公开(公告)号：US07608709B2

公开(公告)日：2009-10-27

申请号：US11359369

申请日：2006-02-23

申请人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Keitaro Sugita

发明人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Keitaro Sugita

IPC分类号： C07F9/535

CPC分类号： C07F15/008 ,  C07F9/650952

摘要： An optically active 2,3-bis(dialkylphosphino)pyrazine derivative represented by formula (1) is disclosed. The pyrazine derivative is preferably a quinoxaline derivative represented by formula (2). In formula (1) and (2), R1 is preferably a t-butyl or adamantyl group, and R2 is preferably a methyl group. wherein R1 is a substitutable straight chain or branched alkyl group having 2 to 10 carbon atoms; R2 is a substitutable straight chain or branched alkyl group having fewer carbon atoms than R1; and R3 and R4, which may be the same or different, are each a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, or R3 and R4 are taken together to form a saturated or unsaturated ring. wherein R1 and R2 are as defined above; and R5 is a monovalent substituent.

摘要翻译： 公开了由式（1）表示的光学活性2,3-双（二烷基膦基）吡嗪衍生物。 吡嗪衍生物优选为式（2）表示的喹喔啉衍生物。 在式（1）和（2）中，R1优选为叔丁基或金刚烷基，R2优选为甲基。 其中R1是具有2-10个碳原子的可取代的直链或支链烷基; R2是具有比R1少的碳原子的可取代的直链或支链烷基; 和可以相同或不同的R 3和R 4各自为氢原子或具有1至6个碳原子的烷基，或者R 3和R 4一起形成饱和或不饱和的环。 其中R1和R2如上所定义; R5是一价取代基。

公开(公告)号：US20070021610A1

公开(公告)日：2007-01-25

申请号：US11359369

申请日：2006-02-23

申请人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Keitaro Sugita

发明人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Keitaro Sugita

IPC分类号： C07F15/00 ,  C07F9/6509

CPC分类号： C07F15/008 ,  C07F9/650952

摘要： An optically active 2,3-bis(dialkylphosphino)pyrazine derivative represented by formula (1) is disclosed. The pyrazine derivative is preferably a quinoxaline derivative represented by formula (2). In formula (1) and (2), R1 is preferably a t-butyl or adamantyl group, and R2 is preferably a methyl group. wherein R1 is a substituted or unsubstituted, straight chain or branched alkyl group having 2 to 10 carbon atoms; R2 is a substituted or unsubstituted, straight chain or branched alkyl group having fewer carbon atoms than R1; and R3 and R4, which may be the same or different, are each a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, or R3 and R4 are taken together to form a saturated or unsaturated ring. wherein R1 and R2 are as defined above; and R5 is a monovalent substituent.

摘要翻译： 公开了由式（1）表示的光学活性2,3-双（二烷基膦基）吡嗪衍生物。 吡嗪衍生物优选为式（2）表示的喹喔啉衍生物。 式（1）和（2）中，R 1优选为叔丁基或金刚烷基，R 2优选为甲基。 其中R 1是具有2至10个碳原子的取代或未取代的直链或支链烷基; R 2是具有比R 1更少的碳原子的取代或未取代的直链或支链烷基; R 3和R 4可以相同或不同，分别为氢原子或具有1-6个碳原子的烷基，或R“ 3和R 4一起形成饱和或不饱和的环。 其中R 1和R 2如上定义; R 5是一价取代基。

公开(公告)号：US20080221362A1

公开(公告)日：2008-09-11

申请号：US12073415

申请日：2008-03-05

申请人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Youichi Saitoh ,  Aya Koide

发明人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Youichi Saitoh ,  Aya Koide

IPC分类号： C07F9/54

CPC分类号： C07F9/5027 ,  C07B53/00 ,  C07F9/5013

摘要： An optically-active bis(alkynylphosphino)ethane-borane derivative represented by formula (1): wherein R1 and R2, which may be the same or different, each represent an alkyl group, a phenyl group, an alkylsilyl group or a hydrogen atom; R3 represents a branched alkyl group, an alicyclic hydrocarbon group or an aromatic hydrocarbon group; and the asterisk * indicates an optically-active site. The derivative (1) is prepared by bromination of, e.g., an (S)-t-butylmethylphosphine-borane, reaction with an alkynyl lithium, deprotonation, followed by oxidative coupling. Deprotection of the derivative (1) by deboranation gives an optically-active bis(alkynylphosphino)ethane derivative useful as a ligand providing an asymmetric catalyst for catalytic asymmetric synthesis. The asymmetric catalyst having the ligand exhibits high selectivity and catalyst activity.

摘要翻译： 由式（1）表示的光学活性双（炔基膦基）乙烷 - 硼烷衍生物：其中R 1和R 2可以相同或不同，表示 烷基，苯基，烷基甲硅烷基或氢原子; R 3表示支链烷基，脂环族烃基或芳香族烃基; 星号*表示光学活性位点。 衍生物（1）通过例如（S） - 叔丁基甲基膦 - 硼烷的溴化，与炔基锂的反应，去质子化，然后进行氧化偶联来制备。 衍生物（1）通过脱硼脱保护得到用作催化不对称合成的不对称催化剂的配体的光学活性双（炔基膦基）乙烷衍生物。 具有配体的不对称催化剂表现出高选择性和催化剂活性。

公开(公告)号：US07649117B2

公开(公告)日：2010-01-19

申请号：US12179088

申请日：2008-07-24

申请人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Miwako Nishimura ,  Aya Koide

发明人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Miwako Nishimura ,  Aya Koide

IPC分类号： C07C45/65

CPC分类号： C07C45/64 ,  C07B53/00 ,  C07B2200/07 ,  C07C67/31 ,  C07C231/12 ,  C07C231/16 ,  C07C69/675 ,  C07C69/732 ,  C07C69/734 ,  C07C235/06

摘要： Disclosed is a process of preparing an optically active β-hydroxycarboxylic acid derivative comprising asymmetrically hydrogenating a β-keto compound in the presence of a catalyst comprising a transition metal complex compound having a 2,3-bis(dialkylphosphino)pyrazine derivative as a ligand. The pyrazine derivative is preferably a quinoxaline derivative, and the transition metal is preferably ruthenium. Preferred examples of the quinoxaline derivative are (S,S)-2,3-bis(tert-butylmethylphosphino)quinoxaline, (R,R)-bis(tert-butylmethylphosphino)quinoxaline, (S,S)-bis(tert-adamantylmethylphosphino)quinoxaline, and (R,R)-bis(adamantylmethylphosphino)quinoxaline.

摘要翻译： 公开了一种制备光学活性β-羟基羧酸衍生物的方法，包括在包含具有2,3-双（二烷基膦基）吡嗪衍生物作为配体的过渡金属络合物的催化剂存在下不对称氢化β-酮化合物的方法。 吡嗪衍生物优选为喹喔啉衍生物，过渡金属优选为钌。 喹喔啉衍生物的优选实例是（S，S）-2,3-双（叔丁基甲基膦基）喹喔啉，（R，R） - 双（叔丁基甲基膦基）喹喔啉，（S，S） - 双（叔 - 金刚烷基甲基膦基 ）喹喔啉和（R，R） - 双（金刚烷基甲基膦基）喹喔啉。

公开(公告)号：US07534920B2

公开(公告)日：2009-05-19

申请号：US12073415

申请日：2008-03-05

申请人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Youichi Saitoh ,  Aya Koide

发明人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Youichi Saitoh ,  Aya Koide

IPC分类号： C07F9/02

CPC分类号： C07F9/5027 ,  C07B53/00 ,  C07F9/5013

摘要： An optically-active bis(alkynylphosphino)ethane-borane derivative represented by formula (1): wherein R1 and R2, which may be the same or different, each represent an alkyl group, a phenyl group, an alkylsilyl group or a hydrogen atom; R3 represents a branched alkyl group, an alicyclic hydrocarbon group or an aromatic hydrocarbon group; and the asterisk * indicates an optically-active site. The derivative (1) is prepared by bromination of, e.g., an (S)-t-butylmethylphosphine-borane, reaction with an alkynyl lithium, deprotonation, followed by oxidative coupling. Deprotection of the derivative (1) by deboranation gives an optically-active bis(alkynylphosphino)ethane derivative useful as a ligand providing an asymmetric catalyst for catalytic asymmetric synthesis. The asymmetric catalyst having the ligand exhibits high selectivity and catalyst activity.

摘要翻译： 由式（1）表示的光学活性双（炔基膦基）乙烷 - 硼烷衍生物：其中R1和R2可以相同或不同，各自表示烷基，苯基，烷基甲硅烷基或氢原子; R3表示支链烷基，脂环族烃基或芳香族烃基; 星号*表示光学活性位点。 衍生物（1）通过例如（S） - 叔丁基甲基膦 - 硼烷的溴化，与炔基锂的反应，去质子化，然后进行氧化偶联来制备。 衍生物（1）通过脱硼脱保护得到用作催化不对称合成的不对称催化剂的配体的光学活性双（炔基膦基）乙烷衍生物。 具有配体的不对称催化剂表现出高选择性和催化剂活性。

公开(公告)号：US08076480B2

公开(公告)日：2011-12-13

申请号：US12179069

申请日：2008-07-24

申请人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Miwako Nishimura ,  Aya Koide

发明人： Tsuneo Imamoto ,  Kazuhiro Yoshida ,  Miwako Nishimura ,  Aya Koide

IPC分类号： C07D241/36

CPC分类号： C07C231/12 ,  C07B53/00 ,  C07B2200/07 ,  C07C67/343 ,  C07C209/16 ,  C07C2601/14 ,  C07C69/618 ,  C07C211/08 ,  C07C211/35 ,  C07C233/51

摘要： Disclosed is a process of preparing an optically active allyl compound, e.g., as represented by formula (III): comprising asymmetrically coupling an allyl compound with an organic nucleophilic compound in the presence of a catalyst. The catalyst is preferably a transition metal complex compound having a phosphine ligand. The phosphine ligand is preferably a 2,3-bis(dialkylphosphino)pyrazine derivative. The pyrazine derivative is preferably a quinoxaline derivative. The transition metal is preferably palladium.

摘要翻译： 公开了制备光学活性烯丙基化合物的方法，例如由式（III）表示的方法：包括在催化剂存在下使烯丙基化合物与有机亲核化合物不对称偶合。 催化剂优选为具有膦配体的过渡金属络合物。 膦配体优选为2,3-双（二烷基膦基）吡嗪衍生物。 吡嗪衍生物优选为喹喔啉衍生物。 过渡金属优选为钯。

公开(公告)号：US08797712B2

公开(公告)日：2014-08-05

申请号：US13534000

申请日：2012-06-27

申请人： Hideki Otsuka ,  Kazuhiro Yoshida

发明人： Hideki Otsuka ,  Kazuhiro Yoshida

IPC分类号： H01G4/228 ,  H01G4/06

CPC分类号： H01G2/06 ,  H01G4/228 ,  H01G4/232 ,  H01G4/30 ,  H05K3/3426 ,  H05K2201/10636 ,  H05K2201/10946 ,  Y02P70/611 ,  Y02P70/613

摘要： In a ceramic capacitor, first and second electrode terminals each include a bonded-to-substrate portion, a first bonded-to-electrode portion bonded to a first edge of one of first and second external electrodes, a second bonded-to-electrode portion bonded to a second edge of the one of first and second external electrodes and disposed at a distance from the first bonded-to-electrode portion in the first directions, and a connecting portion connecting the first and second bonded-to-electrode portions and the bonded-to-substrate portion. W1/W0 is about 0.3 or more, and h/L is about 0.1 or more.

摘要翻译： 在陶瓷电容器中，第一和第二电极端子各自包括接合到衬底部分，第一接合电极部分接合到第一和第二外部电极之一的第一边缘，第二接合电极部分 接合到第一外部电极和第二外部电极中的一个的第二边缘并且在第一方向上与第一接合电极部分设置一定距离，以及连接第一和第二接合电极部分和第二接合电极部分的连接部分， 键合到衬底部分。 W1 / W0为约0.3以上，h / L约为0.1以上。

公开(公告)号：US08616775B2

公开(公告)日：2013-12-31

申请号：US13616851

申请日：2012-09-14

申请人： Hayao Watanabe ,  Masaki Kuwahara ,  Kazuhiro Yoshida

发明人： Hayao Watanabe ,  Masaki Kuwahara ,  Kazuhiro Yoshida

IPC分类号： F16C32/00 ,  H02K5/16 ,  G01B7/30

CPC分类号： G01B7/30 ,  F16C19/362 ,  F16C41/007 ,  F16C2300/14

摘要： Provided is a roller bearing device, which is suitable for preventing misdetection of a rotation sensor when a moment load is applied. A thin motor 100 includes a cross roller bearing 14 having an inner ring 14a and an outer ring 14b, a stator 22 supported by the inner ring 14a, a rotor 12 supported by the outer ring 14b, a motor unit 16 that applies rotation torque to the rotor 12, and a resolver 30 that detects a rotation angle position of the rotor 12. The resolver 30, the cross roller bearing 14, and the motor unit 16 are arranged in the recited order from the radially inner side on a radially identical plane.

摘要翻译： 提供一种滚子轴承装置，其适用于在施加力矩载荷时防止旋转传感器错误检测。 薄电动机100包括具有内环14a和外环14b，由内环14a支撑的定子22，由外环14b支撑的转子12的交叉滚子轴承14，将旋转扭矩施加到 转子12和检测转子12的旋转角度位置的旋转变压器30.旋转变压器30，交叉滚子轴承14和马达单元16以径向相同的平面的径向内侧的顺序排列 。

公开(公告)号：US08382934B2

公开(公告)日：2013-02-26

申请号：US13183511

申请日：2011-07-15

申请人： Hiroki Horiguchi ,  Yuji Kimura ,  Kazuhiro Yoshida

发明人： Hiroki Horiguchi ,  Yuji Kimura ,  Kazuhiro Yoshida

IPC分类号： B29C65/02 ,  B32B37/14

CPC分类号： G01P15/18 ,  B81B2201/0235 ,  B81B2203/0118 ,  B81C1/00269 ,  G01P1/023 ,  G01P15/0802 ,  G01P15/123 ,  G01P2015/0828 ,  H01L21/50 ,  H01L23/10 ,  H01L2924/0002 ,  Y10T29/49002 ,  Y10T156/10 ,  H01L2924/00

摘要： A triaxial acceleration sensor which has a structure including a cover joined to a substrate including a mechanically operable functional unit to be sealed, is adapted in such a way that the joined state can be reliably obtained so as to not interfere with a displacement of the functional unit. A sealing frame is made of a heated polyimide on a periphery of an upper main surface of a substrate provided with a functional unit, and a sealing layer made of a polyimide is formed over an entire lower main surface of a cover. For integrating the substrate and the cover so as to seal the functional unit, the sealing frame and the sealing layer are joined to each other by heating and pressurizing the sealing frame and the sealing layer at a temperature that is about 50° C. to about 150° C. higher than a glass transition temperature of the polyimide while bringing the sealing frame and the sealing layer into contact with each other. In this case, a recess is formed in the vicinity of a portion of the sealing layer to be brought into contact with the sealing frame so that a bump, generated from the sealing layer which is deformed in the joining step, is prevented from protruding toward the functional unit.

摘要翻译： 一种三轴加速度传感器，其具有包括接合到包括要被密封的机械可操作功能单元的基板的盖的结构，使得可以可靠地获得接合状态，以便不干扰功能的位移 单元。 密封框架由设置有功能单元的基板的上主表面的周边上的加热的聚酰亚胺制成，并且在盖的整个下主表面上形成由聚酰亚胺制成的密封层。 为了整合基板和盖以便密封功能单元，密封框架和密封层通过在约50℃到约50℃的温度下加热和加压密封框架和密封层而彼此接合 比使聚酰亚胺的玻璃化转变温度高150℃，同时使密封框和密封层相互接触。 在这种情况下，在密封层的一部分附近形成凹部以与密封框架接触，从而防止在接合步骤中变形的密封层产生的凸块朝向 功能单元。

公开(公告)号：US08367792B2

公开(公告)日：2013-02-05

申请号：US13455442

申请日：2012-04-25

申请人： Nobumasa Ootake ,  Kazuhiro Yoshida ,  Kenichi Watanabe ,  Yasuhito Yamaryo

发明人： Nobumasa Ootake ,  Kazuhiro Yoshida ,  Kenichi Watanabe ,  Yasuhito Yamaryo

IPC分类号： C08G77/16

CPC分类号： C08G77/04 ,  C08G77/14

摘要： A polysiloxane represented by the formula (1) or (2): where R, R1, R2, m and n are defined in the specification.

摘要翻译： 由式（1）或（2）表示的聚硅氧烷：其中R，R 1，R 2，m和n在说明书中定义。