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公开(公告)号：US09862788B2
公开(公告)日：2018-01-09
申请号：US14127799
申请日：2012-07-02
申请人： Stefan Hilf , Alexander Klein , Heike Heeb , Ingrid Kizewski , Sebastian Grimm , Michael Flittner
发明人： Stefan Hilf , Alexander Klein , Heike Heeb , Ingrid Kizewski , Sebastian Grimm , Michael Flittner
IPC分类号： C08F224/00 , C09D4/06 , C09D133/06 , C08F220/18 , C08K3/40 , C09D5/00 , C08K5/14
CPC分类号： C08F224/00 , C08F220/18 , C08K3/40 , C08K5/14 , C09D4/06 , C09D5/00 , C09D133/066 , C08F2220/1858 , C08F2220/282 , C08F2222/1013
摘要： The present invention relates to an innovative (meth)acrylic reactive resin which cures with low odor or odorlessly. The present invention relates more particularly to reactive resins comprising high-boiling, reactive (meth)acrylic monomers from the group of the polar, cyclically substituted esters of (meth)acrylic acid, more particularly glycerol acetal, ketal or carbonate methacrylates. These new components are used as substitutes for MMA, which represents the major part of the odor nuisance in the existing, prior-art reactive resin systems. Using these new components it is possible to obtain resin formulations which have glass transition temperatures similar to, and properties comparable with, MMA-based resins. The innovative reactive resins are able in addition to exhibit more rapid curing than prior-art MMA-based systems. Reactive resins for the purposes of the invention are reactive monomer mixtures or mixtures of monomers and polymers that when used as a 2-component system can be readily cured.
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公开(公告)号：US20140128536A1
公开(公告)日：2014-05-08
申请号：US14127799
申请日：2012-07-02
申请人： Stefan Hilf , Alexander Klein , Heike Heeb , Ingrid Kizewski , Sebastian Grimm , Michael Flittner
发明人： Stefan Hilf , Alexander Klein , Heike Heeb , Ingrid Kizewski , Sebastian Grimm , Michael Flittner
IPC分类号： C08F224/00 , C09D5/00 , C08K3/40
CPC分类号： C08F224/00 , C08F220/18 , C08K3/40 , C08K5/14 , C09D4/06 , C09D5/00 , C09D133/066 , C08F2220/1858 , C08F2220/282 , C08F2222/1013
摘要： The present invention relates to an innovative (meth)acrylic reactive resin which cures with low odour or odourlessly. The present invention relates more particularly to reactive resins comprising high-boiling, reactive (meth)acrylic monomers from the group of the polar, cyclically substituted esters of (meth)acrylic acid, more particularly glycerol acetal, ketal or carbonate methacrylates. These new components are used as substitutes for MMA, which represents the major part of the odour nuisance in the existing, prior-art reactive resin systems. Using these new components it is possible to obtain resin formulations which have glass transition temperatures similar to, and properties comparable with, MMA-based resins. The innovative reactive resins are able in addition to exhibit more rapid curing than prior-art MMA-based systems. Reactive resins for the purposes of the invention are reactive monomer mixtures or mixtures of monomers and polymers that when used as a 2-component system can be readily cured.
摘要翻译： 本发明涉及以低气味或无味地固化的创新（甲基）丙烯酸反应性树脂。 本发明更具体地涉及包含来自（甲基）丙烯酸的极性环状取代的酯，更特别是甘油缩醛，缩酮或碳酸甲酯的组的高沸点，反应性（甲基）丙烯酸单体的反应性树脂。 这些新组分被用作MMA的替代物，其代表了现有的现有技术的反应性树脂体系中的气味滋扰的主要部分。 使用这些新的组分，可以获得具有与MMA基树脂相似的性能和与MMA基树脂相当的性能的玻璃化转变温度的树脂配方。 创新的反应性树脂除了表现出比现有技术的基于MMA的系统更快的固化之外。 用于本发明目的的反应性树脂是反应性单体混合物或单体和聚合物的混合物，当用作2-组分体系时，可以容易地固化。
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公开(公告)号：US20130289164A1
公开(公告)日：2013-10-31
申请号：US13978481
申请日：2011-12-15
申请人： Stefan Hilf , Dirk Poppe , Alexander Klein , Heike Heeb , Armin Steffan
发明人： Stefan Hilf , Dirk Poppe , Alexander Klein , Heike Heeb , Armin Steffan
IPC分类号： E01F9/04
CPC分类号： E01F9/506 , C08F220/10 , C08F265/06 , C08F285/00
摘要： The present invention comprises a novel formulation for marking trafficways, for example roads, which when compared with the prior art have improved mechanical properties and improved heat resistance during curing. The invention also relates to improved reactive resins for other applications than roadmarkings. The present invention in particular relates to reactive resins which comprise core-shell particles.
摘要翻译： 本发明包括用于标记交通道路的新型配方，例如道路，当与现有技术相比时，其具有改善的机械性能和改善的固化期间的耐热性。 本发明还涉及用于除道路标记之外的其它应用的改进的反应性树脂。 本发明特别涉及包含核 - 壳颗粒的反应性树脂。
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公开(公告)号：US20140323001A1
公开(公告)日：2014-10-30
申请号：US14360442
申请日：2012-11-06
CPC分类号： C08J3/24 , B29B13/00 , C08J5/04 , C08J5/24 , Y10T442/20
摘要： In the present process, reversibly crosslinking composites or storage-stable prepregs are produced by means of a hetero Diels-Alder reactions (HDA,) for example of PMMA polymers. At slightly elevated temperature, these prepregs can be reversibly decrosslinked again by a retro hetero Diels-Alder reaction so that they become moldable. The back-reaction to products which are again crosslinked or high molecular weight then takes place at room temperature.
摘要翻译： 在本方法中，可逆交联的复合材料或储存稳定的预浸料通过例如PMMA聚合物的异质Diels-Alder反应（HDA）产生。 在稍微升高的温度下，这些预浸料坯可以通过复杂的异质Diels-Alder反应再次可逆地交联，使得它们变成可模塑的。 然后对于再次交联或高分子量的产物进行反应，然后在室温下进行。
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公开(公告)号：US20120289657A1
公开(公告)日：2012-11-15
申请号：US13519169
申请日：2011-01-04
申请人： Stefan Hilf , Friedrich Georg Schmidt , Andre Hennig , Simon Krause , Christopher Barner-Kowollik , Andrew John Inglis , Leena Nebhani
发明人： Stefan Hilf , Friedrich Georg Schmidt , Andre Hennig , Simon Krause , Christopher Barner-Kowollik , Andrew John Inglis , Leena Nebhani
CPC分类号： C09J4/00 , B33Y70/00 , C08F8/00 , C08F8/26 , C08F8/34 , C08G81/02 , C08J3/246 , C08K5/38 , C09D11/00 , C08F120/14
摘要： The present invention relates to an innovative method for controlling the viscosity of, for example, adhesives or coating formulations. The method for controlling viscosity allows very rapid thermoplastic curing of a formulation even at room temperature and a significant reduction in the viscosity at higher temperatures, thereby regaining the capacity for simple processing and allowing, for example, the originally bonded substrates to be separated from one another again with ease. A particular aspect in this context is that a plurality of cycles of thermoplastic curing and a significant reduction in the viscosity are possible with the present system.
摘要翻译： 本发明涉及用于控制例如粘合剂或涂料制剂的粘度的创新方法。 用于控制粘度的方法即使在室温下也能快速地热处理制剂，并且在较高温度下粘度显着降低，从而恢复简单加工的能力，并且允许例如将原始粘结的基材从一个 另一个又轻松的。 在本文中的一个特定方面是，本系统可以进行热塑性固化的多个循环和粘度的显着降低。
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公开(公告)号：US09550851B2
公开(公告)日：2017-01-24
申请号：US14651317
申请日：2013-11-11
申请人： Christopher Barner-Kowollik , Kim Klaus Oehlenschlaeger , Stefan Hilf , Friedrich Georg Schmidt , Nathalie Guimard , Jan Mueller
发明人： Christopher Barner-Kowollik , Kim Klaus Oehlenschlaeger , Stefan Hilf , Friedrich Georg Schmidt , Nathalie Guimard , Jan Mueller
IPC分类号： C09J133/14 , C09J141/00 , C09J147/00 , C09D133/14 , C09D141/00 , C09D147/00 , C09D11/00 , C08F236/22 , C09D4/00 , C09J4/00 , C08F220/10 , C08F220/28 , C08F234/04 , C09D133/08 , C09J133/08
CPC分类号： C08F236/22 , C08F220/10 , C08F220/28 , C08F234/04 , C08F2220/281 , C09D4/00 , C09D11/00 , C09D133/08 , C09D133/14 , C09D141/00 , C09D147/00 , C09J4/00 , C09J133/08 , C09J133/14 , C09J141/00 , C09J147/00
摘要： A method for the reversible crosslinking of, for example, adhesives or coating materials, and a composition stable on storage at room temperature for implementing the crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it contains two components, A and B, where component A is a compound having at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.
摘要翻译： 用于例如粘合剂或涂层材料的可逆交联的方法以及在室温下储存以稳定实施交联反应的组合物。 可逆交联方法即使在低的第一温度也允许非常快速的交联，并且在更高的温度下还能消除交联，从而回收热塑性的加工性，并且例如允许原来粘结的基材再次彼此分离。 特别的方面是本发明的系统可以交联和消除交联的多个循环。 用于可逆交联的系统的特征在于其包含两种组分A和B，其中组分A是具有至少两个受保护的二硫代酯官能度的化合物，优选氰基二硫代酯官能团，组分B是具有至少两个二烯 功能。
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公开(公告)号：US20130303678A1
公开(公告)日：2013-11-14
申请号：US13988147
申请日：2011-10-12
IPC分类号： C08L33/08 , C09J133/08 , C09D11/00 , C09D133/08
CPC分类号： C08L33/08 , B33Y70/00 , C08F2/60 , C08J3/243 , C08J3/246 , C09D11/00 , C09D133/08 , C09J133/08
摘要： The present invention relates to innovative materials which can be crosslinked by means of two different crosslinking mechanisms, the first crosslinking mechanism being an irreversible crosslinking. The second crosslinking mechanism is a thermoreversible mechanism.As a result of this thermoreversible change in the arc length, properties of the crosslinked material can be decisively changed and controlled, including flexibility, elasticity and other mechanical properties, but also chemical properties, the gas permeability and vapour permeability and storage capacity of the network. In this way it would be possible, for example, to store energy sources such as fuels.
摘要翻译： 本发明涉及可通过两种不同交联机理交联的创新材料，第一交联机理是不可逆交联。 第二种交联机制是一种热可逆机制。 由于电弧长度的这种热可逆变化，交联材料的性能可以被决定性地改变和控制，包括柔性，弹性等机械性能，还包括化学性质，透气性和透气性以及网络的储存能力 。 以这种方式，例如可能存储诸如燃料的能量源。
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8.发明申请MOULDINGS BASED ON DIENE-FUNCTIONALIZED (METH)ACRYLATES AND (HETERO-)DIELS-ALDER DIENOPHILES, WITH REVERSIBLE CROSSLINKING 审中-公开基于二烯官能化（甲基）丙烯酸酯和（异 - ）二甲苯二异氰酸酯的模具，具有可逆交联公开(公告)号：US20160304683A1
公开(公告)日：2016-10-20
申请号：US15037833
申请日：2014-11-06
CPC分类号： C08J5/24 , B29B13/02 , B29B13/08 , B29B15/10 , B29C35/02 , B29C35/16 , B29C70/48 , B29K2033/08 , B29L2031/753 , C08F220/18 , C08J2333/12 , C08F220/40 , C08F220/38 , C08F220/36
摘要： The invention relates to a method for the production of storage-stable prepregs and moulded objects produced therefrom (composite components). The composition used according to the invention for the production of the prepregs here contains A) monomers, in particular (meth)acrylates and/or styrene, B) at least one (meth)acrylate with a residue which contains a conjugated diene, C) a crosslinker having at least two dienophilic groups, and D) at least one suitable initiator.Alternatively, instead of or additionally to the components B) and C), the composition can contain a product C′ of a Diels-Alder reaction of the two components B) and C).
摘要翻译： 或者，代替组分B）和C），组合物可以包含两种组分B）和C）的Diels-Alder反应的产物C'。
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公开(公告)号：US09169363B2
公开(公告)日：2015-10-27
申请号：US14360442
申请日：2012-11-06
CPC分类号： C08J3/24 , B29B13/00 , C08J5/04 , C08J5/24 , Y10T442/20
摘要： In the present process, reversibly crosslinking composites or storage-stable prepregs are produced by means of a hetero Diels-Alder reactions (HDA,) for example of PMMA polymers. At slightly elevated temperature, these prepregs can be reversibly decrosslinked again by a retro hetero Diels-Alder reaction so that they become moldable. The back-reaction to products which are again crosslinked or high molecular weight then takes place at room temperature.
摘要翻译： 在本方法中，可逆交联的复合材料或储存稳定的预浸料通过例如PMMA聚合物的异质Diels-Alder反应（HDA）产生。 在稍微升高的温度下，这些预浸料坯可以通过复杂的异质Diels-Alder反应再次可逆地交联，使得它们变成可模塑的。 然后对于再次交联或高分子量的产物进行反应，然后在室温下进行。
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公开(公告)号：US08987380B2
公开(公告)日：2015-03-24
申请号：US13519169
申请日：2011-01-04
申请人： Stefan Hilf , Friedrich Georg Schmidt , Andre Hennig , Simon Krause , Christopher Barner-Kowollik , Andrew John Inglis , Leena Nebhani
发明人： Stefan Hilf , Friedrich Georg Schmidt , Andre Hennig , Simon Krause , Christopher Barner-Kowollik , Andrew John Inglis , Leena Nebhani
IPC分类号： C08L33/12 , C08F120/10 , C08L45/00 , C08L33/08 , C08L81/00 , C09J4/00 , C08F8/00 , C08F8/26 , C08F8/34 , C08G81/02 , C08J3/24 , C09D11/00 , C08K5/38
CPC分类号： C09J4/00 , B33Y70/00 , C08F8/00 , C08F8/26 , C08F8/34 , C08G81/02 , C08J3/246 , C08K5/38 , C09D11/00 , C08F120/14
摘要： The present invention relates to an innovative method for controlling the viscosity of, for example, adhesives or coating formulations. The method for controlling viscosity allows very rapid thermoplastic curing of a formulation even at room temperature and a significant reduction in the viscosity at higher temperatures, thereby regaining the capacity for simple processing and allowing, for example, the originally bonded substrates to be separated from one another again with ease. A particular aspect in this context is that a plurality of cycles of thermoplastic curing and a significant reduction in the viscosity are possible with the present system.
摘要翻译： 本发明涉及用于控制例如粘合剂或涂料制剂的粘度的创新方法。 用于控制粘度的方法即使在室温下也能快速地热处理制剂，并且在较高温度下粘度显着降低，从而恢复简单加工的能力，并且允许例如将原始粘结的基材从一个 另一个又轻松的。 在本文中的一个特定方面是，本系统可以进行热塑性固化的多个循环和粘度的显着降低。
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