diffusion barrier layer by annealing the titanium film after ion-implantation of oxygen ion into a surface region of the titanium film so as to change titanium in the surface region to titanium dioxide, and forming a high dielectric constant capacitor on the titanium dioxide film.

摘要翻译： 一种用于制造用于集成电路的电容器的方法，包括以下步骤：在衬底上形成用于粘附层的钛膜，通过在离子注入氧离子之后将钛膜退火形成用于扩散阻挡层的二氧化钛膜 钛膜的表面区域，以将表面区域中的钛变为二氧化钛，并在二氧化钛膜上形成高介电常数电容器。

公开(公告)号：US06809000B2

公开(公告)日：2004-10-26

申请号：US09797987

申请日：2001-03-05

申请人： Keisaku Nakao ,  Akihiro Matsuda ,  Yasufumi Izutsu ,  Toyoji Ito ,  Takumi Mikawa ,  Toru Nasu ,  Yoshihisa Nagano ,  Keisuke Tanaka ,  Toshie Kutsunai

发明人： Keisaku Nakao ,  Akihiro Matsuda ,  Yasufumi Izutsu ,  Toyoji Ito ,  Takumi Mikawa ,  Toru Nasu ,  Yoshihisa Nagano ,  Keisuke Tanaka ,  Toshie Kutsunai

IPC分类号： H01L2120

CPC分类号： H01L28/55

摘要： The semiconductor device of the invention includes a capacitor device, which is formed on a substrate and which includes a capacitive lower electrode, a capacitive insulating film made of an insulating metal oxide film and a capacitive upper electrode. An interlevel insulating film having an opening reaching the capacitive upper electrode is formed over the capacitor device. A metal interconnection including a titanium film is formed over the interlevel insulating film so as to be electrically connected to the capacitive upper electrode through the opening. An anti-diffusion film having conductivity is formed between the capacitive upper electrode and the metal interconnection for preventing titanium atoms composing the titanium film of the metal interconnection from passing through the capacitive upper electrode and diffusing into the capacitive insulating film.

摘要翻译： 本发明的半导体器件包括形成在基板上的电容器器件，其包括电容式下电极，由绝缘金属氧化物膜制成的电容绝缘膜和电容上电极。 在电容器装置上形成具有到达电容上电极的开口的层间绝缘膜。 在层间绝缘膜上形成包括钛膜的金属互连，以便通过开口与电容上电极电连接。 在电容上电极和金属互连之间形成具有导电性的防扩散膜，以防止构成金属互连的钛膜的钛原子通过电容上电极并扩散到电容绝缘膜。

公开(公告)号：US06239462B1

公开(公告)日：2001-05-29

申请号：US09120893

申请日：1998-07-23

申请人： Keisaku Nakao ,  Akihiro Matsuda ,  Yasufumi Izutsu ,  Toyoji Ito ,  Takumi Mikawa ,  Toru Nasu ,  Yoshihisa Nagano ,  Keisuke Tanaka ,  Toshie Kutsunai

发明人： Keisaku Nakao ,  Akihiro Matsuda ,  Yasufumi Izutsu ,  Toyoji Ito ,  Takumi Mikawa ,  Toru Nasu ,  Yoshihisa Nagano ,  Keisuke Tanaka ,  Toshie Kutsunai

IPC分类号： H01L27108

CPC分类号： H01L28/55

摘要： The semiconductor device of the invention includes a capacitor device, which is formed on a substrate and which includes a capacitive lower electrode, a capacitive insulating film made of an insulating metal oxide film and a capacitive upper electrode. An interlevel insulating film having an opening reaching the capacitive upper electrode is formed over the capacitor device. A metal interconnection including a titanium film is formed over the interlevel insulating film so as to be electrically connected to the capacitive upper electrode through the opening. An anti-diffusion film having conductivity is formed between the capacitive upper electrode and the metal interconnection for preventing titanium atoms composing the titanium film of the metal interconnection from passing through the capacitive upper electrode and diffusing into the capacitive insulating film.

摘要翻译： 本发明的半导体器件包括形成在基板上的电容器器件，其包括电容式下电极，由绝缘金属氧化物膜制成的电容绝缘膜和电容上电极。 在电容器装置上形成具有到达电容上电极的开口的层间绝缘膜。 在层间绝缘膜上形成包括钛膜的金属互连，以便通过开口与电容上电极电连接。 在电容上电极和金属互连之间形成具有导电性的防扩散膜，以防止构成金属互连的钛膜的钛原子通过电容上电极并扩散到电容绝缘膜。

公开(公告)号：US20050045990A1

公开(公告)日：2005-03-03

申请号：US10950532

申请日：2004-09-28

申请人： Keisaku Nakao ,  Akihiro Matsuda ,  Yasufumi Izutsu ,  Toyoji Ito ,  Takumi Mikawa ,  Toru Nasu ,  Yoshihisa Nagano ,  Keisuke Tanaka ,  Toshie Kutsunai

发明人： Keisaku Nakao ,  Akihiro Matsuda ,  Yasufumi Izutsu ,  Toyoji Ito ,  Takumi Mikawa ,  Toru Nasu ,  Yoshihisa Nagano ,  Keisuke Tanaka ,  Toshie Kutsunai

IPC分类号： H01L21/02 ,  H01L21/8242 ,  H01L21/00

CPC分类号： H01L28/55

摘要： The semiconductor device of the invention includes a capacitor device, which is formed on a substrate and which includes a capacitive lower electrode, a capacitive insulating film made of an insulating metal oxide film and a capacitive upper electrode. An interlevel insulating film having an opening reaching the capacitive upper electrode is formed over the capacitor device. A metal interconnection including a titanium film is formed over the interlevel insulating film so as to be electrically connected to the capacitive upper electrode through the opening. An anti-diffusion film having conductivity is formed between the capacitive upper electrode and the metal interconnection for preventing titanium atoms composing the titanium film of the metal interconnection from passing through the capacitive upper electrode and diffusing into the capacitive insulating film.

摘要翻译： 本发明的半导体器件包括形成在基板上的电容器器件，其包括电容式下电极，由绝缘金属氧化物膜制成的电容绝缘膜和电容上电极。 在电容器装置上形成具有到达电容上电极的开口的层间绝缘膜。 在层间绝缘膜上形成包括钛膜的金属互连，以便通过开口与电容上电极电连接。 在电容上电极和金属互连之间形成具有导电性的防扩散膜，以防止构成金属互连的钛膜的钛原子通过电容上电极并扩散到电容绝缘膜。

公开(公告)号：US06169304A

公开(公告)日：2001-01-02

申请号：US09071534

申请日：1998-05-04

申请人： Koji Arita ,  Eiji Fujii ,  Yasuhiro Shimada ,  Yasuhiro Uemoto ,  Toru Nasu ,  Akihiro Matsuda ,  Yoshihisa Nagano ,  Atsuo Inoue ,  Taketoshi Matsuura ,  Tatsuo Otsuki

发明人： Koji Arita ,  Eiji Fujii ,  Yasuhiro Shimada ,  Yasuhiro Uemoto ,  Toru Nasu ,  Akihiro Matsuda ,  Yoshihisa Nagano ,  Atsuo Inoue ,  Taketoshi Matsuura ,  Tatsuo Otsuki

IPC分类号： H01L2976

CPC分类号： H01L27/11502 ,  H01L27/10852 ,  H01L27/11585 ,  H01L27/1159 ,  H01L28/40 ,  H01L28/55 ,  H01L28/60 ,  H01L28/75 ,  Y10S438/958

摘要： A semiconductor device forming a capacitor through an interlayer insulating layer on a semiconductor substrate on which an integrated circuit is formed. This semiconductor device has an interlayer insulating layer with moisture content of 0.5 g/cm3 or less, which covers the capacitor in one aspect, and has a passivation layer with hydrogen content of 1021 atoms/cm3 or less, which covers the interconnections of the capacitor in other aspect. By thus constituting, deterioration of the capacitor dielectric can be prevented which brings about the electrical reliability of the ferroelectric layer or high dielectric layer.

摘要翻译： 一种通过半导体衬底上的层间绝缘层形成电容器的半导体器件，其上形成集成电路。 该半导体装置具有含水量为0.5g / cm 3以下的层间绝缘层，其在一个方面覆盖电容器，并且具有氢含量为1021原子/ cm3以下的钝化层，其覆盖电容器的互连 在其他方面。 通过这样构成，可以防止导致铁电层或高介电层的电可靠性的电容器电介质的劣化。