利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

7 条记录 (耗时 0.027 秒)

    Polymerizable polyol (allyl carbonate) compositions
    1.
    发明授权
    Polymerizable polyol (allyl carbonate) compositions 有权
    可聚合多元醇（碳酸烯丙酯）组合物

    公开(公告)号：US06423803B1

    公开(公告)日：2002-07-23

    申请号：US09461847

    申请日：1999-12-15

    申请人： Vidhu J. Nagpal ,  Charles R. Wiedrich

    发明人： Vidhu J. Nagpal ,  Charles R. Wiedrich

    IPC分类号： C08F1824

    CPC分类号： C08F283/06 ,  C08F290/06 ,  C08L51/003 ,  C08L51/08

    摘要： A polymerizable composition is described, which composition comprises a polyol(allyl carbonate) monomer, e.g., diethylene glycol bis(allyl carbonate) monomer, and an additive represented by the general formula, R2—O&Parenopenst;R3O&Parenclosest;x&Parenopenst;R4O&Parenclosest;y&Parenopenst;R5O&Parenclosest;zR6 wherein R2 and R6 are each selected independently from hydrogen, C1-C20 linear or branched alkyl, cycloalkyl having from 5 to 7 carbon atoms in the cyclic ring, aryl, C2-C20 linear or branched alkanoyl, cycloalkanoyl having from 5 to 7 carbon atoms in the cyclic ring and aroyl, R2 and R6 each being free of radically polymerizable ethylenically unsaturated groups; R3O and R5O are the same or different; R4O is different than each of R3O and R5O; R3O, R4O and R5O are each independently a divalent residue of an epoxide; x and z are each independently a number from 0 to 200, provided that the sum of x and z is greater than zero; and y is a number from 3 to 200. The additive is present in the composition of the present invention in an amount at least sufficient such that a polymerizate of the composition is substantially free of tinting defects, such as ferns and moons.

    摘要翻译： 描述了一种可聚合组合物，该组合物包含多元醇（碳酸烯丙酯）单体，例如二甘醇双（烯丙基碳酸酯）单体和由通式表示的添加剂，其中R2和R6各自独立地选自氢，C1- C20环直链或支链烷基，环中具有5-7个碳原子的环烷基，芳基，C2-C20直链或支链烷酰基，在环中具有5-7个碳原子的环烷酰基和芳酰基，R2和R6各自为 的可自由基聚合的烯属不饱和基团; R3O和R5O相同或不同; R4O不同于R3O和R5O; R3O，R4O和R5O各自独立地为环氧化物的二价残基; x和z各自独立地为0至200的数，条件是x和z之和大于零; y是3至200的数。该添加剂以至少足够的量存在于本发明的组合物中，使得组合物的聚合物基本上不含着色缺陷，例如蕨类植物和卫星。

    Polymerizable polyol (allyl carbonate) compositions
    2.
    发明授权
    Polymerizable polyol (allyl carbonate) compositions 有权
    可聚合多元醇（碳酸烯丙酯）组合物

    公开(公告)号：US6077921A

    公开(公告)日：2000-06-20

    申请号：US206144

    申请日：1998-12-07

    申请人： Vidhu J. Nagpal ,  Charles R. Wiedrich

    发明人： Vidhu J. Nagpal ,  Charles R. Wiedrich

    IPC分类号： C08F18/24

    CPC分类号： C08F18/24

    摘要： Described is a polymerizable organic composition comprising a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), and an additive represented by the general formulaR.sub.2 --O--(R.sub.3 O).sub.m --(CH.sub.2 CH.sub.2 O).sub.n-1 --CH.sub.2 CH.sub.2 --Xwherein R.sub.2 is a monovalent organic radical having a terminal ethylenically unsaturated group, e.g., allyl, R.sub.3 O is a divalent radical derived from an epoxide other than ethylene oxide, e.g., butylene oxide, m is a number from 0 to 100, n is a number between 3 and 100, and X is selected from halide, hydroxyl, quaternary ammonium groups, the acid groups acetic acid, sulfonic acid, sulfuric acid, isethionic acid and phosphoric acid, salts of said acid groups, alkoxy groups and carboxylic acid ester groups. The additive is present in the composition in an amount at least sufficient such that a polymerizate, e.g., a plus lens, obtained from said composition is substantially free of tinting defects, e.g., ferns and/or moons.

    摘要翻译： 描述了包含多元醇（碳酸烯丙酯），例如二甘醇双（烯丙基碳酸酯）和由通式R 2 O-O-（R 3 O）m - （CH 2 CH 2 O）n-1-CH 2 CH 2-X所表示的添加剂的可聚合有机组合物，其中 R2是具有末端烯属不饱和基团的单价有机基团，例如烯丙基，R3O是衍生自环氧乙烷以外的环氧化物的二价基团，例如环氧丁烷，m是0至100的数，n是 3和100，X选自卤化物，羟基，季铵基，酸基团乙酸，磺酸，硫酸，羟乙磺酸和磷酸，所述酸基，烷氧基和羧酸酯基的盐。 添加剂以至少足够的量存在于组合物中，使得由所述组合物获得的聚合物，例如正透镜基本上不含着色缺陷，例如蕨类植物和/或卫星。

    Polymerizable polyol (allyl carbonate) compositions
    3.
    发明授权
    Polymerizable polyol (allyl carbonate) compositions 有权
    可聚合多元醇（碳酸烯丙酯）组合物

    公开(公告)号：US07214754B2

    公开(公告)日：2007-05-08

    申请号：US10336118

    申请日：2003-01-03

    申请人： Vidhu J. Nagpal

    发明人： Vidhu J. Nagpal

    IPC分类号： C08F26/02 ,  C08F226/02 ,  G02B1/04 ,  G02B1/10

    CPC分类号： C08F218/00 ,  C08F18/16 ,  C08F290/06 ,  C08F290/061 ,  C08F290/067 ,  C08L71/02 ,  G02B1/041 ,  Y10S348/902 ,  C08L31/00 ,  C08L2666/04

    摘要： A polymerizable composition is described, which composition comprises a major amount of a polyol(allyl carbonate) monomer, e.g., diethylene glycol bis(allyl carbonate) monomer, and a minor amount of a radically polymerizable second monomer represented by the general formula, wherein R2 is a polyvalent linking group that is free of urethane linkages, e.g., R2 may be a residue of a polyisocyanate, such as isophorone diisocyanate; R3 is a residue of a material having a single hydroxy group and at least one allyl group, R3 being free of urethane linkages, e.g., R3 may be a residue of a poly(alkylene glycol) allyl ether, such as poly(1,2-propylene glycol) allyl ether; and j is a number from 2 to 4. The second monomer may also be present in the composition in an amount at least sufficient such that a polymerizate, e.g., a plus ophthalmic lens, obtained from the composition is substantially free of tinting defects, e.g., ferns and/or moons.

    摘要翻译： 描述了一种可聚合组合物，该组合物包含主要量的多元醇（碳酸烯丙酯）单体，例如二甘醇双（烯丙基碳酸酯）单体和少量由通式表示的可自由基聚合的第二单体，其中R 2是不含氨基甲酸酯键的多价连接基团，例如R 2可以是多异氰酸酯的残基，例如异佛尔酮二异氰酸酯; R 3是具有单个羟基和至少一个烯丙基的物质的残基，R 3不含氨基甲酸酯键，例如R 3， 可以是聚（亚烷基二醇）烯丙基醚的残基，例如聚（1,2-丙二醇）烯丙基醚; 并且j是2至4的数。第二单体还可以以至少足够的量存在于组合物中，使得由组合物获得的聚合物，例如加眼镜片基本上不含着色缺陷，例如 ，蕨类植物和/或卫星。

    TINTED ARTICLE HAVING A HIGH REFRACTIVE INDEX
    4.
    发明申请
    TINTED ARTICLE HAVING A HIGH REFRACTIVE INDEX 审中-公开
    具有高折射率的特定文章

    公开(公告)号：US20090081463A1

    公开(公告)日：2009-03-26

    申请号：US11859017

    申请日：2007-09-21

    申请人： Vidhu J. Nagpal ,  Robert D. Herold

    发明人： Vidhu J. Nagpal ,  Robert D. Herold

    IPC分类号： B32B33/00 ,  B05D1/36

    CPC分类号： C08G18/10 ,  C08G18/3225 ,  C08G18/3876 ,  C08G18/775 ,  C08J7/04 ,  C08J2375/04 ,  G02B1/10 ,  Y10T428/31

    摘要： Disclosed is a tinted article formed from a substrate having a refractive index of at least 1.57 comprising at least partially polymerized sulfur-containing polyurethane material and/or at least partially polymerized sulfur-containing polyurethaneurea material; an intermediate coating applied to at least a portion of the substrate; a tintable hardcoat applied to at least a portion of the intermediate coating; and tint applied to at least a portion of the tintable hardcoat. Methods for preparing the tinted articles also are provided.

    摘要翻译： 公开了一种由基材形成的着色制品，该基材的折射率至少为1.57，包括至少部分聚合的含硫聚氨酯材料和/或至少部分聚合的含硫聚氨酯脲材料; 施加到所述基材的至少一部分的中间涂层; 施加到中间涂层的至少一部分的可着色硬涂层; 并且着色应用于可着色硬涂层的至少一部分。 还提供了制备着色制品的方法。

    POLYUREAURETHANE COMPOSITION HAVING IMPROVED COLOR STABILITY
    5.
    发明申请
    POLYUREAURETHANE COMPOSITION HAVING IMPROVED COLOR STABILITY 审中-公开
    具有改善颜色稳定性的聚氨酯组合物

    公开(公告)号：US20080071016A1

    公开(公告)日：2008-03-20

    申请号：US11844588

    申请日：2007-08-24

    申请人： David J. Boettcher ,  William H. McDonald ,  Vidhu J. Nagpal ,  Daryl J. Robinson ,  Robert A. Smith

    发明人： David J. Boettcher ,  William H. McDonald ,  Vidhu J. Nagpal ,  Daryl J. Robinson ,  Robert A. Smith

    IPC分类号： C08L75/04 ,  C08J3/00

    CPC分类号： G02B1/04 ,  C08G18/10 ,  C08G18/4277 ,  C08G18/758 ,  C08K5/005 ,  C08K5/3475 ,  C08L75/04 ,  C08G18/3237

    摘要： The present invention provides a polyureaurethane composition comprising: a) the reaction product of: 1) a polyurethane prepolymer comprising a polyisocyanate and at least one OH-containing material; and 2) an amine-containing curing agent, wherein the equivalent ratio of the amine-containing curing agent of 2) to the polyurethane prepolymer of 1) is from 0.75 to 0.98; b) a hydroxyphenylbenzotriazole present in the polyureaurethane composition in an amount from 0.75 to 1.1 percent, based on the total weight of resin solids in the polyureaurethane composition; and c) a multifunctional hindered phenol type anti-oxidant present in an amount from 0.25 to 1.5 percent, based on the total weight of resin solids in the polyureaurethane composition wherein b) and c) are combined in amounts to provide the polyureaurethane composition with a Δ Yellowness Index of less than 1.85 in the 60/80 Accelerated Warehouse Aging Test.

    摘要翻译： 本发明提供一种聚脲氨酯组合物，其包含：a）反应产物：1）包含多异氰酸酯和至少一种含OH材料的聚氨酯预聚物; 和2）含胺固化剂，其中2）的胺类固化剂与1）的聚氨酯预聚物的当量比为0.75至0.98; b）基于聚脲氨酯组合物中树脂固体的总重量，在聚脲氨酯组合物中存在的羟基苯基苯并三唑的量为0.75-1.1％ 和c）基于聚脲氨酯组合物中树脂固体的总重量，0.25至1.5％的量的多官能受阻酚型抗氧化剂，其中b）和c）的用量合并得到聚脲氨酯组合物 在60/80加速仓库老化测试中，黄油指数小于1.85。