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公开(公告)号：US06740616B2
公开(公告)日：2004-05-25
申请号：US09799593
申请日：2001-03-07
IPC分类号： B01J2906
CPC分类号： B01J37/04 , B01J29/005 , B01J29/06 , B01J29/40 , B01J29/42 , B01J29/7007 , B01J29/86 , B01J29/89 , C07C41/06 , C07C43/13
摘要： A process for preparing glycol monoethers from olefins comprises reacting the olefins with an epoxidizing reagent in the simultaneous presence of hydroxyl-containing organic compounds over a mixture of epoxidation catalysts and alkoxylation catalysts.
摘要翻译： 从烯烃制备乙二醇单醚的方法包括在环氧化催化剂和烷氧基化催化剂的混合物中同时存在含羟基的有机化合物的同时使烯烃与环氧化试剂反应。
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公开(公告)号：US06380119B1
公开(公告)日：2002-04-30
申请号：US09424854
申请日：2000-01-13
IPC分类号： B01J2990
CPC分类号： B01J29/90 , B01J38/20 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： A process for regenerating a zeolite catalyst comprises the following stages: (I) Heating a partially or completely deactivated catalyst to 250-600° C. in an atmosphere which contains less than 2% by volume of oxygen, (II) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from 0.1 to 4% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof, and (III) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from more than 4 to 100% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof.
摘要翻译： 再生沸石催化剂的方法包括以下步骤：（I）在含有少于2体积％氧气的气氛中将部分或完全失活的催化剂加热至250-600℃，（II）将催化剂处理 250至800℃，优选350至600℃，含有0.1至4体积％的供氧物质或氧气或其两种或多种的混合物的气流和 （III）在250至800℃，优选350至600℃下处理催化剂，其中气流含有超过4至100体积％的供氧物质或氧气或 其两种或更多种的混合物。
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公开(公告)号：US06491861B1
公开(公告)日：2002-12-10
申请号：US09424857
申请日：1999-12-06
IPC分类号： B28B320
CPC分类号： B01J37/0018 , B01J29/04 , B01J29/89 , C04B38/08 , C04B2111/00129 , C07D301/12 , C04B35/01 , C04B38/0051 , C04B35/16 , C04B35/6325 , C04B2103/0093
摘要： A process for the production of a molding containing at least one zeolite, wherein the at least one zeolite contains a titanium-, zirconium-, chromium-, niobium-, iron- or vanadium-containing zeolite: (I) adding a mixture consisting of at least one alcohol selected from the group consisting of methanol, ethanol, propanol or butanol, and water to a mixture containing said zeolite or a mixture of two or more thereof, and (II) kneading, molding, drying and calcining the mixture from (I); wherein the molding is useful as a catalyst, particularly in epoxidation reactions.
摘要翻译： 一种制备含有至少一种沸石的模塑方法，其中所述至少一种沸石含有含钛，锆，铬，铌，铁或钒的沸石：（I）加入由 将选自甲醇，乙醇，丙醇或丁醇的至少一种醇和水混合到含有所述沸石或其两种或更多种的混合物的混合物中，和（II）将混合物从（ I）;其中模制物可用作催化剂，特别是在环氧化反应中。
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公开(公告)号：US06239315B1
公开(公告)日：2001-05-29
申请号：US09403590
申请日：1999-10-25
IPC分类号： C07C4311
CPC分类号： B01J37/04 , B01J29/005 , B01J29/06 , B01J29/40 , B01J29/42 , B01J29/7007 , B01J29/86 , B01J29/89 , C07C41/06 , C07C43/13
摘要： A process for preparing glycol monoethers from olefins comprises reacting the olefins with an epoxidizing reagent in the simultaneous presence of hydroxyl-containing organic compounds over a mixture of epoxidation catalysts and alkoxylation catalysts.
摘要翻译： 从烯烃制备乙二醇单醚的方法包括在环氧化催化剂和烷氧基化催化剂的混合物中同时存在含羟基的有机化合物的同时使烯烃与环氧化试剂反应。
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5.发明授权Method for oxidizing an organic compound containing at least one C-C double bond 有权氧化含有至少一个C-C双键的有机化合物的方法公开(公告)号：US06518441B2
公开(公告)日：2003-02-11
申请号：US09424847
申请日：1999-12-06
申请人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
发明人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
IPC分类号： C07D30112
CPC分类号： C07D301/19 , B01J29/90 , B01J38/14 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： A process for oxidizing an organic compound having at least one C—C double bond or a mixture of two or more thereof comprises the following steps: (I) preparing a hydroperoxide, (II) reacting an organic compound having at least one C—C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst, (III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and (IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).
摘要翻译： 氧化具有至少一个CC双键的有机化合物或其两种或多种的混合物的方法包括以下步骤：（I）制备氢过氧化物，（II）使具有至少一个CC双键的有机化合物或 在沸石催化剂存在下，在步骤（I）中制备的氢过氧化物的两种或更多种的混合物与再生步骤（II）中使用的至少部分失活的沸石催化剂的（III）反应，和（Ⅳ）进行步骤 （II）使用含有在步骤（III）中再生的催化剂的沸石催化剂。
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公开(公告)号：US06710002B2
公开(公告)日：2004-03-23
申请号：US10061282
申请日：2002-02-04
IPC分类号： B01L2990
CPC分类号： B01J29/90 , B01J38/20 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： A process for regenerating a zeolite catalyst comprises the following stages: (I) Heating a partially or completely deactivated catalyst to 250-600° C. in an atmosphere which contains less than 2% by volume of oxygen, (II) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from 0.1 to 4% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof, and (III) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from more than 4 to 100% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof.
摘要翻译： 再生沸石催化剂的方法包括以下步骤：（I）在含有少于2体积％氧气的气氛中将部分或完全失活的催化剂加热至250-600℃，（II）将催化剂处理 250至800℃，优选350至600℃，含有0.1至4体积％的供氧物质或氧气或其两种或多种的混合物的气流和 （III）在250至800℃，优选350至600℃下处理催化剂，其中气流含有超过4至100体积％的供氧物质或氧气或 其两种或更多种的混合物。
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7.发明授权Method for oxidizing an organic compound having at least one C-C double bond 失效氧化具有至少一个C-C双键的有机化合物的方法公开(公告)号：US06348607B1
公开(公告)日：2002-02-19
申请号：US09806514
申请日：2001-04-16
IPC分类号： C07D30108
CPC分类号： C07D301/10 , C07D301/08 , Y02P20/125
摘要： In a process for oxidizing an organic compound containing at least one C—C double bond, or a mixture of two or more thereof, which comprises the step (II) below: (II) reaction of the organic compound or the mixture of two or more thereof with a medium comprising molecular oxygen in the presence of a heterogeneous catalyst, the medium further comprises carbon monoxide (CO).
摘要翻译： 在含有至少一种CC双键的有机化合物或其两种或更多种的混合物的方法中，所述方法包括以下步骤（II）：（II）有机化合物或其两种或多种的混合物的反应 在非均相催化剂存在下，使用包含分子氧的介质，所述介质还包含一氧化碳（CO）。
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8.发明授权Gauze catalyst based on titanium or vanadium zeolites and inert gauze fabrics for accelerating oxidation reactions 失效基于钛或钒沸石和惰性纱布织物的纱布催化剂，用于加速氧化反应
公开(公告)号：US6106797A
公开(公告)日：2000-08-22
申请号：US117293
申请日：1998-08-26
申请人： Ulrich Muller , Franz Josef Brocker , Georg Heinrich Grosch , Hermann Putter , Michael Schulz , Norbert Rieber , Wolfgang Harder
发明人： Ulrich Muller , Franz Josef Brocker , Georg Heinrich Grosch , Hermann Putter , Michael Schulz , Norbert Rieber , Wolfgang Harder
IPC分类号： B01J29/04 , B01J29/89 , B01J35/04 , B01J35/06 , B01J37/02 , C01B15/029 , C01B21/14 , C07D301/12
CPC分类号： B01J29/04 , B01J29/89 , C01B15/029 , C01B21/1436 , C01B21/1454 , C07D301/12 , B01J35/04 , B01J37/0246
摘要： The present invention relates to a gauze catalyst based on titanium or vanadium zeolites and inert gauze fabrics which is suitable for accelerating oxidation reactions such as epoxidation of olefins, hydrogen peroxide production or hydroxylamine synthesis.
摘要翻译： PCT No.PCT / EP97 / 00804 Sec。 371日期：1998年8月26日 102（e）日期1998年8月26日PCT 1997年2月20日PCT PCT。 出版物WO97 / 31711 日期1997年9月4日本发明涉及一种基于钛或钒沸石和惰性纱布织物的纱布催化剂，其适用于加速氧化反应，例如烯烃的环氧化，过氧化氢生产或羟胺合成。
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9.发明授权Oxidation catalyst and process for the production of epoxides from olefines, hydrogen and oxygen using said oxidation catalyst 有权氧化催化剂和使用所述氧化催化剂从烯烃，氢气和氧气生产环氧化物的方法
公开(公告)号：US6008389A
公开(公告)日：1999-12-28
申请号：US147383
申请日：1998-12-14
IPC分类号： C07D301/06 , B01J29/04 , B01J29/89 , C07D301/04 , C07D301/10 , C07D303/04 , B01J21/16 , B01J23/52 , B01J23/66
CPC分类号： B01J29/04 , B01J29/89 , C07D301/04
摘要： An oxidation catalyst based on titanium silicalites or vanadium silicalites having a zeolite structure and containing from 0.01 to 30% by weight of one or more noble metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver has been molded by a compacting shaping process.This oxidation catalyst is used for the preparation of epoxides, in particular propylene oxide, from olefins, hydrogen and oxygen.
摘要翻译： PCT No.PCT / EP97 / 02821 Sec。 371 1998年12月14日第 102（e）日期1998年12月14日PCT提交1997年5月30日PCT公布。 出版物WO97 / 47386 日期1997年12月18日具有沸石结构的钛硅沸石或钒硅沸石的氧化催化剂，含有0.01〜30重量％的选自钌，铑，钯，锇，铱的一种或多种贵金属， 铂，铼，金和银已经通过压实成型工艺成型。 该氧化催化剂用于从烯烃，氢气和氧气制备环氧化物，特别是环氧丙烷。
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公开(公告)号：US06551546B1
公开(公告)日：2003-04-22
申请号：US09646902
申请日：2000-10-10
IPC分类号： B28B100
CPC分类号： C04B14/047 , B01J29/04 , B01J29/06 , B01J29/89 , B01J37/0009 , B01J37/0018 , B01J37/0045 , B01J37/033 , B01J2229/42 , C04B28/00 , C04B28/24 , C04B38/08 , C07D301/12 , C04B24/32 , C04B38/0051 , C04B40/0071 , C04B14/066
摘要： A process for producing a shaped body comprising at least one porous oxidic material and at least one metal oxide comprises the following step (i): (i) mixing the porous oxidic material or materials with at least one metal oxide sol which has a low content of alkali metal and alkaline earth metal ions and/or at least one metal oxide which has a low content of alkali metal and alkaline earth metal ions.
摘要翻译： 一种生产包含至少一种多孔氧化物材料和至少一种金属氧化物的成形体的方法包括以下步骤（i）：（i）将多孔氧化物材料与至少一种具有低含量的金属氧化物溶胶混合 的碱金属和碱土金属离子和/或至少一种具有低碱金属和碱土金属离子含量的金属氧化物。
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