摘要:
The invention is directed to the use of multifunctional thiol compounds as adhesion promoters and/or primers to enhance the adhesion of photo or electron beam curable polymers, coatings, adhesives, or sealants to gold, other precious metals, and their alloys. Actinic radiation and electron beam (nullEBnull) radiation can be used to cure such compositions. The resulting cured compositions are optically clear, low Tg (null30null C.), high refractive index (>1.50 at 1541 nm), thermally, oxidatively, and hydrolytically stable adhesives and/or coatings for glass and/or metal. The adhesive compositions containing such multifunction thiols can survive, without delamination or separation, testing conditions of 85null C. and 85% relative humidity (nullRHnull) for a time in excess of 500 hours. In particular embodiments the invention is directed to the use of oligomers or prepolymers formed from the reaction of one or a plurality of multifunctional maleimide compounds with one or a plurality of multifunctional thiols to form materials for use in adhesives or compositions suitable for adhesive use in optical communications.
摘要:
A method for the reversible crosslinking of, for example, adhesives or coating materials, and a composition stable on storage at room temperature for implementing the crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it contains two components, A and B, where component A is a compound having at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.
摘要:
A composition for a pressure-sensitive adhesive, includes (A) a (meth)acrylic ester polymer having a trithiocarbonate structure, having hydroxyl groups at both ends of a molecule and having a weight-average molecular weight (Mw), as measured by gel permeation chromatography, of 50,000 to 300,000, and (B) an isocyanate compound having an average number of isocyanate groups in one molecule being more than 2.
摘要:
The present invention relates to an innovative method for the reversible crosslinking of, for example, adhesives or coating materials, and to a composition stable on storage at room temperature for implementing this crosslinking reaction.The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect here is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it consists of two components, A and B, in which component A is a compound comprising at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.
摘要:
The invention relates to a process for preparing pressure-sensitive adhesives (PSAs) which have high molar masses in combination with a narrow molar mass distribution, and also to PSAs, especially polyacrylate-based PSAs, prepared accordingly. It has been found that, surprisingly, polymers with high molar masses and a narrow molar mass distribution, more particularly polyacrylates with high molar masses and a narrow molar mass distribution, can be prepared outstandingly in particular by means of RAFT processes in the presence of a diradical initiator which undergoes thermal cyclization to form a diradical, these polymers being suitable for use as high-shear-strength PSAs.
摘要:
The present invention relates to a polyester film having an antistatic highly adhesive layer and a process for producing the film, said layer comprising a copolymer (A) and a (co)polymer (B), said copolymer (A) being obtained by copolymerizing ##STR1## N-methylol acrylamide, and optionally an ethylenic compound having a carboxy group, and optionally a comonomer, and said (co)polymer (B) being obtained by copolymerizing ##STR2## and optionally a comonomer. The polyester film of the present invention is useful for magnetic cards and the like.
摘要:
Embodiments provide adhesives for apparel products. The apparel product includes a major component and a minor component. The major component forms a base portion of the apparel product and is configured to be supported and worn at least partially over a portion of a wearer. The minor component of the apparel product forms a secondary portion and is configured to be coupled to the major component. An adhesive is disposed at least partially between a portion of the major component and a portion of the minor component. The adhesive includes a material having a thioester bond.
摘要:
A hot melt adhesive comprises a polylactide homopolymer or copolymer, such as polylactic acid; sulfonated copolyester; and at least one plasticizer, and is compostable. The plasticizer may be a solid plasticizer, such as a benzoate, and a second plasticizer may also be used. The adhesive is suitable for use in a variety of applications, such as case and carton applications, use with burlap or other compostable substrates for tree bulbs or plant seeds, and use with other compostable films, and is especially appropriate for dual-walled paperboard beverage cups. The adhesive demonstrates good bond performance comparable to non-compostable adhesives over a range of temperatures, reflective of the temperatures of hot and cold beverages.
摘要:
There is provided a waterborne adhesive composition comprising a vinyl polymer that comprises a) 0 to 0.4% polymerized units of carboxyl functional monomer, by weight based on the weight of said vinyl polymer, and (b) 0.1% to 10% polymerized units of sulfonic acid functional monomer, by weight based on the weight of said vinyl polymer. Also provided is a method of bonding substrates with such a composition and a bonded article made by such a method.
摘要:
The invention is directed to the use of multifunctional thiol compounds as adhesion promoters and/or primers to enhance the adhesion of photo or electron beam curable polymers, coatings, adhesives, or sealants to gold, other precious metals, and their alloys. Actinic radiation and electron beam (“EB”) radiation can be used to cure such compositions. The resulting cured compositions are optically clear, low Tg (≦30° C.), high refractive index (>1.50 at 1541 nm), thermally, oxidatively, and hydrolytically stable adhesives and/or coatings for glass and/or metal. The adhesive compositions containing such multifunction thiols can survive, without delamination or separation, testing conditions of 85° C. and 85% relative humidity (“RH”) for a time in excess of 500 hours. In particular embodiments the invention is directed to the use of oligomers or prepolymers formed from the reaction of one or a plurality of multifunctional maleimide compounds with one or a plurality of multifunctional thiols to form materials for use in adhesives or compositions suitable for adhesive use in optical communications.