公开(公告)号：US20100154867A1

公开(公告)日：2010-06-24

申请号：US12626088

申请日：2009-11-25

申请人： Stephen J. Bennison ,  Kristof Proost ,  Richard Allen Hayes

发明人： Stephen J. Bennison ,  Kristof Proost ,  Richard Allen Hayes

IPC分类号： H01L31/048 ,  B32B37/00 ,  B29C65/02

CPC分类号： B32B17/10036 ,  B32B17/10174 ,  B32B17/10743 ,  B32B37/1018 ,  B32B2309/10 ,  B32B2327/12 ,  B32B2457/12 ,  H01L31/02008 ,  H01L31/0488 ,  Y02E10/50 ,  Y10T156/10

摘要： A thin film solar cell module comprising thin film solar cells deposited on a first float glass sheet, an ionomer encapsulant sheet and a float glass protective sheet.

摘要翻译： 一种薄膜太阳能电池模块，包括沉积在第一浮法玻璃板上的薄膜太阳能电池，离子聚合物密封片和浮法玻璃保护片。

公开(公告)号：US20090250100A1

公开(公告)日：2009-10-08

申请号：US12417692

申请日：2009-04-03

申请人： Richard Allen Hayes ,  Rebecca L. Smith ,  Kristof Proost

发明人： Richard Allen Hayes ,  Rebecca L. Smith ,  Kristof Proost

IPC分类号： H01L31/048 ,  B32B37/10 ,  B32B37/14

CPC分类号： B32B17/10761 ,  B32B17/10018 ,  B32B17/10853 ,  B32B37/1018 ,  B32B2309/02 ,  B32B2309/105 ,  B32B2309/12 ,  B32B2327/12 ,  B32B2329/06 ,  B32B2457/12 ,  H01L31/048 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T156/10

摘要： A solar cell module comprising a solar cell layer comprised of one or a plurality of electrically interconnected solar cells and an encapsulant layer comprised or made of a poly(vinyl butyral) sheet having melt flow rate (MFR) of about 0.8 to about 2 g/10 min as determined according to ASTM 1238 (150° C., 5 kg load, 2 mm orifice) and a process for producing the same.

摘要翻译： 一种太阳能电池模块，包括由一个或多个电互连的太阳能电池组成的太阳能电池层和由熔体流动速率（MFR）为约0.8至约2g / m 2的聚（乙烯醇缩丁醛）片材制成或制成的密封剂层， 根据ASTM 1238（150℃，5kg负荷，2mm孔）测定的10分钟及其制备方法。

公开(公告)号：US08445776B2

公开(公告)日：2013-05-21

申请号：US12475776

申请日：2009-06-01

申请人： Richard Allen Hayes ,  Rebecca L. Smith ,  Kristof Proost ,  Steven C. Pesek ,  Charles Anthony Smith

发明人： Richard Allen Hayes ,  Rebecca L. Smith ,  Kristof Proost ,  Steven C. Pesek ,  Charles Anthony Smith

IPC分类号： H01L25/00 ,  H01L31/042 ,  B32B37/02 ,  C08F220/06 ,  C08F118/02

CPC分类号： B32B17/10743 ,  B32B9/005 ,  B32B15/04 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10853 ,  B32B27/06 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/283 ,  B32B27/286 ,  B32B27/302 ,  B32B27/304 ,  B32B27/306 ,  B32B27/308 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B27/38 ,  B32B27/40 ,  B32B2255/26 ,  B32B2270/00 ,  B32B2307/3065 ,  B32B2307/308 ,  B32B2307/412 ,  B32B2307/54 ,  B32B2307/558 ,  B32B2327/12 ,  B32B2457/00 ,  H01L31/0481 ,  Y02E10/549 ,  Y02P70/521 ,  Y10T156/10 ,  Y10T156/1093 ,  C08F210/02 ,  C08F220/06 ,  C08F2500/12

摘要： A solar cell module comprising a solar cell layer and a sheet comprising at least one layer of a sodium ionomer composition, wherein the sodium ionomer composition consists essentially of a sodium ionomer that is an ionic, neutralized derivative of a precursor α-olefin carboxylic acid copolymer, wherein about 10% to about 35% of the total content of the carboxylic acid groups present in the precursor α-olefin carboxylic acid copolymer have been neutralized with sodium ions, and wherein the precursor α-olefin carboxylic acid copolymer comprises (i) copolymerized units of an α-olefin having 2 to 10 carbons and (ii) about 20 to about 25 wt %, based on the total weight of the α-olefin carboxylic acid copolymer, of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8.

摘要翻译： 一种太阳能电池模块，包括太阳能电池层和包含至少一层钠离子交联聚合物组合物的片材，其中所述钠离聚物组合物基本上由钠离子交联聚合物组成，所述钠离聚物是前体α-烯烃羧酸共聚物的离子型中​​和衍生物 ，其中存在于前体α-烯烃羧酸共聚物中的羧酸基团的总含量的约10％至约35％已经用钠离子中和，并且其中前体α-烯烃羧酸共聚物包含（i）共聚的 具有2至10个碳的α-烯烃的单元和（ii）基于α-烯烃羧酸共聚物的总重量的约20至约25重量％的α，β-烯属不饱和羧酸的共聚单元 有3到8。

公开(公告)号：US20100167061A1

公开(公告)日：2010-07-01

申请号：US12610701

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/08 ,  B32B27/00 ,  B32B27/40 ,  B32B17/10

CPC分类号： B32B17/10743 ,  B32B17/10018 ,  B32B2367/00 ,  Y10T428/31507 ,  Y10T428/31573 ,  Y10T428/31645 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31938

摘要： A laminate comprises an ionomeric interlayer sheet which, in turn, comprises or is prepared from a sodium/zinc mixed ionomer that comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 70 to about 1000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry.

摘要翻译： 层压材料包括离聚物中间层片材，其又包含钠盐/锌混合离子交换聚合物或由钠/锌混合离聚​​物制备，所述钠/锌混合离聚​​物包含羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约70至约1000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。

公开(公告)号：US20100112356A1

公开(公告)日：2010-05-06

申请号：US12610688

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B17/10 ,  B32B27/32 ,  B32B15/08 ,  B32B27/36

CPC分类号： C08F220/06 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  Y10T428/31507 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31938

摘要： A safety laminate comprises an interlayer that comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of a first α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of a first α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; and has a melt flow rate of about 10 to about 4000 g/10 min. When neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. The ionomer composition may further comprise a second ionomer that has a melt flow rate of about 10 g/10 min or less.

摘要翻译： 安全层压板包括中间层，其包含作为前体酸共聚物的中和物的离聚物。 前体酸共聚物包含具有2至10个碳原子的第一α-烯烃和约20至约30重量％的具有3-8个碳原子的第一个α，β-烯属不饱和羧酸的共聚单元的共聚单元; 并具有约10至约4000g / 10min的熔体流动速率。 当中和至约40％至约90％的水平时，当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生熔体流动速率为约0.7至约25g / 10min的钠离聚物， 不可检测的或低于约3.0J / g的冷冻焓。 离聚物组合物还可以包含熔体流动速率为约10g / 10分钟或更短的第二离聚物。

公开(公告)号：US20090242030A1

公开(公告)日：2009-10-01

申请号：US12411863

申请日：2009-03-26

申请人： CYNTHIA H. KIRSCHNER ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Richard Allen Hayes ,  David F. Kristunas

发明人： CYNTHIA H. KIRSCHNER ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Richard Allen Hayes ,  David F. Kristunas

IPC分类号： H01L31/0256

CPC分类号： B32B27/08 ,  B32B7/12 ,  B32B9/005 ,  B32B9/045 ,  B32B15/08 ,  B32B15/09 ,  B32B17/064 ,  B32B17/10018 ,  B32B17/10743 ,  B32B17/10761 ,  B32B17/10853 ,  B32B18/00 ,  B32B27/16 ,  B32B27/18 ,  B32B27/22 ,  B32B27/28 ,  B32B27/30 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/38 ,  B32B27/40 ,  B32B27/42 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2270/00 ,  B32B2307/50 ,  B32B2307/518 ,  B32B2307/54 ,  B32B2307/554 ,  B32B2307/558 ,  B32B2307/734 ,  B32B2367/00 ,  B32B2419/00 ,  B32B2457/12 ,  B32B2605/006 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T428/24942 ,  Y10T428/26 ,  Y10T428/31511 ,  Y10T428/31565 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31797

摘要： Provided is a high performance anti-spall laminate article comprising a bi-layer polymeric composite. The bi-layer composite includes a polymeric sheet and a poly(ethylene terephthalate) (PET) film laminated to each other. The PET film has a tensile modulus of about 600,000 psi or higher in both the machine direction (MD) and the transverse direction (TD), a shock brittleness index of about 55 Joules or higher in the machine direction and about 25 joules or higher in the transverse direction, and a percent elongation at break (EOB) of about 110-160 in the machine direction and about 60-110 in the transverse direction.

摘要翻译： 提供了一种包含双层聚合物复合材料的高性能防剥落层压制品。 双层复合材料包括聚合物片材和彼此层压的聚对苯二甲酸乙二醇酯（PET）膜。 PET膜在机械方向（MD）和横向（TD）上的拉伸模量为约600,000psi或更高，冲击脆性指数在机器方向约为55焦耳或更高，约25焦耳或更高 横向和百分比断裂伸长率（EOB）在机器方向约为110-160°，横向方向为约60-110。

公开(公告)号：US08399098B2

公开(公告)日：2013-03-19

申请号：US12610701

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/08 ,  B32B27/00 ,  B32B27/40 ,  B32B17/10 ,  C08F20/06 ,  C08F8/00 ,  C08L31/00

CPC分类号： B32B17/10743 ,  B32B17/10018 ,  B32B2367/00 ,  Y10T428/31507 ,  Y10T428/31573 ,  Y10T428/31645 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31938

摘要： A laminate comprises an ionomeric interlayer sheet which, in turn, comprises or is prepared from a sodium/zinc mixed ionomer that comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 70 to about 1000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry.

摘要翻译： 层压材料包括离聚物中间层片材，其又包含钠盐/锌混合离子交换聚合物或由钠/锌混合离聚​​物制备，所述钠/锌混合离聚​​物包含羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约70至约1000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。

公开(公告)号：US08399097B2

公开(公告)日：2013-03-19

申请号：US12610688

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B17/10 ,  B32B27/32 ,  B32B15/08 ,  B32B27/36

CPC分类号： C08F220/06 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  Y10T428/31507 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31938

摘要： A safety laminate comprises an interlayer that comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of a first α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of a first α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; and has a melt flow rate of about 10 to about 4000 g/10 min. When neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. The ionomer composition may further comprise a second ionomer that has a melt flow rate of about 10 g/10 min or less.

摘要翻译： 安全层压板包括中间层，其包含作为前体酸共聚物的中和物的离聚物。 前体酸共聚物包含具有2至10个碳原子的第一α-烯烃和约20至约30重量％的具有3-8个碳原子的第一个α，β-烯属不饱和羧酸的共聚单元的共聚单元; 并具有约10至约4000g / 10min的熔体流动速率。 当中和至约40％至约90％的水平时，当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生熔体流动速率为约0.7至约25g / 10min的钠离聚物， 不可检测的或低于约3.0J / g的冷冻焓。 离聚物组合物还可以包含熔体流动速率为约10g / 10分钟或更短的第二离聚物。

公开(公告)号：US07960017B2

公开(公告)日：2011-06-14

申请号：US11584988

申请日：2006-10-23

申请人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Stephen J. Bennison ,  Richard Allen Hayes

发明人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Stephen J. Bennison ,  Richard Allen Hayes

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/30 ,  B32B17/06

CPC分类号： B32B17/10036 ,  B32B17/10743 ,  B32B27/08 ,  B32B27/302 ,  B32B27/308 ,  B32B27/32 ,  B32B27/365 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0876 ,  C08L33/02 ,  C08L2205/02 ,  Y10T428/31507 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938 ,  C08L2666/04 ,  C08L2666/06

摘要： The invention describes a polymeric sheet that has at least one layer that comprises an ionomer or ionomer blend that incorporates a partially neutralized alpha, beta-ethylenically unsaturated carboxylic acid component and is useful in glass laminate applications. The ionomer or ionomer blend contains one or more monovalent metal ions in an amount ranging from about 1 to about 60%, preferably about 10 to about 55%, and more preferably about 15 to about 50%, and one or more polyvalent metal ions in an amount ranging from about 40 to about 99%, preferably about 45 to about 90%, and more preferably about 50 to about 85%. This ratio range of monovalent and polyvalent metal neutralization ions provides synergistically greater adhesion to glass than found for either the monovalent or the polyvalent metal neutralization ions alone.

摘要翻译： 本发明描述了一种聚合物片材，其具有至少一层包含离聚物或离聚物共混物的层，该混合物掺入部分中和的α，β-烯键式不饱和羧酸组分，并且可用于玻璃层压应用。 离聚物或离聚物共混物含有一种或多种一价金属离子，其量为约1至约60％，优选约10至约55％，更优选约15至约50％，以及一种或多种多价金属离子 约40至约99％，优选约45至约90％，更优选约50至约85％的量。 单价和多价金属中和离子的这种比例范围提供了与单独或多价金属中和离子单独发现的对玻璃的协同增加的粘合力。

公开(公告)号：US20130225749A1

公开(公告)日：2013-08-29

申请号：US13407829

申请日：2012-02-29

申请人： Elliott Echt ,  Richard Allen Hayes

发明人： Elliott Echt ,  Richard Allen Hayes

IPC分类号： C08L29/04

CPC分类号： C08L29/04 ,  C08L23/0876

摘要： Disclosed is a composition comprising (a) a poly(vinyl alcohol) characterized by (i) a hydrolysis level of from about 85 to about 93 mole % and a 4 weight % aqueous viscosity at 20° C. of 15 centipoise or less; or (ii) a hydrolysis level of about 95 mole % or greater; and (b) an ionomer comprising a parent acid copolymer comprising copolymerized units of ethylene and acrylic acid or methacrylic acid with melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts.

摘要翻译： 公开了一种组合物，其包含（a）聚（乙烯醇），其特征在于（i）水解度为约85-约93摩尔％，在20℃下的4重量％水性粘度为15厘泊或更小; 或（ii）约95摩尔％以上的水解度; 和（b）包含母体酸共聚物的离聚物，其包含乙烯和丙烯酸或甲基丙烯酸的共聚单元，熔体流动速率为约200至约1000g / 10min，其中约50％至约70％的羧酸 共聚物的基团被中和到羧酸盐。