摘要:
A curable silicone composition based on an organopolysiloxane having a cyclotrisiloxane structure quickly cures by brief heating or ultraviolet exposure. It further contains an acid, acid generator, base or base generator or an oniom salt photo-initiator as a curing agent. The cured product has release property from adhesive substance which remains unchanged with the lapse of time and good mold release properties, and thus provides a lightly releasable cured film. The composition is widely used as adhesive tape backing agents, mold release agents, protective coating agents, water and oil repellent agents, and paint base.
摘要:
The invention provides a high-sensitivity ultraviolet-curable organopolysiloxane composition suitable for use as a surface-release treatment of various substrate such as release-paper sheets and the like. The composition comprises, as the essential ingredients, (a) an organopolysiloxane having a viscosity in the range from 50 to 3000 centipoise at 25.degree. C. and containing, in a molecule, at least one (meth)acryloxy-substituted monovalent hydrocarbon group or at least one epoxy- or glycidyloxy-substituted monovalent hydrocarbon group, and (b) a sulfonate compound such as 2-hydroxy-3-oxy-2,3-diphenylpropyl methanesulfonate as the photopolymerization initiator. The sensitivity of the composition to photopolymerization can be further increased by the addition of a specific salt such as sodium hexafluoroantimonate and sodium hexafluorophosphate.
摘要:
An epoxy group-bearing organopolysiloxane or organosilane is prepared by effecting addition reaction between an organohydropolysiloxane or organohydrosilane and an alkenyl group-bearing epoxy compound in the presence of an addition reaction catalyst. A cyano group-bearing compound is co-present in the reaction system. The end organopolysiloxane or organosilane having a stabilized viscosity is obtained while avoiding gelation or thickening during reaction.
摘要:
A UV light-curable organopolysiloxane composition which comprises (A) 100 parts by weight of an organopolysiloxane having at least one functional epoxy group in one molecule, (B) from 1 to 100 parts by weight of a polyether compound of the formula, R.sup.1 --(OR.sup.2).sub.n --OR.sup.3, wherein R.sup.1 represents an alkyl or alkenyl group having from 1 to 8 carbon atoms, R.sup.2 represents an alkylene group having from 2 to 4 carbon atoms, R.sup.3 represents a hydrogen atom or an alkyl or alkenyl group having from 1 to 8 carbon atoms, and n is an integer of from 1 to 50, and (C) from 0.01 to 40 parts by weight of all onium salt photoinitiator.
摘要:
A solventless addition-curable pressure sensitive silicone adhesive composition is provided. The composition comprises (A) an alkenyl group-containing polydiorganosiloxane; (B) a condensation product of (a) a polydiorganosiloxane having hydroxyl group or an alkoxy group on opposite ends of the molecular chain and (b) a polyorganosiloxane containing R13SiO1/2 unit and SiO2 unit as critical components and also a HOSiO3/2 unit in the molecule; (C1) a polyorganohydrosiloxane having at least three SiH groups per molecule; (C2) a polydiorganohydrosiloxane having SiH group on opposite ends; and (D) a platinum group metal catalyst. Use of the present composition enables production of a pressure sensitive adhesive agent having flexibility, pressure sensitive adhesiveness, and heat resistance, and the present composition is particularly effective for use as a buffer member having pressure sensitive adhesiveness.
摘要:
There is provided a sheet used for manufacturing multilayer electronic parts in which accuracy in shape and formation position and uniformity in thickness of a complex configuration with recesses and projections of an insulating layer or the like are assured. A layer made of a photosensitive material containing a powder having a specific electric characteristic is formed on a light transmissive base member. A mask having a plurality of patterns with different transmittances for ultraviolet light is disposed on the back side of the base member. The photosensitive material is subjected to an exposure process in which it is irradiated with ultraviolet light or the like through the mask. The photosensitive material is subjected to development process after the exposure process.
摘要:
A method of preparing (meth)acryl group-containing organosiloxanes, wherein only the alkoxy group(s) of a (meth)acryl group-containing alkoxysilane compound is(are) selectively hydrolyzed using a cation exchange resin as acid catalyst.
摘要:
An addition curing silicone composition comprising (A) an organopolysiloxane containing at least two alkenyl groups, (B) an adhesion promoter, (C) an organohydrogenpolysiloxane, and (D) a platinum catalyst is suited for use in release paper or film. The adhesion promoter is a compound which contains per molecule at least one substituent group having a functional group capable of radical reaction upon exposure to heat and/or UV, and at least one substituent group having a group capable of reaction with alkenyl and/or SiH group.
摘要:
This invention relates to a silicone pressure-sensitive adhesive composition including: (A) a polydiorganosiloxane composed of a linear polydiorganosiloxane (A1) having two or more alkenyl groups within each molecule and a linear polydiorganosiloxane (A2) having SiOH groups at terminals thereof and no alkenyl groups, which is represented by the formula R22(HO)SiO—(R22SiO)d—SiR22(OH), wherein d represents an integer satisfying 500≦d≦20,000; (B) a polyorganosiloxane including R33SiO1/2 units, SiO2 units and Si atom-bonded hydroxyl group-containing units; (C) a polyorganohydrogensiloxane having three or more SiH groups within each molecule; (D) a reaction retarder; (E) a platinum group metal-based catalyst; and (F) a metal compound represented by formula MYx, wherein the polyorganosiloxane (B) is condensed with the linear polydiorganosiloxane (A2). The composition exhibits powerful adhesive strength to silicone rubbers and is useful for, by example, producing a pressure-sensitive tape.
摘要:
An object of the invention is to provide a flat ceramic sheet including an internal electrode used for manufacturing a multilayer ceramic electronic part. Specifically, an electrode portion is formed on a surface of a transparent base member, and a photosensitive slurry containing dielectric powder is applied thereon. The photosensitive slurry is exposed from the backside of the base member up to a predetermined thickness, and then it is subjected to development. After that, the base member is removed. Thus, a ceramic green sheet is obtained.