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公开(公告)号:US20250130499A1
公开(公告)日:2025-04-24
申请号:US18626242
申请日:2024-04-03
Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.
Inventor: Yen-Yu KUO , An-Ren ZI , Ching-Yu CHANG
IPC: G03F7/11 , C08L43/04 , H01L21/027
Abstract: A resist underlayer composition for extreme ultraviolet lithography is provided. The composition includes a first polymer, a second polymer, an acid generator and a solvent. The first polymer includes a first polymer backbone and an etching resistance enhancement unit covalently bonded to the first polymer backbone via a first linker. The etching resistance enhancement unit includes a silicon-containing unit including silicon-oxygen bonds or a metal-containing unit including metal-oxygen bonds. The second polymer includes a second polymer backbone and a crosslinker unit covalently bonded to the second polymer backbone via a second linker. The crosslinker unit includes one or more crosslinkable groups.
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公开(公告)号:US20190122881A1
公开(公告)日:2019-04-25
申请号:US16021521
申请日:2018-06-28
Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.
Inventor: An-Ren ZI , Chin-Hsiang LIN , Ching-Yu CHANG
IPC: H01L21/027 , H01L21/311 , G03F7/20
CPC classification number: H01L21/0274 , G03F7/70033 , H01L21/311
Abstract: A method for forming a semiconductor device structure is provided. The method includes forming a material layer over a substrate and forming a resist layer over the material layer. The resist layer includes an inorganic material and an auxiliary, and the inorganic material includes a plurality of metallic cores, and a plurality of first linkers bonded to the metallic cores. The method also includes exposing a portion of the resist layer by performing an exposure process, and the auxiliary reacts with the first linkers during the exposure process. The method further includes etching a portion of the resist layer to form a patterned resist layer and patterning the material layer by using the patterned resist layer as a mask. The method also includes removing the patterned resist layer.
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公开(公告)号:US20240329535A1
公开(公告)日:2024-10-03
申请号:US18361298
申请日:2023-07-28
Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.
Inventor: Yen-Yu KUO , An-Ren ZI , Chen-Yu LIU , Ching-Yu CHANG , Chin-Hsiang LIN
IPC: G03F7/09 , C09D125/06 , C09D133/12 , G03F7/004 , H01L21/033
CPC classification number: G03F7/091 , C09D125/06 , C09D133/12 , G03F7/0044 , H01L21/033
Abstract: A method of forming semiconductor device includes depositing a coating layer over a substrate, forming a photoresist layer over the coating layer, exposing the photoresist layer to actinic radiation, and developing the photoresist layer to form a patterned photoresist layer. The coating layer includes a polymer containing a first unit having a pendant hydrogen donor group capable of producing a hydrogen radical upon exposure to the actinic radiation or heat, and a second unit having a pendant water donor group capable of producing water upon exposure to the actinic radiation or heat.
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公开(公告)号:US20200013618A1
公开(公告)日:2020-01-09
申请号:US16572286
申请日:2019-09-16
Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.
Inventor: Ming-Hui WENG , An-Ren ZI , Ching-Yu CHANG , Chin-Hsiang LIN , Chen-Yu LIU
IPC: H01L21/033 , H01L21/311 , H01L21/3115 , H01L21/02
Abstract: A method for forming a semiconductor device structure is provided. The method includes forming a material layer over a substrate and forming a resist layer over the material layer. The resist layer includes an inorganic material and an auxiliary. The inorganic material includes a plurality of metallic cores and a plurality of first linkers bonded to the metallic cores. The method includes exposing a portion of the resist layer. The resist layer includes an exposed region and an unexposed region. In the exposed region, the auxiliary reacts with the first linkers. The method also includes removing the unexposed region of the resist layer by using a developer to form a patterned resist layer. The developer includes a ketone-based solvent having a formula (a) or the ester-based solvent having a formula (b).
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公开(公告)号:US20180315617A1
公开(公告)日:2018-11-01
申请号:US15726040
申请日:2017-10-05
Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.
Inventor: An-Ren ZI , Joy CHENG , Ching-Yu CHANG
IPC: H01L21/3213 , C08F12/08
Abstract: Provided is a material composition and method for that includes providing a substrate and forming a resist layer over the substrate. In various embodiments, the resist layer includes a metal complex including a radical generator, an organic core, and an organic solvent. By way of example, the organic core includes at least one cross-linker site. In some embodiments, an exposure process is performed to the resist layer. After performing the exposure process, the exposed resist layer is developed to form a patterned resist layer.
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公开(公告)号:US20210366711A1
公开(公告)日:2021-11-25
申请号:US17226872
申请日:2021-04-09
Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
Inventor: An-Ren ZI , Chun-Chih HO , Yahru CHENG , Ching-Yu CHANG
IPC: H01L21/033 , H01L21/308 , G03F7/20
Abstract: In a method of manufacturing a semiconductor device, a metallic photoresist layer is formed over a target layer to be patterned, the metallic photoresist layer is selectively exposed to actinic radiation to form a latent pattern, and the latent pattern is developed by applying a developer to the selectively exposed photoresist layer to form a pattern. The metallic photo resist layer is an alloy layer of two or more metal elements, and the selective exposure changes a phase of the alloy layer.
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公开(公告)号:US20200328075A1
公开(公告)日:2020-10-15
申请号:US16780791
申请日:2020-02-03
Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
Inventor: An-Ren ZI , Ching-Yu CHANG
IPC: H01L21/02 , C11D1/72 , C11D1/66 , C11D1/02 , C11D11/00 , C11D3/43 , H01L21/308 , H01L21/027
Abstract: A cleaning solution includes first solvent having Hansen solubility parameters 25>δd>13, 25>δp>3, and 30>δh>4; acid having acid dissociation constant, pKa, of −11 pKa>9.5; and surfactant. Surfactant is one or more of ionic surfactant, polyethylene oxide and polypropylene oxide, non-ionic surfactant, and combinations. Ionic surfactant is selected from group consisting of R is substituted or unsubstituted aliphatic, alicyclic, or aromatic group, and non-ionic surfactant has A-X or A-X-A-X structure, A is unsubstituted or substituted with oxygen or halogen, branched or unbranched, cyclic or non-cyclic, saturated C2-C100 aliphatic or aromatic group, and X includes polar functional groups selected from —OH, ═O, S P, P(O2), —C(═O)SH, —C(═O)OH, —C(═O)OR—, —O—; —N—, —C(═O)NH, —SO2OH, —SO2SH, —SOH, —SO2—, —CO—, —CN—, —SO—, —CON—, —NH—, —SO3NH—, SO2NH.
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公开(公告)号:US20190384170A1
公开(公告)日:2019-12-19
申请号:US16163425
申请日:2018-10-17
Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
Inventor: An-Ren ZI , Chin-Hsiang LIN , Ching-Yu CHANG
IPC: G03F7/004 , G03F7/20 , G03F7/16 , G03F7/38 , G03F7/11 , G03F7/30 , G03F7/42 , G03F7/039 , G03F7/038 , H01L21/027
Abstract: A method of forming a photoresist pattern includes forming a protective layer over a photoresist layer formed on a substrate, and selectively exposing the protective layer and the photoresist layer to actinic radiation. The protective layer and the photoresist layer are developed to form a pattern in the photoresist layer, and the protective layer is removed. The protective layer includes a polymer having pendant fluorocarbon groups and pendant acid leaving groups.
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公开(公告)号:US20190146342A1
公开(公告)日:2019-05-16
申请号:US15994615
申请日:2018-05-31
Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
Inventor: An-Ren ZI , Chin-Hsiang LIN , Ching-Yu CHANG , Joy CHENG
IPC: G03F7/038 , G03F7/38 , H01L21/027 , G03F7/20
Abstract: A method of forming a photoresist pattern includes forming a protective layer over a photoresist layer formed on a substrate, and selectively exposing the photoresist layer to actinic radiation. The photoresist layer is developed to form a pattern in the photoresist layer, and the protective layer is removed. The protective layer includes a polymer having fluorocarbon pendant groups.
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公开(公告)号:US20240419069A1
公开(公告)日:2024-12-19
申请号:US18335852
申请日:2023-06-15
Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.
Inventor: An-Ren ZI , Yen-Yu KUO , Ching-Yu CHANG , Chin-Hsiang LIN
Abstract: A method for forming a semiconductor device is provided. The method includes forming a photoresist layer comprising an organometallic compound over a substrate. The organometallic compound includes a metal core, at least one hydrolyzable ligand bonded to the metal core, and at least one photoacid generator ligand bonded to the metal core. The method further includes selectively exposing the photoresist layer to radiation and developing the photoresist layer to form a pattern in the photoresist layer.
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