摘要:
Provided is an alkali-metal titanate in which the content and adhesivity of the fibrous potassium titanate is significantly reduced.The alkali-metal titanate includes 0.5 mol to 2.2 mol of potassium oxide in terms of potassium atoms, 0.05 mol to 1.4 mol of sodium oxide in terms of sodium atoms, and 0 mol to 1.4 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate, in which a total content of potassium oxide in terms of potassium atoms, sodium oxide in terms of sodium atoms, and lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate is 1.8 mol to 2.3 mol; and the alkali-metal titanate has a single phase conversion ratio of 85% to 100%, a fiber ratio of 0% by volume to 10% by volume, and a moisture content of 0% by mass to 1.0% by mass.
摘要:
A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10−4 Scm−1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1−a)LaxLi2-3xTiO3-aSrTiO3, (1−a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55≦x≦0.59, 0≦a≦0.2, M=at least one of Fe or Ga), amount of Al contained is 0.35 mass % or less as Al2O3, amount of Si contained is 0.1 mass % or less as SiO2, and average particle diameter is 18 μm or more.
摘要:
A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10−4 Scm−1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1−a)LaxLi2-3xTiO3-aSrTiO3, (1−a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, and Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55≦x≦0.59, 0≦a≦0.2, M=at least one of Al, Fe and Ga), and concentration of S is 1500 ppm or less. The material is obtained by sintering raw material powder mixture having S content amount of 2000 ppm or less in the entirety of raw material powders for mixture, that is, titanium raw material, lithium raw material, and lanthanum raw material.
摘要:
Provided is an alkali-metal titanate in which the content and adhesivity of the fibrous potassium titanate is significantly reduced.The alkali-metal titanate includes 0.5 mol to 2.2 mol of potassium oxide in terms of potassium atoms, 0.05 mol to 1.4 mol of sodium oxide in terms of sodium atoms, and 0 mol to 1.4 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate, in which a total content of potassium oxide in terms of potassium atoms, sodium oxide in terms of sodium atoms, and lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate is 1.8 mol to 2.3 mol; and the alkali-metal titanate has a single phase conversion ratio of 85% to 100%, a fiber ratio of 0% by volume to 10% by volume, and a moisture content of 0% by mass to 1.0% by mass.
摘要:
A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10−4 Scm−1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1−a)LaxLi2-3xTiO3-aSrTiO3, (1−a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55≦x≦0.59, 0≦a≦0.2, M=at least one of Fe or Ga), amount of Al contained is 0.35 mass % or less as Al2O3, amount of Si contained is 0.1 mass % or less as SiO2, and average particle diameter is 18 μm or more.
摘要:
A method for producing a potassium titanate easily produces a potassium titanate having a high single phase ratio and a significantly reduced fibrous potassium titanate content in high yield. The method for producing a potassium titanate includes: a mixing step that mixes a titanium raw material with a potassium raw material, the titanium raw material including 0 to 60 mass % of titanium oxide having a specific surface area of 1 to 2 m2/g, 40 to 100 mass % of titanium oxide having a specific surface area of 7 to 200 m2/g, and 0 to 4.5 mass % in total of one or more materials selected from titanium metal and titanium hydride, and the potassium raw material including a potassium compound; a calcination step that calcines a raw material mixture obtained by the mixing step at a calcination temperature of 950 to 990° C.; and a grinding step that grinds a calcined powder obtained by the calcination step using one or more means selected from a vibrating mill and an impact pulverizer.
摘要:
A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10−4 Scm−1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1-a)LaxLi2-3xTiO3-aSrTiO3, (1-a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, and Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55≦x≦0.59, 0≦a≦0.2, M=at least one of Al, Fe and Ga), and concentration of S is 1500 ppm or less. The material is obtained by sintering raw material powder mixture having S content amount of 2000 ppm or less in the entirety of raw material powders for mixture, that is, titanium raw material, lithium raw material, and lanthanum raw material.
摘要:
A method for producing a potassium titanate easily produces a potassium titanate having a high single phase ratio and a significantly reduced fibrous potassium titanate content in high yield. The method for producing a potassium titanate includes: a mixing step that mixes a titanium raw material with a potassium raw material, the titanium raw material including 0 to 60 mass % of titanium oxide having a specific surface area of 1 to 2 m2/g, 40 to 100 mass % of titanium oxide having a specific surface area of 7 to 200 m2/g, and 0 to 4.5 mass % in total of one or more materials selected from titanium metal and titanium hydride, and the potassium raw material including a potassium compound; a calcination step that calcines a raw material mixture obtained by the mixing step at a calcination temperature of 950 to 990° C.; and a grinding step that grinds a calcined powder obtained by the calcination step using one or more means selected from a vibrating mill and an impact pulverizer.