Nylon copolymers containing dimeric acid comonomers
    1.
    发明授权
    Nylon copolymers containing dimeric acid comonomers 有权
    含有二聚酸共聚单体的尼龙共聚物

    公开(公告)号:US06835800B2

    公开(公告)日:2004-12-28

    申请号:US10325866

    申请日:2002-12-23

    IPC分类号: C08G6926

    CPC分类号: C08G69/34

    摘要: A method for preparing a nylon 6 copolymer containing dimeric acid comonomers. The method includes reacting 80.0˜99.9 mol % of caprolactam, 0.1˜3.0 mol % of dimeric acid and 0.1˜3.0 mol % of 2-methyl-1,5-pentadiamine in a polymerization reaction. Moreover, the invention provides a method for preparing a nylon 66 copolymer containing dimeric acid comonomers, which comprising reacting 60.0˜90 mol % of hexadiacid and hexadiamine, 0.1˜3.0 mol % of dimeric acid and 0.1-3.0 mol % of 2-methyl-1,5-pentadiamine in a polymerization reaction. The reaction temperature for both of the methods are at 200˜280° C.

    摘要翻译: 一种制备含有二聚酸共聚单体的尼龙6共聚物的方法。 该方法包括在聚合反应中使80.0〜99.9mol%的己内酰胺,0.1〜3.0mol%的二聚酸和0.1〜3.0mol%的2-甲基-1,5-五胺。 此外,本发明提供一种制备含二聚酸共聚单体的尼龙66共聚物的方法,其包括使60.0〜90摩尔%的六己酸和己二胺,0.1〜3.0摩尔%的二聚酸和0.1-3.0摩尔%的2-甲基 - 1,5-戊二胺在聚合反应中。 两种方法的反应温度为200〜280℃

    Method for preparing nylon 6 copolymer containing sulfonate comonomers
    2.
    发明授权
    Method for preparing nylon 6 copolymer containing sulfonate comonomers 有权
    制备含有磺酸共聚单体的尼龙6共聚物的方法

    公开(公告)号:US06812324B2

    公开(公告)日:2004-11-02

    申请号:US10325857

    申请日:2002-12-23

    IPC分类号: C08G6928

    CPC分类号: C08G69/265

    摘要: A method for preparing nylon 6 copolymer containing 5-sulfoisophthalate salts comonomer. The method includes the steps of reacting 5-sulfoisophthalate salts ester with aliphatic diamine in a molar ratio of 2˜20 at 160˜200° C., followed by completely removing the unreacted aliphatic diamine, to obtain the intermediate compound with terminal amine, 5-sulfobenzenediamide compound (formula III). Next, caprolactam and aliphatic diacid (formula IV) are reacted at 200˜260° C. to form an oligomer with a low molecular weight. 5-Sulfobenzenediamide (formula III) and catalyst are then added into the oligomer obtained in previous step to cause a polymerization reaction at 200˜280° C. to obtain nylon 6 copolymer containing 5-sulfoisophthalate salt comonomer. The molar ratio of E/C is 0.005˜0.150 and the molar ratio of D/E is 1.05-1.00. Compounds present in the water extract are greatly reduced.

    摘要翻译: 一种制备含5-磺基间苯二甲酸盐共聚单体的尼龙6共聚物的方法。 该方法包括在160〜200℃下使5-磺基间苯二甲酸盐酯与摩尔比为2〜20的脂肪族二胺反应,然后将未反应的脂肪族二胺完全除去,得到末端胺的中间体化合物5 - 磺基二苯胺二胺化合物(式III)。 接着,将己内酰胺和脂肪族二酸(式Ⅳ)在200〜260℃反应,形成低分子量低聚物。 然后将5-磺基苯二甲酰胺(式III)和催化剂加入到前一步骤中获得的低聚物中,以在200〜280℃进行聚合反应,得到含有5-磺基间苯二甲酸盐共聚单体的尼龙6共聚物。 E / C摩尔比为0.005〜0.150,D / E摩尔比为1.05〜1.00。 存在于水提取物中的化合物大大降低。

    Activated carbon fibers and precursor material thereof
    3.
    发明授权
    Activated carbon fibers and precursor material thereof 有权
    活性碳纤维及其前体材料

    公开(公告)号:US08030407B2

    公开(公告)日:2011-10-04

    申请号:US11892639

    申请日:2007-08-24

    IPC分类号: C08L39/04

    摘要: An activated carbon fiber for fabricating a supercapacitor electrode and its precursor material are provided. The precursor material of the activated carbon fiber includes polyacrylonitrile (PAN) and a polymer having formula (I): wherein R1 is cyano, phenyl, acetate, or methoxycarbonyl, R2 is  R3 is C1-7 alkyl, X is chlorine, bromine, tetrafluoroborate (BF4), hexafluorophosphate (PF6), or NH(SO2CH3)2, and m/n is 1-99/99-1.

    摘要翻译: 提供用于制造超级电容器电极的活性炭纤维及其前体材料。 活性炭纤维的前体材料包括聚丙烯腈(PAN)和具有式(I)的聚合物:其中R1是氰基,苯基,乙酸酯或甲氧基羰基,R2是R3是C1-7烷基,X是氯,溴,四氟硼酸根 (BF4),六氟磷酸盐(PF6)或NH(SO2CH3)2,m / n为1-99 / 99-1。

    Free radical polymerization process and polymers obtained thereby
    4.
    发明授权
    Free radical polymerization process and polymers obtained thereby 有权
    自由基聚合方法和由此获得的聚合物

    公开(公告)号:US07514511B2

    公开(公告)日:2009-04-07

    申请号:US11216154

    申请日:2005-09-01

    IPC分类号: C08F2/04 C08F26/06 C08F20/54

    摘要: Free radical polymerization process for preparing polymers with low polydispersity index and polymers obtained thereby. The process includes polymerizing at least one reactive monomer with at least one initiator and at least one ionic liquid (serving as solvent) to obtain polymers having a low polydispersity index of less than 1.5, wherein the reactive monomer is a nitrogen-containing monomer. In addition, the free radical polymerization processes have reaction time within 3 hours.

    摘要翻译: 用于制备具有低多分散指数的聚合物的自由基聚合方法和由此得到的聚合物。 该方法包括使至少一种反应性单体与至少一种引发剂和至少一种离子液体(用作溶剂)聚合以获得低分子量指数小于1.5的聚合物,其中反应性单体是含氮单体。 此外,自由基聚合方法在3小时内具有反应时间。

    Aliphatic copolyesters and method of preparing the same
    5.
    发明授权
    Aliphatic copolyesters and method of preparing the same 有权
    脂肪族共聚酯及其制备方法

    公开(公告)号:US08022169B2

    公开(公告)日:2011-09-20

    申请号:US12104480

    申请日:2008-04-17

    IPC分类号: C08G63/42 C08G63/08

    摘要: A method of preparing an aliphatic copolyester by mixing a first compound defined by the equation: and a catalyst, and adding a second compound defined by and a lactide, wherein the second compound and the lactide have a total weight less than the first compound, wherein a is 10-230, b, d and e have a ratio of 10-35:10-35:80-30, c is 1-4, and f is 1-10. The method further adds the second compound and the lactide, wherein the second compound and the lactide have a total weight less than the first compound, the second compound and the lactide in the prior mixing step. The method further adds the second compound and the lactide, wherein the second compound and the lactide have a total weight less than the first compound, the second compound and the lactide in of the prior mixing steps.

    摘要翻译: 通过将由下式定义的第一化合物与催化剂混合制备脂肪族共聚酯的方法,并加入由丙交酯定义的第二化合物,其中第二化合物和丙交酯的总重量小于第一化合物,其中 a为10-230,b,d和e的比例为10-35:10-35:80-30,c为1-4,f为1-10。 该方法进一步添加第二化合物和丙交酯,其中第二化合物和丙交酯的总重量小于先前混合步骤中的第一化合物,第二化合物和丙交酯。 该方法进一步添加第二化合物和丙交酯,其中第二化合物和丙交酯的总重量小于先前混合步骤中的第一化合物,第二化合物和丙交酯。

    Activated carbon fibers and precursor material thereof
    6.
    发明申请
    Activated carbon fibers and precursor material thereof 有权
    活性碳纤维及其前体材料

    公开(公告)号:US20080287607A1

    公开(公告)日:2008-11-20

    申请号:US11892639

    申请日:2007-08-24

    IPC分类号: C08L39/04

    摘要: An activated carbon fiber for fabricating a supercapacitor electrode and its precursor material are provided. The precursor material of the activated carbon fiber includes polyacrylonitrile (PAN) and a polymer having formula (I): wherein R1 is cyano, phenyl, acetate, or methoxycarbonyl, R2 is R3 is C1-7 alkyl, X is chlorine, bromine, tetrafluoroborate (BF4), hexafluorophosphate (PF6), or NH(SO2CH3)2, and m/n is 1-99/99-1.

    摘要翻译: 提供用于制造超级电容器电极的活性炭纤维及其前体材料。 活性碳纤维的前体材料包括聚丙烯腈(PAN)和具有式(I)的聚合物:其中R 1是氰基,苯基,乙酸酯或甲氧基羰基,R 2 是R 3是C 1-7烷基,X是氯,溴,四氟硼酸盐(BF 4 N 4),六氟磷酸盐(PF 3) 6)或NH(SO 2 CH 3)2,m / n为1-99 / 99-1 。

    Polypropylene derivatives and preparation thereof
    7.
    发明申请
    Polypropylene derivatives and preparation thereof 审中-公开
    聚丙烯衍生物及其制备方法

    公开(公告)号:US20080161498A1

    公开(公告)日:2008-07-03

    申请号:US11907593

    申请日:2007-10-15

    IPC分类号: C08F255/08 C08F4/04 C08F4/30

    摘要: A polypropylene derivative is provided. The polypropylene derivative includes a reactive monomer grafted on polypropylene, with a grafting yield exceeding 5%. A method of preparing the polypropylene derivative is also disclosed. The method includes mixing a reactive monomer, polypropylene, and a compatibilizer in a twin screw extruder to prepare a polypropylene derivative with reactive monomers grafted thereon, with a grafting ratio exceeding 5%.

    摘要翻译: 提供聚丙烯衍生物。 聚丙烯衍生物包括接枝在聚丙烯上的反应性单体,接枝率超过5%。 还公开了制备聚丙烯衍生物的方法。 该方法包括在双螺杆挤出机中混合反应性单体,聚丙烯和增容剂以制备接枝反应性单体的聚丙烯衍生物,接枝率超过5%。

    POLYPROPYLENE DERIVATIVES AND PREPARATION THEREOF
    9.
    发明申请
    POLYPROPYLENE DERIVATIVES AND PREPARATION THEREOF 审中-公开
    聚丙烯衍生物及其制备方法

    公开(公告)号:US20080242803A1

    公开(公告)日:2008-10-02

    申请号:US12135476

    申请日:2008-06-09

    摘要: A polypropylene derivative is provided. The polypropylene derivative includes a reactive monomer grafted on polypropylene, with a grafting yield exceeding 5%. A method for preparing the polypropylene derivative is also disclosed. The method includes mixing a reactive monomer, polypropylene and a compatibilizer to prepare a polypropylene derivative grafted with the reactive monomer, with a grafting yield exceeding 5%.

    摘要翻译: 提供聚丙烯衍生物。 聚丙烯衍生物包括接枝在聚丙烯上的反应性单体,接枝率超过5%。 还公开了制备聚丙烯衍生物的方法。 该方法包括混合反应性单体,聚丙烯和增容剂以制备接枝反应性单体的聚丙烯衍生物,接枝率大于5%。