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1.发明授权
公开(公告)号：US4247621A
公开(公告)日：1981-01-27
申请号：US670956
申请日：1976-03-26
申请人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura , Akihiro Furuta
发明人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura , Akihiro Furuta
CPC分类号： G03F7/027 , C08L67/06 , Y10S430/118 , Y10S430/121
摘要： An original pattern plate obtained by the use of a photo-sensitive resin composition comprising:(A) an unsaturated polyester having an acid value of from 10 to 40 and having not less than 50% by mole of unsaturated acids in the acid component,(B) a photo-polymerizable, ethylenically unsaturated compound which essentially contains a compound having a photo-polymerizable, ethylenically unsaturated linkage and at least one hydroxyl group,(C) a melamine compound of the formula:(C.sub.3 H.sub.6-(m+n) N.sub.6)(CH.sub.2 OH).sub.m (CH.sub.2 OR).sub.n wherein R is an alkyl group having 1 to 4 carbon atoms, m is from 0 to 6, n is from 0 to 6 and m+n is from 1.5 to 6, or its condensate having an average condensation degree of not more than 4,(D) a photo-polymerization initiator, and(E) a thermal polymerization inhibitor,the weight proportion of the components (A), (B) and (C) satisfying the relationships of the following equations: 1/5.ltoreq.B/(A+B).ltoreq.3/5 and 1/50.ltoreq.C/(A+B+C).ltoreq.1/5, which is improved in mechanical strength, particularly in resistance to heat and pressure.
摘要翻译： 通过使用感光性树脂组合物获得的原始图案板，其包含：（A）酸成分中不饱和酸的酸值为10〜40，不少于50摩尔％的不饱和聚酯（ B）可光聚合的烯属不饱和化合物，其基本上含有具有可光聚合的烯属不饱和键和至少一个羟基的化合物，（C）下式的三聚氰胺化合物：（C 3 H 6 - （m + n）N 6 ）（CH 2 OH）m（CH 2 OR）n，其中R为具有1至4个碳原子的烷基，m为0至6，n为0至6，m + n为1.5至6，或其缩合物具有 平均缩合度不大于4，（D）光聚合引发剂和（E）热聚合抑制剂，满足以下关系的组分（A），（B）和（C）的重量比例 方程式：1/5
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公开(公告)号：US4140605A
公开(公告)日：1979-02-20
申请号：US789652
申请日：1977-04-21
申请人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura , Akihiro Furuta
发明人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura , Akihiro Furuta
IPC分类号： C08F2/00 , C08F2/44 , C08F2/48 , C08F2/50 , C08F4/00 , C08F216/06 , C08F220/26 , C08F283/00 , C08G12/26 , C08J3/24 , C08K5/34 , C08K5/3492 , C08L29/04 , C08L33/00 , C08L33/02 , C08L67/00 , C08L67/06
CPC分类号： C08F220/26 , C08K5/34922
摘要： A crosslinkable composition comprising:(I) a melamine compound of the formula:(C.sub.3 H.sub.6-(m+n) N.sub.6) (CH.sub.2 OH.sub.m (CH.sub.2 OR).sub.n wherein R is an alkyl group having 1 to 4 carbon atoms, m is from 0 to 6, n is from 0 to 6 and m + n is from 1.5 to 6, or its condensate having an average condensation degree of not more than 4;(II) a compound having at least two functional groups condensable with the component (I) and an average molecular weight of not less than 1,000;(III) a compound having an ethylenically un-unsaturated linkage photopolymerizable by actinic light;(IV) a photopolymerization initiator; and(V) a thermal polymerization inhibitor.
摘要翻译： 一种可交联组合物，其包含：
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3.发明授权
公开(公告)号：US3960685A
公开(公告)日：1976-06-01
申请号：US521151
申请日：1974-11-05
申请人： Takezo Sano , Yukikazu Uemura , Akihiro Furuta
发明人： Takezo Sano , Yukikazu Uemura , Akihiro Furuta
CPC分类号： G03F7/0325
摘要： A photosensitive resin composition comprising pullulan, which is a polymer having repetition units of maltotriose and is represented by the formula, ##SPC1##Wherein n is an integer of 20 to 8,000, and/or a derivative thereof, a photopolymerizable monomer, a photosensitizer and a thermal polymerization inhibitor, or comprising the said pullulan, which has been incorporated with a photoactive reaction group to provide photosensitivity, and a photosensitizer, is a novel composition low in viscosity which can be prepared by use of water and can be formed into a photosensitive plate capable of being developed with water to give a clear image. Since the pullulan in said composition has no toxicity, the waste water formed at the time of development of said photosensitive plate can be treated with ease.
摘要翻译： 一种感光性树脂组合物，其包含支链淀粉，其是具有麦芽三糖重复单元并由下式表示的聚合物：其中N是20至8,000的整数，和/或其衍生物，可光聚合的单体，光致变色剂和热聚合 抑制剂或包含已经与光敏反应组合并提供光敏性的已知PULLULAN和光敏剂是一种低粘度的新型组合物，可通过使用水制备，并可形成可感知的感光层 用水开发以清除图像。 由于所述组合物中的支链淀粉没有毒性，因此可以容易地处理在所述感光板显影时形成的废水。
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4.发明授权Resin original pattern plate and method for transferring relieved pattern thereof to thermoplastic resin material 失效树脂原版图案及其缓解图案转移到热塑性树脂材料的方法
公开(公告)号：US4297945A
公开(公告)日：1981-11-03
申请号：US19143
申请日：1979-03-09
申请人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura
发明人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura
CPC分类号： B41C3/00 , G03F7/027 , Y10S428/908 , Y10S428/914 , Y10T428/24612
摘要： Relieved pattern of a resin original pattern plate, which does not exhibit fluidity at transferring temperature and possesses elastic modulus no smaller than 10 kg/cm.sup.2, preferably no smaller than 100 kg/cm.sup.2, is transferred onto thermoplastic resin material having fluidity at the transferring temperature (ASTM D1238, load 21.6 kg) of at least 0.01 dg/min, preferably at least 0.1 dg/min, by pressing the thermoplastic resin material to the original pattern plate under a pressure condition where elastic deformation of the original pattern plate is kept within 10%. The resin original pattern plate is prepared by controlling the photo-polymerizable resin composition to adjust its crosslink-ability and then photo-polymerizing, whereby the resulting resin original pattern plate possesses an elastic modulus of 10 kg/cm.sup.2 or higher at transferring temperature. The photo-polymerizable resin composition includes, as its major ingredients, either polymer, polyfunctional monomer (10-90% by weight, preferably 30-70% by weight, and having viscosity of at least 10.sup.3 poise at transferring temperature), photo-sensitizer and thermal polymerization inhibitor, or cross-linkable polymer (having at least 1000 molecular weight and double bonds at least one for each 1000 molecular weight), monomer (5-50% by weight, preferably 10-40% by weight), photosensitizer and thermal polymerization inhibitor.
摘要翻译： 在转印温度下不具有流动性并且不小于10kg / cm 2，优选不小于100kg / cm 2的弹性模量的树脂原版图案的缓冲图案转印到在转印温度下具有流动性的热塑性树脂材料上 （ASTM D1238，负荷21.6kg）为至少0.01dg / min，优选至少0.1dg / min，通过在原始图案板的弹性变形保持在其内的压力条件下将热塑性树脂材料压制到原始图案板上 10％。 通过控制光聚合性树脂组合物调节其交联性，然后进行光聚合，制备树脂原图板，由此得到的树脂原始图案板在转印温度下的弹性模量为10kg / cm 2以上。 可光聚合树脂组合物包括聚合物，多官能单体（10-90重量％，优选30-70重量％，并且在转印温度下具有至少103泊的粘度）作为其主要成分，光敏剂 和热聚合抑制剂或可交联聚合物（每1000分子量具有至少1000个分子量和双键至少一个），单体（5-50重量％，优选10-40重量％），光敏剂和 热聚合抑制剂。
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5.发明授权Resin original pattern plate and method for transferring relieved pattern thereof to thermoplastic resin material 失效树脂原版图案及其缓解图案转移到热塑性树脂材料的方法
公开(公告)号：US4156389A
公开(公告)日：1979-05-29
申请号：US682724
申请日：1976-05-03
申请人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura
发明人： Takezo Sano , Tadanori Inoue , Yukikazu Uemura
摘要： Relieved pattern of a resin original pattern plate, which does not exhibit fluidity at transferring temperature and possesses elastic modulus no smaller than 10 kg/cm.sup.2, preferably no smaller than 100 kg/cm.sup.2, is transferred onto thermoplastic resin material having fluidity at the transferring temperature (ASTM D1238, load 21.6 kg) of at least 0.01 dg/min, preferably at least 0.1 dg/min, by pressing the thermoplastic resin material to the original pattern plate under a pressure condition where elastic deformation of the original pattern plate is kept within 10%. The resin original pattern plate is prepared by controlling the photopolymerizable resin composition to adjust its cross-linkability and then photo-polymerizing, whereby the resulting resin original pattern plate possesses an elastic modulus of 10 kg/cm.sup.2 or higher at transferring temperature. The photo-polymerizable resin composition includes, as its major ingredients, either polymer, polyfunctional monomer (10- 90% by weight, preferably 30- 70% by weight, and having viscosity of at least 10.sup.3 poise at transferring temperature), photo-sensitizer and thermal polymerization inhibitor, or cross-linkable polymer (having at least 1000 molecular weight and double bonds at least one for each 1000 molecular weight), monomer (5- 50% by weight, preferably 10- 40% by weight), photosensitizer and thermal polymerization inhibitor.
摘要翻译： 在转印温度下不具有流动性并且不小于10kg / cm 2，优选不小于100kg / cm 2的弹性模量的树脂原版图案的缓冲图案转印到在转印温度下具有流动性的热塑性树脂材料上 （ASTM D1238，负荷21.6kg）为至少0.01dg / min，优选至少0.1dg / min，通过在原始图案板的弹性变形保持在其内的压力条件下将热塑性树脂材料压制到原始图案板上 10％。 通过控制可光聚合的树脂组合物来调节其交联性，然后进行光聚合，制备树脂原始图案板，由此得到的树脂原始图案板在转印温度下的弹性模量为10kg / cm 2以上。 可光聚合树脂组合物包括聚合物，多官能单体（10-90重量％，优选30-70重量％，转印温度下粘度至少为103泊）的主要成分，光敏剂 和热聚合抑制剂或可交联聚合物（每1000个分子量具有至少1000个分子量和双键至少一个），单体（5-50重量％，优选10-40重量％），光敏剂和 热聚合抑制剂。
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公开(公告)号：US4288529A
公开(公告)日：1981-09-08
申请号：US115492
申请日：1980-01-25
申请人： Takezo Sano , Haruo Inoue , Akihiro Furuta
发明人： Takezo Sano , Haruo Inoue , Akihiro Furuta
CPC分类号： G03F7/12 , G03F7/2012
摘要： A photo-curable composite material used for preparing various stencils for screen printing, textile printing or the like, which comprises a flat, flexible and photo-transmitting thin film (A); a flat and flexible film (B); a liquid photo-curable resin and a flat screen material, said films (A) and (B) being air-tightly bonded to each other at the peripheral portion thereof to form a flat inner space therein, said liquid resin being filled in said inner space to form a layer and said screen material also being placed in the inner space substantially in parallel with the inner walls of the films (A) and (B).
摘要翻译： 用于制备用于丝网印刷，纺织品印刷等的各种模版的光固化复合材料，其包括平坦，柔性和光致透明薄膜（A）; 扁平柔软的薄膜（B）; 液体光固化树脂和平板筛网材料，所述膜（A）和（B）在其周边部分彼此气密地结合以在其中形成平坦的内部空间，所述液体树脂填充在所述内部 形成层的空间，并且所述屏幕材料也被放置在基本上与膜（A）和（B）的内壁平行的内部空间中。
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7.发明授权
公开(公告)号：US4216287A
公开(公告)日：1980-08-05
申请号：US888864
申请日：1978-03-22
申请人： Takezo Sano , Haruo Inoue , Akihiro Furuta
发明人： Takezo Sano , Haruo Inoue , Akihiro Furuta
CPC分类号： G03F7/12 , G03F7/2012
摘要： A photo-curable composite material used for preparing various stencils for screen printing, textile printing or the like, which comprises a flat, flexible and photo-transmitting thin film (A); a flat and flexible film (B); a liquid photo-curable resin and a flat screen material, said films (A) and (B) being air-tightly bonded to each other at the peripheral portion thereof to form a flat inner space therein, said liquid resin being filled in said inner space to form a layer and said screen material also being placed in the inner space substantially in parallel with the inner walls of the films (A) and (B).
摘要翻译： 用于制备用于丝网印刷，纺织品印刷等的各种模版的光固化复合材料，其包括平坦，柔性和光致透明薄膜（A）; 扁平柔软的薄膜（B）; 液体光固化树脂和平板筛网材料，所述膜（A）和（B）在其周边部分彼此气密地结合以在其中形成平坦的内部空间，所述液体树脂填充在所述内部 形成层的空间，并且所述屏幕材料也被放置在基本上与膜（A）和（B）的内壁平行的内部空间中。
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8.发明授权Process for producing photo-curable composite materials useful for preparing stencils 失效用于制备可用于制备模版的光固化复合材料的方法
公开(公告)号：US4302528A
公开(公告)日：1981-11-24
申请号：US56640
申请日：1979-07-11
申请人： Takezo Sano , Haruo Inoue , Akihiro Furuta
发明人： Takezo Sano , Haruo Inoue , Akihiro Furuta
CPC分类号： B32B37/24 , B29C43/305 , G03F7/12 , G03F7/16 , Y10S430/136
摘要： An improved process for producing a photo-curable composite material using a liquid photo-curable resin, which comprises holding a liquid photo-curable resin with a screen material between two films, at least one of the films having photo-transmitting properties, and passing the films holding the liquid photo-curable resin and the screen material through a gap (e.g. between two rollers). The process of the present invention can produce photo-curable composite materials useful for preparing various stencils for screen printing, textile printing, or the like at a low cost and with less production of defects.
摘要翻译： 一种改进的使用液体光固化树脂生产光固化复合材料的方法，该方法包括将具有筛网材料的液体光固化树脂保持在两个膜之间，至少一个具有光透射性质的膜和通过 通过间隙（例如在两个辊之间）保持液体光固化树脂和筛网材料的膜。 本发明的方法可以以低成本制造用于丝网印刷，纺织印刷等各种模板的光固化复合材料，并且产生较少的缺陷。
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公开(公告)号：US4727344A
公开(公告)日：1988-02-23
申请号：US914521
申请日：1986-10-02
申请人： Hirofumi Koga , Kozo Maenishi , Shuichi Kashimoto , Sueaki Honda , Kenichi Tsuruyoshi , Takezo Sano
发明人： Hirofumi Koga , Kozo Maenishi , Shuichi Kashimoto , Sueaki Honda , Kenichi Tsuruyoshi , Takezo Sano
CPC分类号： H01F7/1646 , H01H50/44 , H01H51/2209 , H01F7/122 , H01H2050/046 , H01H2051/2218
摘要： A polarized relay with an electromagnetic drive comprises an electromagnetic yoke composed of a core wound with a coil and a yoke body, and having one end portion of one magnetic polarity and a pair of bifurcated end portions of the other magnetic polarity opposite to the one magnetic polarity. The bifurcated end portions are separated in opposition from each other. The one end portion of the yoke is disposed between the bifurcated end portions so as to cooperate to form a pair of working gaps. A movable block of a substantially C-like configuration incorporating a permanent magnet has two magnetic pole pieces which are disposed within the working gaps, respectively. Guide is provided for guiding the movable block in response to energization and deenergization of the coil so that the pole pieces are movable within the respective working gaps. A contact mechanism including movable contacts is mechanically coupled to the movable block to make or break circuit.
摘要翻译： 具有电磁驱动的极化继电器包括由卷绕有线圈的磁芯和磁轭体构成的电磁轭，具有一个磁极的一个端部和与一个磁性相反的另一个磁极的一对分叉端部 极性。 分叉的端部彼此相对分离。 轭的一端部设置在分叉端部之间，以配合形成一对工作间隙。 具有永磁体的基本上C形结构的可动块分别具有设置在工作间隙内的两个磁极片。 引导件用于响应于线圈的通电和断电引导可移动块，使得极片在相应的工作间隙内可移动。 包括可移动触点的接触机构机械耦合到可移动块以产生或断开电路。
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公开(公告)号：US4163725A
公开(公告)日：1979-08-07
申请号：US761904
申请日：1977-01-24
IPC分类号： C08J7/00 , B01D71/68 , B29C59/14 , C08G75/20 , C08L81/06 , D06M14/18 , C08J3/24 , C08J3/28 , C08J7/10
CPC分类号： B01D71/68 , B01D67/0013 , B01D67/009 , B29C59/14 , C08L81/06 , D06M14/18 , B29K2081/00 , B29K2105/24 , B29L2031/755
摘要： A method for the preparation of semipermeable membrane which comprises exposing porous shaped articles of polysulfone to a plasma.The resulting semipermeable membrane is very useful for separating substances by reverse osmosis or ultrafiltration.
摘要翻译： 一种制备半透膜的方法，其包括将聚砜的多孔成形制品暴露于等离子体中。
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