Polymers with h-bridge forming functionalities for improving anti-wear protection
    1.
    发明申请
    Polymers with h-bridge forming functionalities for improving anti-wear protection 有权
    具有h桥形成功能的聚合物,用于改善抗磨损保护

    公开(公告)号:US20070197409A1

    公开(公告)日:2007-08-23

    申请号:US10592363

    申请日:2005-02-24

    Abstract: The invention relates to lubricating oil formulations comprising copolymers or graft copolymers produced by radically polymerising polymerisable monomers and, in addition comprising long-chain ethylenically unsaturated compounds containing alkyl, in particular acrylate or methacrylate substitutes provided with hydrogen-bridge donator functions. The monomer exhibiting a hydrogen-bridge donator property is contained, according to said invention, in the polymer backbone or in graft side branches. Apart from the polymers containing monomers provided with hydrogen-bridge donator functions, said invention relates to polymers containing monomers simultaneously carrying donator and acceptor functions. It was found that the hydrogen-bridge donator functions of a polymer, in particular a simultaneous availability of the hydrogen-bridge donator and acceptor functions produce the positive effects on the anti-wear protection and on a detergency and dispersancy action. The inventive polymers are suitable, in the form of additives, for lubricating oil formulations, for example for motor oils or hydraulic fluids exhibiting an improved anti-wear behavior.

    Abstract translation: 本发明涉及包含通过自由基聚合可聚合单体制备的共聚物或接枝共聚物的润滑油配方,并且还包括含有烷基的长链烯键式不饱和化合物,特别是具有氢桥供体功能的丙烯酸酯或甲基丙烯酸酯替代物。 根据本发明,显示出氢桥供体特性的单体在聚合物主链或接枝侧分支中。 除了含有提供氢桥供体功能的单体的聚合物外,所述发明涉及含有单体同时承载载体和受体功能的聚合物。 发现聚合物的氢桥供体功能,特别是氢桥供体和受体功能的同时可用性对抗磨损保护和去污力和分散作用产生积极影响。 本发明的聚合物以添加剂的形式适用于润滑油制剂,例如对于表现出改进的抗磨损行为的机油或液压油。

    Functionalized polymer composition for grease
    6.
    发明申请
    Functionalized polymer composition for grease 有权
    润滑脂的官能化聚合物组合物

    公开(公告)号:US20040254080A1

    公开(公告)日:2004-12-16

    申请号:US10458505

    申请日:2003-06-10

    Abstract: A grease composition containing a polymer with (a) monomers (i) at least one unsaturated null,null-carboxylic acid ester containing an alkyl group with about 10 to about 20 carbon atoms; and (ii) at least one unsaturated null,null-carboxylic acid ester containing an alkyl group with about 4 to about 11 carbon atoms different from monomer (i); and (iii) at least one unsaturated dicarboxylic acid anhydride or derivatives thereof; and (iv) optionally at least one unsaturated null,null-carboxylic acid ester containing an alkyl group with about 1 to about 3 carbon atoms; and optionally (b) at least one non-monomeric amine with primary functionality, secondary functionality or mixtures thereof; and optionally (c) other performance additives; and (d) at least one thickening agent, and (e) an oil of lubricating viscosity. The invention further relates to the process to make the composition and its use in greases.

    Abstract translation: 一种含有聚合物的润滑脂组合物,其包含(a)单体(i)至少一种含有约10至约20个碳原子的烷基的不饱和α,β-羧酸酯; 和(ii)至少一种含有与单体(i)不同的约4至约11个碳原子的烷基的不饱和α,β-羧酸酯; 和(iii)至少一种不饱和二羧酸酐或其衍生物; 和(iv)任选至少一种含有约1至约3个碳原子的烷基的不饱和α,β-羧酸酯; 和任选地(b)至少一种具有伯官能团,二级官能团或其混合物的非单体胺; 和(c)其它性能添加剂; 和(d)至少一种增稠剂,和(e)润滑粘度的油。 本发明还涉及使组合物及其在油脂中的应用的方法。

    Copolymer dispersants via vinyl terminated propene polymers
    8.
    发明授权
    Copolymer dispersants via vinyl terminated propene polymers 失效
    共聚物分散剂通过乙烯基封端的丙烯聚合物

    公开(公告)号:US5616153A

    公开(公告)日:1997-04-01

    申请号:US538310

    申请日:1995-10-03

    Abstract: A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C.sub.2 and C.sub.4 to C.sub.10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C.sub.4 to C.sub.10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer. The novel dispersants made from the copolymers and terpolymers of the invention can be polymeric succinic ester-amide dispersants, polymeric succinimide dispersants, polymeric succinic amide-triazole dispersants, or polymeric succinic triazole dispersants. Fuel and lubricant compositions containing such additives are a part of the invention.

    Abstract translation: 教导了不饱和酸性反应物和无规乙烯基封端的丙烯聚合物(VTPP)的新型共聚物及其在制备燃料和润滑剂添加剂中的用途。 VTPP具有大量含有末端乙烯基不饱和键,数均分子量至少为500的聚合物链,并且包含至少70重量%的丙烯和0至30重量%的至少一种选自以下的烯烃: 的C2和C4至C10烯烃。 不饱和酸性反应物包含至少一种不饱和C 4至C 10羧酸或二羧酸或酸酐。 通过使无规VTPP共聚物与选自胺,醇,金属反应物及其混合物的至少一种亲核试剂在有效形成亲核的加合物的条件下接触来制备本发明的油性组合物中的油溶性分散剂添加剂 试剂与共聚物。 由本发明的共聚物和三元共聚物制成的新型分散剂可以是聚合琥珀酸酯 - 酰胺分散剂,聚合琥珀酰亚胺分散剂,聚合琥珀酰胺 - 三唑分散剂或聚合琥珀酸三唑分散剂。 包含这些添加剂的燃料和润滑剂组合物是本发明的一部分。

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