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1.发明申请NANO-SCALE GAS SEPARATION DEVICE UTILIZING THIN FILM STRUCTURES FOR HYDROGEN PRODUCTION 审中-公开采用薄膜生产的薄膜结构的纳米级气体分离装置公开(公告)号：US20100316918A1
公开(公告)日：2010-12-16
申请号：US12296404
申请日：2007-04-09
CPC分类号： C01B3/503 , B01D53/228 , B01D69/02 , B01D69/12 , B01D71/024 , B01D2325/02 , B01D2325/04 , B01D2325/26 , C01B3/34 , C01B2203/0233 , C01B2203/0405 , C01B2203/041 , C01B2203/0465 , C01B2203/0495 , C01B2203/067 , C01B2203/1241 , Y02E60/566
摘要： In various aspects, provided are substantially single phase ceramic membranes, gas separation devices based thereon, and methods of making the membranes. In various embodiments, the membranes and devices can be used for hydrogen production, such as in a fuel-cell.
摘要翻译： 在各个方面，提供基本上单相陶瓷膜，基于其的气体分离装置和制造膜的方法。 在各种实施方案中，膜和装置可以用于氢生产，例如在燃料电池中。
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2.发明申请公开(公告)号：US20100255387A1
公开(公告)日：2010-10-07
申请号：US12521572
申请日：2007-12-27
CPC分类号： H01M8/1246 , H01M2008/1293 , H01M2300/0068 , Y02E60/525 , Y02P70/56
摘要： In various aspects, provided are methods for: (a) improving oxygen incorporation in a solid oxide layer less than about 1000 nm thick; (b) extending the on-set of mixed conduction in a solid oxide layer less than about 1000 nm thick; (c) modulating the electrical conductivity of oxide ion conducting layer less than about 1000 nm thick; (d) decreasing the conductivity of an oxide ion conducting layer less than about 1000 nm thick; (e) improving the performance of a solid oxide fuel cell; and (f) improving the performance of a gas separation device. In various embodiments, the methods comprise exposing oxygen to light having one or more wavelengths in the range between about 100 nm to about 365 nm and contacting the layer with the oxygen so exposed. In various embodiments, the methods provide the potential for tailoring the surface catalytic activity of oxygen-ion and mixed conductors used in various solid-state devices.
摘要翻译： 在各个方面，提供了以下方法：（a）改善小于约1000nm厚的固体氧化物层中的氧结合; （b）在小于约1000nm厚的固体氧化物层中延伸一组混合导电; （c）调制小于约1000nm厚的氧化物离子传导层的电导率; （d）降低小于约1000nm厚的氧化物离子传导层的导电性; （e）提高固体氧化物燃料电池的性能; 和（f）提高气体分离装置的性能。 在各种实施方案中，所述方法包括将氧气暴露于具有在约100nm至约365nm范围内的一个或多个波长的光并使该层与暴露的氧接触。 在各种实施方案中，该方法提供了调整用于各种固态器件中的氧离子和混合导体的表面催化活性的潜力。
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3.发明申请High Performance Redox Capacitors Using Materials Possessing Non-Stoichiometry and Defect Chemical Equilibrium 有权使用具有非化学计量和缺陷化学平衡的材料的高性能氧化还原电容器公开(公告)号：US20110297420A1
公开(公告)日：2011-12-08
申请号：US13202121
申请日：2010-02-18
CPC分类号： H01G11/86 , H01G11/02 , H01G11/04 , H01G11/28 , H01G11/46 , H01G11/58 , H01G11/62 , Y02E60/13 , Y02T10/7022 , Y10T29/43
摘要： A pseudocapacitor employs plates having an active material of a nanoparticles sized ceramic mixed ionic-electronic conductor such as may have the nominal formula of ABO3, A2BO4, AB2O4, and AO2, where A and B are metals. The active material may be prepared to promote sublattice vacancies to provide for the storage of additional charge.
摘要翻译： 假电容器采用具有纳米颗粒尺寸的陶瓷混合离子电子导体的活性材料的板，例如可以具有标称式ABO3，A2BO4，AB2O4和AO2，其中A和B是金属。 可以制备活性材料以促进亚晶格空位以提供额外电荷的储存。
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4.发明授权Composite mixed oxide ionic and electronic conductors for hydrogen separation 有权用于氢气分离的复合混合氧化物离子和电子导体公开(公告)号：US07588626B2
公开(公告)日：2009-09-15
申请号：US11255650
申请日：2005-10-21
IPC分类号： B01D53/22
CPC分类号： B01D67/0041 , B01D53/228 , B01D53/32 , B01D69/141 , B01D71/024 , B01D2325/22 , B01D2325/26 , B01J8/009 , B01J19/0073 , C01B3/503 , C01B13/0255 , C01B2203/025 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2210/0053 , H01M8/0662 , H01M8/0681 , H01M8/0687 , H01M2008/1095 , Y02E60/364 , Y02P20/149
摘要： A mixed ionic and electronic conducting membrane includes a two-phase solid state ceramic composite, wherein the first phase comprises an oxygen ion conductor and the second phase comprises an n-type electronically conductive oxide, wherein the electronically conductive oxide is stable at an oxygen partial pressure as low as 10−20 atm and has an electronic conductivity of at least 1 S/cm. A hydrogen separation system and related methods using the mixed ionic and electronic conducting membrane are described.
摘要翻译： 混合的离子和电子导电膜包括两相固态陶瓷复合材料，其中第一相包括氧离子导体，第二相包括n型电子导电氧化物，其中电子导电氧化物在氧气部分是稳定的 压力低至10-20atm，电导率至少为1S / cm。 描述了使用混合的离子和电子导电膜的氢分离系统和相关方法。
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公开(公告)号：US08139343B2
公开(公告)日：2012-03-20
申请号：US13041808
申请日：2011-03-07
IPC分类号： H01G9/00
CPC分类号： H01G9/02 , H01G9/155 , Y02E60/13 , Y02T10/7022
摘要： An electrical energy storage device includes a first electrode; a second electrode; a separator; and an electrolyte; where the separator is an electronic insulator; the separator is positioned between the first and second electrodes; the separator includes a first surface proximal to the first electrode and a second surface proximal to the second electrode; the separator is configured to support an electric double layer at the first surface, the second surface, or at both the first surface and the second surface; and the device is an electrical energy storage device.
摘要翻译： 电能存储装置包括第一电极; 第二电极; 分隔符 和电解质; 其中分离器是电子绝缘体; 分离器位于第一和第二电极之间; 分离器包括靠近第一电极的第一表面和靠近第二电极的第二表面; 隔板构造成在第一表面，第二表面或第一表面和第二表面处支撑双电层; 并且该装置是电能存储装置。
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6.发明申请Composite mixed oxide ionic and electronic conductors for hydrogen separation 有权用于氢气分离的复合混合氧化物离子和电子导体公开(公告)号：US20060191408A1
公开(公告)日：2006-08-31
申请号：US11255650
申请日：2005-10-21
IPC分类号： B01D53/22
CPC分类号： B01D67/0041 , B01D53/228 , B01D53/32 , B01D69/141 , B01D71/024 , B01D2325/22 , B01D2325/26 , B01J8/009 , B01J19/0073 , C01B3/503 , C01B13/0255 , C01B2203/025 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2210/0053 , H01M8/0662 , H01M8/0681 , H01M8/0687 , H01M2008/1095 , Y02E60/364 , Y02P20/149
摘要： A mixed ionic and electronic conducting membrane includes a two-phase solid state ceramic composite, wherein the first phase comprises an oxygen ion conductor and the second phase comprises an n-type electronically conductive oxide, wherein the electronically conductive oxide is stable at an oxygen partial pressure as low as 10−20 atm and has an electronic conductivity of at least 1 S/cm. A hydrogen separation system and related methods using the mixed ionic and electronic conducting membrane are described.
摘要翻译： 混合的离子和电子导电膜包括两相固态陶瓷复合材料，其中第一相包括氧离子导体，第二相包括n型电子导电氧化物，其中电子导电氧化物在氧气部分是稳定的 压力低至10〜20大气压，电子传导率至少为1S / cm。 描述了使用混合的离子和电子导电膜的氢分离系统和相关方法。
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公开(公告)号：US20110157771A1
公开(公告)日：2011-06-30
申请号：US13041808
申请日：2011-03-07
IPC分类号： H01G9/004
CPC分类号： H01G9/02 , H01G9/155 , Y02E60/13 , Y02T10/7022
摘要： An electrical energy storage device includes a first electrode; a second electrode; a separator; and an electrolyte; where the separator is an electronic insulator; the separator is positioned between the first and second electrodes; the separator includes a first surface proximal to the first electrode and a second surface proximal to the second electrode; the separator is configured to support an electric double layer at the first surface, the second surface, or at both the first surface and the second surface; and the device is an electrical energy storage device.
摘要翻译： 电能存储装置包括第一电极; 第二电极; 分隔符 和电解质; 其中分离器是电子绝缘体; 分离器位于第一和第二电极之间; 分离器包括靠近第一电极的第一表面和靠近第二电极的第二表面; 隔板构造成在第一表面，第二表面或第一表面和第二表面处支撑双电层; 并且该装置是电能存储装置。
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公开(公告)号：US20110017493A1
公开(公告)日：2011-01-27
申请号：US12841466
申请日：2010-07-22
CPC分类号： C01B31/02 , B01D2253/102 , B01D2253/304 , B01J20/20 , B01J20/28004 , B01J20/324 , B01J20/3293 , C01B32/05 , C01B32/20 , Y02C10/08 , Y10T428/249921 , Y10T428/2989
摘要： The preset invention is a hierarchically-structured carbon microbead and method for forming the microbead utilizing hydrothermal carbonization of a biomass/catalyst mixture to produce partially carbonized amorphous microspheres, wherein the biomass is an inexpensive material containing a high oxygen content component (e.g., sugar, starch, alcohol), and the catalyst is a metal or metal-containing compound, preferably a transition metal compound, and more specifically a transition metal selected from Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, and Pt. Subsequently, a heat treatment is performed where the amorphous microspheres are heated to a temperature that is sufficiently high so as to result in carbonization, graphitization, and production of a carbonaceous coating or shell on the core of the microbead.
摘要翻译： 本发明是利用生物质/催化剂混合物的水热碳化来形成微珠的层级结构的碳微珠和方法，以生产部分碳化的无定形微球，其中生物质是含有高含氧量成分（例如糖， 淀粉，醇），催化剂为金属或金属的化合物，优选为过渡金属化合物，更具体地为选自Fe，Co，Ni，Ru，Rh，Pd，Os，Ir和Pt的过渡金属。 随后，进行热处理，其中无定形微球体被加热至足够高的温度，从而在微珠核心上进行碳化，石墨化和碳质涂层或壳的生产。
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公开(公告)号：US09309121B2
公开(公告)日：2016-04-12
申请号：US12841466
申请日：2010-07-22
CPC分类号： C01B31/02 , B01D2253/102 , B01D2253/304 , B01J20/20 , B01J20/28004 , B01J20/324 , B01J20/3293 , C01B32/05 , C01B32/20 , Y02C10/08 , Y10T428/249921 , Y10T428/2989
摘要： The preset invention is a hierarchically-structured carbon microbead and method for forming the microbead utilizing hydrothermal carbonization of a biomass/catalyst mixture to produce partially carbonized amorphous microspheres, wherein the biomass is an inexpensive material containing a high oxygen content component (e.g., sugar, starch, alcohol), and the catalyst is a metal or metal-containing compound, preferably a transition metal compound, and more specifically a transition metal selected from Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, and Pt. Subsequently, a heat treatment is performed where the amorphous microspheres are heated to a temperature that is sufficiently high so as to result in carbonization, graphitization, and production of a carbonaceous coating or shell on the core of the microbead.
摘要翻译： 本发明是利用生物质/催化剂混合物的水热碳化来形成微珠的层级结构的碳微珠和方法，以生产部分碳化的无定形微球，其中生物质是含有高含氧量成分（例如糖， 淀粉，醇），催化剂为金属或金属的化合物，优选为过渡金属化合物，更具体地为选自Fe，Co，Ni，Ru，Rh，Pd，Os，Ir和Pt的过渡金属。 随后，进行热处理，其中无定形微球体被加热至足够高的温度，从而在微珠核心上进行碳化，石墨化和碳质涂层或壳的生产。
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10.发明授权High performance redox capacitors using materials possessing non-stoichiometry and defect chemical equilibrium 有权使用具有非化学计量和缺陷化学平衡的材料的高性能氧化还原电容器公开(公告)号：US08737040B2
公开(公告)日：2014-05-27
申请号：US13202121
申请日：2010-02-18
IPC分类号： H01G9/00
CPC分类号： H01G11/86 , H01G11/02 , H01G11/04 , H01G11/28 , H01G11/46 , H01G11/58 , H01G11/62 , Y02E60/13 , Y02T10/7022 , Y10T29/43
摘要： A pseudocapacitor employs plates having an active material of a nanoparticles sized ceramic mixed ionic-electronic conductor such as may have the nominal formula of ABO3, A2BO4, AB2O4, and AO2, where A and B are metals. The active material may be prepared to promote sublattice vacancies to provide for the storage of additional charge.
摘要翻译： 假电容器采用具有纳米颗粒尺寸的陶瓷混合离子电子导体的活性材料的板，例如可以具有标称式ABO3，A2BO4，AB2O4和AO2，其中A和B是金属。 可以制备活性材料以促进亚晶格空位以提供额外电荷的储存。
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