公开(公告)号：US4565859A

公开(公告)日：1986-01-21

申请号：US696239

申请日：1985-01-29

申请人： Takaaki Murai ,  Shoji Watanabe ,  Kimio Inoue ,  Toyokazu Yagii

发明人： Takaaki Murai ,  Shoji Watanabe ,  Kimio Inoue ,  Toyokazu Yagii

IPC分类号： C08G59/02 ,  C08G59/34 ,  C08G65/14 ,  C08G65/26 ,  C08G65/332 ,  C08G59/42

CPC分类号： C08G59/027 ,  C08G59/02 ,  C08G65/14 ,  C08G65/26 ,  C08G65/3322

摘要： A polyether compound having ether groups and vinyl double bonds represented by formula (I) ##STR1## wherein R.sub.1 represents a residue of an organic compound having l active hydrogen atoms, n.sub.1 through n.sub.l each represents 0 or an integer of from 1 to 100, the sum of the integers represented by n.sub.1 through n.sub.l is from 1 to 100, andl represents an integer of from 1 to 100, and A represents ##STR2## and a process for production thereof; an epoxy resin represented by formula (II) ##STR3## wherein R.sub.1 and n.sub.1 through n.sub.l are defined above, and B is an oxycyclohexane unit having a substituent and is represented by formula (III) ##STR4## wherein X represents a ##STR5## --CH.dbd.CH.sub.2, or ##STR6## groups, wherein R.sub.2 represents an alkyl group, an alkylcarbonyl group, or an arylcarbonyl group, provided that the epoxy resin represented by formula (II) contains at least one ##STR7## group, and a process for production thereof; and an epoxy resin comprising an epoxy resin as in formula (II), are disclosed.

摘要翻译： 具有由式（I）表示的醚基和乙烯基双键的聚醚化合物其中R 1表示具有1个活性氢原子的有机化合物的残基，n1至n1各自表示0或1〜 100，由n1〜n1表示的整数的和为1〜100，l表示1〜100的整数，A表示其生成方法。 （II）表示的环氧树脂其中R1和n1至n1如上定义，B是具有取代基的氧代环己烷单元，由式（III）表示。其中X 表示式（II）表示的环氧树脂包含至少一个“IMA”> -CH = CH 2或基团，其中R 2表示烷基，烷基羰基或芳基羰基， 组及其生产方法; 和包含式（II）中的环氧树脂的环氧树脂。

公开(公告)号：US4663429A

公开(公告)日：1987-05-05

申请号：US760782

申请日：1985-07-31

申请人： Takaaki Murai ,  Shoji Watanabe ,  Kimio Inoue ,  Tomohisa Isobe ,  Naoki Nakashima ,  Takuya Miho ,  Yoshiyuki Ikemoto

发明人： Takaaki Murai ,  Shoji Watanabe ,  Kimio Inoue ,  Tomohisa Isobe ,  Naoki Nakashima ,  Takuya Miho ,  Yoshiyuki Ikemoto

IPC分类号： C08G63/60 ,  C08L67/06 ,  C08G63/10

CPC分类号： C08G63/60 ,  C08L67/06

摘要： A process for producing a lactone polymer which comprises reacting an ester compound synthesized from an alcohol and an acid or acid anhydride thereof with a lactone and a ring-opening polymerization initiator without being accompanied by condensation. The thus produced lactone polymer is effective for preventing shrinkage of thermosetting resins, particularly unsaturated polyester resins.

摘要翻译： 一种内酯聚合物的制备方法，其包括使由醇和其酸或酸酐合成的酯化合物与内酯和开环聚合引发剂反应而不伴随冷凝。 由此制得的内酯聚合物对于防止热固性树脂，特别是不饱和聚酯树脂的收缩是有效的。

公开(公告)号：US4835213A

公开(公告)日：1989-05-30

申请号：US19166

申请日：1987-02-26

申请人： Takaaki Murai ,  Shoji Watanabe ,  Kimio Inoue ,  Tomohisa Isobe ,  Naoki Nakashima ,  Takuya Miho ,  Yoshiyuki Ikemoto

发明人： Takaaki Murai ,  Shoji Watanabe ,  Kimio Inoue ,  Tomohisa Isobe ,  Naoki Nakashima ,  Takuya Miho ,  Yoshiyuki Ikemoto

IPC分类号： C08G63/60 ,  C08L67/06

CPC分类号： C08G63/60 ,  C08L67/06

摘要： A process for producing a lactone polymer which comprises reacting an ester compound synthesized from an alcohol and an acid or acid anhydride thereof with a lactone and a ring-opening polymerization initiator without being accompanied by condensation. The thus produced lactone polymer is effective for preventing shrinkage of thermosetting resins, particularly unsaturated polyester resins.

摘要翻译： 一种内酯聚合物的制备方法，其包括使由醇和其酸或酸酐合成的酯化合物与内酯和开环聚合引发剂反应而不伴随冷凝。 由此制得的内酯聚合物对于防止热固性树脂，特别是不饱和聚酯树脂的收缩是有效的。

公开(公告)号：US5770301A

公开(公告)日：1998-06-23

申请号：US732226

申请日：1996-10-25

申请人： Takaaki Murai ,  Ryuta Miyake

发明人： Takaaki Murai ,  Ryuta Miyake

IPC分类号： B32B27/08 ,  B32B27/16 ,  C08J7/04 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36

CPC分类号： C08J7/045 ,  B32B27/08 ,  B32B27/16 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/31663 ,  Y10T428/31667

摘要： At least one side of a polyester or other base film is successively covered with an inorganic layer composed of a silicon oxide or the like and a coating layer comprising a silane coupling agent and a barrier resin (e.g. vinylidene chloride-based copolymer, ethylene-vinyl alcohol copolymer) to provide a barrier composite film. The amount of the silane coupling agent is about 0.05 to 10 parts by weight relative to 100 parts by weight of the barrier resin. A heat-sealing layer is optionally formed on the surface of the barrier resin coating layer or on the other side of the base film. Such barrier composite film has excellent transparency and retains high barrier properties and adhesive properties of covering layer despite its thin covering layer.

摘要翻译： PCT No.PCT / JP96 / 00614 Sec。 371日期1996年10月25日第 102（e）日期1996年10月25日PCT 1996年3月13日PCT公布。 出版物WO96 / 28299 日期1996年9月19日聚酯或其他基膜的至少一面依次被由氧化硅等构成的无机层和包含硅烷偶联剂和阻隔树脂（例如偏二氯乙烯基 共聚物，乙烯 - 乙烯醇共聚物）以提供阻隔复合膜。 相对于100重量份的阻隔树脂，硅烷偶联剂的量为约0.05至10重量份。 可选地，在隔离树脂涂层的表面或基膜的另一侧上形成热封层。 这种阻隔复合膜具有优异的透明性，并且尽管其覆盖层薄，但仍具有高覆盖层的阻隔性和粘合性。

公开(公告)号：US4841017A

公开(公告)日：1989-06-20

申请号：US167680

申请日：1988-03-11

申请人： Takaaki Murai ,  Katsuhisa Sakai

发明人： Takaaki Murai ,  Katsuhisa Sakai

IPC分类号： C08G59/02 ,  C08G59/34 ,  C08G65/14

CPC分类号： C08G59/027 ,  C08G59/02 ,  C08G65/14

摘要： Disclosed as a polyether compound having ether groups and vinyl double bonds represented by formula (I) ##STR1## and an epoxy resin represented by formula (II) ##STR2## wherein R.sup.1 represents a residue group of an organic compound having l active hydrogen atoms, n1 through nl each represents 0 or an integer of from 1 to 100, the sum of integers represented by n1 through nl is from 1 to 100, and l represents an integer of from 1 to 100, and A represents from 1 to 100, and A represents ##STR3## or a mixture of ##STR4## wherein R.sup.2 represents a residue group of mono epoxy compound, and B represents ##STR5## or a mixture of ##STR6## wherein X represents a ##STR7## group, wherein R.sup.3 represents a hydrogen atom, an alkyl group, an alkyl carbonyl group, or an arylcarbonyl group, provided that the epoxy resin represented by formula (II) contains at least one ##STR8## group: In a further aspect, the invention relates to processes for production thereof.

公开(公告)号：US5510428A

公开(公告)日：1996-04-23

申请号：US342633

申请日：1994-11-21

申请人： Yoshiyuki Harano ,  Sozo Namai ,  Katsuyuki Maeda ,  Takaaki Murai

发明人： Yoshiyuki Harano ,  Sozo Namai ,  Katsuyuki Maeda ,  Takaaki Murai

IPC分类号： C08G59/34 ,  C08G59/68 ,  C08G63/58 ,  C08G63/91 ,  C08G65/14 ,  C08G65/26 ,  C09D163/00 ,  C09D167/00 ,  C08F20/00 ,  C07D301/14

CPC分类号： C08G59/027 ,  C08G59/68 ,  C08G63/58 ,  C08G63/918 ,  C08G65/14 ,  C08G65/2615 ,  C09D163/00 ,  C09D167/00 ,  Y10S525/922

摘要： Compositions (I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions (XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), and or (d), where(a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom; and (d) is at east one of an unsaturated monocarboxylic compound or an unsaturated monocarboxylic ester having a hydroxyl group.

摘要翻译： 包含具有乙烯基作为侧链和环氧化组合物（XI），（XII）和（XIII））的化合物（I），（II）和（III）），其可以通过（a）与 （b）或（b）+（c）和（d），其中（a）是至少一种在分子中具有至少一个乙烯基和一个环氧基的化合物; （b）是多元化合物，其酸酐，末端具有羧基的聚合物和具有羧基作为侧链的聚合物中的至少一种; （c）是至少一种具有至少一个活性氢原子的有机化合物; 和（d）在不饱和单羧酸化合物或具有羟基的不饱和单羧酸酯的东侧。

公开(公告)号：US5143997A

公开(公告)日：1992-09-01

申请号：US595423

申请日：1990-10-11

申请人： Toshio Endo ,  Takaaki Murai ,  Tatsumi Fujii

发明人： Toshio Endo ,  Takaaki Murai ,  Tatsumi Fujii

IPC分类号： C08F299/02 ,  C08G18/44 ,  C08G18/81 ,  C08G64/02

CPC分类号： C08G64/0291 ,  C08F299/024 ,  C08G18/44 ,  C08G18/8175 ,  C08G64/0216

摘要： A polycarbonate polyol composition which can be used to prepare polycarbonate(meth)acrylate and urethane(meth)acrylate compositions is obtained by the ester interchange reaction of a polycarbonate diol composition with a triol and/or tetraol. The (meth)acrylate compositions have excellent photo and electron beam curability and the cured layers prepared therefrom have excellent heat resistance under moisture conditions.

公开(公告)号：US4978691A

公开(公告)日：1990-12-18

申请号：US356909

申请日：1989-05-25

申请人： Takaaki Murai ,  Tatsumi Fujii

发明人： Takaaki Murai ,  Tatsumi Fujii

IPC分类号： C08G18/44 ,  C08G64/02

CPC分类号： C08G18/44 ,  C08G64/0208 ,  C08G2101/0008 ,  C08G2101/0025

摘要： A polycarbonatediol composition is disclosed having the property of being liquid at room temperature because of its crystallinity being disordered due to random structures, which comprises a mixture of 1,6-hexanediol and polyvalent alcohol having at least one side chain. Accordingly, the disclosed composition has excellent processability in the case of preparing a polyurethane resin, etc.Further disclosed is a polyurethane resin prepared by reaction of an organic diisocyanate compound with the polycarbonatediol composition. The polyurethane resin has excellent properties under low temperature conditions, while retaining high levels of mechanical strength, excellent resistibility under high heat and moisture conditions, etc., thereby maintaining a good balance of properties. The polyurethane resin in accordance with the present invention, is useful in a very wide variety of forms, including spandex, rigid or flexible urethane foams, thermoplastic urethane elastomers and thermosetting urethane elastomers, adhesives, synthetic leather, and paints, etc.

公开(公告)号：US5494977A

公开(公告)日：1996-02-27

申请号：US342784

申请日：1994-11-21

申请人： Yoshiyuki Harano ,  Sozo Namai ,  Katsuyki Maeda ,  Takaaki Murai

发明人： Yoshiyuki Harano ,  Sozo Namai ,  Katsuyki Maeda ,  Takaaki Murai

IPC分类号： C08G59/34 ,  C08G59/68 ,  C08G63/58 ,  C08G63/91 ,  C08G65/14 ,  C08G65/26 ,  C09D163/00 ,  C09D167/00 ,  C08F20/00

CPC分类号： C08G59/027 ,  C08G59/68 ,  C08G63/58 ,  C08G63/918 ,  C08G65/14 ,  C08G65/2615 ,  C09D163/00 ,  C09D167/00 ,  Y10S525/922

摘要： Compositions(I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions(XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), and or (d), where(a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom; and (d) is at least one of an unsaturated monocarboxylic compound or an unsaturated monocarboxylic ester having a hydroxyl group.

摘要翻译： 包含具有乙烯基作为侧链和环氧化组合物（XI），（XII）和（XIII））的化合物（I），（II）和（III）），其可以通过（a）与 （b）或（b）+（c）和（d），其中（a）是至少一种在分子中具有至少一个乙烯基和一个环氧基的化合物; （b）是多元化合物，其酸酐，末端具有羧基的聚合物和具有羧基作为侧链的聚合物中的至少一种; （c）是至少一种具有至少一个活性氢原子的有机化合物; 和（d）是具有羟基的不饱和一元羧酸化合物或不饱和一元羧酸酯中的至少一种。

公开(公告)号：US5100999A

公开(公告)日：1992-03-31

申请号：US403434

申请日：1989-09-06

申请人： Takaaki Murai ,  Tatsumi Fujii

发明人： Takaaki Murai ,  Tatsumi Fujii

IPC分类号： C08G18/44 ,  C08G64/02 ,  C08G64/18

CPC分类号： C08G64/183 ,  C08G18/44 ,  C08G64/0208 ,  C08G2101/0008 ,  C08G2101/0025

摘要： A polycarbonatediol composition is disclosed having carbonate bonds and from about 1 to 40 ether bonds to one carbonate bond in a molecule, which can provide polyurethanes having high mechanical strength and heat and moisture resistibility, and furthermore having improved properties at low temperatures.Further disclosed is a polyurethane resin prepared by reaction of an organic diisocyanate compound with the polycarbonatediol composition. The polyurethane resin has excellent properties under low temperature conditions, while retaining high levels of mechanical strength, excellent resistibility under high heat and moisture conditions, etc., thereby maintaining a good balance of properties. The polyurethane resin in accordance with the present invention is useful in a very wide variety of forms, including spandex, rigid or flexible urethane foams, thermoplastic urethane elastomers and thermosetting urethane elastomers, adhesives, synthetic leather, paints, etc.