公开(公告)号：US20060257660A1

公开(公告)日：2006-11-16

申请号：US11430622

申请日：2006-05-09

申请人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

发明人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

IPC分类号： B32B5/16

CPC分类号： C08F6/008 ,  C08K3/36 ,  Y10T428/2982 ,  C08L27/06

摘要： The present invention provides an antistatic agent for vinyl chloride-based resins which can impart superior antistatic properties to the vinyl chloride-based resin, and which can thereby solve various problems arising from charging of the vinyl chloride-based resin with static electricity, a vinyl chloride-based resin composition containing this antistatic agent, and a method for manufacturing this composition. The present invention provides an antistatic agent for vinyl chloride-based resins which consists of silica particles containing at least 99.0% by mass of SiO2 and 0.00005% 80.5 ppm by mass or less of sodium, and which has such a particle size distribution that at least 98% by mass of the silica particles is occupied by the particles having a particle diameter in the range from 30 to 1,000 nm.

摘要翻译： 本发明提供了一种氯乙烯类树脂的抗静电剂，其可以赋予氯乙烯类树脂优异的抗静电性能，从而可以解决由静电装入氯乙烯类树脂引起的各种问题，乙烯基 含有该抗静电剂的氯化物系树脂组合物及其制造方法。 本发明提供了一种氯乙烯类树脂的抗静电剂，其由含有至少99.0质量％SiO 2和0.00005％80.5质量ppm以下的二氧化硅粒子构成，其具有 这样的粒度分布，使得至少98质量％的二氧化硅粒子被粒径在30〜1000nm的粒子占据。

公开(公告)号：US07514495B2

公开(公告)日：2009-04-07

申请号：US11430622

申请日：2006-05-09

申请人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

发明人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

IPC分类号： C08K3/36

CPC分类号： C08F6/008 ,  C08K3/36 ,  Y10T428/2982 ,  C08L27/06

摘要： The present invention provides an antistatic agent for vinyl chloride-based resins which can impart superior antistatic properties to the vinyl chloride-based resin, and which can thereby solve various problems arising from charging of the vinyl chloride-based resin with static electricity, a vinyl chloride-based resin composition containing this antistatic agent, and a method for manufacturing this composition. The present invention provides an antistatic agent for vinyl chloride-based resins which consists of silica particles containing at least 99.0% by mass of SiO2 and 0.00005% 80.5 ppm by mass or less of sodium, and which has such a particle size distribution that at least 98% by mass of the silica particles is occupied by the particles having a particle diameter in the range from 30 to 1,000 nm.

摘要翻译： 本发明提供了一种氯乙烯类树脂的抗静电剂，其可以赋予氯乙烯类树脂优异的抗静电性能，从而可以解决由静电装入氯乙烯类树脂引起的各种问题，乙烯基 含有该抗静电剂的氯化物系树脂组合物及其制造方法。 本发明提供了一种氯乙烯类树脂的抗静电剂，其由含有至少99.0质量％的SiO 2和0.00005％的80.5质量ppm以下的二氧化硅粒子组成，并且其粒径分布至少为 二氧化硅粒子的98质量％被粒径在30〜1000nm的粒子所占据。

公开(公告)号：US20070282027A1

公开(公告)日：2007-12-06

申请号：US11758418

申请日：2007-06-05

申请人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

发明人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

IPC分类号： C08L75/00

CPC分类号： C08J9/0038 ,  C04B26/08 ,  C04B2111/00129 ,  C08J9/0066 ,  C08J2327/06 ,  C08K3/013 ,  C08K3/04 ,  C08K5/49 ,  C08L27/06 ,  C08L27/18 ,  C08L2205/02 ,  C04B14/024 ,  C04B14/042 ,  C04B14/06 ,  C04B14/10 ,  C04B14/28 ,  C04B14/303 ,  C04B14/304 ,  C04B14/305 ,  C04B24/003 ,  C04B24/2682 ,  C04B38/02 ,  C08L2666/04

摘要： A thermally expandable vinyl chloride resin composition is provided. It includes (A) 100 parts by mass of a vinyl chloride resin, (B) 5 to 200 parts by mass of an inorganic filler, (C) 10 to 300 parts by mass of a thermally expandable graphite, (D) 0.1 to 10 parts by mass of a fluororesin, and (E) 10 to 300 parts by mass of a phosphorus compound. The composition exhibits favorable thermal expansion properties and favorable shape retention following thermal expansion upon exposure to high temperatures.

摘要翻译： 提供了一种热膨胀性氯乙烯树脂组合物。 它包括（A）100质量份氯乙烯树脂，（B）5至200质量份无机填料，（C）10至300质量份可热膨胀石墨，（D）0.1至10 质量份的氟树脂，（E）10〜300质量份的磷化合物。 该组合物在暴露于高温下时显示出良好的热膨胀性能和良好的热膨胀后的形状保持性。

公开(公告)号：US20110294941A1

公开(公告)日：2011-12-01

申请号：US13115369

申请日：2011-05-25

申请人： Tatsuya FUJIMOTO ,  Tadashi Amano ,  Manabu Furudate ,  Tomohiro Inoue ,  Shinji Fujimoto ,  Ken Yahata

发明人： Tatsuya FUJIMOTO ,  Tadashi Amano ,  Manabu Furudate ,  Tomohiro Inoue ,  Shinji Fujimoto ,  Ken Yahata

IPC分类号： C08K3/22 ,  B82Y30/00

CPC分类号： B82Y30/00

摘要： Provided is a vinyl chloride-based resin composition including a vinyl chloride-based resin and a titanium dioxide having an average particle diameter of 5 to 50 nm, in an amount of 1,000 ppm to 10,000 ppm, by mass, relative to the mass of the vinyl chloride-based resin. By adding a titanium dioxide having an average particle diameter of 5 to 50 nm to a vinyl chloride-based resin in an amount described above, a vinyl chloride-based resin composition of excellent thermal stability can be obtained. In the vinyl chloride-based resin composition, the crystalline form of the titanium dioxide is preferably anatase, rutile, or a combination thereof. Also provided is a method of producing a vinyl chloride-based polymer composition that includes subjecting a vinyl chloride monomer, or a mixture of a vinyl chloride monomer and a monomer that is copolymerizable therewith, to suspension polymerization within an aqueous medium, and also includes adding a titanium dioxide having an average particle diameter of 5 to 50 nm to the raw material prior to commencement of the polymerization, to the reaction mixture during the polymerization, to the reaction product following completion of the polymerization, or to a combination of two or more of the raw material, the reaction mixture and the reaction product. The vinyl chloride-based polymer composition obtained using this method exhibits excellent thermal stability.

摘要翻译： 本发明提供一种氯乙烯类树脂组合物，其含有平均粒径为5〜50nm的氯乙烯类树脂和二氧化钛，相对于质量为1000〜10000ppm 氯乙烯类树脂。 通过向上述量的氯乙烯类树脂中添加平均粒径为5〜50nm的二氧化钛，可以得到热稳定性优异的氯乙烯系树脂组合物。 在氯乙烯系树脂组合物中，二氧化钛的结晶形态优选为锐钛矿型，金红石型，或其组合。 还提供了一种生产氯乙烯基聚合物组合物的方法，该组合物包括使氯乙烯单体或氯乙烯单体与其可共聚的单体的混合物在水性介质中进行悬浮聚合，并且还包括加入 在聚合开始前与原料平均粒径为5〜50nm的二氧化钛，聚合期间的反应混合物，聚合完成后的反应产物，或两种以上的组合 的原料，反应混合物和反应产物。 使用该方法获得的基于氯乙烯的聚合物组合物显示出优异的热稳定性。

公开(公告)号：US07847012B2

公开(公告)日：2010-12-07

申请号：US11758418

申请日：2007-06-05

申请人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

发明人： Tatsuya Fujimoto ,  Ken Yahata ,  Tadashi Amano

IPC分类号： C08L27/06

CPC分类号： C08J9/0038 ,  C04B26/08 ,  C04B2111/00129 ,  C08J9/0066 ,  C08J2327/06 ,  C08K3/013 ,  C08K3/04 ,  C08K5/49 ,  C08L27/06 ,  C08L27/18 ,  C08L2205/02 ,  C04B14/024 ,  C04B14/042 ,  C04B14/06 ,  C04B14/10 ,  C04B14/28 ,  C04B14/303 ,  C04B14/304 ,  C04B14/305 ,  C04B24/003 ,  C04B24/2682 ,  C04B38/02 ,  C08L2666/04

摘要： A thermally expandable vinyl chloride resin composition is provided. It includes (A) 100 parts by mass of a vinyl chloride resin, (B) 5 to 200 parts by mass of an inorganic filler, (C) 10 to 300 parts by mass of a thermally expandable graphite, (D) 0.1 to 10 parts by mass of a fluororesin, and (E) 10 to 300 parts by mass of a phosphorus compound. The composition exhibits favorable thermal expansion properties and favorable shape retention following thermal expansion upon exposure to high temperatures.

摘要翻译： 提供了一种热膨胀性氯乙烯树脂组合物。 它包括（A）100质量份氯乙烯树脂，（B）5至200质量份无机填料，（C）10至300质量份可热膨胀石墨，（D）0.1至10 质量份的氟树脂，（E）10〜300质量份的磷化合物。 该组合物在暴露于高温下时显示出良好的热膨胀性能和良好的热膨胀后的形状保持性。

公开(公告)号：US20050181223A1

公开(公告)日：2005-08-18

申请号：US11046751

申请日：2005-02-01

申请人： Michio Aizawa ,  Masahiro Usuki ,  Tatsuya Fujimoto ,  Shigehiro Hoshida ,  Tadashi Amano

发明人： Michio Aizawa ,  Masahiro Usuki ,  Tatsuya Fujimoto ,  Shigehiro Hoshida ,  Tadashi Amano

IPC分类号： B32B15/088 ,  B32B15/08 ,  C08G69/26 ,  C09J179/08 ,  H05K1/03 ,  H05K3/38

CPC分类号： B32B7/12 ,  B32B15/08 ,  B32B15/20 ,  B32B27/06 ,  B32B27/281 ,  B32B27/34 ,  B32B2307/306 ,  B32B2307/74 ,  H05K1/0346 ,  H05K3/386 ,  H05K2201/0145 ,  H05K2201/0154 ,  H05K2201/0355 ,  Y10T428/31681

摘要： A flexible metal foil-polyimide laminate is prepared by joining a polyimide film to a metal foil via an intervening adhesive layer. The adhesive is a mixture of polyamic acids: (A) the reaction product of 3,4,3′,4′-biphenyltetracarboxylic anhydride with p-phenylenediamine, (B) the reaction product of 3,4,3′,4′-biphenyltetracarboxylic anhydride with 4,4′-diaminodiphenyl ether, and (C) the reaction product of pyromellitic dianhydride with 4,4′-diaminodiphenyl ether, in a weight ratio (A+B)/C between 75/25 and 25/75. The method is simple and inexpensive, and yields a flexible metal foil-polyimide laminate that is improved in peel strength and curling resistance while maintaining the heat resistance of polyimide.

摘要翻译： 通过中间粘合剂层将聚酰亚胺膜与金属箔接合来制备柔性金属箔 - 聚酰亚胺层压体。 粘合剂是聚酰胺酸的混合物：（A）3,4,3'，4'-联苯四羧酸酐与对苯二胺的反应产物，（B）3,4,3'，4'- 联苯四羧酸酐与4,4'-二氨基二苯醚，（C）均苯四酸二酐与4,4'-二氨基二苯醚的反应产物，重量比（A + B）/ C在75/25和25/75之间。 该方法简单且便宜，并且产生柔软的金属箔 - 聚酰亚胺层压板，其在保持聚酰亚胺的耐热性的同时提高了剥离强度和抗卷曲性。

公开(公告)号：US09463436B2

公开(公告)日：2016-10-11

申请号：US14115209

申请日：2012-05-10

申请人： Manabu Furudate ,  Tomohiro Inoue ,  Shiro Takahashi ,  Yoshitsugu Eguchi ,  Tadashi Amano

发明人： Manabu Furudate ,  Tomohiro Inoue ,  Shiro Takahashi ,  Yoshitsugu Eguchi ,  Tadashi Amano

IPC分类号： B01J21/08 ,  B01J37/03 ,  B01J37/08 ,  B01J23/14 ,  B01J35/00 ,  C09D1/00 ,  C09D5/16 ,  B01J21/06 ,  C01G23/047 ,  C01G23/04 ,  C01G23/053 ,  B01J35/02 ,  C08K3/22

CPC分类号： B01J21/08 ,  B01J21/06 ,  B01J21/063 ,  B01J23/14 ,  B01J35/004 ,  B01J35/023 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  C01G23/04 ,  C01G23/047 ,  C01G23/053 ,  C08K2003/2241 ,  C09D1/00 ,  C09D5/1618

摘要： A method for manufacturing a microparticulate anatase or rutile titanium oxide dispersion from a peroxotitanic acid solution optionally containing tin, wherein the method for manufacturing an anatase or rutile titanium oxide dispersion is characterized in that the peroxotitanic acid solution is fed continuously to a flow reactor and subjected to hydrothermal treatment at 150 to 250° C. and 0.5 to 10 MPa. The invention makes it possible to provide a method for manufacturing a microparticulate anatase or rutile titanium oxide dispersion having excellent stability in regard to the titanium oxide microparticles and enabling a high-transparency photocatalytic thin film to be produced, and to provide a member having a photocatalytic thin film formed on the surface using this dispersion.

摘要翻译： 一种由任选含有锡的过氧钛酸溶液制备微粒锐钛矿或金红石型二氧化钛分散体的方法，其中所述锐钛型或金红石型氧化钛分散体的制造方法的特征在于，将过氧钛酸溶液连续供给流动反应器， 在150〜250℃，0.5〜10MPa下进行水热处理。 本发明使得可以提供一种在氧化钛微粒上具有优异的稳定性的微粒锐钛矿或金红石型氧化钛分散体的制造方法，能够制造高透光性的光催化薄膜，提供具有光催化剂 使用该分散体在表面上形成薄膜。

公开(公告)号：US20140127514A1

公开(公告)日：2014-05-08

申请号：US14116665

申请日：2012-05-31

申请人： Tomohiro Inoue ,  Manabu Furudate ,  Yoshitsugu Eguchi ,  Tadashi Amano

发明人： Tomohiro Inoue ,  Manabu Furudate ,  Yoshitsugu Eguchi ,  Tadashi Amano

IPC分类号： C09D1/00

CPC分类号： C09D1/00 ,  B01J21/063 ,  B01J21/08 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0219 ,  B01J37/033 ,  C09D5/1662 ,  C09D7/61 ,  C09D7/67 ,  C09D183/02 ,  H01L31/048 ,  H02S40/10 ,  Y02E10/50 ,  Y10T428/31507 ,  Y10T428/31667

摘要： An inorganic hydrophilic coating solution including (a) an aqueous solution containing an amorphous silicate compound obtained by hydrolyzing and condensing a tetrafunctional silicon compound having a purity of 99.0 mass % or greater in an aqueous medium in the presence of a basic compound at a temperature within a range from normal temperature to 170° C., (b) water, and optionally, (c) not more than 30 mass % of an alcohol, a ketone, or a surfactant, where the concentration of the solid fraction derived from the aqueous solution containing the amorphous silicate compound is 0.01 to 2.0 mass % and the pH is 5 to 8; an inorganic hydrophilic coating film formed from a dried and cured product of the inorganic hydrophilic coating solution; a member having a substrate and the inorganic hydrophilic coating film formed on the surface of the substrate; and a cover panel for a solar cell module including the member.

摘要翻译： 一种无机亲水性涂料溶液，其包括（a）含有无定形硅酸盐化合物的水溶液，所述无定形硅酸盐化合物通过在碱性化合物的存在下，在碱性化合物的存在下，在碱性化合物的存在下水解和缩合纯度为99.0质量％以上的四官能硅化合物， （b）水，和（c）不大于30质量％的醇，酮或表面活性剂，其中固体成分的浓度来源于水溶液 含有无定形硅酸盐化合物的溶液为0.01〜2.0质量％，pH为5〜8; 由无机亲水性涂布液的干燥固化物形成的无机亲水性涂膜; 具有基材和在所述基材的表面上形成的无机亲水性涂膜的部件; 以及包括该构件的太阳能电池模块用盖板。

公开(公告)号：US20080241452A1

公开(公告)日：2008-10-02

申请号：US11865330

申请日：2007-10-01

申请人： Kazunori KONDO ,  Shigehiro Hoshida ,  Tadashi Amano

发明人： Kazunori KONDO ,  Shigehiro Hoshida ,  Tadashi Amano

IPC分类号： C08K5/53 ,  B32B33/00 ,  C09J7/02 ,  B32B7/12

CPC分类号： H05K3/386 ,  B32B7/12 ,  C08K5/0066 ,  C08K5/5317 ,  C09J7/35 ,  C09J2205/102 ,  C09J2433/00 ,  C09J2463/00 ,  C09J2471/00 ,  H05K1/0353 ,  H05K2201/012 ,  H05K2201/0133 ,  H05K2201/0769 ,  Y10T428/14 ,  Y10T428/266 ,  Y10T428/2804

摘要： The present invention provides a halogen-free, flame retardant adhesive composition that exhibits excellent anti-migration properties, not only within single layer structures, but also within multilayer structures of much higher density such as copper-clad laminates.The flame retardant adhesive composition according to the present invention comprises: (A) a halogen-free epoxy resin, (B) a carboxyl group-containing acrylic resin and/or a carboxyl group-containing acrylonitrile-butadiene rubber, (C) a curing agent, (E) specific phosphinate and/or diphosphonate compounds, and (F) an ion scavenger and/or a heavy metal deactivator.

摘要翻译： 本发明提供了一种无卤阻燃粘合剂组合物，其不仅在单层结构内，而且在诸如覆铜层压板之类的高密度多层结构内表现出优异的抗迁移性能。 根据本发明的阻燃粘合剂组合物包括：（A）无卤环氧树脂，（B）含羧基的丙烯酸树脂和/或含羧基的丙烯腈 - 丁二烯橡胶，（C）固化 （E）特定的次膦酸盐和/或二膦酸盐化合物，和（F）离子清除剂和/或重金属钝化剂。

公开(公告)号：US20080176995A1

公开(公告)日：2008-07-24

申请号：US12017869

申请日：2008-01-22

申请人： Makoto OOURA ,  Tadashi Amano ,  Minoru Shigemitsu ,  Shingo Niinobe

发明人： Makoto OOURA ,  Tadashi Amano ,  Minoru Shigemitsu ,  Shingo Niinobe

IPC分类号： C09K3/00 ,  C08L27/06

CPC分类号： C08F14/06 ,  C08L1/284 ,  C08L27/06 ,  C08F2/20 ,  C08L2666/26

摘要： Provided is a dispersion stabilizer for suspension polymerization that contains a hydroxypropylmethylcellulose with a degree of methoxy group substitution of 27 to 30% by mass and a degree of hydroxypropoxy group substitution of 5 to 12% by mass, in which the viscosity at 20° C. of a 2% by mass aqueous solution of the hydroxypropylmethylcellulose is within a range from 5 to 1,600 mPa·s, and in 2 ml of a 0.2% by mass solution of the hydroxypropylmethylcellulose, the number of undissolved fibers with a particle size within a range from 8 to 200 μm, as measured by a Coulter counter method, is not more than 1,000, and the number of undissolved fibers with a particle size of 50 μm or greater measured using the same method is not more than 20. By employing a method of producing a vinyl chloride-based polymer that uses this dispersion stabilizer, a vinyl chloride-based polymer with extremely low levels of fish eyes and defects derived from foreign objects can be produced.

摘要翻译： 提供一种悬浮聚合用分散稳定剂，其含有甲氧基取代度为27〜30质量％，羟基丙氧基取代度为5〜12质量％的羟丙基甲基纤维素，其中20℃下的粘度 的羟丙基甲基纤维素的2质量％水溶液在5〜1600mPa.s的范围内，在2ml的0.2质量％羟丙基甲基纤维素溶液中，粒径在一定范围内的未溶解纤维的数量 通过Coulter反方法测量的8至200μm的不超过1,000个，使用相同方法测量的粒径为50μm或更大的未溶解纤维的数量不超过20.通过采用方法 制造使用该分散稳定剂的基于氯乙烯的聚合物，可以制造具有极低水平鱼眼的氯乙烯类聚合物和由异物衍生的缺陷。