公开(公告)号：US20160346773A1

公开(公告)日：2016-12-01

申请号：US14725616

申请日：2015-05-29

Applicant: UOP LLC

Inventor： Richard R. Willis ,  Steven C. Greene

IPC: B01J29/70 ,  B01J37/08 ,  B01J37/00 ,  B01J37/06 ,  B01J35/08 ,  B01J37/04

CPC classification number: B01J37/0072 ,  B01J23/08 ,  B01J29/405 ,  B01J35/08 ,  B01J37/06 ,  B01J37/08 ,  C07C2/76 ,  C07C2529/40 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08

Abstract: A catalyst composite and a process for preparing the catalyst composite are described. The catalyst composite includes a microporous material having a gallium component dispersed thereon; and a hydroxy metal oxide binder, where the metal is zirconium, titanium, or a mixture thereof. The process includes mixing a gelling agent, water, and the hydroxy metal oxide binder precursor to form a solution. The solution is combined with a microporous material to form a slurry, and the slurry is formed into a shaped article. The article is dried to convert the hydroxy metal oxide binder precursor into a hydroxy metal oxide binder and form the catalyst composite.

Abstract translation: 描述了催化剂复合材料和制备催化剂复合材料的方法。 所述催化剂复合体包括其上分散有镓成分的微孔材料; 和羟基金属氧化物粘合剂，其中金属是锆，钛或它们的混合物。 该方法包括混合胶凝剂，水和羟基金属氧化物粘合剂前体以形成溶液。 将溶液与微孔材料结合以形成浆料，并将浆料形成成型制品。 将制品干燥以将羟基金属氧化物粘合剂前体转化为羟基金属氧化物粘合剂并形成催化剂复合材料。

公开(公告)号：US20220023846A1

公开(公告)日：2022-01-27

申请号：US17380667

申请日：2021-07-20

Applicant: UOP LLC

Inventor： Paula Bogdan ,  Melanie Timmons Schaal ,  Susie C. Martins ,  Lisa Knight ,  Wharton Sinkler ,  Gregory Kuzmanich ,  Maureen Bricker ,  Suheil F. Abdo ,  Stuart Miller ,  Wei Pan ,  Richard R. Willis

IPC: B01J29/70 ,  B01J37/04 ,  B01J35/00 ,  B01J37/08 ,  B01J29/08 ,  B01J37/00 ,  C10G47/16

Abstract: A hydroprocessing catalyst with improved performance has been produced that involves an intimately mixed unsupported metal oxide with a zeolite or other acid function. The intimate mixing allows an intimate interaction between the unsupported metal oxide and the acid function. The hydroprocessing catalyst may be used alone or may be incorporated with a portion of a conventional hydrocracking catalyst.

公开(公告)号：US20180371335A1

公开(公告)日：2018-12-27

申请号：US15630297

申请日：2017-06-22

Applicant: UOP LLC

Inventor： Antoine Negiz ,  Shurong Yang ,  Richard R. Willis ,  Gregory J. Gajda ,  Suheil F. Abdo ,  Lisa M. Knight ,  Hayim Abrevaya

IPC: C10G45/64 ,  C10G45/62 ,  C10G45/54 ,  C10G45/72 ,  C10G49/26

CPC classification number: C10G45/64 ,  C10G45/54 ,  C10G45/60 ,  C10G45/62 ,  C10G45/72 ,  C10G47/12 ,  C10G47/18 ,  C10G47/20 ,  C10G49/26

Abstract: A catalyst composition comprising a support comprising a mixture of amorphous silica-alumina and non-zeolitic alumina comprising no more than 75 wt % amorphous silica-alumina and having a ratio of moles of silicon to moles of aluminum in the range of about 0.05 to about 0.50. A first hydrogenation metal comprising platinum, a second hydrogenation metal from Group VIIB or Group VIII of the Periodic Table other than platinum and an optional third metal from Group IA of the Periodic Table may be deposited on the support. The ratio of moles of silicon to the moles of the first hydrogenation metal, the second hydrogenation metal and the optional third metal on the support may be between about 15 and about 75.

公开(公告)号：US20170334746A1

公开(公告)日：2017-11-23

申请号：US15587784

申请日：2017-05-05

Applicant: UOP LLC

Inventor： Rashmi Patwardhan ,  Richard R. Willis ,  Jon E. Ball ,  Paulina Jakubczak ,  Mark G. Riley ,  William C. Schwerin ,  Roberto C. Flores

IPC: C02F1/42 ,  B01J41/10 ,  B01J41/02 ,  C02F101/22 ,  C02F101/10 ,  C02F101/14

Abstract: A composition, process and apparatuses for removal of one or more contaminant anions from water are provided. In an embodiment, the process includes treating the water with a composition comprising a layered metal hydroxy salt, wherein the layered metal hydroxy salt is a compound comprising (a) a metal (b) a framework hydroxide, and (c) a replaceable anion.

公开(公告)号：US10759680B2

公开(公告)日：2020-09-01

申请号：US15587784

申请日：2017-05-05

Applicant: UOP LLC

Inventor： Rashmi Patwardhan ,  Richard R. Willis ,  Jon E. Ball ,  Paulina Jakubczak ,  Mark G. Riley ,  William C. Schwerin ,  Roberto C. Flores

IPC: C02F1/42 ,  B01J41/10 ,  B01J41/02 ,  C02F1/52 ,  C02F101/10 ,  C02F101/14 ,  C02F101/22

Abstract: A composition, process and apparatuses for removal of one or more contaminant anions from water are provided. In an embodiment, the process includes treating the water with a composition comprising a layered metal hydroxy salt, wherein the layered metal hydroxy salt is a compound comprising (a) a metal (b) a framework hydroxide, and (c) a replaceable anion.

公开(公告)号：US20160001265A1

公开(公告)日：2016-01-07

申请号：US14321657

申请日：2014-07-01

Applicant: UOP LLC

Inventor： Richard R. Willis ,  Colleen Costello ,  Jeffrey Noga ,  Paulina Jakubczak

IPC: B01J21/04 ,  C01F7/02 ,  B01J35/10 ,  C07C4/06

CPC classification number: B01J21/04 ,  B01J23/888 ,  B01J35/1019 ,  C01F7/021 ,  C01P2002/60 ,  C01P2006/12 ,  C01P2006/80 ,  C10G45/04 ,  C10G47/12 ,  C10G49/02 ,  C10G2300/70

Abstract: Aluminas with increased surface acidity, methods of making the same, and methods for using the same are provided. In an exemplary embodiment, a method for increasing the surface acidity of an alumina material includes providing an alumina starting material, and processing the alumina starting material under hydrothermal conditions in the presence of one or more organic acids to generate a hydrothermally treated alumina. In this embodiment, the one or more organic acids includes a polyprotic organic acid with a pKa value of about 0 to about 10, and the resulting hydrothermally treated alumina has increased surface acidity relative to the alumina starting material.

Abstract translation: 提供了具有增加的表面酸度的Aluminas，其制备方法及其使用方法。 在一个示例性实施方案中，提高氧化铝材料的表面酸度的方法包括提供氧化铝起始材料，并且在水热条件下在一种或多种有机酸的存在下处理氧化铝起始原料以产生水热处理的氧化铝。 在该实施方案中，一种或多种有机酸包括pKa值为约0至约10的多重有机酸，并且所得水热处理的氧化铝相对于氧化铝起始材料具有增加的表面酸度。

公开(公告)号：US11826738B2

公开(公告)日：2023-11-28

申请号：US17380667

申请日：2021-07-20

Applicant: UOP LLC

Inventor： Paula Bogdan ,  Melanie Timmons Schaal ,  Susie C. Martins ,  Lisa Knight ,  Wharton Sinkler ,  Gregory Kuzmanich ,  Maureen Bricker ,  Suheil F. Abdo ,  Stuart Miller ,  Wei Pan ,  Richard R. Willis

IPC: B01J35/00 ,  B01J29/70 ,  B01J29/08 ,  B01J37/04 ,  C10G49/08 ,  B01J37/00 ,  B01J37/08 ,  C10G47/16

CPC classification number: B01J29/7007 ,  B01J29/084 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/04 ,  B01J37/08 ,  C10G47/16 ,  C10G49/08 ,  C10G2300/1074 ,  C10G2300/70

Abstract: A hydroprocessing catalyst with improved performance has been produced that involves an intimately mixed unsupported metal oxide with a zeolite or other acid function. The intimate mixing allows an intimate interaction between the unsupported metal oxide and the acid function. The hydroprocessing catalyst may be used alone or may be incorporated with a portion of a conventional hydrocracking catalyst.

公开(公告)号：US10472577B2

公开(公告)日：2019-11-12

申请号：US15630297

申请日：2017-06-22

Applicant: UOP LLC

Inventor： Antoine Negiz ,  Shurong Yang ,  Richard R. Willis ,  Gregory J. Gajda ,  Suheil F. Abdo ,  Lisa M. Knight ,  Hayim Abrevaya ,  John A. Petri

IPC: C10G45/64 ,  C10G45/62 ,  C10G45/54 ,  C10G45/72 ,  C10G49/26 ,  C10G45/60 ,  C10G47/12 ,  C10G47/18 ,  C10G47/20

Abstract: A catalyst composition comprising a support comprising a mixture of amorphous silica-alumina and non-zeolitic alumina comprising no more than 75 wt % amorphous silica-alumina and having a ratio of moles of silicon to moles of aluminum in the range of about 0.05 to about 0.50. A first hydrogenation metal comprising platinum, a second hydrogenation metal from Group VIIB or Group VIII of the Periodic Table other than platinum and an optional third metal from Group IA of the Periodic Table may be deposited on the support. The ratio of moles of silicon to the moles of the first hydrogenation metal, the second hydrogenation metal and the optional third metal on the support may be between about 15 and about 75.