摘要:
There is disclosed alkylthiomethyl oxazolines such as 2-(octadecylthiomethyl)-5-ethyl-5-methylol-2-oxazoline, suitable for use in drilling fluids as a lubricity agent and/or anti-oxidant.
摘要:
Aqueous drilling fluids containing a minor amount of an additive composition featuring oxazolines of C.sub.1 -C.sub.30 alkylthioglycolic acid. Such fluids are especially useful where reduced torque drilling fluids are needed. Another embodiment of this invention relates to a method of drilling utilizing the above-described fluids.
摘要:
Aqueous drilling fluids containing a minor amount of an additive composition featuring mono- and di-esters of C.sub.12 -C.sub.50 aliphatic hydrocarbon substituted succinic acids or anhydrides, such as octadecenyl succinic anhydride with thio-bis-alkanols such as dithiodiethanol. Such fluids are especially useful where reduced torque drilling fluids are needed. Another embodiment of this invention relates to a method of drilling utilizing the above-described fluids.
摘要:
An additive composition effective in the release of stuck pipe in a borehole during a drilling operation which composition contains a propoxylated lactone acid, e.g. a C.sub.8 -C.sub.22 alkyl lactone acids having from 10 to 13 propylene glycol units, an oil-soluble emulsifier-wetting agent and a liquid hydrocarbon diluent and for enhanced elevated temperature emulsion stability may include an imidazoline.
摘要:
There is a disclosed an improved lubricating oil dispersant suitable for both gasoline engine and diesel engine lubricating oil, the dispersant being prepared in a sequential process whereby a polyolefin succinic anhydride is reacted first with an alkylene polyamine and subsequently with maleic anhydride of a C.sub.1 -C.sub.18 alkenyl or alkyl succinic anhydride to provide a diimide dispersant having a final mole ratio of 2.3 to 3.0 moles of anhydride per mole of polyamine.
摘要:
Deposit formation on the interior surfaces of structures confining heated hydrocarbon fluids such as refinery units, particularly preheating stages associated with process units such as distillation units, hydrotreaters and thermal crackers, is inhibited by incorporating in the feed stock a small percentage (usually at least about 0.0005 weight percent) of a macrocyclic polyamine formed by cyclodehydration of reaction products of hydrocarbon substituted succinic anhydrides or carboxylic acids with poly 3-amino propyl compounds or by acylation of macrocyclic polyamine and polycyclic polyamines with hydrocarbon substituted succinic anhydride or carboxylic acids. It is desirable in some instances to dissolve additionally in the hydrocarbon fluid such as a feed stock along with the macrocyclic polyamine an oil-soluble dispersant, antioxidant and mixtures thereof.
摘要:
Oil soluble viscosity index improving ethylene copolymers, such as copolymers of ethylene and propylene; and ethylene, propylene and diolefin; etc., are reacted or grafted with ethylenically unsaturated carboxylic acid moieties, preferably maleic anhydride moieties, and reacted with polyamines having two or more primary amine groups and a branched carboxylic acid component, preferably alkylene polyamine and branched monocarboxylic acid having 2 to 6 aliphatic hydrocarbon branches of 8 to 24 carbons each. Or the grafted ethylene copolymer can be reacted with already formed salts, and amides, etc. of said polyamine and branched acid component. These reactions can permit the incorporation of varnish inhibition and dispersancy into the ethylene copolymer while inhibiting cross-linking with resulting viscosity increase, haze or gelling. The aforesaid grafting reaction may be carried out thermally, or more preferably with a free radical initiator such as a peroxide in a mineral lubricating oil, in which case the branched acid component, preferably also acts to solubilize insoluble compounds formed by side reactions, such as maleic anhydride grafted oil molecules reacted with amine, to thereby inhibit haze formation, particularly when preparing oil concentrates of the V.I.-dispersant additive for later addition to lubricating oils.
摘要:
Lubricating oil compositions which contain polycarboxylic acid-glycol esters as friction modifiers in combination with hydrocarbon soluble borated or non-borated alkenyl succinimide dispersant and especially those also containing metal additives are stabilized against tendency of such components to form sediment upon storage through addition of small proportions of a co-dispersant being an oil-soluble hydrocarbyl substituted mono or bis-oxazoline or lactone oxazoline.
摘要:
A lubricating oil composition having improved friction reducing properties and the method of reducing friction in internal combustion engines by lubricating said engines with said lubricating oil which contains an effective friction reducing amount of an additive which is the reaction product of dimer carboxylic acid and a polyhydric alcohol having at least 2 hydroxyl groups in combination with an oil soluble alkanol or an oil soluble alkyl phosphate.
摘要:
Oil soluble viscosity index improving ethylene copolymers, such as copolymers of ethylene and propylene; and ethylene, propylene and diolefin; etc., are reacted or grafted with ethylenically unsaturated carboxylic acid moieties, preferably maleic anhydride moieties, and reacted with polyamines having two or more primary amine groups and a C.sub.22 to C.sub.28 olefin carboxylic acid component, preferably alkylene polyamine and alkenyl succinic anhydride, respectively. These reactions can permit the incorporation of varnish inhibition and dispersancy into the ethylene copolymer while inhibiting cross-linking with resulting viscosity increase, haze or gelling. The aforesaid grafting reaction may be carried out thermally, or more preferably with a free radical initiator such as a peroxide in a mineral lubricating oil, in which case the olefin carboxylic acid component, preferably also acts to solubilize insoluble compounds formed by side reactions, such as maleic anhydride grafted oil molecules reacted with amine, to thereby inhibit haze formation, particularly when preparing oil concentrates of the V.I.-dispersant additive for later addition to lubricating oils.