摘要:
To provide a refrigerating unit using ammonia as a refrigerant, which uses a lubricant that is excellent in the compatibility with an ammonia refrigerant as well as in the lubricity and the stability. An ammonia refrigerating unit formed by a refrigerating cycle including a refrigeration compressor, a condenser, an expansion valve and an evaporator, wherein a working is circulated in said refrigerating cycle, the working fluid including ammonia and a lubricant that contains a polyether compound represented by one of the following formula (1) or (2): X{—O—(AO)n—H}p (1) X{—O—(AO1)a—(AO2)b—H}p (2) [wherein X represents a residue resulting from removing a hydroxyl group from a monool or a polyol; (AO)n represents an AO chain constituted by copolymerization of EO and C3 or more AO; (AO1)a represents an AO chain constituted by copolymerization of EO and PO and/or BO; AO2 represents C3 or more AO; and in the formula (1), the number of the secondary hydroxyl groups from among hydroxyl groups at the structural terminal is 50% or more of the total number of the hydroxyl groups].
摘要:
To provide a polyalkylene glycol-based refrigerant oil for refrigerators using ammonia as a refrigerant. The present invention provides a lubricant for refrigerators using ammonia refrigerant, comprising polyethers selected from the group consisting of a polyether represented by the following general formula (1) X—{—O—(AO)n—H}p (1) (wherein X is a residue of a monool or polyol from which a hydroxyl group is eliminated; (AO)n is a polyoxyalkylene group formed by copolymerization of EO and an AO having 3 or more carbon atoms; n is 2 or more; and p is a valence of X) and having 50% or more of secondary hydroxyl groups among the hydroxyl groups located at the terminal of the structure based on the total hydroxyl groups, or a polyether represented by the following general formula (2) X—{—O—(AO1)a—(AO2)b—H}p (2) (wherein X is a residue of a monool or polyol from which a hydroxyl group is eliminated; (AO1)n is a polyoxyalkylene group formed by copolymerization of ethylene oxide and propylene oxide and/or butylene oxide; AO2 is an oxyalkylene group having 3 or more carbon atoms; a is 2 or more; b is 1 or more; and p is a valence of X).
摘要:
A lubricant for a refrigerator using ammonia as the refrigerant, which contains an additive selected from antioxidant, anti-wear additive and metal deactivator, and the polyether compound represented by the following general formula (1) or (2): X{—O—(AO)n—H}p (1) X{—O—(AO1)a—(AO2)b—H}p (2)
摘要:
The present invention provides a lubricant for a compression type refrigeration system using ammonia as a refrigerant, which comprises polyether compounds and aromatic amine compounds or phenothiazine compounds, and preferably further comprises alcohol compounds such as polyhydric alcohol partial ether and/or benzotriazole compounds. Further, the present invention provides a working fluid composition comprising the lubricant and an ammonia refrigerant, and a refrigeration system which is filled with the working fluid composition. The lubricant has not only good compatibility with ammonia, but excellent stability and lubricating property, and therefore can suitably used in a compression type refrigeration system using an ammonia refrigerant that does not have the possibility of ozone layer depletion and global warming phenomenon.
摘要:
This invention provides a refrigerator oil, a working fluid for a refrigerator, and a method for lubricating a refrigeration system, which can inhibit the creation of deposits attributable to metal working oils remaining within a refrigeration system. The refrigerator oil contains: a polyhydric alcohol ester compound as a lube base oil, and 0.5 to 4.5% by weight of at least one polyoxyalkylene compound. The working fluid for a refrigerator, containing: the above refrigerator oil, and a hydrofluorocarbon refrigerant. A method for lubricating a refrigeration system contaminated with metal working oils, containing a component sparingly soluble in the polyhydric alcohol ester compound or the hydrofluorocarbon refrigerant, or metal working oils, containing a component highly reactive with the polyhydric alcohol ester compound or the hydrofluorocarbon refrigerant, remaining therein, wherein the above working fluid for a refrigerator is used as a working fluid. According to the present invention, occurrence of deposits in the system, especially in a capillary in the system, can be prevented
摘要:
A lubricating oil additive contains a partially etherified polyhydric alcohol which has at least two hydroxyl groups and at least one hydrocarbon group having a least one double bond bonded thereto through an ether linkage as an active component. The lubricating additive is added to a lube base oil to form a lubricating oil which imparts excellent wear resistance, scarcely corrodes metallic substances, scarcely swells rubbers or resins and scarcely forms sludge due to thermal oxidation. The lubricating oil is mixed with a refrigerant to give a working fluid suitable for refrigerant compressors of domestic refrigerators, automotive room air conditioners, refrigerators for industrial use and air conditioners.
摘要:
A process for producing a lubricant base oil with low pour point and high aromaticity from a feedstock oil which is either a distillate fraction boiling at 250.degree. C. or above that is obtained from a paraffin base or mixed base crude or a deasphalted oil obtained from a vacuum distillation residual oil of said crude, and process comprising:(a) the step of bringing said feedstock oil into contact with a hydrofining catalyst in the presence of hydrogen and recovering a hydrofined oil;(b) the step of dewaxing said hydrofined oil and recovering the dewaxed oil;(c) the step of subjecting said dewaxed oil to extraction with a solvent having selective affinity for aromatic hydrocarbons so as to separate the feed into the raffinate portion and the extract portion, and removing the solvent from said extract portion to obtain an extract oil; and(d) the step of treating said extract oil by means of contact with a solid adsorbent or sulfuric acid.
摘要:
A process oil comprising a 95/5 to 5/95 by weight mixture of: an extract having a DMSO extractable content less than 3 wt % obtained by solvent-extracting an oil obtained by deasphalting a vacuum distillation bottom; and either a mineral oil base having a DMSO extractable content less than 3 wt % which is a raffinate obtained by the solvent refining of a vacuum distillate or a mineral oil base having a DMSO extractable content less than 3 wt % obtained by subjecting a raffinate obtained by the solvent refining of a vacuum distillate to hydrorefining and/or dewaxing. The process oil has a kinematic viscosity at lOOoC of less than 32 mm2/s, % CA of 15 to 30, aniline point of lOOoC or lower, weight change through evaporation of 0.5% or less, and mutagenicity index of less than 1.
摘要:
A lubricating oil for a fluorinated hydrocarbon-based refrigerant type compressor, said lubricating oil having a kinematic viscosity at 100.degree. C. being 15 to 30 cSt and comprising, as a base oil, at least one polyoxyalkylene glycol derivative represented by the following formula (I): R.sub.1 --O--�(PO)p(EO.sup.1)q!--(EO.sup.2)r--R.sub.2 (I) in which R.sub.1 is an alkyl group having 1 to 4 carbon atoms, R.sub.2 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, PO is an oxypropylene group, EO.sup.1 and EO.sup.2 are oxyethylene groups, p, q and r are average polymerization degrees of PO, EO.sup.1 and EO.sup.2, respectively, �(PO)p(EO.sup.1)q! is a random copolymer group of PO and EO.sup.1, (EO.sup.2)r is a block polymer group of EO.sup.2, p/(p+q) is 0.70 to 0.95, and r/(p+q+r) is 0.03 to 0.30. A lubricating method and a working fluid composition for the fluorinated hydrocarbon-based refrigerant type compressor are also disclosed.
摘要:
A working fluid composition for a compression type refrigerator, comprising:(A) a refrigerant composed of ammonia or at least one hydrofluorocarbon having the number of carbon being not more than 2 and containing no chlorine; and(B) a lubricant for the refrigerator, said lubricant comprising 100 parts by weight of a synthetic oil and 0.5 to 10.0 parts by weight of at least one benzotriazole derivative expressed by the following formula (I). ##STR1## in which R.sup.1 is hydrogen or an alkyl group having the number of carbons being 1-10, and R.sup.2 and R.sup.3 independently indicate an alkyl group having the number of carbons being 4-18.