摘要:
A fluorine-containing adhesive material comprising a fluorine-containing ethylenic polymer having a carbonate group and/or a carboxylic halide group at a chain end or a side chain of polymer, wherein a total of a number of the carbonate groups and/or carboxylic halide groups is at least 150 relative to 1×106 main chain carbons, can directly impart the firm adherability to a substrate such as a metal, a glass or a resin while maintaining excellent properties such as resistance to chemicals, resistance to solvent, weatherability and resistance to stain possessed by a fluorine-containing polymer.
摘要:
A layer of a tetrafluoroethylene copolymer having 30 to 81% by mole of tetrafluoroethylene and 70 to 19% by mole of at least one other monomer and having a carbonate group in a polymer chain or at a polymer chain terminal, which has a melt flow rate of 0.1 to 100 g/10 minutes (230° C., 5 kg-load) and a melting point of 90 to 230° C. and a layer of a polyolefin resin are adhered with a layer of an ethylene-vinyl acetate copolymer, which satisfies the following relationship: X×Y/100≧7.0, wherein X is a vinyl acetate content (% by mole) and Y is a saponification degree of a methyl ester (%). The resulting laminate has high resistance to fuels, and the layer of the tetrafluoroethylene copolymer having a carbonate group and the layer of the polyolefin resin are firmly adhered.
摘要:
The present invention provides a laminate having an environmental cracking resistance for a fuel and a fuel impermeability and, in addition, higher in productivity. The present invention is a laminate including a chlorotrifluoroethylene copolymer layer (C) and a fluorine-free organic material layer (K), wherein the chlorotrifluoroethylene copolymer has a melt flow rate of 15.0 to 40.0 (g/10 minutes) and contains 15.0 to 25.0 mole percent of chlorotrifluoroethylene units relative to all monomer units.
摘要:
The present invention provides a laminate having an environmental cracking resistance for a fuel and a fuel impermeability and, in addition, higher in productivity. The present invention is a laminate including a chlorotrifluoroethylene copolymer layer (C) and a fluorine-free organic material layer (K), wherein the chlorotrifluoroethylene copolymer has a melt flow rate of 15.0 to 40.0 (g/10 minutes) and contains 15.0 to 25.0 mole percent of chlorotrifluoroethylene units relative to all monomer units.
摘要:
A tetrafluoroethylene copolymer comprising 30 to 81 mole % of tetrafluoroethylene and a 70 to 19 mole % of at least one other monomer, and having terminal carbonate groups at polymer chain ends, which has a melt flow rate of 0.1 to 100 g/10 min. at 200° C. under a load of 5 kg, and a melting point of 90 to 200° C., a laminate comprising a layer of the above tetrafluoroethylene copolymer, and a layer of other material, and a surface film or a transparent filler material for a solar cell, which comprises the above tetrafluoroethylene copolymer is disclosed. The fluororesin can be firmly adhered directly to other materials such as resins, metals, glass, crystalline silicon, polycrystalline silicon and amorphous silicon, while maintaining characteristics such as chemical resistance, solvent resistance, non-tackiness, electrical insulation properties, stain-proofing properties and flame retardance. The fluororesin can also be molded at a lower temperature than conventional fluororesins, and thus can be heat bonded or co-extruded with general purpose resins having low heat resistance.
摘要:
A tetrafluoroethylene copolymer comprising 30 to 81 mole % of tetrafluoroethylene and a 70 to 19 mole % of at least one other monomer, and having terminal carbonate groups at polymer chain ends, which has a melt flow rate of 0.1 to 100 g/10 min. at 200° C. under a load of 5 kg, and a melting point of 90 to 200° C. This copolymer can be firmly adhered directly to other materials such as general-purpose resins while maintaining the good properties of fluororesins such as chemical resistance, weather resistance, solvent resistance, non-tackiness, electrical insulation, stain-proofing properties, and flame retardance, molded at a lower temperature than conventional fluororesins, and heat bonded or co-extruded with general-purpose resins having low heat resistance.
摘要:
The present invention provides a laminate which is highly impermeable to fuels and has high fuel crack resistance. The present invention is a laminate having:a layer (A) comprising a fluorinated ethylenic polymer; a layer (B) comprising a chlorotrifluoroethylene copolymer; and a layer (C) comprising a fluorine-free organic material (P); the fluorinated ethylenic polymer being different from the chlorotrifluoroethylene copolymer forming the layer (B) in one and the same laminate and the layer (A), the layer (B), and the layer (C) being bonded together in that order.
摘要:
A polytetrafluoroethylene fine powder excellent in powder flowability which comprises fine particles (the primary particle) having a mean particle diameter of 0.05 to 1 &mgr;m, an apparent density of 0.52 to 0.70 g/ml, a standard specific gravity (SSG) of 2.14 to 2.23, and a secondary mean particle diameter of 100 to 1000 &mgr;m, antidripping agent using the above polytetrafluoroethylene fine powder, flame resistive resin composition containing this powder, and composition for inhibiting dust characteristics containing this powder.
摘要:
A tetrafluoroethylene/hexafluoropropylene copolymer has improved moldability in melt extrusion molding, especially with significant reduction of defects in high-speed extrusion coating of an electrical wire. The tetrafluoroethylene/hexafluoropropylene copolymer is obtained by polymerization of at least tetrafluoroethylene and hexafluoropropylene selected from the group consisting of tetrafluoroethylene, hexafluoropropylene and a third monomer without mixing with the resin which has the melting point with the difference of 20 degree C. and more from the melting point of the tetrafluoroethylene/hexafluoropropylene copolymer; and has a complex viscosity of from 2.0×I03 to 10.0×I03 Pa*s and a storage modulus of from 0.1 to 3.5 Pa*s in melt viscoelasticity measurement under the condition of atmosphere temperature of 310 degree C. and angular frequency of 0.01 radian/second. The tetrafluoroethylene/hexafluoropropylene copolymer can be used in an electrical wire as a coating on a conductive core.
摘要:
It is an object of the present invention to provide a fluororesin composition which hardly causes molding defects even when high-speed molding is performed in covering extrusion molding within a relatively broad molding temperature range and which can give covered electric wires, in particular foamed electric wires, excellent in surface smoothness.A fluororesin composition comprising a polytetrafluoroethylene [PTFE] having a standard specific gravity of 2.15 to 2.30 and a tetrafluoroethylene/hexafluoropropylene-based copolymer [FEP], the content of said PTFE being 0.01 to 3 parts by mass per 100 parts by mass of said FEP and the alkali metal content being not higher than 5 ppm on the resin composition solid matter basis, wherein said composition is obtained by a method comprising the step (1) of obtaining a cocoagulated fluororesin powder by mixing an aqueous dispersion containing said FEP and an aqueous dispersion containing said PTFE together, followed by coagulation, the step (2) of melt extruding the cocoagulated powder and the step (3) of subjecting the extrusion product to treatment for stabilizing unstable terminal groups in said PTFE and FEP.