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公开(公告)号：US07834071B2
公开(公告)日：2010-11-16
申请号：US11915391
申请日：2006-05-10
IPC分类号： C08K5/49
CPC分类号： C08K5/49 , C08K5/0066 , C08K5/5313 , C09K21/12
摘要： Disclosed is a flame-retardant resin processed article having excellent flame retardance while being free from bleed-out. Specifically, a resin composition containing a cyclic phosphorus compound flame retardant, a hydrophilic silica powder having an average particle diameter of not more than 15 m, and a resin with the total content of the cyclic phosphorus compound and the hydrophilic silica powder being 10-45% by mass is molded into a certain shape or formed into a coating film. The hydrophilic silica powder is preferably composed of porous structures having a pore volume of not more than 1.8 ml/g and a pH of 4-7. More preferably, the hydrophilic silica powder has an oil absorption of not less than 50 ml/100 g in accordance with JIS K5101.
摘要翻译： 公开了一种阻燃树脂加工制品，其具有优异的阻燃性，同时不会渗出。 具体地说，将含有环状磷化合物阻燃剂，平均粒径为15μm以下的亲水性二氧化硅粉末和环状磷化合物和亲水性二氧化硅粉末的总含量为10〜45的树脂组合物 质量％成型为一定形状或形成涂膜。 亲水性二氧化硅粉末优选由孔体积不大于1.8ml / g，pH为4-7的多孔结构体构成。 更优选地，亲水性二氧化硅粉末根据JIS K5101具有不小于50ml / 100g的吸油量。
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公开(公告)号：US07851528B2
公开(公告)日：2010-12-14
申请号：US11915505
申请日：2006-05-23
IPC分类号： C08K5/5313 , C08K5/49
CPC分类号： C08K5/5313 , C08K5/5399 , C09K21/12
摘要： A flame retardant resin treated article that excels in flame retardancy and is free from bleedout. A resin composition comprising a flame retarder of metal phosphinate represented by the general formula: (I) (in the formula, each of R1 and R2 is a C1-C6 alkyl or an aryl group having 12 or less carbon atoms; M is calcium, aluminum or zinc; and when M=aluminum, m=3, and otherwise m=2), a reactive organophosphorus flame retarder having an unsaturated group at its terminal and a resin wherein the total content of metal phosphinate and reactive organophosphorus flame retarder is in the range of 5 to 30 mass % is provided in molded form or coating form.
摘要翻译： 阻燃树脂处理制品，阻燃性优异，无渗漏。 包含由通式（I）表示的金属次膦酸化合物的阻燃剂的树脂组合物（在该式中，R 1和R 2各自是C 1 -C 6烷基或具有12个或更少碳原子的芳基; M是钙， 铝或锌;当M =铝，m = 3，m = 2）时，在其末端具有不饱和基团的反应性有机磷阻燃剂和其中金属次膦酸盐和反应性有机磷阻燃剂的总含量为 5〜30质量％的范围以成形或涂布形式提供。
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公开(公告)号：US07557152B2
公开(公告)日：2009-07-07
申请号：US11816665
申请日：2006-02-16
CPC分类号： C07F9/2462 , C07F9/242 , C07F9/2429 , C07F9/5325 , C08K5/523 , C08K5/5399 , C09K21/12
摘要： Disclosed is a reactive flame retardant which provides a resin with excellent flame retardance even when it is added in a small amount while being prevented from bleedout. Also disclosed is a flame-retardant resin processed article obtained by using such a reactive flame retardant. An organophosphorus compound represented by the general formula (I) below, wherein at least one or more of X1-X3 represent a group containing phosphorus and having a terminal unsaturated group, is used as a reactive flame retardant which is reactive with resins. A flame-retardant resin processed article can be obtained by solidifying the resin composition containing the organophosphorus compound and then reacting it through heating or application of radiation.
摘要翻译： 公开了一种反应性阻燃剂，其即使在防止渗出时少量加入时也提供具有优异阻燃性的树脂。 还公开了通过使用这种反应性阻燃剂获得的阻燃树脂加工制品。 作为与树脂反应的反应性阻燃剂，使用下述通式（I）表示的有机磷化合物，其中X 1 -X 3表示含磷基团，具有末端不饱和基团的基团。 通过使包含有机磷化合物的树脂组合物固化，然后通过加热或施加辐射使其反应，可以获得阻燃树脂加工制品。
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公开(公告)号：US20090048377A1
公开(公告)日：2009-02-19
申请号：US11915391
申请日：2006-05-10
IPC分类号： C07F9/6574
CPC分类号： C08K5/49 , C08K5/0066 , C08K5/5313 , C09K21/12
摘要： Disclosed is a flame-retardant resin processed article having excellent flame retardance while being free from bleed-out. Specifically, a resin composition containing a cyclic phosphorus compound flame retardant, a hydrophilic silica powder having an average particle diameter of not more than 15 m, and a resin with the total content of the cyclic phosphorus compound and the hydrophilic silica powder being 10-45% by mass is molded into a certain shape or formed into a coating film. The hydrophilic silica powder is preferably composed of porous structures having a pore volume of not more than 1.8 ml/g and a pH of 4-7. More preferably, the hydrophilic silica powder has an oil absorption of not less than 50 ml/100 g in accordance with JIS K5101.
摘要翻译： 公开了一种阻燃树脂加工制品，其具有优异的阻燃性，同时不会渗出。 具体地说，将含有环状磷化合物阻燃剂，平均粒径为15μm以下的亲水性二氧化硅粉末和环状磷化合物和亲水性二氧化硅粉末的总含量为10〜45的树脂组合物 质量％成型为一定形状或形成涂膜。 亲水性二氧化硅粉末优选由孔体积不大于1.8ml / g，pH为4-7的多孔结构体构成。 更优选地，亲水性二氧化硅粉末根据JIS K5101具有不小于50ml / 100g的吸油量。
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公开(公告)号：US20090105382A1
公开(公告)日：2009-04-23
申请号：US11915505
申请日：2006-05-23
IPC分类号： C09D5/18 , C08K5/5313 , C09J11/06
CPC分类号： C08K5/5313 , C08K5/5399 , C09K21/12
摘要： A flame retardant resin treated article that excels in flame retardancy and is free from bleedout. A resin composition comprising a flame retarder of metal phosphinate represented by the general formula: (I) (in the formula, each of R1 and R2 is a C1-C6 alkyl or an aryl group having 12 or less carbon atoms; M is calcium, aluminum or zinc; and when M=aluminum, m=3, and otherwise m=2), a reactive organophosphorus flame retarder having an unsaturated group at its terminal and a resin wherein the total content of metal phosphinate and reactive organophosphorus flame retarder is in the range of 5 to 30 mass % is provided in molded form or coating form.
摘要翻译： 阻燃树脂处理制品，阻燃性优异，无渗漏。 包含由通式（I）表示的金属次膦酸化合物的阻燃剂的树脂组合物（在该式中，R 1和R 2各自是C 1 -C 6烷基或具有12个或更少碳原子的芳基; M是钙， 铝或锌;当M =铝，m = 3，m = 2）时，在其末端具有不饱和基团的反应性有机磷阻燃剂和其中金属次膦酸盐和反应性有机磷阻燃剂的总含量为 5〜30质量％的范围以成形或涂布形式提供。
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公开(公告)号：US20090043032A1
公开(公告)日：2009-02-12
申请号：US11816665
申请日：2006-02-16
CPC分类号： C07F9/2462 , C07F9/242 , C07F9/2429 , C07F9/5325 , C08K5/523 , C08K5/5399 , C09K21/12
摘要： Disclosed is a reactive flame retardant which provides a resin with excellent flame retardance even when it is added in a small amount while being prevented from bleedout. Also disclosed is a flame-retardant resin processed article obtained by using such a reactive flame retardant. An organophosphorus compound represented by the general formula (I) below, wherein at least one or more of X1-X3 represent a group containing phosphorus and having a terminal unsaturated group, is used as a reactive flame retardant which is reactive with resins. A flame-retardant resin processed article can be obtained by solidifying the resin composition containing the organophosphorus compound and then reacting it through heating or application of radiation.
摘要翻译： 公开了一种反应性阻燃剂，其即使在防止渗出时少量加入时也提供具有优异阻燃性的树脂。 还公开了通过使用这种反应性阻燃剂获得的阻燃树脂加工制品。 作为与树脂反应的反应性阻燃剂，使用下述通式（I）表示的有机磷化合物，其中X 1 -X 3表示含磷基团，具有末端不饱和基团的基团。 通过使包含有机磷化合物的树脂组合物固化，然后通过加热或施加辐射使其反应，可以获得阻燃树脂加工制品。
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7.发明授权Ultrathin membrane of polymethacrylate or polycrotonate and device provided with ultrathin membrane 失效聚甲基丙烯酸酯或聚氯乙烯的超薄膜和超声波膜提供的装置
公开(公告)号：US5209847A
公开(公告)日：1993-05-11
申请号：US590908
申请日：1990-10-01
申请人： Norihiro Kaiya , Naoyuki Amaya , Yoshishige Murata , Mikio Takagi , Kazuichi Tsuda , Kiyotaka Shigehara , Akira Yamada , Takayuki Otsu
发明人： Norihiro Kaiya , Naoyuki Amaya , Yoshishige Murata , Mikio Takagi , Kazuichi Tsuda , Kiyotaka Shigehara , Akira Yamada , Takayuki Otsu
摘要： An ultrathin polymeric membrane has a membrane thickness of 10 to 1,000 .ANG.. The membrane is constituted of polycarboxylate and obtained by the spin coating method or by the Langmuir-Blodgett method. The polycarboxylate contains recurrent units represented by the formula (I) ##STR1## wherein R.sub.1 and R.sub.2 represent different groups and each stands for a methyl group or a hydrogen atom, and R represents a hydrocarbon group selected from the group consisting of a branched alkyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a substituted alkyl group having 2 to 6 carbon atoms, a substituted cycloalkyl group having 3 to 10 carbon atoms and a siloxanic hydrocarbon group.
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公开(公告)号：US4907038A
公开(公告)日：1990-03-06
申请号：US47887
申请日：1987-05-08
申请人： Kiyotaka Shigehara , Akira Yamada , Masahiko Hara , Hidenari Nakahama , Seizo Miyata , Yoshishige Murata
发明人： Kiyotaka Shigehara , Akira Yamada , Masahiko Hara , Hidenari Nakahama , Seizo Miyata , Yoshishige Murata
CPC分类号： H01L51/5012 , B01D69/122 , B05D1/202 , B82Y30/00 , B82Y40/00 , H01L21/28167 , H01L21/28264 , H01L21/3128 , H01L29/51 , H01L29/518 , H01L51/0075 , Y10S428/91 , Y10T428/268
摘要： A Langmuir-Blodgett ultrathin membrane is constituted of polyfumarate having a degree of polymerization of 20 to 10,000. The polyfumarate is obtained by polymerizing fumarate represented by the general formula of: ##STR1## wherein at least one of R.sub.1 and R.sub.2 represents a bulky hydrocarbon group such as a branched alkyl group, a cycloalkyl group or a substituent thereof, a fluorine-substituted hydrocarbon group, a hetero atom-containing hydrocarbon group or a silicon-containing group.
摘要翻译： Langmuir-Blodgett超薄膜由聚合度为20〜10,000的聚富马酸盐构成。 聚富马酸盐通过聚合由以下通式表示的富马酸盐获得：其中R 1和R 2中的至少一个表示大体积的烃基，例如支链烷基，环烷基或其取代基，氟取代的烃 基团，含杂原子的烃基或含硅基团。
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9.发明授权Plasmid, transformants and process for production of 3- carboxymuconolactone 有权质粒，转化体和生产3-羧基粘康酸内酯的方法公开(公告)号：US08211683B2
公开(公告)日：2012-07-03
申请号：US12310095
申请日：2007-08-10
申请人： Kohei Mase , Toshihisa Shimo , Naoki Ohara , Yoshihiro Katayama , Kiyotaka Shigehara , Eiji Masai , Masao Fukuda , Seiji Ohara , Masaya Nakamura , Yuichiro Otsuka
发明人： Kohei Mase , Toshihisa Shimo , Naoki Ohara , Yoshihiro Katayama , Kiyotaka Shigehara , Eiji Masai , Masao Fukuda , Seiji Ohara , Masaya Nakamura , Yuichiro Otsuka
CPC分类号： C12N9/1007 , C12N9/0008 , C12N9/0069 , C12P17/04
摘要： There is provided a process for industrial production of simple 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone from low molecular mixtures derived from plant components such as vanillin, vanillic acid and protocatechuic acid, via a multistage enzyme reaction. A recombinant plasmid containing a vanillate demethylase gene (vanAB genes), benzaldehyde dehydrogenase gene (ligV gene) and protocatechuate 3,4-dioxygenase gene (pcaHG genes); transformants incorporating the plasmid; and a process for production of 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone characterized by culturing the transformants in the presence of vanillin, vanillic acid, protocatechuic acid or a mixture of two or more thereof.
摘要翻译： 提供了通过多级酶反应从由植物成分如香草醛，香草酸和原儿茶酸衍生的低分子混合物工业生产简单的3-羧基 - 顺式，顺式 - 粘酸和/或3-羧基粘土内酯的方法。 含有香草脱甲基酶基因（vanab基因），苯甲醛脱氢酶基因（ligV基因）和原儿茶素3,4-双加氧酶基因（pcaHG基因）的重组质粒; 掺入质粒的转化体; 以及生产3-羧基 - 顺式，顺式 - 粘酸和/或3-羧基粘土内酯的方法，其特征在于在香草醛，香草酸，原儿茶酸或其两种或更多种的混合物存在下培养转化体。
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10.发明申请GENE-DISRUPTED STRAIN, RECOMBINANT PLASMIDS, TRANSFORMANTS AND PROCESS FOR PRODUCTION OF 3-CARBOXYMUCONOLACTONE 审中-公开基因破坏菌株，重组菌株，转化体和生产3-羧基肉豆蔻酸酯的方法公开(公告)号：US20100209978A1
公开(公告)日：2010-08-19
申请号：US12599787
申请日：2008-05-09
申请人： Toshihisa Shimo , Kohei Mase , Yoshihiro Katayama , Eiji Masai , Masao Fukuda , Kiyotaka Shigehara , Seiji Ohara , Masaya Nakamura , Yuichiro Otsuka
发明人： Toshihisa Shimo , Kohei Mase , Yoshihiro Katayama , Eiji Masai , Masao Fukuda , Kiyotaka Shigehara , Seiji Ohara , Masaya Nakamura , Yuichiro Otsuka
CPC分类号： C12P7/48 , C12N9/0069 , C12P17/04 , C12Y113/11003
摘要： Industrial-scale fermentative production of 3-carboxy-cis,cis-muconic acid from terephthalic acid. Also, a protocatechuate 4,5-ring-cleaving enzyme gene-disrupted strain in which the gene coding for (a) the amino acid sequence set forth in SEQ ID NO: 1 or 3, or (b) the amino acid sequence set forth in SEQ ID NO: 1 or 3 which has a deletion, substitution, addition and/or insertion of one or more amino acids and exhibits protocatechuate 4,5-ring cleavage activity, present in the chromosomal DNA of microbial cells, has been disrupted; recombinant plasmids comprising the Tph gene and protocatechuate 3,4-dioxygenase gene; transformants obtained by introducing the recombinant plasmids into the disrupted strain; and a process for production of 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone characterized by culturing the transformants in the presence of terephthalic acid.
摘要翻译： 从对苯二甲酸工业规模发酵生产3-羧基 - 顺式，顺式 - 粘康酸。 此外，原儿茶素4,5环切割酶基因破坏的菌株，其中编码（a）SEQ ID NO：1或3所示的氨基酸序列的基因，或（b）阐述的氨基酸序列 在具有一个或多个氨基酸的缺失，取代，添加和/或插入并且表现出存在于微生物细胞的染色体DNA中的原儿茶素4,5-环切割活性的SEQ ID NO：1或3已被破坏; 包含Tph基因和原儿茶素3,4-双加氧酶基因的重组质粒; 通过将重组质粒导入破碎的菌株获得的转化体; 以及3-羧基 - 顺式，顺式 - 粘酸和/或3-羧基粘土内酯的制备方法，其特征在于在对苯二甲酸存在下培养转化体。
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