公开(公告)号：US06726994B1

公开(公告)日：2004-04-27

申请号：US09856066

申请日：2001-05-17

申请人： Takayuki Araki ,  Tsuyoshi Miyamori ,  Masaji Komori ,  Yoshito Tanaka ,  Masahiro Kumegawa

发明人： Takayuki Araki ,  Tsuyoshi Miyamori ,  Masaji Komori ,  Yoshito Tanaka ,  Masahiro Kumegawa

IPC分类号： B32B1508

CPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/20 ,  B32B2307/306 ,  B32B2323/04 ,  B32B2379/08 ,  C09D161/06 ,  C09D179/08 ,  C10M169/00 ,  C10M2201/041 ,  C10M2201/066 ,  C10M2213/062 ,  C10M2217/0403 ,  C10M2217/0443 ,  C10N2230/06 ,  C10N2240/02 ,  C10N2250/141 ,  C23C28/00 ,  F16C33/201 ,  H01G7/021 ,  Y02T10/7022 ,  Y10T428/31504 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31678 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31942

摘要： The structural member of the present invention comprises (A) a layer which comprises a fluorine-containing polymer and does not contain an adhesive material other than the fluorine-containing polymer substantially and (B) a substrate, in which the layer (A) is adhered directly to the substrate (B) without interposing a binder therebetween and a longitudinal shear strength between the layer (A) comprising a fluorine-containing polymer and the substrate (B) is not less than 0.98 N/mm2 at 150° C. The structural member comprising a fluorine-containing polymer and a substrate adhered to each other, particularly the structural member having improved adhesive strength at high temperature and the sliding material produced by using the structural member are provided.

摘要翻译： 本发明的结构体包含（A）包含含氟聚合物的层，基本上不含含氟聚合物以外的粘合剂材料，（B）基材，其中层（A）为 在不插入粘合剂的情况下直接粘附到基板（B）上，并且包括含氟聚合物的层（A）和基板（B）之间的纵向剪切强度在150°时不小于0.98N / mm 2 C.包含含氟聚合物和彼此粘合的基材的结构件，特别是具有改善的高温粘合强度的结构件和使用结构件制成的滑动材料。

公开(公告)号：US06479578B2

公开(公告)日：2002-11-12

申请号：US09797693

申请日：2001-03-05

申请人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

IPC分类号： C08F800

CPC分类号： C08L27/12 ,  C08K3/01 ,  C08K3/013 ,  C08L27/18 ,  C08L2205/02 ,  H05K1/034 ,  H05K1/0373 ,  C08L2666/04

摘要： A resin composition which gives a molded article having both of excellent mechanical properties and abrasion resistance with maintaining excellent thermal resistance, chemical resistance, surface characteristics (non-sticking property, low friction property), electric insulating property, etc. of a fluorine-containing polymer; a molded article obtained from the resin composition; and a method for producing the molded article are provided. The resin composition comprises: (A-1) a fluorine-containing ethylenic polymer prepared by copolymerizing at least one of fluorine-containing monomers having any one of hydroxyl, carboxyl, a carboxylate salt group, a carboxylate ester group or epoxy in an amount of 0.05 to 30% by mole on the basis of the total amount of monomers, and (B-1) an inorganic filler or a non-meltable organic filler, wherein said resin composition comprises 1 to 99.5% by weight of the component (A-1) and 0.5 to 99% by weight of the component (B-1).

摘要翻译： 赋予具有优异的机械性能和耐磨性两者的保持优异的含氟的耐热性，耐化学性，表面特性（不粘附性，低摩擦性），电绝缘性等的成型体的树脂组合物 聚合物; 由树脂组合物得到的成型体; 并提供了制造模制品的方法。 树脂组合物包含：（A-1）通过使具有羟基，羧基，羧酸盐基，羧酸酯基或环氧基中的任一个的含氟单体的至少一种共聚合而制备的含氟乙烯性聚合物的量为 基于单体总量为0.05〜30摩尔％，和（B-1）无机填料或不可熔融有机填料，其中所述树脂组合物包含1-99.5重量％的组分（A- 1）和0.5〜99重量％的成分（B-1）。

公开(公告)号：US06225399B1

公开(公告)日：2001-05-01

申请号：US09065032

申请日：1998-04-27

申请人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

IPC分类号： C08F800

CPC分类号： C08L27/12 ,  C08K3/01 ,  C08K3/013 ,  C08L27/18 ,  C08L2205/02 ,  H05K1/034 ,  H05K1/0373 ,  C08L2666/04

摘要： A resin composition which gives a molded article having both of excellent mechanical properties and abrasion resistance with maintaining excellent thermal resistance, chemical resistance, surface characteristics (non-sticking property, low friction property), electric insulating property, etc. of a fluorine-containing polymer; a molded article obtained from the resin composition; and a method for producing the molded article are provided. The resin composition comprises: (A-1) a fluorine-containing ethylenic polymer prepared by copolymerizing at least one of fluorine-containing monomers having any one of hydroxyl, carboxyl, a carboxylate salt group, a carboxylate ester group or epoxy in an amount of 0.05 to 30% by mole on the basis of the total amount of monomers, and (B-1) an inorganic filler or a non-meltable organic filler, wherein said resin composition comprises 1 to 99.5% by weight of the component (A-1) and 0.5 to 99% by weight of the component (B-1).

摘要翻译： 赋予具有优异的机械性能和耐磨性两者的保持优异的含氟的耐热性，耐化学性，表面特性（不粘附性，低摩擦性），电绝缘性等的成型体的树脂组合物 聚合物; 由树脂组合物得到的成型体; 并提供了制造模制品的方法。 树脂组合物包含：（A-1）通过使具有羟基，羧基，羧酸盐基，羧酸酯基或环氧基中的任一个的含氟单体的至少一种共聚合而制备的含氟乙烯性聚合物的量为 基于单体总量为0.05〜30摩尔％，和（B-1）无机填料或不可熔融有机填料，其中所述树脂组合物包含1-99.5重量％的组分（A- 1）和0.5〜99重量％的成分（B-1）。

公开(公告)号：USRE41110E1

公开(公告)日：2010-02-09

申请号：US11512391

申请日：2006-08-30

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

IPC分类号： B32B27/00

CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

摘要翻译： 可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

公开(公告)号：US06207236B1

公开(公告)日：2001-03-27

申请号：US09202592

申请日：1998-12-17

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

IPC分类号： B05D302

CPC分类号： C09D127/12 ,  C09D127/18 ,  C08L2666/54

摘要： To provide the water-repellent coating film having excellent transparency, abrasion resistance, weather resistance and water repellency, the method for producing the coating film, the multi-functional composite material provided with the coating film and the coating composition used therefor which has excellent dispersion stability. The coating composition comprises (A) the fluorine-containing ethylenic polymer prepared by copolymerizing a fluorine-containing ethylenic monomer having at least one functional group selected from hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, (B-1) the metal oxide sol, and (C) the solvent.

摘要翻译： 为了提供具有优异的透明性，耐磨性，耐候性和防水性的防水涂膜，涂膜的制备方法，设置有涂膜的多功能复合材料及其所用的涂料组合物具有优异的分散性 稳定性。 涂料组合物包含（A）通过共聚含有至少一个选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基的官能团的含氟乙烯性单体制备的含氟乙烯性聚合物（B-1 ）金属氧化物溶胶，和（C）溶剂。

公开(公告)号：US06838139B2

公开(公告)日：2005-01-04

申请号：US10241490

申请日：2002-09-12

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

IPC分类号： C08F214/26 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/20 ,  B32B27/00

CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

摘要翻译： 可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

公开(公告)号：US06737164B2

公开(公告)日：2004-05-18

申请号：US09380499

申请日：1999-09-03

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

IPC分类号： B32B2708

CPC分类号： A47J36/02 ,  C08F214/20 ,  C08F216/04 ,  C08F220/00 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544

摘要： Composite materials for cooking apparatuses which are produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps and are excellent in heat resistance, non-sticking property, stain-proofing property, water- and oil-repelling property, stain-removing property, chemical resistance, rust-preventing property, antibacterial property, resistance to energy ray and abrasion resistance. The composite materials for cooking apparatuses are produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

摘要翻译： 用于烹饪设备的复合材料是通过向衬底施加包含具有优异粘合性的含氟聚合物的材料而制成的，而不需要复杂的步骤，并且具有优异的耐热性，不粘附性，防污染性 性能，防油和排斥性能，去污性，耐化学腐蚀性，防锈性，抗菌性，耐光能和耐磨性。 用于烹饪设备的复合材料是通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料制造的，所述官能团通过使（a）0.05〜30摩尔％的含氟乙烯性聚合物中的至少一种 具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体， 没有上述功能组。

公开(公告)号：US06479161B1

公开(公告)日：2002-11-12

申请号：US09425000

申请日：1999-12-03

申请人： Takayuki Araki ,  Shigehito Sagisaka ,  Yoshito Tanaka ,  Masahiro Kumegawa

发明人： Takayuki Araki ,  Shigehito Sagisaka ,  Yoshito Tanaka ,  Masahiro Kumegawa

IPC分类号： B32B2704

CPC分类号： B32B1/08 ,  B32B7/12 ,  B32B15/043 ,  C09J127/16 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31649 ,  Y10T428/31699 ,  Y10T428/31743 ,  Y10T428/3175 ,  Y10T428/31855 ,  Y10T428/31909

摘要： A fluorine-containing adhesive comprising a fluorine-containing ethylenic polymer (A) having functional group which has a crystalline melting point or glass transition temperature of not more than 270° C. and is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of carboxyl and a carboxylic salt group and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers which do not have the above-mentioned functional group and is copolymerizable with the component (a). To provide the fluorine-containing adhesive maintaining chemical resistance, solvent resistance, weather resistance and stain-proofing property and giving direct strong adhesion particularly to a substrate of metal, glass, resin, etc. and an adhesive film and laminated article which are produced from the fluorine-containing adhesive.

摘要翻译： 含有具有官能团的含氟乙烯性聚合物（A）的含氟粘合剂，其具有结晶熔点或玻璃化转变温度不高于270℃，并且通过（a）0.05〜30摩尔％ 的至少一种具有至少一个选自羧基和羧酸盐基团的官能团的含氟乙烯性单体和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体，其中， 不具有上述官能团并且可与组分（a）共聚。 提供维持耐化学性，耐溶剂性，耐候性和防污性的含氟粘合剂，特别是对金属，玻璃，树脂等的基材和粘合剂膜和层压制品的直接强粘合性，其由 含氟粘合剂。

公开(公告)号：US06794027B1

公开(公告)日：2004-09-21

申请号：US09763412

申请日：2001-02-22

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa

IPC分类号： B32B2708

CPC分类号： C09D129/12 ,  C09D127/18 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31544

摘要： To provide the method of forming the thin coating film of fluorine-containing polymer having heat resistance and non-sticking property by adhering directly to a substrate without lowering characteristics such as reflection and light transmission which the substrate has. The thin coating film is a film which comprises a continuous layer of fluorine-containing polymer formed by adhering directly to the substrate and has a thickness of less than 3 &mgr;m, wherein the fluorine-containing polymer in the coating film has a hydrophilic functional group and a crystalline melting point of not less than 200° C.

摘要翻译： 为了提供通过直接粘附到基板上形成具有耐热性和不粘附性的含氟聚合物的薄膜的方法，而不降低基板具有的反射和透光性等特性。 该薄膜是一种膜，其包含通过直接粘附于基材而形成的厚度小于3μm的含氟聚合物的连续层，其中，涂膜中的含氟聚合物具有亲水性官能团， 结晶熔点不低于200℃

公开(公告)号：US06677044B2

公开(公告)日：2004-01-13

申请号：US09423895

申请日：1999-11-16

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

IPC分类号： B32B1508

CPC分类号： C08F214/184 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31547 ,  Y10T428/31678

摘要： A composite material having sliding property is produced by applying, to a substrate, a material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above. The composite material having sliding property which is produced by applying, to the substrate, the material comprising the fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps.

摘要翻译： 通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料，制造具有滑动性的复合材料，该材料通过（a）将0.05〜30摩尔％的含氟乙烯性聚合物 具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体， 没有上述功能组。 具有滑动性的复合材料，其通过向基材施加包含具有优异的粘附性的含氟聚合物的材料而不需要复杂的步骤而制备。