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    Process for producing chemicals from oxygenate
    2.
    发明授权
    Process for producing chemicals from oxygenate 失效
    从含氧化合物生产化学品的方法

    公开(公告)号：US06506954B1

    公开(公告)日：2003-01-14

    申请号：US09687749

    申请日：2000-10-13

    申请人： Stephen H. Brown ,  Larry A. Green ,  Mark F. Mathias ,  David H. Olson ,  Robert A. Ware ,  William A. Weber ,  Reuel Shinnar

    发明人： Stephen H. Brown ,  Larry A. Green ,  Mark F. Mathias ,  David H. Olson ,  Robert A. Ware ,  William A. Weber ,  Reuel Shinnar

    IPC分类号： C07C120

    CPC分类号： C07C2/865 ,  C07C1/20 ,  C07C2/864 ,  C07C15/073 ,  C07C15/08 ,  C07C2521/02 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2527/16 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C07C2529/85 ,  Y02P30/42

    摘要： There is provided a process for converting methanol and/or dimethyl ether to a product containing olefin, e.g., C2 to C4 olefins, C9+ aromatics and non-C9+ aromatics which comprises: 1) contacting a feed which contains methanol and/or dimethyl ether with a catalyst comprising a porous crystalline material, said contacting step being conducted in the presence of aromatics comprising C9 or C9+ aromatic compound produced in said process under conversion conditions including a temperature of 350° C. to 480° C. and a methanol partial pressure in excess of 10 psia (70 kPa), said porous crystalline material having a Diffusion Parameter for 2,2-dimethylbutane of about 0.1 sec−1 to about 20 sec−1 when measured at a temperature of 120° C. and a 2,2-dimethylbutane pressure of 60 torr (8 kPa), and the aromatics being capable of alkylation by the methanol and/or dimethyl ether under said conversion conditions to provide a stream which contains C2 to C4 olefins and C9 or C9+ aromatic compound; 2) separating said stream to form a substantially C2 to C4 olefin product stream and a substantially C9 or C9+ aromatic compound stream; and 3) recycling at least a portion of said substantially C9 or C9+ aromatic compound stream to step 1).

    摘要翻译： 提供了将甲醇和/或二甲醚转化为含烯烃的产物，例如C 2 -C 4烯烃，C 9+芳族化合物和非C 9+芳族化合物的方法，其包括：1）将含有甲醇和/或二甲醚的进料与 包括多孔结晶材料的催化剂，所述接触步骤在包含C9或C9 +芳族化合物的芳族化合物存在下进行，所述芳族化合物在所述方法中产生的转化条件包括350℃至480℃的温度和甲醇分压 超过10psia（70kPa）时，当在120℃的温度下测量时，所述多孔结晶材料具有约0.1秒-1至约20秒-1的2,2-二甲基丁烷扩散参数和2,2 二甲基丁烷压力为60乇（8kPa），芳族化合物在所述转化条件下能够通过甲醇和/或二甲醚进行烷基化，以提供含有C 2 -C 4烯烃和C 9或C 9+芳族化合物的物流; 2） 使所述流形成基本上C2至C4烯烃产物流和基本上C9或C9 +芳族化合物流; 和3）将至少一部分所述基本上C9或C9 +芳族化合物流再循环到步骤1）。

    Process for converting methanol to olefins
    4.
    发明授权
    Process for converting methanol to olefins 失效
    将甲醇转化为烯烃的方法

    公开(公告)号：US06613951B1

    公开(公告)日：2003-09-02

    申请号：US09401078

    申请日：1999-09-23

    申请人： Stephen H. Brown ,  Reuel Shinnar ,  William A. Weber

    发明人： Stephen H. Brown ,  Reuel Shinnar ,  William A. Weber

    IPC分类号： C07C120

    CPC分类号： C07C1/20 ,  C07C2529/40 ,  Y02P30/42

    摘要： There is provided a process for converting methanol or dimethyl ether to a product containing C2 to C4 olefins, which comprises the step of contacting a feed containing methanol or dimethyl ether with a catalyst which comprises a zeolite having 10-ring intersecting channels, such as ZSM-5, and which has a Diffusion Parameter for 2,2-dimethylbutane of less than 100 sec−1 when measured at a temperature of 120° C. and a 2,2-dimethylbutane pressure of 60 torr (8 kPa). The contacting step is conducted at a temperature of 370 to 480° C., a methanol partial pressure of 30 to 150 psia and a methanol conversion per pass of less than 95%.

    摘要翻译： 提供了一种将甲醇或二甲醚转化为含有C2至C4烯烃的产物的方法，其包括使含有甲醇或二甲醚的进料与包含具有10环相交通道的沸石如ZSM的催化剂接触的步骤 -5，当在120℃的温度和60托（8kPa）的2,2-二甲基丁烷压力下测量时，其具有小于100秒-1的2,2-二甲基丁烷的扩散参数。 接触步骤在370至480℃的温度，30至150psia的甲醇分压和小于95％的每次通过的甲醇转化率下进行。

    Process for converting dienes and oxygenates to para-xylene and light olefins
    9.
    发明授权
    Process for converting dienes and oxygenates to para-xylene and light olefins 失效
    将二烯和含氧化合物转化为对二甲苯和轻质烯烃的方法

    公开(公告)号：US06187982B1

    公开(公告)日：2001-02-13

    申请号：US09419228

    申请日：1999-10-15

    申请人： Jeffrey S. Beck ,  Stephen H. Brown ,  William A. Weber

    发明人： Jeffrey S. Beck ,  Stephen H. Brown ,  William A. Weber

    IPC分类号： C07C200

    CPC分类号： C10G55/04 ,  C07C1/20 ,  C07C2529/40 ,  C10G29/16 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P30/42

    摘要： A process useful in steam cracking is disclosed for selectively converting a feed comprising C4+ dienes and oxygenate to a product comprising increased C2+ monoolefins and para-xylene levels by contacting said feed under diolefin conversion conditions with a catalyst comprising a porous crystalline material having a Diffusion Parameter for 2,2-dimethylbutane of about 0.1-100 sec−1 when measured at a temperature of 120° C. and a 2,2-dimethylbutane pressure of 60 torr (8 kPa), a temperature of 430° C. and 0.5 WHSV.

    摘要翻译： 公开了一种可用于蒸汽裂化的方法，用于通过使二烯烃转化条件下的所述进料与包含具有扩散参数的多孔结晶材料的催化剂接触来选择性地将包含C4 +二烯和含氧化合物的进料转化成包含增加的C2 +单烯烃和对二甲苯含量的产物 对于在120℃的温度和60托（8kPa）的2,2-二甲基丁烷压力下测量的约0.1-100秒-1的2,2-二甲基丁烷，温度为430℃和0.5WHSV 。

    Conversion of unsaturated chemicals to oligomers
    10.
    发明授权
    Conversion of unsaturated chemicals to oligomers 失效
    不饱和化合物转化为低聚物

    公开(公告)号：US07626066B2

    公开(公告)日：2009-12-01

    申请号：US11716088

    申请日：2007-03-09

    申请人： Stephen H. Brown ,  Robert A. Crane, Jr. ,  Robert J. Saxton ,  William A. Weber

    发明人： Stephen H. Brown ,  Robert A. Crane, Jr. ,  Robert J. Saxton ,  William A. Weber

    IPC分类号： C07C2/10

    CPC分类号： C10G50/02 ,  C10G50/00

    摘要： An oligomerization process in which hydrocarbon feedstocks are contacted with a hydrotreating catalyst in the absence of hydrogen and in the liquid phase. The catalyst is a heterogeneous catalyst selected from supported reduced metals, metals oxides, metal sulfides and combinations thereof. Preferred catalysts include mixed nickel and molybdenum oxides or mixed cobalt and molybdenum oxides. The process also oligomerizes sulfur compounds so that sulfur containing feedstocks can be treated without deactivating the catalysts.

    摘要翻译： 一种低聚方法，其中烃原料在不存在氢气和液相下与加氢处理催化剂接触。 催化剂是选自负载的还原金属，金属氧化物，金属硫化物及其组合的多相催化剂。 优选的催化剂包括混合的镍和钼氧化物或混合的钴和钼氧化物。 该方法还使硫化合物低聚，使得含硫原料可以在不使催化剂失活的情况下进行处理。