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公开(公告)号：US5187250A
公开(公告)日：1993-02-16
申请号：US813057
申请日：1991-12-23
IPC分类号： C08F10/00 , C08F10/08 , C08F10/14 , C08F110/08 , C08F110/14
CPC分类号： C08F10/14 , C08F10/08 , C08F110/08 , C08F110/14 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A poly-.alpha.-olefin of novel structure which is an addition polymer of an .alpha.-olefin having 4 carbon atoms or more, wherein (a) by the analysis of the peaks attributable to the side chain methylene groups directly bonded to the main chain in the .sup.13 C-NMR spectrum produced by the measurement in 1,2,4-trichloro-benzene, (i) a novel main peak not attributable to the isotactic structure thereof is positioned on the side of higher magnetic field than is the peak attributable to the isotactic structure, and (ii) the intensity of said main peak is 0.3 or more relative to the sum of the intensities of the total peaks attributable to the side chain methylene groups directly bonded to the main chain, and (b) the molecular weight measured by gel permeation chromatography and calculated as polypropylene is not less than 1,000.
摘要翻译： 一种新型结构的聚α-烯烃，它是具有4个碳原子或更多碳原子的α-烯烃的加成聚合物，其中（a）通过分析直接键合到主链上的侧链亚甲基的峰 通过在1,2,4-三氯苯中测量产生的13 C-NMR光谱，（i）不能归因于其全同立构结构的新颖主峰位于比归因于 全同立构结构，和（ii）所述主峰的强度相对于直接键合到主链上的侧链亚甲基的总峰的强度之和为0.3以上，（b）测定的分子量 通过凝胶渗透色谱法测定，其聚丙烯计算值不小于1,000。
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2.发明授权公开(公告)号：US06255425B1
公开(公告)日：2001-07-03
申请号：US08182348
申请日：1994-01-18
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Osamu Uchida , Tutomu Iwatani , Shigeru Kimura , Takeo Inoue
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Osamu Uchida , Tutomu Iwatani , Shigeru Kimura , Takeo Inoue
IPC分类号： C08F21006
CPC分类号： C08J5/18 , C08F210/06 , C08J2323/10 , C08L23/10 , Y10S526/916 , Y10T428/1345 , Y10T428/1352 , Y10T428/1397 , C08F210/16 , C08F2500/16 , C08F2500/03 , C08F210/14 , C08F210/08
摘要： A syndiotactic polypropylene copolymer is disclosed which comprises 70 to 99.9 mole % of propylene and 0.1 to 30 mole % of an olefin other than propylene; in the 13C-NMR spectrum of the syndiotactic polypropylene copolymer, a ratio of the intensity of a peak at about 20.2 ppm to the sum of the intensities of the total peaks attributable to methyl groups in propylene units at about 19-22 ppm being 0.3 or more. Also disclosed are extrusion-molded high-transparency articles, especially films and sheets and blown films, obtained by the extrusion of a polypropylene substantially having a syndiotactic structure.
摘要翻译： 公开了间同立构聚丙烯共聚物，其包含70-99.9摩尔％的丙烯和0.1-30摩尔％的除丙烯以外的烯烃; 在间同立构聚丙烯共聚物的13 C-NMR光谱中，约20.2ppm处的峰强度与归属于丙烯单元的甲基的总峰的强度的总和的比例为约为19-22ppm，为0.3或 更多。 还公开了挤出成型的高透明度制品，特别是通过挤出基本上具有间同立构结构的聚丙烯获得的薄膜和片材和吹塑薄膜。
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公开(公告)号：US5478646A
公开(公告)日：1995-12-26
申请号：US15056
申请日：1993-02-08
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Shigeru Kimura , Nobutaka Uchikawa , Yoichi Kawai , Keigo Suehiro , Satoshi Fukushima
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Shigeru Kimura , Nobutaka Uchikawa , Yoichi Kawai , Keigo Suehiro , Satoshi Fukushima
CPC分类号： D01F6/06 , Y10T428/2913 , Y10T428/2929 , Y10T428/2931
摘要： A fiber excellent in strength and having an average size of 10,000-0.1 denier can be obtained by extruding a raw material composed mainly of a polypropylene having a syndiotactic pentad fraction of 0.7 or more and optionally stretching the resulting extruded material.By using as the raw material a composition consisting of two kinds of polypropylenes each having an intrinsic viscosity .eta..sub.1 or .eta..sub.2, the log(.eta..sub.2 /.eta..sub.1) being more than 0.05 or less than -0.05, and a syndiotactic pentad fraction of 0.7 or more at a weight ratio of 95:5-5:95 or a composition consisting of at least 50 parts by weight of a syndiotactic polypropylene having the intrinsic viscosity .eta..sub.1 and a syndiotactic pentad fraction of 0.7 or above and at most 50 parts by weight of an isotactic polypropylene having the intrinsic viscosity .eta..sub.2, the extrudability is improved and the fiber stretching conditions are broadened.
摘要翻译： 通过将主要由间同立构五单元组分为0.7以上的聚丙烯组成的原料挤出并任选地拉伸所得的挤出材料，可以获得强度优异且平均粒径为10,000-0.1旦尼尔的纤维。 通过使用由两种各自具有特性粘度eta 1或eta 2的聚丙烯组成的组合物，log（eta 2 / eta 1）大于0.05或小于-0.05，并且间同立构五单元组分数 0.7重量％以上，重量比为95:5.5:95的组合物或由至少50重量份的特性粘度η1和间同立构五单元组分数为0.7以上至多50份的间同立构聚丙烯组成的组合物 的特性粘度等于2的全同立构聚丙烯，可挤出性提高，纤维拉伸条件变宽。
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4.发明授权Polypropylene resin compositions of high syndiotacticity and preparation process thereof 失效具有高间同立构规整度的聚丙烯树脂组合物及其制备方法
公开(公告)号：US5314956A
公开(公告)日：1994-05-24
申请号：US10787
申请日：1993-01-29
IPC分类号： C08F2/44 , C08F297/08 , C08L23/12 , C08L23/14 , C08L23/16
CPC分类号： C08F297/083 , C08L23/12 , C08L2207/12 , C08L23/14 , C08L23/142 , C08L23/16 , Y10S526/943
摘要： Disclosed herein is a polypropylene resin composition of a high syndiotacticity comprising a substantial homopolymer of propylene, in which the ratio of the intensity of the peak attributable to the syndiotactic pentad bonds to the sum of the intensities of all the peaks attributable to the methyl groups in the spectrum of the methyl groups measured by .sup.13 C-NMR is 0.7 or more, and a copolymer of ethylene and propylene, and a preparation process thereof.
摘要翻译： 本文公开了一种具有高间同立构规整性的聚丙烯树脂组合物，其包含基本上均匀的丙烯均聚物，其中归因于间同立构五键键的峰的强度与归因于甲基的所有峰的强度之和的比值 通过13 C-NMR测定的甲基的光谱为0.7以上，乙烯与丙烯的共聚物及其制备方法。
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公开(公告)号：US5266641A
公开(公告)日：1993-11-30
申请号：US013175
申请日：1993-01-29
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Tateyo Sasaki , Tutomu Iwatani , Nobutaka Uchikawa , Kouji Kitabayashi
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Tateyo Sasaki , Tutomu Iwatani , Nobutaka Uchikawa , Kouji Kitabayashi
IPC分类号： C08F210/06 , C08F210/08 , C08L23/14
CPC分类号： C08F210/08 , C08F210/06
摘要： Copolymers of butene-1 and propylene, having specific physical properties and substantially a syndiotactic structure; and easily heat-sealable polypropylene resin compositions comprising 5-50 parts by weight of one of the copolymers and 95-50 parts by weight of a stereoregular crystalline propylene-ethylene copolymer or propylene ethylene-C.sub.4-12 -.alpha.-olefin copolymer having specific compositions and melt flow index.
摘要翻译： 具有特定物理性质和基本上间同立构结构的丁烯-1和丙烯的共聚物; 和易于热封的聚丙烯树脂组合物，其包含5-50重量份的一种共聚物和95-50重量份的具有特定组成的立构规整结晶丙烯 - 乙烯共聚物或丙烯乙烯-C4-12-α-烯烃共聚物 和熔体流动指数。
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6.发明授权
公开(公告)号：US5232992A
公开(公告)日：1993-08-03
申请号：US593734
申请日：1990-10-05
CPC分类号： C08J5/00 , B29C67/24 , C08K3/0008 , C08K5/0008 , C08K5/0083 , C08L23/10 , B29C71/02 , B29K2023/12 , C08J2323/10 , C08L2205/02 , C08L2207/12
摘要： According to the present invention, molded articles can be provided in which a melting point attributed to a syndiotactic polypropylene and measured at a temperature rise rate of 10.degree. C./minute by differential scanning thermal analysis is indicated by a substantially single peak, the aforesaid molded articles being obtained by heating, melting and molding a substantially syndiotactic homopolymer of propylene, a substantially syndiotactic copolymer of propylene and a small amount of another olefin, or a mixture of these polymers and a small amount of a substantially isotactic polypropylene, and then subjecting the molded products to a heat treatment. Furthermore, a method for preparing the above-mentioned molded articles is also provided. The molded articles have high stiffness and impact resistance.
摘要翻译： 根据本发明，可以提供通过差示扫描热分析以10℃/分钟的升温速度测定归因于间同立构聚丙烯的熔点的成型体，其基本上由单峰表示，上述 通过加热，熔融和模制丙烯基本上间同立构的均聚物，丙烯和少量另一种烯烃的基本上间同立构共聚物，或这些聚合物和少量的基本上为全同立构的聚丙烯的混合物而获得的模塑制品， 成型产品进行热处理。 此外，还提供了制备上述模制品的方法。 模制品具有高刚度和抗冲击性。
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7.发明授权Polypropylene resin compositions of high syndiotacticity and preparation process thereof 失效高分子量聚丙烯的聚丙烯树脂组合物及其制备方法
公开(公告)号：US5212247A
公开(公告)日：1993-05-18
申请号：US533757
申请日：1990-06-06
IPC分类号： C08F2/44 , C08F297/08 , C08L23/12 , C08L23/14 , C08L23/16
CPC分类号： C08F297/083 , C08L23/12 , C08L2207/12 , C08L23/14 , C08L23/142 , C08L23/16 , Y10S526/943
摘要： Disclosed herein is a polypropylene resin composition of a high syndiotacticity comprising a substantial homopolymer of propylene, in which the ratio of the intensity of the peak attributable to the syndiotactic pentad bonds to the sum of the intensities of all the peaks attributable to the methyl groups in the spectrum of the methyl groups measured by .sup.13 C-NMR is 0.7 or more, and a copolymer of ethylene and propylene, and a preparation process thereof.
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公开(公告)号：US5206324A
公开(公告)日：1993-04-27
申请号：US592315
申请日：1990-10-03
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Tateyo Sasaki , Tutomu Iwatani , Nobutaka Uchikawa , Kouji Kitabayashi
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Tateyo Sasaki , Tutomu Iwatani , Nobutaka Uchikawa , Kouji Kitabayashi
IPC分类号： C08F210/06 , C08F210/08 , C08L23/10 , C08L23/14 , C08L23/20 , C09J123/10
CPC分类号： C08L23/142 , C08F210/08 , C09J123/10 , C08F210/06 , C08L23/20 , Y10S526/943
摘要： Copolymers of butene-1 and propylene, having specific physical properties and substantially a syndiotactic structure; and easily heat-sealable polypropylene resin compositions comprising 5-50 parts by weight of one of the copolymers and 95-50 parts by weight of a stereoregular crystalline propylene-ethylene copolymer or propylene-ethylene-C.sub.4-12 -.alpha.-olefin copolymer having specific compositions and melt flow index.
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公开(公告)号：US5169924A
公开(公告)日：1992-12-08
申请号：US556995
申请日：1990-07-25
IPC分类号： C08F4/642 , C08F10/00 , C08F210/00 , C08F210/06 , C08F210/08
CPC分类号： C08F210/08 , C08F210/06 , Y10S526/943
摘要： A copolymer of propylene and butene-1, the constituent monomer units of which comprise 20-63 wt. % of propylene and 37-80 wt. % of butene-1, and which exhibits 0.5 or more in the ratio of the sum of the intensities of absorptions observed at about 20.0-21.0 ppm to the sum of the intensities of total absorptions attributable to the methyl groups in the propylene units observed at about 19.0-22.0 ppm in the .sup.13 C-NMR spectrum measured in a 1,2,4-trichlorobenzene solution and 0.05 or more in the intrinsic viscosity measured at 135.degree. C. in a tetralin solution.
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公开(公告)号：US5548008A
公开(公告)日：1996-08-20
申请号：US409978
申请日：1995-03-24
CPC分类号： C08K5/3435 , C08K5/526 , C08L23/12 , C08L2201/08 , C08L2207/12 , C08L23/142 , Y10S526/943
摘要： A radiation-resistant polypropylene resin composition is disclosed which comprises a polypropylene having a substantially syndiotactic structure, and if desired, a phosphorus-containing anti-oxidant, an amine-containing anti-oxidant and/or a nucleating agent. Molded articles obtained from this resin composition can be utilized as containers for foods and medicines, and their physical properties scarcely deteriorate during sterilization by radiation.
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