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公开(公告)号：US5225296A
公开(公告)日：1993-07-06
申请号：US616564
申请日：1990-11-21
IPC分类号： C25B11/03 , C25B11/12 , D01F11/16 , H01M4/133 , H01M4/1393 , H01M4/66 , H01M4/96 , H01M10/05
摘要： An electrode comprises a porous carbon sheet comprising (a) carbon fibers and (b) a carbon matrix which comprises carbon particles and is integrally combined with the carbon fibers, having continuous through-holes. This electrode can be used as a cathode or anode for a battery. This type of electrode is prepared by depositing a phenolic resin on a phenolic resin sheet comprising phenolic resin fibers, and carbonizing the phenolic resin and the phenolic resin sheet in an oxygen-free atmosphere at temperatures in the range of 500.degree. C. to 3000.degree. C.
摘要翻译： 电极包括多孔碳片，其包含（a）碳纤维和（b）包含碳颗粒并与碳纤维整体结合的具有连续通孔的碳基体。 该电极可用作电池的阴极或阳极。 这种类型的电极通过将酚醛树脂沉积在包含酚醛树脂纤维的酚醛树脂片上并在酚醛树脂和酚醛树脂片中在500℃至3000℃的温度范围内的无氧气氛中进行碳化来制备。 C。
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公开(公告)号：US5348818A
公开(公告)日：1994-09-20
申请号：US006498
申请日：1993-01-21
申请人： Keiichi Asami , Hideki Takahashi , Katsuo Inoue , Yoshiaki Echigo , Toshiyuki Ohsawa , Toshiyuki Kabata
发明人： Keiichi Asami , Hideki Takahashi , Katsuo Inoue , Yoshiaki Echigo , Toshiyuki Ohsawa , Toshiyuki Kabata
IPC分类号： D01F9/28 , H01M4/02 , H01M4/137 , H01M4/58 , H01M4/587 , H01M4/60 , H01M4/62 , H01M10/0525 , H01M10/0562 , H01M10/36 , C01B31/02
CPC分类号： H01M4/587 , D01F9/28 , H01M10/0525 , H01M4/02 , H01M4/60 , H01M4/624 , H01M10/0562 , H01M4/137 , H01M4/625
摘要： The present invention provides a carbonaceous material suitable for an electrode of a secondary cell. The carbonaceous material has a specific surface area by BET method of at least 10 m.sup.2 /g and a nitrogen/carbon atom weight ratio of 0.15 to 0.01, and is obtained by heat-treating a polyimide polymer having repeating units represented by: ##STR1## wherein R represents a 4 valent aromatic residue having at least one aromatic ring, of which each 2 valences are bonded with an adjacent carbon atom in the aromatic ring, R' represents a divalent aromatic residue having 1 to 4 aromatic rings and n is an integer of at least 2. The present invention also provides a secondary cell using the above mentioned carbonaceous material as electrode.
摘要翻译： 本发明提供适用于二次电池电极的碳质材料。 碳质材料的比表面积通过BET法为至少10m 2 / g，氮/碳原子重量比为0.15〜0.01，通过热处理具有以下的重复单元的聚酰亚胺聚合物得到：＆lt; IMAGE＆gt; （1）其中R表示具有至少一个芳环的4价芳族残基，其中每个2价与芳环中的相邻碳原子键合，R'表示具有1至4个芳环的二价芳族残基和n 是至少为2的整数。本发明还提供了使用上述碳质材料作为电极的二次电池。
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公开(公告)号：US5489492A
公开(公告)日：1996-02-06
申请号：US285121
申请日：1994-08-01
申请人： Keiichi Asami , Hideki Takahashi , Katsuo Inoue , Yoshiaki Echigo , Toshiyuki Ohsawa , Toshiyuki Kabata , Okitoshi Kimura
发明人： Keiichi Asami , Hideki Takahashi , Katsuo Inoue , Yoshiaki Echigo , Toshiyuki Ohsawa , Toshiyuki Kabata , Okitoshi Kimura
摘要： The present invention provides a composite sheet electrode which has high strength, excellent current collecting properties and which is used efficiently as an active material for an electrode. The electrode has excellent discharge capacities and can be easily formed into an electrode terminal. A cell employing this electrode is also disclosed. The invention also provides a composite sheet electrode having a porosity of 20 to 80% containing 5 to 95% by weight of an active material of an electrode, 1 to 50% by weight of a current collecting material and heat fusible short fibers. The present invention also provides a composite sheet electrode having a porosity of 20 to 80%, which is made up of a composite sheet containing 5 to 95% by weight of an active material as an electrode and 5 to 95% by weight of heat fusible short fibers, as well as a current collecting material layer formed on said composite sheet. The present invention further provides a cell employing the latter-mentioned composite sheet electrode.
摘要翻译： 本发明提供一种复合片状电极，它具有高强度，优异的集电性能，并被有效地用作电极的活性材料。 电极具有优异的放电容量，并且可以容易地形成电极端子。 还公开了采用该电极的电池。 本发明还提供一种孔隙率为20〜80％的复合片状电极，含有5〜95重量％的电极活性物质，1〜50重量％的电流收集材料和热熔短纤维。 本发明还提供一种孔隙率为20〜80％的复合片状电极，其由含有5〜95重量％的作为电极的活性物质和5〜95重量％的热熔体的复合片材构成 短纤维，以及形成在所述复合片材上的集电材料层。 本发明还提供一种使用后者的复合片电极的电池。
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公开(公告)号：US4778695A
公开(公告)日：1988-10-18
申请号：US915286
申请日：1986-10-03
申请人： Yoshiaki Echigo , Mutsunori Yamao , Yoshiyuki Suematu , Tadashi Ishikura , Keiichi Asami , Ritsuko Shidei
发明人： Yoshiaki Echigo , Mutsunori Yamao , Yoshiyuki Suematu , Tadashi Ishikura , Keiichi Asami , Ritsuko Shidei
CPC分类号： C08J3/124 , C08J3/14 , C08K3/16 , C08J2361/06 , Y10T428/2989
摘要： A resole resin in the form of microspherical particles whose surfaces are partly or entirely covered with a coating of a substantially water-insoluble inorganic salt and which are not larger than 500 .mu.m in size, and a process for producing such resole resin. The resole resin comprises solid particles that are highly heat reactive and can be stored in a stable manner for a prolonged period. The resin particles can be used with good results in all fields of applications (e.g., moldings, laminations and binders) where conventional phenolic resins are used.
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5.发明授权
公开(公告)号：US4748214A
公开(公告)日：1988-05-31
申请号：US862728
申请日：1986-05-13
申请人： Keiichi Asami , Yoshiaki Echigo , Mutsunori Yamao , Yoshiyuki Suematu , Tadashi Ishikura , Ritsuko Shidei
发明人： Keiichi Asami , Yoshiaki Echigo , Mutsunori Yamao , Yoshiyuki Suematu , Tadashi Ishikura , Ritsuko Shidei
CPC分类号： C08J3/16 , C08G8/08 , C08L61/06 , C08J2361/06
摘要： A process for producing microspherical cured phenolic resin particles having a particle diameter of not more than about 100 .mu.m, which comprises reacting a novolak resin, a phenol and an aldehyde in an aqueous medium in the presence of a basic catalyst and an emulsion stabilizer. Novel microspherical cured phenolic resin particles are produced by this process. The resin particles have excellent impact strength and mechanical properties, a sharp particle size distribution, and a low secondary agglomerate content, and because of these properties, are useful as an excellent modifier or filler for various plastics and rubbers.
摘要翻译： 一种制备粒径不超过约100μm的微球固化酚醛树脂颗粒的方法，包括在碱性催化剂和乳液稳定剂存在下，在水性介质中使酚醛清漆树脂，酚和醛反应。 通过该方法生产新型微球固化酚醛树脂颗粒。 树脂颗粒具有优异的冲击强度和机械性能，尖锐的粒度分布和低的二次附聚物含量，并且由于这些性质，可用作各种塑料和橡胶的优异的改性剂或填料。
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6.发明授权
公开(公告)号：US4640971A
公开(公告)日：1987-02-03
申请号：US755769
申请日：1985-07-17
申请人： Yoshiaki Echigo , Mutsunori Yamao , Yoshiyuki Suematu , Tadashi Ishikura , Keiichi Asami , Ritsuko Shidei
发明人： Yoshiaki Echigo , Mutsunori Yamao , Yoshiyuki Suematu , Tadashi Ishikura , Keiichi Asami , Ritsuko Shidei
CPC分类号： C08J3/124 , C08J3/14 , C08K3/16 , C08J2361/06 , Y10T428/2989
摘要： A resole resin in the form of microspherical particles whose surfaces are partly or entirely covered with a coating of a substantially water-insoluble inorganic salt and which are not larger than 500 .mu.m in size, and a process for producing such resole resin. The resole resin comprises solid particles that are highly heat reactive and can be stored in a stable manner for a prolonged period. The resin particles can be used with good results in all fields of applications (e.g., moldings, laminations and binders) where conventional phenolic resins are used.
摘要翻译： 其表面部分或全部被基本上不溶于水的无机盐的涂层覆盖并且尺寸不大于500μm的微球形颗粒形式的甲阶酚醛树脂和制备这种甲阶酚醛树脂的方法。 甲阶酚醛树脂包括高热反应性的固体颗粒，并且可以以稳定的方式长时间储存。 树脂颗粒可以在使用常规酚醛树脂的所有应用领域（例如，模制品，叠片和粘合剂）中使用良好的结果。
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7.发明授权Spherical particles of thermosetting phenolic resin and process for producing the same 失效热固性酚醛树脂的球形颗粒及其制备方法
公开(公告)号：US4839445A
公开(公告)日：1989-06-13
申请号：US141167
申请日：1988-01-06
申请人： Yoshiaki Echigo , Kenichi Sugawara , Mutsunori Yamao , Yoshiyuki Suematu , Keiichi Asami , Tuneyuki Ohsawa
发明人： Yoshiaki Echigo , Kenichi Sugawara , Mutsunori Yamao , Yoshiyuki Suematu , Keiichi Asami , Tuneyuki Ohsawa
CPC分类号： C08J3/16 , C08J2361/06
摘要： The present invention relates to a process for producing spherical thermosetting phenolic resin particles having a size of no larger than about 1,000 microns, and the spherical thermosetting phenolic resin particles produced by this process.In accordance with the process of the present invention, a novolak resin, and a nitrogenous basic compound, and, optionally, an aldehyde, are reacted while they are suspended in an aqueous medium in the presence of a suspension stabilizer.The thermosetting phenolic resin produced by the process of the present invention not only displays superior thermal curing characteristics during molding; the cured product fabricated by molding this resin also exhibits good physical properties such as improved mechanical strength and heat resistance. Therefore, the spherical thermosetting phenolic resin particles produced by the process of the present invention can be extensively used as molding materials, binders, adhesives, and in many other applications.
摘要翻译： 本发明涉及一种制造尺寸不大于约1,000微米的球形热固性酚醛树脂颗粒的方法和通过该方法制备的球形热固性酚醛树脂颗粒。 根据本发明的方法，在悬浮稳定剂存在下将酚醛清漆树脂和含氮碱性化合物以及任选的醛反应在水性介质中。 通过本发明的方法制备的热固性酚醛树脂不仅在成型期间显示出优异的热固化特性; 通过模塑该树脂制造的固化产物也表现出良好的物理性能，例如改进的机械强度和耐热性。 因此，通过本发明的方法制造的球形热固性酚醛树脂颗粒可以广泛用作模塑材料，粘合剂，粘合剂以及许多其它应用。
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公开(公告)号：US5906712A
公开(公告)日：1999-05-25
申请号：US262370
申请日：1994-06-20
申请人： Keiichi Asami , Kiyotaka Nakanishi , Hideki Takahashi , Ritsuko Shidei , Azusa Yamagata , Yoshiaki Echigo
发明人： Keiichi Asami , Kiyotaka Nakanishi , Hideki Takahashi , Ritsuko Shidei , Azusa Yamagata , Yoshiaki Echigo
IPC分类号： C08J3/205 , D21H13/40 , D21H13/50 , D21H17/35 , D21H17/48 , D21H21/10 , D21H23/76 , D21H13/36
摘要： The present invention provides a process for producing a fiber reinforced composite which contains the reinforcing fibers uniformly dispersed therein and therefore has uniformity of strength. The process comprises;preparing an aqueous slurry which comprises reinforcing fibers, water-soluble organic polymers A charged in water and particulate organic polymers,adding thereto water-soluble organic polymers B charged opposite to said organic polymers A in water to flocculate the solid components in said aqueous slurry, andthen removing aqueous medium and molding.
摘要翻译： 本发明提供一种纤维增强复合材料的制造方法，该复合材料含有均匀分散在其中的增强纤维，因此具有强度均匀性。 该过程包括 制备含水浆料，其包含增强纤维，加入水中的水溶性有机聚合物A和颗粒状有机聚合物，向水中加入与所述有机聚合物A相对的水溶性有机聚合物B，以絮凝所述含水浆料中的固体组分， 然后除去水性介质并成型。
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公开(公告)号：US5817423A
公开(公告)日：1998-10-06
申请号：US607636
申请日：1996-02-27
申请人： Hiroshi Kajimaru , Keiichi Asami , Yoshiaki Iwaya , Yoshiaki Echigo , Akira Ito
发明人： Hiroshi Kajimaru , Keiichi Asami , Yoshiaki Iwaya , Yoshiaki Echigo , Akira Ito
CPC分类号： H01C7/027 , H01C17/06573 , Y10T428/31678 , Y10T428/31692 , Y10T428/31855
摘要： A PTC element comprising a conductive sheet of a crystalline polyolefin matrix and a conductive filler, having provided on both sides thereof an electrode of a metallic foil, the PTC element having a resistivity at 20.degree. C. (.rho..sub.20) of not more than 1.8 .OMEGA..multidot.cm, a peak resistivity (.rho..sub.p) of not less than 2.0.times.10.sup.6 .OMEGA..multidot.cm, and a temperature difference �T.sub.a (0.degree.C.)-T.sub.b (.degree.C.)! of not greater than 10.degree. C., wherein T.sub.a (.degree.C.) is a temperature at which the resistivity is 10.sup.6 times the resistivity at 20.degree. C. (.rho..sub.20) and T.sub.b (.degree.C.) is a temperature at which the resistivity is 10 times the resistivity at 20.degree. C. (.rho..sub.20). The PTC element is produced by a process comprising mixing a crystalline polyolefin and a conductive filler, molding the mixture into a conductive sheet, press bonding under heat a metallic foil to both sides of the conductive sheet, and repeatedly subjecting the conductive sheet to a heating and cooling cycle consisting of heating at a temperature of not lower than (the melting point of the crystalline polyolefin minus 5.degree. C.) and then cooling to a temperature lower than (the melting point of the crystalline polyolefin minus 5.degree. C.). The PTC elements exhibit an extremely low resistivity at 20.degree. C. and a high resistivity at a peak temperature, showing a very steep increase in resistance in a narrow temperature range.
摘要翻译： 一种PTC元件，包括结晶聚烯烃基质和导电填料的导电片，其两侧均设有金属箔的电极，PTC元件的电阻率在20℃（rho 20）不大于1.8 OMEGA xcm，峰值电阻率（rho p）不小于2.0×10 6欧姆×xcm，温度差[Ta（0℃）-Tb（℃）]为10℃以下，其中Ta （℃）是电阻率为20℃时电阻率的106倍的温度（rho 20），Tb（℃）是电阻率为20℃电阻率10倍的温度。 （rho 20）。 PTC元件通过包括混合结晶聚烯烃和导电填料的方法制备，将该混合物成型为导电片，在导热片的两侧将金属箔加热压接，并重复地对导电片进行加热 和冷却循环由不低于（结晶聚烯烃的熔点减去5℃）的温度加热，然后冷却到低于（结晶聚烯烃的熔点减去5℃）的温度。 PTC元件在20℃下表现出非常低的电阻率，在峰值温度下表现出高电阻率，表现出在窄温度范围内电阻非常陡峭的增加。
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10.发明授权Composite carrier particles for electrophotography and process for producing the same 失效用于电摄影的复合载体颗粒及其制造方法
公开(公告)号：US5108862A
公开(公告)日：1992-04-28
申请号：US480492
申请日：1990-02-16
申请人： Souichiro Kishimoto , Tsutomu Sakaida , Yoshiaki Echigo , Keiichi Asami , Tetsuro Toda , Kazuo Fujioka , Eiichi Kurita , Toshiyuki Hakata , Shigeru Takaragi
发明人： Souichiro Kishimoto , Tsutomu Sakaida , Yoshiaki Echigo , Keiichi Asami , Tetsuro Toda , Kazuo Fujioka , Eiichi Kurita , Toshiyuki Hakata , Shigeru Takaragi
CPC分类号： G03G9/1075 , G03G9/10 , G03G9/1135
摘要： Disclosed herein are composite carrier particles for electrophotography comprising 80 to 99% by weight of ferromagnetic fine particles and a phenol resin, and having a number-average particle diameter of 10 to 1,000 .mu.m, a bulk density of not more than 2.0 g /cm.sup.3, and a curved surface configuration, and a process for producing the same.
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