公开(公告)号：US5700899A

公开(公告)日：1997-12-23

申请号：US695525

申请日：1996-08-12

申请人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara ,  Kunio Itoh

发明人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara ,  Kunio Itoh

IPC分类号： C08L83/04 ,  C08G77/04 ,  C08G77/06 ,  C08G77/50 ,  C08K5/00 ,  C08L83/06 ,  C09D183/04 ,  C09D183/14 ,  C08G77/08

CPC分类号： C08K5/0025 ,  C08G77/04 ,  C08G77/50 ,  C09D183/04 ,  C09D183/14

摘要： A curable silicone composition based on an organopolysiloxane having a cyclotrisiloxane structure quickly cures by brief heating or ultraviolet exposure. It further contains an acid, acid generator, base or base generator or an oniom salt photo-initiator as a curing agent. The cured product has release property from adhesive substance which remains unchanged with the lapse of time and good mold release properties, and thus provides a lightly releasable cured film. The composition is widely used as adhesive tape backing agents, mold release agents, protective coating agents, water and oil repellent agents, and paint base.

摘要翻译： 基于具有环三硅氧烷结构的有机聚硅氧烷的可固化有机硅组合物通过短暂加热或紫外线暴露快速固化。 它还含有酸，酸发生剂，碱或碱产生剂或作为固化剂的oniom盐光引发剂。 固化物具有随着时间的流逝而保持不变的粘合物质的脱模性，脱模性良好，因此提供了可轻松固化的膜。 该组合物广泛用作胶带背胶，脱模剂，保护涂层剂，拒水拒油剂和油漆基料。

公开(公告)号：US5190988A

公开(公告)日：1993-03-02

申请号：US706706

申请日：1991-05-29

申请人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara

发明人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara

IPC分类号： C08K5/42 ,  C08F2/50 ,  C08F4/08 ,  C08F290/00 ,  C08F299/08 ,  C08L83/04 ,  C08L83/06 ,  C08L83/07 ,  C09D183/06 ,  C09J183/00 ,  C09J183/07

CPC分类号： C09D183/06

摘要： The invention provides a high-sensitivity ultraviolet-curable organopolysiloxane composition suitable for use as a surface-release treatment of various substrate such as release-paper sheets and the like. The composition comprises, as the essential ingredients, (a) an organopolysiloxane having a viscosity in the range from 50 to 3000 centipoise at 25.degree. C. and containing, in a molecule, at least one (meth)acryloxy-substituted monovalent hydrocarbon group or at least one epoxy- or glycidyloxy-substituted monovalent hydrocarbon group, and (b) a sulfonate compound such as 2-hydroxy-3-oxy-2,3-diphenylpropyl methanesulfonate as the photopolymerization initiator. The sensitivity of the composition to photopolymerization can be further increased by the addition of a specific salt such as sodium hexafluoroantimonate and sodium hexafluorophosphate.

摘要翻译： 本发明提供一种适用于各种基材如脱模纸等的表面剥离处理的高灵敏度紫外线固化型有机基聚硅氧烷组合物。 该组合物包含作为必要成分的（a）在25℃下粘度为50-3000厘泊的有机聚硅氧烷，并且在一分子中含有至少一个（甲基）丙烯酰氧基取代的一价烃基或 至少一个环氧基或缩水甘油氧基取代的一价烃基，和（b）磺酸酯化合物如2-羟基-3-氧基-2,3-二苯基丙基甲磺酸酯作为光聚合引发剂。 通过加入特定的盐如六氟锑酸钠和六氟磷酸钠可以进一步提高组合物对光聚合的敏感性。

公开(公告)号：US5118723A

公开(公告)日：1992-06-02

申请号：US651854

申请日：1991-02-07

申请人： Shinji Irifune ,  Toshio Ohba ,  Yasuaki Hara ,  Masanao Kamei

发明人： Shinji Irifune ,  Toshio Ohba ,  Yasuaki Hara ,  Masanao Kamei

IPC分类号： C08F2/46 ,  C08F2/54 ,  C08F290/00 ,  C08F290/06 ,  C08F299/00

CPC分类号： C08F290/068

摘要： A radiation curable organopolysiloxane-containing composition is disclosed which is curable by the irradiation with actinic rays in a relatively low dose to give a cured layer having excellent surface-releasability so that the composition is useful, for example, as a coating agent of release paper for temporary protection of adhesive surface. The composition comprises (a) 0.1 to 20 parts by weight of a linear organopolysiloxane having at least one vinylphenyl or isopropenylphenyl group bonded to only one of the terminal silicon atoms in the molecular chain and (b) 99.9 to 80 parts by weight of a (meth)acrylate compound which is a (meth)acrylic acid ester of a polyhydric alcohol or a polyester of a polyhydric alcohol and a dibasic carboxylic acid esterified with (meth)acrylic acid at the residual hydroxy groups.

摘要翻译： 公开了一种可辐射固化的含有机聚硅氧烷的组合物，其通过以较低剂量的光化射线照射而可固化，得到具有优异表面剥离性的固化层，使得该组合物可用于例如剥离纸的涂布剂 用于临时保护粘合剂表面。 组合物包含（a）0.1-20重量份具有至少一个乙烯基苯基或异丙烯基苯基的直链有机聚硅氧烷，其仅与分子链中的一个末端硅原子键合，（b）99.9至80重量份的（ 甲基）丙烯酸酯化合物，其是多元醇的（甲基）丙烯酸酯或多元醇的聚酯和在残留羟基上与（甲基）丙烯酸酯化的二元羧酸。

公开(公告)号：US06255428B1

公开(公告)日：2001-07-03

申请号：US09409988

申请日：1999-09-30

申请人： Shunji Aoki ,  Toshio Ohba

发明人： Shunji Aoki ,  Toshio Ohba

IPC分类号： C08G7708

CPC分类号： C08G77/38 ,  C07F7/0879

摘要： An epoxy group-bearing organopolysiloxane or organosilane is prepared by effecting addition reaction between an organohydropolysiloxane or organohydrosilane and an alkenyl group-bearing epoxy compound in the presence of an addition reaction catalyst. A cyano group-bearing compound is co-present in the reaction system. The end organopolysiloxane or organosilane having a stabilized viscosity is obtained while avoiding gelation or thickening during reaction.

摘要翻译： 通过在加成反应催化剂的存在下，通过在有机氢聚硅氧烷或有机氢硅烷和含有烯基的环氧化合物之间进行加成反应来制备含环氧基的有机聚硅氧烷或有机硅烷。 含氰基的化合物共存于反应体系中。 获得具有稳定粘度的末端有机聚硅氧烷或有机硅烷，同时避免反应期间的凝胶化或增稠。

公开(公告)号：US5232997A

公开(公告)日：1993-08-03

申请号：US670276

申请日：1991-03-15

申请人： Kunio Itoh ,  Motoo Fukushima ,  Toshio Ohba ,  Hiroyuki Ohata ,  Harukazu Okuda

发明人： Kunio Itoh ,  Motoo Fukushima ,  Toshio Ohba ,  Hiroyuki Ohata ,  Harukazu Okuda

IPC分类号： C08F230/08 ,  C08F290/06

CPC分类号： C08F230/08 ,  C08F290/068

摘要： An acrylic rubbery polymer having remarkably improved cold resistance can be prepared by modification with an organopolysiloxane by the emulsion copolymerization of a monomeric mixture of two acrylic monomers, of which one is, for example, an alkyl acrylate and the other is an acrylic compound having, in a molecule, at least one ethylenically unsaturated group other than acrylic group in an aqueous emulsion of an organopolysiloxane having a substantial amount of mercapto-substituted monovalent hydrocarbon groups bonded to the silicon atoms.

摘要翻译： 具有显着改善的耐寒性的丙烯酸类橡胶状聚合物可以通过用两种丙烯酸类单体的单体混合物的乳液共聚物进行改性来制备，其中一种是例如丙烯酸烷基酯，另一种是丙烯酸类化合物， 在具有大量巯基取代的单价烃基键合到硅原子的有机聚硅氧烷的水性乳液中，在分子中至少有一个除丙烯酸以外的烯属不饱和基团。

公开(公告)号：US20090311606A1

公开(公告)日：2009-12-17

申请号：US12484898

申请日：2009-06-15

申请人： Hirofumi FUKUOKA ,  Koichiro Watanabe ,  Meguru Kashida ,  Satoru Miyawaki ,  Toshio Ohba

发明人： Hirofumi FUKUOKA ,  Koichiro Watanabe ,  Meguru Kashida ,  Satoru Miyawaki ,  Toshio Ohba

IPC分类号： H01M4/58 ,  H01G9/04

CPC分类号： H01M4/134 ,  H01M4/48 ,  H01M10/0525

摘要： A conductive powder is provided in which particles having silicon crystallites dispersed in a silicon compound are coated on their surface with carbon. The conductive powder develops a diffraction peak assigned to Si(111) around 2θ=28.4° on x-ray diffractometry (Cu—Kα) using copper as the counter cathode, the peak having a half width of at least 1.0°, and has a specific resistance of up to 50 mΩ. The powder is used as a negative electrode material to construct a non-aqueous electrolyte secondary battery, which has a high charge/discharge capacity and improved cycle performance.

摘要翻译： 提供了一种导电粉末，其中具有分散在硅化合物中的硅微晶的颗粒在其表面上涂覆有碳。 使用铜作为对阴极，导电粉末在x射线衍射（Cu-Kalpha）上形成分配给Si（111）约2θ= 28.4°的衍射峰，该峰具有至少1.0°的半宽度，并且具有 比电阻高达50 mOmega。 该粉末用作负极材料，以构建具有高充电/放电容量和改进的循环性能的非水电解质二次电池。

公开(公告)号：US07629393B2

公开(公告)日：2009-12-08

申请号：US11401249

申请日：2006-04-11

申请人： Norifumi Takahashi ,  Toshio Ohba ,  Nobuo Kawada

发明人： Norifumi Takahashi ,  Toshio Ohba ,  Nobuo Kawada

IPC分类号： C08J5/20

CPC分类号： H01M8/1088 ,  C08J5/225 ,  C08J2323/06 ,  C08J2327/18 ,  H01B1/122 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/106 ,  H01M8/1072 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02P70/56

摘要： The present invention relates to a solid polymer electrolyte membrane having both of a higher proton conductivity and a smaller methanol permeability, which can be produced by conducting a graft polymerization of a fluororesin thin membrane irradiated with a radiation with a monofunctional monomer and again irradiating the resulting film with a radiation, followed by conducting a graft polymerization thereof with a polyfunctional monomer; and a high-performance fuel cell comprising the solid polymer electrolyte membrane, a fuel electrode and an air electrode, said solid polymer electrolyte membrane being disposed between the fuel electrode and the air electrode.

摘要翻译： 本发明涉及具有较高质子传导性和较小的甲醇渗透性的固体高分子电解质膜，其可以通过用单功能单体进行辐射照射的氟树脂薄膜进行接枝聚合而产生，并再次照射所得到的 膜，然后用多官能单体进行接枝聚合; 以及包含所述固体高分子电解质膜，燃料极和空气极的高性能燃料电池，所述固体高分子电解质膜设置在所述燃料电极和所述空气极之间。

公开(公告)号：US20050100662A1

公开(公告)日：2005-05-12

申请号：US10963660

申请日：2004-10-14

申请人： Toshio Ohba ,  Shigeru Konishi ,  Mitsuhito Takahashi ,  Norifumi Takahashi

发明人： Toshio Ohba ,  Shigeru Konishi ,  Mitsuhito Takahashi ,  Norifumi Takahashi

IPC分类号： H01M8/02 ,  B05D5/12 ,  C08J5/22 ,  H01M8/10

CPC分类号： C08J5/2293 ,  C08J2327/12 ,  H01M8/1004 ,  H01M8/1081 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P70/56

摘要： An electrolyte membrane for fuel cells is prepared by irradiating with radiation a composition comprising a radiation-curable liquid compound having proton conductivity for curing the liquid compound to form a cured film. The methods of the invention are successful in producing an electrolyte membrane and an electrolyte membrane/electrode assembly for fuel cells while satisfying both the requirements of productivity and cell-related properties including proton conduction and membrane strength.

摘要翻译： 燃料电池用电解质膜是通过用辐射照射包含具有质子传导性的可辐射固化液体化合物的组合物来固化液体化合物以形成固化膜来制备的。 本发明的方法在生产电解质膜和用于燃料电池的电解质膜/电极组件方面是成功的，同时满足生产力和包括质子传导和膜强度的电池相关性质的要求。

公开(公告)号：US06432489B1

公开(公告)日：2002-08-13

申请号：US09805979

申请日：2001-03-15

申请人： Toshio Ohba ,  Nobuo Kawada ,  Masaya Ueno

发明人： Toshio Ohba ,  Nobuo Kawada ,  Masaya Ueno

IPC分类号： C08F246

摘要： Methods for curing a coating material, including a primary coating material, a secondary coating material, and a taping material, on an optical fiber. An optical fiber coating material having (A) 100 parts by weight of a polyether polyurethane bearing at least two ethylenically unsaturated groups with a Mn of 800-10,000, and (B) 1-40 parts by weight of a nitrogenous reactive diluent is cured by irradiating thereto electron beams, produced by driving electrons under an accelerating voltage of 50-190 kV, in a dose of 10-100 kGy. The method succeeds in effectively curing the optical fiber coating material into a cured coating having stable properties.

公开(公告)号：US5266443A

公开(公告)日：1993-11-30

申请号：US726811

申请日：1991-07-08

申请人： Tatsuji Higashi ,  Toshio Ohba

发明人： Tatsuji Higashi ,  Toshio Ohba

IPC分类号： G03F7/00 ,  G03F7/075 ,  G03C1/76

CPC分类号： G03F7/0752

摘要： A dry PS plate having a substrate provided thereon with a photopolymerizable light-sensitive layer and a silicone rubber layer in that order. The silicone rubber layer comprises a product obtained by crosslinking through addition reaction the following components:(a) an alkenylpolysiloxane having at least two alkenyl groups directly bonded to the silicon atoms in each molecule thereof; and(b) a hydrogen polysiloxane of the following general formula I: ##STR1## wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom or methyl group, R.sup.3 and R.sup.4 independently represent a methyl, vinyl or phenyl group, m+n is 5 to 30 and m:n is 3:1 to 1:3. The dry PS plate provides a lithographic printing plate exhibiting excellent tone reproducibility and printing durability as well as not being subject to background contamination.