公开(公告)号：US20110114883A1

公开(公告)日：2011-05-19

申请号：US12933808

申请日：2009-03-24

申请人： Satoshi Murouchi ,  Toshio Nakayama ,  Toru Kitai

发明人： Satoshi Murouchi ,  Toshio Nakayama ,  Toru Kitai

IPC分类号： C09K19/06

CPC分类号： G03B9/08 ,  C08K3/04 ,  C08K7/14 ,  C08K7/26 ,  C08K7/28 ,  C08L67/00

摘要： A liquid crystal polyester resin composition includes, based on 100 parts by mass of a liquid crystal polyester, 15 to 60 parts by mass of talc having a number average particle size of 10 to 50 μm, 25 to 50 parts by mass of a glass fiber having a number average fiber length of 100 to 200 μm and a number average fiber diameter of 4 to 8 μm, and 2 to 10 parts by mass of carbon black, wherein a melt viscosity as determined at a shear rate of 100 sec−1 at 370° C. is 10 to 100 Pa·S and a deflection temperature under load is 220° C. or more. The liquid crystal polyester resin composition is used to provide a liquid crystal polyester resin composition for a camera module, having good heat resistance, rigidity, strength, and moldability, and also an excellent surface exfoliation property in a well balanced manner and being capable of being surface mounted (SMT).

摘要翻译： 液晶聚酯树脂组合物包含基于100质量份的液晶聚酯，15至60质量份数均粒径为10至50μm的滑石，25至50质量份的玻璃纤维 数均纤维长度为100〜200μm，数均纤维直径为4〜8μm，炭黑为2〜10质量份，其中，剪切速度为100sec -1时的熔体粘度为 370℃为10〜100Pa·S，负载挠曲温度为220℃以上。 液晶聚酯树脂组合物用于提供相机模块的液晶聚酯树脂组合物，具有良好的耐热性，刚性，强度和成型性，并且还具有良好平衡的优异的表面剥离性能，并且能够 表面贴装（SMT）。

公开(公告)号：US20100065777A1

公开(公告)日：2010-03-18

申请号：US12307025

申请日：2007-06-28

申请人： Satoshi Murouchi ,  Toshio Nakayama

发明人： Satoshi Murouchi ,  Toshio Nakayama

IPC分类号： C09K19/12

CPC分类号： C08K7/14 ,  C08K2201/016 ,  C08L67/03

摘要： A wholly aromatic liquid crystal polyester resin composition for injection molding, formed by melt-kneading 100 parts by mass of a wholly aromatic liquid crystal polyester resin, and 5 to 20 parts by mass of glass fibers having a number average diameter of 5 to 20 μm and an aspect ratio of 5 or more, the wholly aromatic liquid crystal polyester resin being formed by polycondensation of 60 to 70 mol % of p-hydroxybenzoic acid, 40 to 30 mol % of terephthalic acid and 4,4′-dihydroxydiphenyl combined, and 0 to 5 mol % of isophthalic acid and/or terephthalic acid (for all of these, derivatives thereof are included, and the total of these is 100 mol %). This composition has excellent damping properties, and is suitable for a molding material of an optical pickup lens holder for short type pickups for use in high-speed DVD systems and playback pickups for use in Blu-ray systems.

摘要翻译： 将100质量份全芳香族液晶聚酯树脂熔融混炼，5〜20质量份数均粒径为5〜20μm的玻璃纤维进行注射成型的全芳香族液晶聚酯树脂组合物 纵横比为5以上，全芳香族液晶聚酯树脂通过缩聚60〜70摩尔％的对羟基苯甲酸，40〜30摩尔％的对苯二甲酸和4,4'-二羟基二苯基组合而形成，以及 0〜5摩尔％的间苯二甲酸和/或对苯二甲酸（其中包括所有这些衍生物，总共为100摩尔％）。 该组合物具有优异的阻尼性能，适用于用于高速DVD系统的短型拾音器的光学拾取透镜保持器和用于蓝光系统的回放拾取器的成型材料。

公开(公告)号：US20090250662A1

公开(公告)日：2009-10-08

申请号：US12225567

申请日：2007-03-22

申请人： Satoshi Murouchi ,  Toshio Nakayama

发明人： Satoshi Murouchi ,  Toshio Nakayama

IPC分类号： C09K19/06

CPC分类号： C08K9/02 ,  H01L33/60 ,  Y10T428/10 ,  C08L67/00

摘要： Disclosed is a resin composition produced by melt-kneading a white pigment and a wholly aromatic thermotropic liquid crystal polyester. The resin composition can retain the excellent heat resistance and moldability of the wholly aromatic thermotropic liquid crystal polyester and have a satisfactory level of white light reflectance. The resin composition comprises 35 to 100 parts by weight of a white pigment particle and 100 parts by weight of a wholly aromatic thermotropic liquid crystal polyester, wherein the white pigment particle comprises 3 to 15 mass % of aluminum oxide and 97 to 85 mass % of a white pigment produced by a process including a roasting step and having a surface treated with the aluminum oxide (provided that the sum total of the white pigment and aluminum oxide is defined as 100 mass %). The resin composition can be produced by a process including a melt-kneading step.

摘要翻译： 公开了通过将白色颜料和全芳族热致变液晶聚酯熔融捏合而制得的树脂组合物。 树脂组合物可以保持全芳族热致变液晶聚酯的优异的耐热性和成型性，并且具有令人满意的白光反射率。 该树脂组合物包含35-100重量份白色颜料颗粒和100重量份全芳族热致液晶聚酯，其中白色颜料颗粒包含3-15质量％的氧化铝和97-85质量％的 通过包括焙烧步骤并具有用氧化铝处理的表面（条件是白色颜料和氧化铝的总和定义为100质量％）的方法生产的白色颜料。 树脂组合物可以通过包括熔融捏合步骤的方法制备。

公开(公告)号：US08715526B2

公开(公告)日：2014-05-06

申请号：US13583763

申请日：2011-03-14

申请人： Toru Kitai ,  Toshio Nakayama ,  Satoshi Murouchi

发明人： Toru Kitai ,  Toshio Nakayama ,  Satoshi Murouchi

IPC分类号： C09K19/38 ,  C09K19/54 ,  C08K3/22 ,  C08G63/60 ,  H01L33/60 ,  G02B5/12 ,  C09K19/52 ,  G02B5/30

CPC分类号： C09K19/3809 ,  C08G63/605 ,  C08K3/22 ,  C08K2003/2237 ,  C09K2019/521 ,  G02B5/12 ,  G02B5/30 ,  G02B5/3016 ,  H01L33/60 ,  Y10T428/10

摘要： The fully-aromatic thermotropic liquid crystal polyester resin composition of the present invention comprises 100 parts by mass of a fully-aromatic thermotropic liquid crystal polyester; and 50 to 150 parts by mass of titanium oxide, wherein the fully-aromatic thermotropic liquid crystal polyester comprises a repeating structural unit represented by the following formula (1), a repeating structural unit represented by the following formula (2), and a repeating structural unit represented by the following formula (3), and comprises 65 mole % to 78 mole % of the repeating structural unit represented by the formula (1). wherein X and Y each represent a divalent group having an aromatic ring.

摘要翻译： 本发明的全芳族热致液晶聚酯树脂组合物包含100质量份全芳族热致液晶聚酯; 和50〜150质量份的氧化钛，其中，所述全芳香族热致变液晶聚酯包含由下式（1）表示的重复结构单元，由下式（2）表示的重复结构单元和重复 由下式（3）表示的结构单元，由式（1）表示的重复结构单元的65摩尔％〜78摩尔％。 其中X和Y各自表示具有芳环的二价基团。

公开(公告)号：US08192645B2

公开(公告)日：2012-06-05

申请号：US12933967

申请日：2009-03-24

申请人： Satoshi Murouchi ,  Toshio Nakayama ,  Toru Kitai

发明人： Satoshi Murouchi ,  Toshio Nakayama ,  Toru Kitai

IPC分类号： C09K19/38 ,  C09K19/52 ,  C09K19/20 ,  C09K19/54 ,  C08K3/04 ,  C08K3/34 ,  C08K3/40

CPC分类号： H04N5/2251 ,  C08K3/04 ,  C08K3/22 ,  C08K7/28 ,  C08L67/03 ,  C09K19/3809 ,  G03B9/00 ,  H04N5/2257

摘要： A resin composition for surface-mountable (SMT) camera modules which is excellent in the balance between heat resistance, rigidity, strength or moldability and surface exfoliation characteristics is provided by using a liquid-crystal polyester resin composition which comprises 100 parts by mass of a liquid-crystal polyester, 15 to 60 parts by mass of talc having a number-mean particle diameter of 10 to 50 μm, 25 to 50 parts by mass of glass fiber having a number-mean fiber length of 100 to 200 μm, 6 to 20 parts by mass of titanium oxide, and 2 to 10 parts by mass of carbon black and which exhibits a melt viscosity of 10 to 100 Pa S as determined at a shear rate of 100 sec−1 and 370° C. and a deflection temperature under load of 220° C. or above.

摘要翻译： 通过使用液晶聚酯树脂组合物提供了耐热性，刚性，强度或成型性和表面剥离特性之间的平衡优异的表面贴装（SMT）相机模块用树脂组合物，其包含100质量份 液晶聚酯，15〜60质量份的平均粒径为10〜50μm的滑石，25〜50质量份的数均纤维长度为100〜200μm的玻璃纤维，6〜 20质量份氧化钛和2〜10质量份炭黑，并且在剪切速率为100秒-1和370℃下测定的熔体粘度为10〜100Pa·s，挠曲温度 在220°C或以上的负载下。

公开(公告)号：US20110089371A1

公开(公告)日：2011-04-21

申请号：US12933967

申请日：2009-03-24

申请人： Satoshi Murouchi ,  Toshio Nakayama ,  Toru Kitai

发明人： Satoshi Murouchi ,  Toshio Nakayama ,  Toru Kitai

IPC分类号： C09K19/00

CPC分类号： H04N5/2251 ,  C08K3/04 ,  C08K3/22 ,  C08K7/28 ,  C08L67/03 ,  C09K19/3809 ,  G03B9/00 ,  H04N5/2257

摘要： A resin composition for surface-mountable (SMT) camera modules which is excellent in the balance between heat resistance, rigidity, strength or moldability and surface exfoliation characteristics is provided by using a liquid-crystal polyester resin composition which comprises 100 parts by mass of a liquid-crystal polyester, 15 to 60 parts by mass of talc having a number-mean particle diameter of 10 to 50 μm, 25 to 50 parts by mass of glass fiber having a number-mean fiber length of 100 to 200 μm, 6 to 20 parts by mass of titanium oxide, and 2 to 10 parts by mass of carbon black and which exhibits a melt viscosity of 10 to 100 Pa S as determined at a shear rate of 100 sec−1 and 370° C. and a deflection temperature under load of 220° C. or above.

摘要翻译： 通过使用液晶聚酯树脂组合物提供了耐热性，刚性，强度或成型性和表面剥离特性之间的平衡优异的表面贴装（SMT）相机模块用树脂组合物，其包含100质量份 液晶聚酯，15〜60质量份的平均粒径为10〜50μm的滑石，25〜50质量份的数均纤维长度为100〜200μm的玻璃纤维，6〜 20质量份氧化钛和2〜10质量份炭黑，并且在剪切速率为100秒-1和370℃下测定的熔体粘度为10〜100Pa·s，挠曲温度 在220°C或以上的负载下。

公开(公告)号：US09234092B2

公开(公告)日：2016-01-12

申请号：US13497186

申请日：2010-08-18

申请人： Toshio Nakayama ,  Satoshi Murouchi ,  Miyuki Shiraishi

发明人： Toshio Nakayama ,  Satoshi Murouchi ,  Miyuki Shiraishi

IPC分类号： C09K19/06 ,  C08K9/06 ,  C09K19/38 ,  F21V7/22 ,  C08K7/04 ,  C08K9/02 ,  B29L11/00 ,  B29K105/00 ,  B29K105/16 ,  H01L33/48

CPC分类号： C08K9/06 ,  B29K2105/0079 ,  B29K2105/16 ,  B29L2011/0083 ,  C08K7/04 ,  C08K9/02 ,  C09K19/3809 ,  F21V7/22 ,  H01L33/486 ,  H01L2924/0002 ,  C08L67/03 ,  H01L2924/00

摘要： A liquid-crystal polyester resin composition according to the present invention contains 100 parts by mass of a liquid-crystal polyester (A), 50 to 150 parts by mass of a titanium oxide (B) having been subjected to an aluminum oxide treatment, a silicon oxide treatment and an organosiloxane treatment as surface treatments, and 0 to 50 parts by mass of an inorganic fibrous filler (C).

摘要翻译： 本发明的液晶聚酯树脂组合物含有100质量份液晶聚酯（A），50〜150质量份已经进行了氧化铝处理的氧化钛（B）， 氧化硅处理和作为表面处理的有机硅氧烷处理，以及0〜50质量份的无机纤维状填料（C）。

公开(公告)号：US08658057B2

公开(公告)日：2014-02-25

申请号：US13498816

申请日：2010-06-28

申请人： Toshio Nakayama ,  Satoshi Murouchi

发明人： Toshio Nakayama ,  Satoshi Murouchi

IPC分类号： C09K19/52 ,  C09K19/54 ,  C09K19/00 ,  C09K19/02 ,  B22F1/00

CPC分类号： B29C45/00 ,  B29K2067/00 ,  B29K2105/0079 ,  C08K3/04 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/009 ,  C09K19/3809 ,  C08L67/03

摘要： A liquid crystal polyester resin composition for camera modules is used, the composition including, based on 100 parts by mass of the composition as a whole, (A) 49.5 to 69.5 parts by mass of a liquid crystal polyester, (B) 30.0 to 50.0 parts by mass of an irregular form or spherical powder having a Mohs hardness of 5 or higher and a primary particle diameter of 5 μm or less, and (C) 0.5 to 5.0 parts by mass of carbon black. The use of the resin composition allows a reduction in the amount of dust generated (particles falling off) during the production of the camera, the use of the camera, and the operation of the camera modules. The resin composition has high surface hardness, is excellent in balance between heat resistance, stiffness, moldability, and resistance to falling of particles off a surface, and causes no malfunction during autofocus control.

摘要翻译： 使用相机模块用液晶聚酯树脂组合物，该组合物基于100质量份的组合物作为整体，（A）为49.5〜69.5质量份的液晶聚酯，（B）为30.0〜50.0 摩尔硬度为5以上，一次粒径为5μm以下的不规则形状或球状粉末质量，（C）为0.5〜5.0质量份的炭黑。 使用树脂组合物可以减少相机生产过程中产生的粉尘量（颗粒脱落），照相机的使用以及相机模块的操作。 该树脂组合物具有高表面硬度，耐热性，刚度，成型性以及颗粒从表面脱落的阻力之间的平衡优异，并且在自动对焦控制期间不会发生故障。

公开(公告)号：US07737198B2

公开(公告)日：2010-06-15

申请号：US10519046

申请日：2003-06-19

申请人： Satoshi Murouchi ,  Toshio Nakayama ,  Yoshikuni Yamada

发明人： Satoshi Murouchi ,  Toshio Nakayama ,  Yoshikuni Yamada

IPC分类号： C08J9/32

CPC分类号： C08K7/24 ,  C08K2201/016 ,  H05K1/024 ,  H05K1/0373 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/3154 ,  Y10T428/31725 ,  C08L67/00

摘要： A molded product of a wholly aromatic liquid crystal polyester resin composition having a dielectric constant of 3.0 or less and a dielectric dissipation factor of 0.04 or less and is obtained by an injection molding of a composition comprising 90 to 45 percent by weight of the wholly aromatic liquid crystal polyester having a melting point of 320C or more, 10 to 40 percent by weight of an inorganic spherical hollow material having an aspect ratio of 2 or less, and 0 to 15 percent by weight of an inorganic filler having an aspect ratio of 4 or more. The molded product has dielectric properties suitable for information and telecommunications equipment, and is excellent in solder heat resistance, processability, and dimensional stability. The molded product is advantageous as a substrate material for use in information and telecommunications equipment such as a cellular mobile phone and as a fixing/holding member of a transmitter-receiver element.

摘要翻译： 介电常数为3.0以下，介电耗散系数为0.04以下的全芳香族液晶聚酯树脂组合物的成型体，是通过注塑成型包含90〜45重量％的全芳族化合物 熔点为320℃以上的液晶聚酯，纵横比为2以下的无机球状中空材料为10〜40重量％，纵横比为4的无机填料为0〜15重量％ 或者更多。 该模制产品具有适用于信息和通信设备的介电特性，并具有优异的焊料耐热性，加工性和尺寸稳定性。 模制产品作为用于诸如蜂窝移动电话的信息和通信设备以及作为发射机 - 接收机元件的固定/保持构件的基板材料是有利的。

公开(公告)号：US20070173565A1

公开(公告)日：2007-07-26

申请号：US11578980

申请日：2005-04-19

申请人： Satoshi Murouchi ,  Toshio Nakayama ,  Yoshikuni Yamada

发明人： Satoshi Murouchi ,  Toshio Nakayama ,  Yoshikuni Yamada

IPC分类号： C08J9/32

CPC分类号： G02B7/028 ,  C08G63/605 ,  C08K7/12 ,  C08K2201/016 ,  G11B7/0935 ,  G11B7/22 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/3154 ,  Y10T428/31725

摘要： An optical pickup lens holder which comprises a wholly aromatic liquid crystalline polyester resin composition comprising 97 to 45 mass percent of a wholly aromatic liquid crystalline polyester having a melting point of 320° C. or more, 3 to 50 mass percent of an inorganic spherical hollow material having an aspect ration of 2 or less and 0 to 30 percent by mass of an inorganic filler having as aspect ratio of 4 or more, wherein the percentages are made to 100 percent by mass in total, and having a specific gravity in the range of 1.00 to 1.35. The optical pickup lens holder exhibits excellent characteristics as an optical pickup lens holder, while containing good heat resistance in soldering and good processability inherent in a liquid crystalline polyester, exhibits high injection processability and high adaptability to a soldering process even when a sheet form lens holder having a thin part and an opening port, and is restricted in the temperature rise of the part near a driving coil.

摘要翻译： 一种光学拾取透镜保持器，其包括全芳族液晶聚酯树脂组合物，其包含熔体为320℃以上的全固化液晶聚酯的97〜45质量％，无机球状中空部的3〜50质量％ 长宽比为4以上的无机填料的比例为2以下，0〜30质量％的材料，其中所述百分比总计为100质量％，比重在该范围内 为1.00至1.35。 光拾取透镜保持器作为光学拾取透镜保持器具有优异的特性，同时在液晶聚酯中具有良好的耐焊接性和良好的加工性，即使当片状透镜保持架也具有高的注射加工性和对焊接工艺的高适应性 具有薄的部分和开口，并且限制在驱动线圈附近的部分的温度上升。