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    Process for isomerization dewaxing of hydrocarbon streams
    3.
    发明授权
    Process for isomerization dewaxing of hydrocarbon streams 有权
    烃流异构化脱蜡方法

    公开(公告)号：US06652735B2

    公开(公告)日：2003-11-25

    申请号：US09843125

    申请日：2001-04-26

    申请人： Thomas F. Degnan ,  Philip J. Angevine

    发明人： Thomas F. Degnan ,  Philip J. Angevine

    IPC分类号： C10G7338

    CPC分类号： C10G45/62 ,  B01J29/74 ,  B01J29/7415 ,  B01J29/80 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/64 ,  C10G65/043

    摘要： A process for isomerization dewaxing of a hydrocarbon feed which includes contacting the hydrocarbon feed with a large pore size, small crystal size, crystalline molecular sieve and an intermediate pore size, small crystal size, crystalline molecular sieve to produce a dewaxed product with a reduced pour point and a reduced cloud point. In a preferred embodiment, the feed is contacted with the molecular sieves sequentially, first with the large pore sieve followed by the intermediate pore sieve.

    摘要翻译： 烃原料异构化脱蜡的方法，其包括使烃进料与大孔径，小结晶尺寸，结晶分子筛和中等孔径，小晶体尺寸，结晶分子筛接触以产生具有降低的倾倒的脱蜡产物 点和减少的浊点。 在一个优选的实施方案中，进料与分子筛依次接触，首先用大孔筛，然后是中间孔筛。

    Aromatic alkylation process
    4.
    发明授权
    Aromatic alkylation process 有权
    芳香烷基化工艺

    公开(公告)号：US06313362B1

    公开(公告)日：2001-11-06

    申请号：US09213798

    申请日：1998-12-17

    申请人： John R. Green ,  Thomas F. Degnan ,  Yun-Yang Huang ,  Chaya R. Venkat ,  Ronald A. Weiss

    发明人： John R. Green ,  Thomas F. Degnan ,  Yun-Yang Huang ,  Chaya R. Venkat ,  Ronald A. Weiss

    IPC分类号： C07C264

    CPC分类号： C07C15/085 ,  C07C15/073

    摘要： Akylation product is contacted with a purification medium in a liquid phase pre-reaction step to remove impurities and form a purified stream. The purified stream may then be further processed by liquid phase transalkylation to convert the polyalkylated aromatic compound to a monoalkylated aromatic compound. The process may use a large pore molecular sieve catalyst such as MCM-22 as the purification medium in the pre-reaction step because of its high reactivity for alkylation, strong retention of catalyst poisons and low reactivity for oligomerization under the pre-reactor conditions. Olefins, diolefins, styrene, oxygenated organic compounds, sulfur containing compounds, nitrogen containing compounds and oligomeric compounds are removed.

    摘要翻译： 将Akylation产物在液相预反应步骤中与净化介质接触以除去杂质并形成纯化的物流。 然后可以通过液相烷基转移进一步处理纯化的物流，以将多烷基化芳族化合物转化为单烷基化芳族化合物。 在预反应步骤中，该方法可以使用大孔分子筛催化剂例如MCM-22作为纯化介质，因为其在烷基化反应活性高，催化剂毒物强烈的保留和在反应器前条件下的低聚反应低。 除去烯烃，二烯烃，苯乙烯，含氧有机化合物，含硫化合物，含氮化合物和低聚物。

    Hydrocarbon coversion using improved zeolite Beta catalyst
    5.
    发明授权
    Hydrocarbon coversion using improved zeolite Beta catalyst 失效
    使用改进的沸石β催化剂进行烃转化

    公开(公告)号：US5658454A

    公开(公告)日：1997-08-19

    申请号：US461484

    申请日：1995-06-05

    申请人： Robert P. L. Absil ,  Thomas F. Degnan ,  George H. Hatzikos ,  Jocelyn A. Kowalski ,  Thomas Mebrahtu ,  Grant H. Yokomizo

    发明人： Robert P. L. Absil ,  Thomas F. Degnan ,  George H. Hatzikos ,  Jocelyn A. Kowalski ,  Thomas Mebrahtu ,  Grant H. Yokomizo

    IPC分类号： B01J29/40 ,  B01J29/70 ,  B01J37/00 ,  C10G11/05 ,  C07C4/06 ,  C10G47/04

    CPC分类号： C10G11/05 ,  B01J29/7007 ,  B01J37/0009 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/40 ,  B01J29/7034 ,  B01J29/7042

    摘要： A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphor and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate be used in the as-synthesized form or in the calcined form. included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalyst containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.

    摘要翻译： 一种催化剂组合物，其包含具有沸石β，磷光体和基本上不含结晶磷酸铝的结构的结晶金属硅酸盐，其具有改善的对蒸汽失活的抗性，其具有比不用磷制备的类似催化剂更高的裂化活性。 结晶金属硅酸盐以合成形式或煅烧形式使用。 包括制备催化剂组合物的方法和通过本发明方法在有机转化方法中制备的催化剂的使用方法。 本发明的具体实施方案涉及用于制备含有β沸石结构的磷的磷和结晶金属硅酸盐的各种技术。 根据本发明方法制备的催化剂可用于有机化合物，例如烃化合物，转化方法。 有机化合物转化方法包括裂化，加氢裂化和烷基转移等。

    Catalyst and process for producing low-aromatics distillates
    7.
    发明授权
    Catalyst and process for producing low-aromatics distillates 失效
    用于生产低芳烃馏出物的催化剂和方法

    公开(公告)号：US5451312A

    公开(公告)日：1995-09-19

    申请号：US143407

    申请日：1993-10-26

    申请人： Minas R. Apelian ,  Thomas F. Degnan ,  Stuart S. Shih

    发明人： Minas R. Apelian ,  Thomas F. Degnan ,  Stuart S. Shih

    IPC分类号： B01J23/58 ,  B01J29/04 ,  B01J37/00 ,  C10G45/54 ,  C10G65/08 ,  C10G45/12 ,  C10G45/52

    CPC分类号： C10G45/54 ,  B01J29/041 ,  B01J37/0009

    摘要： This invention provides a process for producing a distillate boiling-range hydrocarbon product which comprises hydrotreating a hydrodesulfurized aromatic, substantially dealkylated hydrocarbon feed produced by the catalytic cracking of a hydrocarbon fraction, the feed having an initial boiling point of at least 300.degree. F., an aromatic content of at least about 30 weight percent, a hydrogen content not more than about 12 weight percent and a sulfur content of not more than 5000 ppmw, in the presence of a catalyst comprising an inorganic, non-layered, porous, crystalline phase material having pores with diameters of at least about 13 .ANG. and exhibiting, after calcination, an X-ray diffraction pattern with at least one peak with a relative intensity of 100 at a d-spacing greater than about 18 .ANG., said material containing at least one Group VIII metal and less than 5000 ppm Na, said process being carried out at a hydrogen partial pressure of not more than 1000 psig to evolve product containing less than about 10 weight percent aromatics and less than 300 ppmw sulfur at a 390.degree. F.+ feed conversion of less than about 30 weight percent.

    摘要翻译： 本发明提供了一种生产馏出物沸点烃产物的方法，该方法包括加氢处理通过烃馏分的催化裂化产生的加氢脱硫的芳族，基本上脱烷基化的烃进料，该原料的起始沸点至少为300°F， 在包含无机，非层状，多孔的结晶相的催化剂存在下，至少约30重量％的芳族含量，不超过约12重量％的氢含量和不大于5000ppmw的硫含量 具有直径至少约为13的孔的材料，并且在煅烧后表现出具有至少一个在d-间距大于约18的相对强度为100的峰的X射线衍射图，所述材料至少包含 一个Ⅷ族金属和小于5000ppm的Na，所述方法在不超过1000psig的氢分压下进行，以产生pr 含量小于约10重量％的芳族化合物和小于300ppmw的硫在390°F +进料转化率小于约30重量％。

    Process for preparing dialkylnaphthalene
    10.
    发明授权
    Process for preparing dialkylnaphthalene 失效
    制备二烷基萘的方法

    公开(公告)号：US5001295A

    公开(公告)日：1991-03-19

    申请号：US494203

    申请日：1990-03-15

    申请人： Philip J. Angevine ,  Thomas F. Degnan ,  David O. Marler

    发明人： Philip J. Angevine ,  Thomas F. Degnan ,  David O. Marler

    IPC分类号： B01J29/04 ,  C07C2/12

    CPC分类号： C07C2/12 ,  B01J29/04 ,  C07C2529/70

    摘要： A catalytic process is provided for the preparation of dialkylnaphthalenes by alkylating a 2-alkylnaphthalene with an alkylating agent having an aliphatic group of from one to five carbon atoms, such as methanol. The catalyst comprises a synthetic zeolite characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.

    摘要翻译： 提供了通过用具有1至5个碳原子的脂族基团如甲醇的烷基化烷基化2-烷基萘来制备二烷基萘的催化方法。 该催化剂包括合成沸石，其特征在于X射线衍射图包括在12.36 +/- 0.4,11.03 +/- 0.2,8.83±0.14,6.18±0.12,6.00±0.10， 4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。