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1.发明授权Tertiary phosphine compound and transition metal complex comprising the same as ligand 失效包含与配体相同的叔膦化合物和过渡金属络合物
公开(公告)号：US5523437A
公开(公告)日：1996-06-04
申请号：US280814
申请日：1994-07-26
IPC分类号： B01J31/24 , C07B53/00 , C07B59/00 , C07C1/213 , C07F9/50 , C07F15/00 , C07C2/02 , C07F7/08 , C07F9/02
CPC分类号： B01J31/2447 , C07B53/00 , C07B59/001 , C07C1/213 , C07F15/0066 , C07F9/5022 , B01J2231/323 , B01J2231/641 , B01J2531/824 , B01J31/04 , B01J31/223 , C07C2531/24
摘要： A tertiary phosphine compound of the formula (1): ##STR1## wherein R.sup.1 and R.sup.2 represent independently from each other a hydrogen atom or a methyl group, or together form --CH.dbd.CH--CH.dbd.CH--; R.sup.3 is a hydrogen atom or a cycloalkyl group having 5 to 7 carbon atoms or a lower alkyl group which may be substituted with a halogen atom, a lower alkoxy group, a lower alkoxyalkoxy group or a phenyl group; X.sup.1 is a halogen atom when both R.sup.1 and R.sup.2 are hydrogen atoms, or a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group when at least one of R.sup.1 and R.sup.2 is not a hydrogen atoms; and m is an integer of 1 to 5, which is useful as a ligand of a transition metal complex that can catalyze various reactions.
摘要翻译： 式（1）的叔膦化合物：氢原子或甲基彼此相同，或一起形成-CH = CH-CH = CH-; R3是氢原子或碳原子数5〜7的环烷基或可以被卤素原子，低级烷氧基，低级烷氧基烷氧基或苯基取代的低级烷基; 当R1和R2中的至少一个不是氢原子时，当R1和R2都是氢原子时，X1是卤素原子，或者氢原子，卤原子，低级烷基或低级烷氧基; m为1〜5的整数，可用作催化各种反应的过渡金属络合物的配体。
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2.发明授权Optically active tertiary phosphine compound and transition metal complex using the same as ligand 失效光学有效的磷酸三钙化合物和使用其作为配体的过渡金属络合物
公开(公告)号：US5231202A
公开(公告)日：1993-07-27
申请号：US850998
申请日：1992-03-12
CPC分类号： C07F7/14 , C07F15/0066 , C07F9/5022
摘要： A phosphine compound represented by formula (I): ##STR1## wherein Ph represents a phenyl group; and R represents a lower alkyl group or --OR.sup.1, wherein R.sup.1 represents a hydrogen atom, a cycloalkyl group having from 5 to 7 carbon atoms, or an alkyl group having from 1 to 6 carbon atoms which may be substituted with a halogen atom, a lower alkoxy group, a lower alkoxy group-substituted lower alkoxy group, or a phenyl group, and a transition metal complex using the phosphine compound (I) as a ligand are disclosed. The transition metal complex, when used as a catalyst for various enantioselective synthesis reactions, e.g., enantioselective silylation reaction, provides a desired product in high yield at high optical purity. The absolute configuration of the product can be arbitrarily selected by selecting the optical isomer of the ligand in the transition metal complex catalyst.
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公开(公告)号：US20050042546A1
公开(公告)日：2005-02-24
申请号：US10921935
申请日：2004-08-20
申请人： Jun Ozaki , Yasuhiro Uozumi
发明人： Jun Ozaki , Yasuhiro Uozumi
IPC分类号： B41C1/10 , C08F220/58 , C08F222/40 , G03F7/00
CPC分类号： C08F222/40 , B41C1/1008 , B41C2210/02 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , C08F220/58
摘要： An object of the present invention is to provide a base plate for a lithographic printing plate comprising a photosensitive layer that prevent the occurrence of the fingerprint rub-off phenomena and abrasion phenomena and offer superior anti-abrasiveness and chemical resistance. The present invention provides a copolymer having monomeric units shown in formula (I) and (II); an image-forming composition comprising the copolymer; and a base plate for a lithographic printing plate comprising, on a support structure, a photosensitive layer that contains the copolymer.
摘要翻译： 本发明的目的是提供一种用于平版印刷版的基板，其包括防止指纹擦除现象和磨损现象发生的感光层，并提供优异的抗磨损性和耐化学性。 本发明提供具有式（I）和（II）所示的单体单元的共聚物; 包含该共聚物的成像组合物; 以及用于平版印刷版的基板，在支撑结构上包含含有该共聚物的光敏层。
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4.发明申请公开(公告)号：US20080176739A1
公开(公告)日：2008-07-24
申请号：US11885734
申请日：2005-12-01
申请人： Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
发明人： Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
IPC分类号： B01J31/18
CPC分类号： C07C45/39 , B01J23/42 , B01J31/068 , B01J31/1658 , B01J31/1805 , B01J31/2291 , B01J31/4038 , B01J31/4069 , B01J35/0013 , B01J35/006 , B01J2231/70 , B01J2531/828 , C07C51/235 , Y02P20/584 , C07C49/413 , C07C49/217 , C07C49/78 , C07C49/04 , C07C49/76 , C07C57/44
摘要： To provide a catalyst that has sufficient catalytic activity as a platinum catalyst and yet is readily separated from a target material and can be reused. A resin-supported platinum cluster catalyst containing a resin layer comprising a platinum particle core, the average diameter of which is from 1 nm to 10 nm, and a compound containing nitrogen (general formula R1NH2) surrounding the core. This catalyst can be obtained by forming a platinum complex from a compound containing nitrogen represented by the general formula R1NR22 (in the formula, R1 represents a carrier with a hydrophilic molecular chain and R2 represents a hydrogen atom, an alkyl group and the like) and a platinum compound represented by the general formula M(PtX4-nR3n)m (in the formula, M represents an alkali metal and the like, X represents a halogen atom and the like, R3 represents an unsaturated organic ligand, n represents an integer from zero to four and m represents an integer indicating the electrical charge of the metal, M) and allowing this platinum complex to react with a reducing agent in an aqueous solvent.
摘要翻译： 提供具有作为铂催化剂的足够的催化活性并且容易与目标材料分离并且可以重复使用的催化剂。 含有包含平均直径为1nm〜10nm的铂粒子核的树脂层的树脂负载的铂簇催化剂和含有氮的化合物（通式R 1〜N 2 N 2 ）。 该催化剂可以通过从由通式R 1，R 2，R 2，R 2，R 2，R 2，R 2，R 2，R 3，R 3， R 1表示具有亲水性分子链的载体，R 2表示氢原子，烷基等）和由通式M表示的铂化合物 （在式中，M表示碱金属，并且其中R 1，R 2，R 3，R 4，R 5， X表示卤素原子等，R 3表示不饱和有机配位体，n表示0〜4的整数，m表示金属M的电荷的整数，M表示 使该铂络合物与水溶剂中的还原剂反应。
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5.发明申请Aluminum support for lithographic printing plate and base plate for lithographic printing plate 失效用于平版印刷版的铝支架和用于平版印刷版的基板公开(公告)号：US20050142493A1
公开(公告)日：2005-06-30
申请号：US11017102
申请日：2004-12-21
申请人： Jun Ozaki , Yasuhiro Uozumi
发明人： Jun Ozaki , Yasuhiro Uozumi
IPC分类号： G03F7/004 , B41C1/10 , B41N1/08 , B41N1/14 , B41N3/03 , C23C22/36 , C23C28/00 , C25D11/24 , G03F7/00 , G03F7/09
CPC分类号： B41N3/038 , B41C1/1008 , B41C2210/02 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41N3/034 , C25D11/24 , C25D11/246
摘要： An object of the present invention is to provide a support for lithographic printing plates provided with a photosensitive layer containing an acid generator and an acid-decomposable compound, that offers superior sensitivity, chemical resistance, print durability, and little scumming during printing. The present invention provides an aluminum support for a lithographic printing plate, the support being obtainable by treating a surface of an anodized aluminum plate with a treatment liquid comprising metal fluoride, metal phosphate salt, and perchlorate, and a base plate for a lithographic printing plate using the same.
摘要翻译： 本发明的目的是提供一种具有含有酸产生剂和酸可分解化合物的感光层的平版印刷版的支持体，其在印刷过程中具有优异的灵敏度，耐化学性，印刷耐久性和少量浮渣。 本发明提供了一种用于平版印刷版的铝载体，该载体可通过用包含金属氟化物，金属磷酸盐和高氯酸盐的处理液处理阳极氧化铝板的表面，以及用于平版印刷版的基板 使用相同
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6.发明授权公开(公告)号：US07897817B2
公开(公告)日：2011-03-01
申请号：US11885734
申请日：2005-12-01
申请人： Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
发明人： Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
IPC分类号： C07C49/00
CPC分类号： C07C45/39 , B01J23/42 , B01J31/068 , B01J31/1658 , B01J31/1805 , B01J31/2291 , B01J31/4038 , B01J31/4069 , B01J35/0013 , B01J35/006 , B01J2231/70 , B01J2531/828 , C07C51/235 , Y02P20/584 , C07C49/413 , C07C49/217 , C07C49/78 , C07C49/04 , C07C49/76 , C07C57/44
摘要： To provide a catalyst that has sufficient catalytic activity as a platinum catalyst and yet is readily separated from a target material and can be reused. A resin-supported platinum cluster catalyst containing a resin layer comprising a platinum particle core, the average diameter of which is from 1 nm to 10 nm, and a compound containing nitrogen (general formula R1NH2) surrounding the core. This catalyst can be obtained by forming a platinum complex from a compound containing nitrogen represented by the general formula R1NR22 (in the formula, R1 represents a carrier with a hydrophilic molecular chain and R2 represents a hydrogen atom, an alkyl group and the like) and a platinum compound represented by the general formula M(PtX4-nR3n)m (in the formula, M represents an alkali metal and the like, X represents a halogen atom and the like, R3 represents an unsaturated organic ligand, n represents an integer from zero to four and m represents an integer indicating the electrical charge of the metal, M) and allowing this platinum complex to react with a reducing agent in an aqueous solvent.
摘要翻译： 提供具有作为铂催化剂的足够的催化活性并且容易与目标材料分离并且可以重复使用的催化剂。 含有包含平均直径为1nm〜10nm的铂粒子核心的树脂层的树脂负载的铂簇催化剂和包含核的氮（通式R 1 NH 2）的化合物。 该催化剂可以通过由通式R1NR22表示的含氮化合物形成铂络合物（式中，R1表示具有亲水性分子链的载体，R2表示氢原子，烷基等）和 由通式M（PtX4-nR3n）m表示的铂化合物（式中，M表示碱金属等，X表示卤素原子等，R3表示不饱和有机配体，n表示来自 0至4，m表示金属的电荷的整数，M），并允许该铂络合物在水性溶剂中与还原剂反应。
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公开(公告)号：US20100219978A1
公开(公告)日：2010-09-02
申请号：US11990154
申请日：2006-08-02
申请人： Yasuhiro Uozumi
发明人： Yasuhiro Uozumi
IPC分类号： H04B1/20
CPC分类号： G11B33/10 , G11B20/10 , G11B31/02 , G11B33/12 , G11B2020/10546 , Y10T307/724 , Y10T307/729
摘要： One aspect of the present invention can include a playback device capable of externally receiving a playback signal for playing back a sound or an image, and capable of transmitting the playback signal to the playback device if it is detected that a predetermined electric source was externally supplied.
摘要翻译： 本发明的一个方面可以包括能够外部接收用于播放声音或图像的重放信号的回放装置，并且如果检测到外部提供了预定的电源，则能够将重放信号发送到重放装置 。
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公开(公告)号：US08576046B2
公开(公告)日：2013-11-05
申请号：US11990154
申请日：2006-08-02
申请人： Yasuhiro Uozumi
发明人： Yasuhiro Uozumi
IPC分类号： H04B1/20
CPC分类号： G11B33/10 , G11B20/10 , G11B31/02 , G11B33/12 , G11B2020/10546 , Y10T307/724 , Y10T307/729
摘要： One aspect of the present invention can include a playback device capable of externally receiving a playback signal for playing back a sound or an image, and capable of transmitting the playback signal to the playback device if it is detected that a predetermined electric source was externally supplied.
摘要翻译： 本发明的一个方面可以包括能够外部接收用于播放声音或图像的重放信号的回放装置，并且如果检测到外部提供了预定的电源，则能够将重放信号发送到重放装置 。
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公开(公告)号：US20090299101A1
公开(公告)日：2009-12-03
申请号：US12097862
申请日：2006-10-11
申请人： Yasuhiro Uozumi , Yoichi Yamada
发明人： Yasuhiro Uozumi , Yoichi Yamada
CPC分类号： C07B37/04 , B01J31/0239 , B01J31/06 , B01J31/165 , B01J37/16 , B01J2531/82 , C07C45/71 , C07C49/04 , C07C49/213
摘要： The present invention provides a catalyst, which has enough catalytic activity as a transition metal particle catalyst including platinum family and the like, is easily separable from products, is reusable and is easily prepared. To prepare the transition metal cluster catalyst of the present invention, an insoluble complex is prepared by forming a complex between a polymer with nitrogen-containing group, such as pyridinium and ammonium group in the principal chain, and a later transition metal compound; and then reducing the complex with a reductant. The transition metal forms clusters, which are stabilized by the polymers. Namely, the present invention is a transition metal cluster catalyst, wherein transition metal clusters are supported by a polymer, which is obtained by reduction reaction of a complex of a transition metal and a polymer with nitrogen-containing group. The transition metal cluster catalyst of the present invention is an extremely useful catalyst for oxidation, reduction, cross-coupling, Heck reaction, alkylation reaction and the like.
摘要翻译： 本发明提供了具有足够的催化活性的催化剂，其作为包括铂族等的过渡金属颗粒催化剂容易与产物分离，可重复使用且易于制备。 为了制备本发明的过渡金属簇催化剂，通过在具有含氮基团的聚合物如主链中的吡啶鎓和铵基之间形成络合物和后来的过渡金属化合物来制备不溶性络合物; 然后用还原剂还原络合物。 过渡金属形成簇，其被聚合物稳定。 也就是说，本发明是一种过渡金属簇催化剂，其中过渡金属簇由聚合物负载，该过渡金属簇通过过渡金属和聚合物与含氮基团的络合物的还原反应获得。 本发明的过渡金属簇催化剂是用于氧化，还原，交叉偶联，Heck反应，烷基化反应等的非常有用的催化剂。
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公开(公告)号：US07164026B2
公开(公告)日：2007-01-16
申请号：US10704576
申请日：2003-11-12
申请人： Yasuhiro Uozumi , Heiko Hoche , Kenzo Sumi
发明人： Yasuhiro Uozumi , Heiko Hoche , Kenzo Sumi
IPC分类号： C07F7/02 , C07D413/02
CPC分类号： C07D263/12 , C07D263/14 , Y02P20/582
摘要： A polymer-carrying optically active binaphthyl type oxazoline compound having axial asymmetry, represented by the following general formula (1) (wherein R1 and R2 may be the same or different from each other and each represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms or the like; R3 is a hydrogen atom or —R5—X—R6; R4 is a hydrogen atom or the like; R5 is a straight- or branched-chain aliphatic hydrocarbon chain which may have a directly or indirectly bonded substituent; X is CH2, CO2, O, CONR7 or NR7; R6 is a directly or indirectly bonded polymer; and R7 is a hydrogen atom or the like), and to a transition metal complex which uses the compound as the ligand.
摘要翻译： 由以下通式（1）表示的具有轴不对称性的聚合物携带光学活性的联萘型恶唑啉化合物（其中R 1和R 2可以相同或不同） 彼此分别表示氢原子，碳原子数为1〜6的烷基等; R 3是氢原子或-R 5 -SR R 4是氢原子等; R 5是直链或支链脂族烃链，其可以具有 直接或间接键合的取代基; X是CH 2，CO 2，O，CONR 7或NR 7; R 6是直接或间接结合的聚合物; R 7是氢原子等）和使用该化合物作为配体的过渡金属络合物。
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