Layered product olefin foam and use

    公开(公告)号:US07582352B2

    公开(公告)日:2009-09-01

    申请号:US10069603

    申请日:2001-06-29

    IPC分类号: B32B27/32 B29C39/12

    摘要: The foamed laminate based on olefin according to the present invention is composed of a substrate layer of a foamed body made of either an ethylenic thermoplastic elastomer comprising a polyethylene resin and an ethylene/α-olefin copolymer having a Mooney viscosity ML1+4 (100° C.) of 90-250 and an ethylene content of 70-95 mole % or an ethylenic thermoplastic elastomer composition comprising 100 parts by weight of an olefinic thermoplastic elastomer and 1-20 parts by weight of an olefinic thermoplastic resin and, under lamination thereon, a skin layer made of either an ultrahigh molecular weight polyolefin resin having an intrinsic viscosity of 3.5-8.3 dl/g or made of an olefinic thermoplastic elastomer composition comprising an olefinic thermoplastic elastomer and a lubricant. The foamed laminate according to the present invention is easy in recycled use, obtainable at a high foaming expansion ratio with soft hand touch and is superior in the appearance, abrasion resistance, durability and sliding performance.

    Thermoplastic olefin elastomer composition
    4.
    发明授权
    Thermoplastic olefin elastomer composition 失效
    热塑性烯烃弹性体组合物

    公开(公告)号:US06803398B1

    公开(公告)日:2004-10-12

    申请号:US09486368

    申请日:2000-02-28

    IPC分类号: C08K515

    摘要: An olefin-based thermoplastic elastomer composition comprising a thermoplastic elastomer blended with other resins and rubbers is provided. The thermoplastic elastomer contains polypropylene resin and an olefin-based copolymer rubber, and optionally, a linear polyethylene resin, and the thermoplastic elastomer has been crosslinked to a gel content of 95% or higher. A polyolefin resin, an olefin-based copolymer rubber and a softening agent are further blended with optional inorganic filler to provide the olefin-based thermoplastic elastomer composition. This composition is excellent in oil resistance and extrudability, and well-adapted for use as an energy-saving, resources-saving elastomer in applications including surface or skin material in autoparts, industrial mechanical parts, electric and electronic parts, and construction materials.

    摘要翻译: 提供了包含与其它树脂和橡胶共混的热塑性弹性体的烯烃类热塑性弹性体组合物。 热塑性弹性体含有聚丙烯树脂和烯烃系共聚物橡胶,任意地为直链状聚乙烯树脂,热塑性弹性体的交联凝胶含量为95%以上。 将聚烯烃树脂,烯烃类共聚物橡胶和软化剂进一步与任选的无机填料共混以提供烯烃系热塑性弹性体组合物。 该组合物的耐油性和挤出性优异,适用于汽车零部件,工业机械部件,电气电子部件和建筑材料中的表面或表皮材料的节能,节省资源的弹性体。

    Olefin thermoplastic elastomer foamed products and processes for
preparing the same
    6.
    发明授权
    Olefin thermoplastic elastomer foamed products and processes for preparing the same 失效
    烯烃热塑性弹性体发泡产品及其制备方法

    公开(公告)号:US5728744A

    公开(公告)日:1998-03-17

    申请号:US754800

    申请日:1996-11-21

    CPC分类号: C08L23/16 C08L23/10 C08L23/20

    摘要: Disclouse is an olefin thermoplastic elastomer foamed product obtained by heating a foamable composition comprising a partially crosslinked thermoplastic elastomer composition (A), a specific olefin plastic (B) and a foaming agent (C) in specific proportions. The partially crosslinked thermoplastic elastomer (A) is obtained by dynamically heat-treating a mixture in the presence of organic peroxide, said mixture comprising specific proportions of a peroxide-crosslinkable copolymer rubber (a), which is a specific ethylene/.alpha.-olefin/nonconjugated diene copolymer rubber, and a peroxide-decomposable olefin plastic (b), which is a (co)polymer containing 50 to 100% by mol of an .alpha.-olefin of 3 to 20 carbon atoms and has a specific MFR. The olefin plastic (B) is a (co)polymer containing 50 to 100% by mol of an .alpha.-olefin of 2 to 20 carbon atoms and has a specific MFR. Also disclosed is a process for preparing the olefin thermoplastic elastomer foamed product. The foamed product of the invention is free from surface roughening caused by defoaming even when an expansion ratio is 2 or more times. Besides, the foamed product is soft to the touch and shows excellent heat resistance and weathering resistance. According to the process of the invention, the foamed product can be prepared through simplified steps with high productivity.

    摘要翻译: Disclouse是通过以特定比例加热包含部分交联的热塑性弹性体组合物(A),特定烯烃塑料(B)和发泡剂(C))的可发泡组合物而获得的烯烃热塑性弹性体发泡产品。 部分交联的热塑性弹性体(A)通过在有机过氧化物存在下动态热处理混合物获得,所述混合物包含特定比例的过氧化物可交联的共聚物橡胶(a),其是特定的乙烯/α-烯烃/ 非共轭二烯共聚物橡胶,和过氧化物可分解的烯烃塑料(b),它是含有50〜100摩尔%的碳原子数3〜20的α-烯烃(具有MFR)的(共)聚合物。 烯烃塑料(B)是含有50〜100摩尔%的碳原子数2〜20的α-烯烃的(共)聚合物,并且具有特定的MFR。 还公开了一种制备烯烃热塑性弹性体发泡产品的方法。 本发明的发泡产品即使在膨胀比为2次以上时,也不会发生由消泡引起的表面粗糙化。 此外,发泡产品触感柔软,耐热性和耐候性优异。 根据本发明的方法,可以通过简化的步骤以高生产率制备发泡产品。

    Ornamental member
    8.
    发明授权
    Ornamental member 失效
    装饰成员

    公开(公告)号:US5015537A

    公开(公告)日:1991-05-14

    申请号:US405243

    申请日:1989-09-11

    IPC分类号: B44F1/08

    摘要: An improved ornamental member including at least two types of Cr or Ti hard films of different color tones disposed by ion plating on a substrate is prepared. The laminate includes a combination of Cr and Ti hard films including a stainless steel colored Cr hard film layer containng Cr, N and C as the main constituents, a gold colored Ti hard film having Ti and N as the main constitutents, a dark grey Ti hard film having Ti, N and C as the main constituents, a blue Ti hard film having Ti and O as the main constituents and a brown Ti hard film having Ti, O and C as the main constituents. The thickness of a single year of hard film is between about 0.2 and 1.5 .mu.m and the total film thickness at the laminated portion is less than about 3 .mu.m. Preferably, each hard film layer is between about 0.2 and 0.8 .mu.m.

    摘要翻译: 制备改进的装饰构件,其包括在衬底上通过离子电镀设置的不同色调的至少两种类型的Cr或Ti硬膜。 层压体包括Cr和Ti硬膜的组合,其包括以Cr,N和C为主要成分的不锈钢着色的Cr硬质膜层,以Ti和N为主要成分的金色Ti硬质膜,深灰色Ti 具有Ti,N和C作为主要成分的硬质膜,以Ti和O为主要成分的蓝色Ti硬质膜和以Ti,O和C为主要成分的棕色Ti硬质膜。 一年硬膜的厚度为0.2〜1.5μm左右,层叠部的膜厚为3μm以下。 优选地,每个硬膜层在约0.2和0.8μm之间。

    Thermoplastic elastomer composition and process for preparation thereof
    10.
    发明授权
    Thermoplastic elastomer composition and process for preparation thereof 失效
    热塑性弹性体组合物及其制备方法

    公开(公告)号:US4650830A

    公开(公告)日:1987-03-17

    申请号:US615244

    申请日:1984-05-30

    摘要: Disclosed is a thermoplastic elastomer composition excellent in the injection fusion bondability and the surface gloss, which comprises (1) an amorphous ethylene/.alpha.-olefin copolymer (a) and (2) (i) a lowly crystalline copolymer (b) of propylene with an .alpha.-olefin having at least 4 carbon atoms, (ii) a polymer (d) composed mainly of 1-butene or (iii) a combination of the copolymer (b) or the polymer (d) with a crystalline polymer (c) composed mainly of propylene, wherein the component (1) is present in an amount of 10 to 95% by weight based on the total amount of the components (1) and (2), the component (2) is present in an amount of 5 to 90% by weight based on the total amount of the components (1) and (2), and the component (1) or the components (1) and (2) are partially crosslinked.The partial crosslinking is effected by grafting of a radical-polymerizable monomer having at least two polymerizable groups.

    摘要翻译: 公开了注射熔融粘合性和表面光泽度优异的热塑性弹性体组合物,其包括(1)无定形乙烯/α-烯烃共聚物(a)和(2)(i)低结晶性丙烯共聚物(b) 具有至少4个碳原子的α-烯烃,(ii)主要由1-丁烯组成的聚合物(d)或(iii)共聚物(b)或聚合物(d)的组合与结晶聚合物(c) 主要由丙烯组成,其中组分(1)以组分(1)和(2)的总量计为10至95重量%的量存在,组分(2)的存在量为 基于组分(1)和(2)的总量和组分(1)或组分(1)和(2)的5-90重量%部分交联。 部分交联通过接枝具有至少两个可聚合基团的可自由基聚合的单体来实现。