摘要:
To provide a polyalkylene glycol-based refrigerant oil for refrigerators using ammonia as a refrigerant. The present invention provides a lubricant for refrigerators using ammonia refrigerant, comprising polyethers selected from the group consisting of a polyether represented by the following general formula (1) X—{—O—(AO)n—H}p (1) (wherein X is a residue of a monool or polyol from which a hydroxyl group is eliminated; (AO)n is a polyoxyalkylene group formed by copolymerization of EO and an AO having 3 or more carbon atoms; n is 2 or more; and p is a valence of X) and having 50% or more of secondary hydroxyl groups among the hydroxyl groups located at the terminal of the structure based on the total hydroxyl groups, or a polyether represented by the following general formula (2) X—{—O—(AO1)a—(AO2)b—H}p (2) (wherein X is a residue of a monool or polyol from which a hydroxyl group is eliminated; (AO1)n is a polyoxyalkylene group formed by copolymerization of ethylene oxide and propylene oxide and/or butylene oxide; AO2 is an oxyalkylene group having 3 or more carbon atoms; a is 2 or more; b is 1 or more; and p is a valence of X).
摘要:
To provide a refrigerating unit using ammonia as a refrigerant, which uses a lubricant that is excellent in the compatibility with an ammonia refrigerant as well as in the lubricity and the stability. An ammonia refrigerating unit formed by a refrigerating cycle including a refrigeration compressor, a condenser, an expansion valve and an evaporator, wherein a working is circulated in said refrigerating cycle, the working fluid including ammonia and a lubricant that contains a polyether compound represented by one of the following formula (1) or (2): X{—O—(AO)n—H}p (1) X{—O—(AO1)a—(AO2)b—H}p (2) [wherein X represents a residue resulting from removing a hydroxyl group from a monool or a polyol; (AO)n represents an AO chain constituted by copolymerization of EO and C3 or more AO; (AO1)a represents an AO chain constituted by copolymerization of EO and PO and/or BO; AO2 represents C3 or more AO; and in the formula (1), the number of the secondary hydroxyl groups from among hydroxyl groups at the structural terminal is 50% or more of the total number of the hydroxyl groups].
摘要:
Provided is a low-temperature fluidity improver capable of efficiently improving the low-temperature fluidity of a biodiesel fuel. The low-temperature fluidity improver for biodiesel fuels includes a specific aromatic carboxylic acid-based compound.
摘要:
The object of the present invention is to provide a lubricant for refrigerators having good compatibility with chlorine-free Flon-type coolants, good lubricity and resistant to hygroscopicity and a composition for refrigerators using this lubricant. This lubricant contains a monomethylether of polyoxyethyleneoxypropyleneglycol where the end group at the hydrogen terminal is an oxyethylene group, represented by the following general formula (1): CH3O(AO)m(CH2CH2O)nH wherein the AO group represents oxypropylene group, or copolymeric group of oxypropylene groups and oxyethylene groups wherein the copolymeric form may be a block type and/or a random type, m is a number of 1≦m≦50, n is a number of 1≦n≦10, and the content of the oxyethylene group in the compound ranges from 5 to 60 percent by weight. A composition for refrigerators using said lubricant is also provided.
摘要翻译:本发明的目的是提供一种与无氯Flon型冷却剂具有良好相容性,良好的润滑性和耐吸湿性的冰箱的润滑剂,以及使用该润滑剂的冰箱组合物。该润滑剂含有聚氧乙烯氧基丙二醇的单甲醚,其中末端 氢原子基团是由以下通式(1)表示的氧化乙烯基团:其中AO基团表示氧化亚丙基,或氧化丙烯基团和氧化乙烯基团的共聚基团,其中共聚形式可以是嵌段型和/或 随机型,m为1 <= m <= 50的数,n为1 <= n <10的数,化合物中氧乙烯基的含量为5〜60重量%。 还提供了使用所述润滑剂的冰箱组合物。
摘要:
A radio communication system is provided at an entrance gate of traffic facilities for radio communicating with a communication device carried by a vehicle. The system includes a first communication unit for transmitting first entrance data relative to the entrance gate of the traffic facilities to the communication device carried by the vehicle coming into the entrance gate, a discriminating unit for determining a vehicle type showing a kind of incoming vehicle, and a second communication unit, provided on an opposite side of the entrance gate from the first communication unit, along a direction of progress of the vehicle, for transmitting a second entrance data including data relative to the determined vehicle type to the communication device when the first communication unit transmits the first entrance data to the communication device.
摘要:
The present invention relates to a lubricated refrigerant for use in refrigerators employing hydrofluorocarbon coolants such as R 134a, R 32, R 125 and the like. The lubricated refrigerant contains fluorocarbon coolant, synthetic oil and a carbodiimide compound represented by the following general formula. R.sub.1 --N.dbd.C.dbd.N--R.sub.2, wherein R.sub.1 and R.sub.2 represent hydrogen atoms or hydrocarbly groups or nitrogen and/or oxygen containing hydrocarbly groups, and R.sub.1 and R.sub.2 may be the same or different groups. The refrigerant composition according to the present invention preferably contains said hydrofluorocarbon coolant and said lubricant at a given blending ratio.
摘要:
A lubricant for use in a refrigerator which operates with a chlorine-free Flon (fluorocarbon)-type refrigerant whose molecules do not contain chlorine. The lubricant contains a synthetic oil, and molybdenumoxysulfide diorganophosphorodithioate given by the following formula (1) and/or molybdenumoxysulfide diorganodithiocarbamate given by the following formula (2), the content of the compounds of formulae (1) and (2) in total ranges from 0.1 to 10 wt % to the content of the synthetic oil: {(RO)2PS2}2Mo2SXOY (1) where R represents a hydrocarbon group having 3 to 20 carbon atoms, and X and Y are numbers which meet the conditions of O≦X≦4, 0≦Y≦4 and X+Y=4; and (R′2NCS2)2Mo2SX′OY′ (2) where R′ is a hydrocarbon group having 3 to 20 carbon atoms and X′ and Y′ are numbers which meet the conditions of )≦X′≦4, 0≦Y′≦4 and X′+Y′=4.
摘要翻译:一种用于冰箱的润滑剂,其用分子不含氯的无氯Flon(氟碳)型制冷剂操作。 润滑剂含有合成油和由下式(1)给出的氧化钼二硫化物二有机二硫代磷酸酯和/或由下式(2)给出的二氧硫化二硅二有机二硫代氨基甲酸酯,式(1)和(2)化合物的含量总计为 相对于合成油的含量为0.1〜10重量%:其中R表示碳原子数3〜20的烃基,X和Y为满足O <= X <= 4,0 <= Y < = 4,X + Y = 4; 并且其中R'是具有3至20个碳原子的烃基,X'和Y'是满足条件的数字)= = X'<= 4,0 <= Y'<= 4和X'+ Y'= 4。
摘要:
The objective of the present invention resides in providing a lubricant for refrigerators that reacts rapidly with free acids and contains a stabilizer that has good compatibility with a chlorine-free Flon-thpe coolant such as Flon 134a and the like whose molecules do not contain chlorine. The lubricant for refrigerators employing a chlorine-free Flon-type coolant in accordance with the present invention 100 parts by weight of a synthetic oil and is compounded with 0.05 to 15 parts by weight of an alicyclic epoxy compound having one or more functional groups represented by the following formula: ##STR1## (wherein R.sub.1 and R.sub.2 independently represent a hydrogen or methyl group, and may be the same or different).