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公开(公告)号：US20060276334A1
公开(公告)日：2006-12-07
申请号：US10566453
申请日：2004-07-30
IPC分类号： B01J21/04
CPC分类号： C07C45/35 , B01J19/249 , B01J19/32 , B01J23/30 , B01J32/00 , B01J37/0203 , B01J37/0225 , B01J2219/2453 , B01J2219/2459 , B01J2219/2462 , B01J2219/2479 , B01J2219/2485 , B01J2219/3221 , B01J2219/32213 , B01J2219/32227 , B01J2219/32408 , B01J2219/32466 , B01J2219/32475 , C07C51/252 , F28F3/14 , C07C47/22 , C07C57/04
摘要： A catalyst support including a body having a surface and a coating bonded to the surface is disclosed. The coating includes fissures exhibiting a total fissure length of at least about 500 m/m2 and an adhesive tensile strength of at least about 500 N/m2. Using a catalyst support body to serve in the catalytic reaction of reactants, for example, in a partial oxidation of propene and acrolein to acrolein and acrylic acid, is disclosed. Also disclosed are processes for the: (a) production of a coating for a catalyst support body, (b) preparation of an organic molecule containing at least one double bond and oxygen, (c) production of a water-absorbing polymer, and (d) production of a water-absorbing hygiene article, and chemical products or the use of (meth)acrylic acid in chemical products.
摘要翻译： 公开了一种催化剂载体，其包括具有表面的主体和与表面结合的涂层。 涂层包括表现出至少约500m / m 2的总裂缝长度和至少约500N / m 2的粘合抗拉强度的裂缝。 使用催化剂载体用于反应物的催化反应，例如，将丙烯和丙烯醛部分氧化成丙烯醛和丙烯酸。 还公开了以下方法：（a）生产催化剂载体的涂层，（b）制备含有至少一个双键和氧的有机分子，（c）制备吸水聚合物和（ d）生产吸水卫生用品，化学制品或化学产品中使用（甲基）丙烯酸。
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2.发明申请DEVICE AND METHOD FOR TESTING CATALYSTS WITH VARIABLE PROCESS PRESSURE ADJUSTMENT 有权用于测试具有可变过程压力调节的催化剂的装置和方法公开(公告)号：US20130273662A1
公开(公告)日：2013-10-17
申请号：US13880821
申请日：2011-10-17
IPC分类号： G01N31/10
CPC分类号： G01N31/10 , B01J19/0046 , B01J19/0093 , B01J2219/00286 , B01J2219/00389 , B01J2219/00391 , B01J2219/00423 , B01J2219/00477 , B01J2219/00495 , B01J2219/00585 , B01J2219/00596 , B01J2219/00601 , B01J2219/00689 , B01J2219/00707 , B01J2219/00747 , B01J2219/00792 , B01J2219/00835 , B01J2219/00869 , B01J2219/00873 , B01J2219/00963 , B01J2219/00986
摘要： The present invention relates to a catalysis apparatus for testing catalysts with variable process pressure adjustment over a pressure range from 0.01 millibar to 300 bar. The apparatus preferably has a plurality of reaction chambers (101, 102, . . . ) arranged in parallel, the reaction chamber outlet-side lines (211, 212, . . . ) of which are divided into two groups of sub-lines. One group of main lines (411, 412, . . . ) is operatively connected to a regulating valve (61), which is common to all of the main lines, and to an exhaust-air line (62), and the second group of secondary lines (311, 312, 313, . . . ) and switching valves (321, 322, . . . ) is operatively connected to an analysis unit (34). It is preferable for reaction chamber outlet-side lines (201, 202, . . . ) to be equipped in each case with a separate line for regulating fluid supply (211, 212, . . . ). In a preferred embodiment, the connecting points of the reaction chamber outlet-side lines (201, 202, . . . ) to the respective main lines (411, 412, . . . ) and secondary lines (311, 312, . . . ) have in each case one mixing vessel (301, 302, . . . ).
摘要翻译： 本发明涉及一种用于在0.01毫巴至300巴的压力范围内测试具有可变过程压力调节的催化剂的催化装置。 该装置优选地具有并排布置的多个反应室（101,102 ...），反应室出口侧管线（211,212 ...）被分成两组子管线。 一组主线路（411,412 ...）可操作地连接到所有主线路和排气管线（62）共同的调节阀（61），并且第二组 的二次管线（311,312,313 ......）和切换阀（321,322 ...）可操作地连接到分析单元（34）。 反应室出口侧管线（201,202 ...）最好在各种情况下配备一条用于调节流体供应（211,212 ...）的单独管线。 在一个优选实施例中，反应室出口侧线（201,202 ...）到相应主线（411,412 ...）和次级线（311,312 ...）的连接点。 ）在每种情况下都具有一个混合容器（301,302 ......）。
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公开(公告)号：US07678361B2
公开(公告)日：2010-03-16
申请号：US10553312
申请日：2004-03-31
申请人： Georg Markowz , Johannes Albrecht , Johannes Ehrlich , Michael Jucys , Elias Klemm , Armin Lange De Oliveira , Reinhard Machnik , Juergen Rapp , Ruediger Schuette , Steffen Schirrmeister , Olaf Von Morstein , Hartmut Hederer , Martin Schmitz-Niederau
发明人： Georg Markowz , Johannes Albrecht , Johannes Ehrlich , Michael Jucys , Elias Klemm , Armin Lange De Oliveira , Reinhard Machnik , Juergen Rapp , Ruediger Schuette , Steffen Schirrmeister , Olaf Von Morstein , Hartmut Hederer , Martin Schmitz-Niederau
IPC分类号： B01J19/24 , C01B15/029 , C07C27/00 , C07C27/12 , C07C39/04 , C07C27/06 , C07D301/12
CPC分类号： B01F5/0471 , B01F13/0059 , B01F2005/0034 , B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/0086 , B01J2219/00889
摘要： The present invention discloses a microreactor for performing heterogeneous catalytic reactions, being of plate or stack construction for industrial use, with provision made for chambers between the plates for the chemical reaction and for the heat removal. Inside the reaction chambers, catalyst material is applied to the internal walls or filled into recesses, and in all chambers there are spacers. In particular the slot-shaped reaction chambers have channels with a hydraulic diameter smaller than 1500 μm and a ratio of free slot width to free slot height in the range of 10 to 450.
摘要翻译： 本发明公开了一种用于进行非均相催化反应的微反应器，它是用于工业应用的板或堆叠结构，为用于化学反应和排热的板之间的室提供。 在反应室内部，将催化剂材料施加到内壁或填充到凹部中，并且在所有室中都存在间隔物。 特别地，槽形反应室具有水力直径小于1500μm的通道，并且自由槽宽度与自由槽高度的比率在10至450的范围内。
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4.发明授权Methane aromatization catalyst, method of making and method of using the catalyst 有权甲烷芳构化催化剂，制备方法和使用催化剂的方法公开(公告)号：US09079169B2
公开(公告)日：2015-07-14
申请号：US13105499
申请日：2011-05-11
CPC分类号： C07C2/76 , B01J23/28 , B01J29/076 , B01J29/48 , B01J31/26 , B01J35/023 , B01J37/0201 , B01J37/0203 , B01J37/08 , B01J37/086 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/20 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/46 , C07C2523/50 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2529/40 , C07C2529/65 , C07C2531/26 , Y02P20/52 , C07C15/04
摘要： A catalyst for converting methane to aromatic hydrocarbons is described herein. The catalyst comprises an active metal or a compound thereof, and an inorganic oxide support wherein the active metal is added to the support in the form of metal oxalate. The metal oxalate-derived catalyst exhibits superior performance in the conversion of methane-rich feed to aromatics products relative to catalysts prepared from non-oxalate metal precursors. A method of making the catalyst and a method of using the catalyst are also described.
摘要翻译： 本文描述了将甲烷转化为芳族烃的催化剂。 催化剂包含活性金属或其化合物，以及无机氧化物载体，其中活性金属以草酸金属的形式加入到载体中。 相对于由非草酸盐金属前体制备的催化剂，草酸金属催化剂在富含甲烷的进料与芳烃产物的转化中表现出优异的性能。 还描述了制备催化剂的方法和使用该催化剂的方法。
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5.发明申请SINC-CONTAINING METHANE AROMATIZATION CATALYST, METHOD OF MAKING A METHOD OF USING THE CATALYST 有权含SINC的甲烷芳构化催化剂，使用催化剂的方法的制备方法公开(公告)号：US20140073828A1
公开(公告)日：2014-03-13
申请号：US13981342
申请日：2012-01-24
CPC分类号： B01J29/48 , B01J29/405 , B01J37/0203 , B01J37/0213 , B01J37/32 , B01J2229/18 , C07C2/76 , C07C2529/40 , C07C2529/48 , Y02P20/52 , Y02P20/588 , C07C15/04
摘要： A catalyst for converting methane to aromatic hydrocarbons is described herein. The catalyst comprises an active metal or a compound thereof, zinc or a compound thereof and an inorganic oxide support wherein the active metal is added to the support as a metal oxalate. A method of making the catalyst and a method of using the catalyst are also described.
摘要翻译： 本文描述了将甲烷转化为芳族烃的催化剂。 催化剂包括活性金属或其化合物，锌或其化合物和无机氧化物载体，其中活性金属作为草酸金属加入到载体中。 还描述了制备催化剂的方法和使用该催化剂的方法。
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6.发明授权Zinc containing methane aromatization catalyst, method of making a method of using the catalyst 有权含有甲烷芳构化催化剂的锌，制备使用该催化剂的方法公开(公告)号：US09339802B2
公开(公告)日：2016-05-17
申请号：US13981342
申请日：2012-01-24
IPC分类号： B01J23/06 , B01J23/28 , B01J29/40 , B01J37/00 , B01J37/12 , B01J29/48 , B01J37/02 , B01J37/32 , C07C2/76
CPC分类号： B01J29/48 , B01J29/405 , B01J37/0203 , B01J37/0213 , B01J37/32 , B01J2229/18 , C07C2/76 , C07C2529/40 , C07C2529/48 , Y02P20/52 , Y02P20/588 , C07C15/04
摘要： A catalyst for converting methane to aromatic hydrocarbons is described herein. The catalyst comprises an active metal or a compound thereof, zinc or a compound thereof and an inorganic oxide support wherein the active metal is added to the support as a metal oxalate. A method of making the catalyst and a method of using the catalyst are also described.
摘要翻译： 本文描述了将甲烷转化为芳族烃的催化剂。 催化剂包括活性金属或其化合物，锌或其化合物和无机氧化物载体，其中活性金属作为草酸金属加入到载体中。 还描述了制备催化剂的方法和使用该催化剂的方法。
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7.发明授权Device and method for testing catalysts with variable process pressure adjustment 有权用于测试具有可变过程压力调节的催化剂的装置和方法公开(公告)号：US09228985B2
公开(公告)日：2016-01-05
申请号：US13880821
申请日：2011-10-17
CPC分类号： G01N31/10 , B01J19/0046 , B01J19/0093 , B01J2219/00286 , B01J2219/00389 , B01J2219/00391 , B01J2219/00423 , B01J2219/00477 , B01J2219/00495 , B01J2219/00585 , B01J2219/00596 , B01J2219/00601 , B01J2219/00689 , B01J2219/00707 , B01J2219/00747 , B01J2219/00792 , B01J2219/00835 , B01J2219/00869 , B01J2219/00873 , B01J2219/00963 , B01J2219/00986
摘要： The present invention relates to a catalysis apparatus for testing catalysts with variable process pressure adjustment over a pressure range from 0.01 millibar to 300 bar. The apparatus preferably has a plurality of reaction chambers (101, 102, . . . ) arranged in parallel, the reaction chamber outlet-side lines (211, 212, . . . ) of which are divided into two groups of sub-lines. One group of main lines (411, 412, . . . ) is operatively connected to a regulating valve (61), which is common to all of the main lines, and to an exhaust-air line (62), and the second group of secondary lines (311, 312, 313, . . . ) and switching valves (321, 322, . . . ) is operatively connected to an analysis unit (34). It is preferable for reaction chamber outlet-side lines (201, 202, . . . ) to be equipped in each case with a separate line for regulating fluid supply (211, 212, . . . ). In a preferred embodiment, the connecting points of the reaction chamber outlet-side lines (201, 202, . . . ) to the respective main lines (411, 412, . . . ) and secondary lines (311, 312, . . . ) have in each case one mixing vessel (301, 302, . . . ).
摘要翻译： 本发明涉及一种用于在0.01毫巴至300巴的压力范围内测试具有可变过程压力调节的催化剂的催化装置。 该装置优选地具有并排布置的多个反应室（101,102 ...），反应室出口侧管线（211,212 ...）被分成两组子管线。 一组主线路（411,412 ...）可操作地连接到所有主线路和排气管线（62）共同的调节阀（61），并且第二组 的二次管线（311,312,313 ......）和切换阀（321,322 ...）可操作地连接到分析单元（34）。 反应室出口侧管线（201,202 ...）最好在各种情况下配备一条用于调节流体供应（211,212 ...）的单独管线。 在一个优选实施例中，反应室出口侧线（201,202 ...）到相应主线（411,412 ...）和次级线（311,312 ...）的连接点。 ）在每种情况下都具有一个混合容器（301,302 ......）。
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公开(公告)号：US08691181B2
公开(公告)日：2014-04-08
申请号：US12599748
申请日：2008-05-09
CPC分类号： C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0844 , C01B2203/86 , Y02P20/133 , Y02P20/134 , Y02P30/30
摘要： A process for preparing and converting synthesis gas, which has a plurality of different operating states which consist essentially of mutually alternating (i) daytime operation and (ii) nighttime operation, daytime operation (i) comprising principally dry reforming and steam reforming with supply of renewable energy, and nighttime operation (ii) comprising principally the partial oxidation of hydrocarbons, and the synthesis gas produced being used to produce products of value.
摘要翻译： 一种用于制备和转化合成气的方法，其具有多个不同的运行状态，其基本上由相互交替的（i）白天操作和（ii）夜间操作，白天操作（i）组成，主要包括干重整和蒸汽重整， 可再生能源和夜间操作（ii）主要包括烃的部分氧化，以及所生产的合成气用于产生有价值的产品。
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公开(公告)号：US20100305221A1
公开(公告)日：2010-12-02
申请号：US12599748
申请日：2008-05-09
IPC分类号： C07C27/00
CPC分类号： C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0844 , C01B2203/86 , Y02P20/133 , Y02P20/134 , Y02P30/30
摘要： A process for preparing and converting synthesis gas, which has a plurality of different operating states which consist essentially of mutually alternating (i) daytime operation and (ii) nighttime operation, daytime operation (i) comprising principally dry reforming and steam reforming with supply of renewable energy, and nighttime operation (ii) comprising principally the partial oxidation of hydrocarbons, and the synthesis gas produced being used to produce products of value.
摘要翻译： 一种用于制备和转化合成气的方法，其具有多个不同的运行状态，其基本上由相互交替的（i）白天操作和（ii）夜间操作，白天操作（i）组成，主要包括干重整和蒸汽重整， 可再生能源和夜间操作（ii）主要包括烃的部分氧化，以及所生产的合成气用于产生有价值的产品。
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