公开(公告)号：US11577014B2

公开(公告)日：2023-02-14

申请号：US16506465

申请日：2019-07-09

Applicant: UOP LLC

Inventor： Gregory John Lewis ,  Paulina Jakubczak ,  Julio C. Marte ,  William Christopher Sheets

IPC: A61M1/16 ,  A61M1/28 ,  A61M1/36 ,  B01D15/36 ,  B01D69/02 ,  B01D69/08 ,  B01D69/10 ,  B01J39/02 ,  B01J39/09 ,  B01J39/10 ,  B01J47/12 ,  A61M1/34 ,  B01J47/127

Abstract: A process for removing Sr2+ toxins from bodily fluids is disclosed. The process involves contacting the bodily fluid with an ion exchanger to remove the metal toxins in the bodily fluid, including blood and gastrointestinal fluid. Alternatively, blood can be contacted with a dialysis solution which is then contacted with the ion exchanger. The ion exchangers are represented by the following empirical formula: AmZraTibSncMdSixOy. A composition comprising the above ion exchange compositions in combination with bodily fluids or dialysis solution is also disclosed. The ion exchange compositions may be supported by porous networks of biocompatible polymers such as carbohydrates or proteins.

公开(公告)号：US20210008266A1

公开(公告)日：2021-01-14

申请号：US16506377

申请日：2019-07-09

Applicant: UOP LLC

Inventor： Gregory John Lewis ,  Paulina Jakubczak ,  Julio C. Marte ,  William Christopher Sheets

IPC: A61M1/28 ,  B01D15/36 ,  B01D69/08 ,  B01D69/02 ,  B01J39/02 ,  B01J39/09 ,  B01J47/127 ,  B01J39/26 ,  B01J47/02 ,  B01J47/018

Abstract: A process for removing Co2+, Pb2+, Cd2+ and Cr3+ toxins from bodily fluids is disclosed. The process involves contacting the bodily fluid with an ion exchange composition to remove the metal toxins in the bodily fluid, including blood and gastrointestinal fluid. Alternatively, blood can be contacted with a dialysis solution which is then contacted with the ion exchange composition. The ion exchange compositions are represented by the following empirical formula: AmZraTibSncMdSixOy. A composition comprising the above ion exchange compositions in combination with bodily fluids or dialysis solution is also disclosed. The ion exchange compositions may be supported by porous networks of biocompatible polymers such as carbohydrates or proteins.

公开(公告)号：US09233856B2

公开(公告)日：2016-01-12

申请号：US14186741

申请日：2014-02-21

Applicant: UOP LLC

Inventor： Gregory J. Lewis ,  Paulina Jakubczak ,  Julio C. Marte ,  Susan C. Koster ,  Mark A. Miller ,  Lisa M. Knight ,  Jaime G. Moscoso

IPC: C02F1/42 ,  C02F1/28 ,  B01J20/18 ,  C02F101/20

CPC classification number: C02F1/281 ,  B01J20/186 ,  C02F2001/425 ,  C02F2101/20

Abstract: A process for removing Hg2+ ions from a liquid stream is disclosed. The process involves contacting the liquid stream with specified UOP Zeolitic Materials. These molecular sieves are particularly effective in removing Hg2+ ions from aqueous streams even in the presence of Mg2+ and Ca2+ ions. The effective molecular sieves have an intermediate range of Si/Al ratios between about 2 and 20 and preferably between 3 and 10.

Abstract translation: 公开了从液体流中除去Hg 2+离子的方法。 该方法包括使液体流与指定的UOP沸石材料接触。 即使在Mg2 +和Ca2 +离子存在下，这些分子筛也能从水流中去除Hg2 +离子。 有效分子筛的Si / Al比例介于约2与20之间，优选3至10之间。

公开(公告)号：US08916738B2

公开(公告)日：2014-12-23

申请号：US14224412

申请日：2014-03-25

Applicant: UOP LLC

Inventor： Gregory J. Lewis ,  Lisa M. Knight ,  Paulina Jakubczak ,  Justin E. Stanczyk

IPC: C07C2/66 ,  C07C2/58 ,  C07C5/13 ,  C07C5/22 ,  C07C6/12 ,  C07C2/02 ,  C07C1/00 ,  C07C4/12 ,  C10G47/20 ,  C10G11/04 ,  C10G35/06 ,  C10G45/00 ,  C10G65/04 ,  C10G29/00 ,  C01B39/54 ,  C01B3/26 ,  C07C1/22 ,  C10G11/05

CPC classification number: C10G47/20 ,  C01B3/26 ,  C01B39/54 ,  C07C1/22 ,  C07C2/58 ,  C07C2/66 ,  C07C2529/84 ,  C10G11/05 ,  C07C15/02 ,  C07C15/107

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+ or DEDMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions have the LEV topology and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.

Abstract translation: 已经合成了一系列名为AlPO-67的结晶微孔金属磷酸盐系列。 这些金属磷酸盐由经验式R + rMm2 + EPxSiyOz表示，其中R是有机铵阳离子，例如ETMA +或DEDMA +，M是骨架金属碱土金属或价态2+的过渡金属，E是三价骨架元素，例如 铝或镓。 AlPO-67组合物具有LEV拓扑结构，并且具有用于进行各种烃转化方法的催化性能和用于分离至少一种组分的分离性能。

公开(公告)号：US20140154177A1

公开(公告)日：2014-06-05

申请号：US13690087

申请日：2012-11-30

Applicant: UOP LLC

Inventor： Gregory J. Lewis ,  Lisa M. Knight ,  Paulina Jakubczak ,  Justin E. Stanczyk

IPC: C01B39/54 ,  C07F19/00

CPC classification number: C01B39/54 ,  C01B37/04 ,  C01B37/065 ,  C01B37/08 ,  C07F19/00

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+ or DEDMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions exhibit the LEV framework topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

Abstract translation: 已经合成了一系列名为AlPO-67的结晶微孔金属磷酸盐系列。 这些金属磷酸盐由经验式R + rMm2 + EPxSiyOz表示，其中R是有机铵阳离子，例如ETMA +或DEDMA +，M是骨架金属碱土金属或价态2+的过渡金属，E是三价骨架元素，例如 铝或镓。 AlPO-67组合物表现出LEV框架拓扑结构，并且具有用于进行各种烃转化方法和用于分离至少一种组分的分离性能的催化性质。

公开(公告)号：US08569558B1

公开(公告)日：2013-10-29

申请号：US13690078

申请日：2012-11-30

Applicant: UOP LLC

Inventor： Gregory J. Lewis ,  Lisa M. Knight ,  Paulina Jakubczak ,  Justin E. Stanczyk

IPC: C07C2/66

CPC classification number: C10G47/20 ,  C01B3/26 ,  C01B39/54 ,  C07C1/22 ,  C07C2/58 ,  C07C2/66 ,  C07C2529/84 ,  C10G11/05 ,  C07C15/02 ,  C07C15/107

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+ or DEDMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions have the LEV topology and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.

Abstract translation: 已经合成了一系列名为AlPO-67的结晶微孔金属磷酸盐系列。 这些金属磷酸盐由经验式R + rMm2 + EPxSiyOz表示，其中R是有机铵阳离子，例如ETMA +或DEDMA +，M是骨架金属碱土金属或价态2+的过渡金属，E是三价骨架元素，例如 铝或镓。 AlPO-67组合物具有LEV拓扑结构，并且具有用于进行各种烃转化方法的催化性能和用于分离至少一种组分的分离性质。

公开(公告)号：US11484875B2

公开(公告)日：2022-11-01

申请号：US16506419

申请日：2019-07-09

Applicant: UOP LLC

Inventor： Gregory John Lewis ,  Paulina Jakubczak ,  Julio C. Marte ,  William Christopher Sheets

IPC: B01J20/00 ,  B01J39/02 ,  A61M1/28 ,  A61K45/06

Abstract: A process for removing Hg2+ toxins from bodily fluids is disclosed. The process involves contacting the bodily fluid with a titanium metallate ion exchanger to remove the metal toxins in the bodily fluid, including blood and gastrointestinal fluid. Alternatively, blood can be contacted with a dialysis solution which is then contacted with the ion exchanger. The titanium metallate ion exchangers are represented by the following empirical formula: AmTiNbaSixOy. A composition is provided with the combination of the titanium metallate ion exchanger and bodily fluids or dialysis solutions. Also, provided is an apparatus comprising a matrix and the titanium metallate ion exchanger.

公开(公告)号：US20220096724A1

公开(公告)日：2022-03-31

申请号：US17396035

申请日：2021-08-06

Applicant: UOP LLC

Inventor： Francis Stephen Lupton ,  Gregory J. Lewis ,  James M. Hodges ,  Paulina Jakubczak ,  Mimoza Sylejmani-Rekaliu ,  William Sheets

IPC: A61M1/36 ,  A61M1/28 ,  A61K38/06 ,  A61K31/198 ,  A61K31/194 ,  A61K31/10 ,  A61K31/35 ,  A61K31/44 ,  A61K31/341 ,  A61K31/4184 ,  A61K33/24 ,  B01D15/36 ,  B01D69/08 ,  B01D69/14

Abstract: A process for removing Pb2+, Hg2+ and other heavy metal toxins from bodily fluids is disclosed. The process involves treating a patient with a small molecule heavy metal chelator to remove these toxins from bones and soft tissue cells into the blood or other bodily fluid. Then an ion exchange composition is used to ion exchange the heavy metal toxins from bodily fluids either within the body or by treatment outside the body such as by dialysis. The ion exchange compositions may be supported by porous networks of biocompatible polymers such as carbohydrates or proteins.

公开(公告)号：US20170334746A1

公开(公告)日：2017-11-23

申请号：US15587784

申请日：2017-05-05

Applicant: UOP LLC

Inventor： Rashmi Patwardhan ,  Richard R. Willis ,  Jon E. Ball ,  Paulina Jakubczak ,  Mark G. Riley ,  William C. Schwerin ,  Roberto C. Flores

IPC: C02F1/42 ,  B01J41/10 ,  B01J41/02 ,  C02F101/22 ,  C02F101/10 ,  C02F101/14

Abstract: A composition, process and apparatuses for removal of one or more contaminant anions from water are provided. In an embodiment, the process includes treating the water with a composition comprising a layered metal hydroxy salt, wherein the layered metal hydroxy salt is a compound comprising (a) a metal (b) a framework hydroxide, and (c) a replaceable anion.

公开(公告)号：US09150436B2

公开(公告)日：2015-10-06

申请号：US13924971

申请日：2013-06-24

Applicant: UOP LLC

Inventor： Gregory J. Lewis ,  Paulina Jakubczak ,  Julio C. Marte

IPC: C02F1/42 ,  B01J20/02 ,  C02F1/28 ,  C02F101/20 ,  C02F103/10 ,  B01J39/10

CPC classification number: C02F1/42 ,  B01J20/02 ,  B01J39/10 ,  C02F1/281 ,  C02F2001/425 ,  C02F2101/20 ,  C02F2103/10

Abstract: A process for removing Hg2+ ions from a liquid stream is disclosed. The process involves contacting the liquid stream with specified ion-exchangers based on manganese oxides and metallomanganese oxides of the form An+wM3+xMn1-xO2 where A can be cations such as Na+ or Mg2+, M3+ can be metals such as Fe3+ or Co3+, and the TIC, the theoretical ion exchange capacity per framework metal atom, varies from 0.08 to 0.25. These ion-exchangers are particularly effective in removing Hg2+ ions from aqueous streams even in the presence of Mg2+ and Ca2+ ions.

Abstract translation: 公开了从液体流中除去Hg 2+离子的方法。 该方法包括使液体物流与基于氧化锰和形式为An + wM3 + xMn1-xO2的金属锰氧化物的特定离子交换剂接触，其中A可以是阳离子如Na +或Mg2 +，M3 +可以是金属如Fe3 +或Co3 +， TIC，每个骨架金属原子的理论离子交换能力从0.08变化到0.25。 即使在Mg2 +和Ca2 +离子存在下，这些离子交换剂也特别有效地从水流中除去Hg2 +离子。